公开(公告)号：US08039575B2

公开(公告)日：2011-10-18

申请号：US12445739

申请日：2007-10-11

申请人： Toshio Isozaki ,  Kouji Satou

发明人： Toshio Isozaki ,  Kouji Satou

IPC分类号： C08G64/00 ,  C08G63/528

CPC分类号： C08L83/10 ,  B29C45/0001 ,  B29K2069/00 ,  B29K2483/00 ,  B29K2995/0016 ,  C08K7/14 ,  C08L69/00 ,  C08L83/04 ,  C08L83/00 ,  C08L2666/14

摘要： Provided are a polycarbonate resin composition containing a glass filler, which is excellent in transparency, strength, and heat resistance and provided with high flame retardancy even without using a flame retardant, and a polycarbonate resin molded article obtained by molding the resin composition. The flame-retardant polycarbonate resin composition contains a combination including (A) 55 to 95 mass % of an aromatic polycarbonate resin containing a polycarbonate-polyorganosiloxane copolymer and (B) 45 to 5 mass % of a glass filler having a refractive index smaller or larger than a refractive index of the aromatic polycarbonate resin by 0.002 or less, and (C) 0.05 to 20.0 parts by mass of a silicone compound having a reactive functional group with respect to 100 parts by mass of the combination. The polycarbonate resin molded article has a thickness of 0.3 to 10 mm which is obtained by molding the composition.

摘要翻译： 提供一种含有玻璃填料的聚碳酸酯树脂组合物，其透明性，强度和耐热性优异，即使不使用阻燃剂也具有高阻燃性，并且通过模塑树脂组合物而获得的聚碳酸酯树脂模塑制品。 阻燃性聚碳酸酯树脂组合物含有（A）55〜95质量％的含有聚碳酸酯 - 聚有机硅氧烷共聚物的芳香族聚碳酸酯树脂和（B）45〜5质量％的折射率越小越好的玻璃填料的组合 相对于100质量份的组合，芳族聚碳酸酯树脂的折射率为0.002以下，（C）0.05〜20.0质量份具有反应性官能团的硅氧烷化合物。 聚碳酸酯树脂成形体的厚度为0.3〜10mm，通过成型而得到。

公开(公告)号：US20100286321A1

公开(公告)日：2010-11-11

申请号：US12747688

申请日：2008-12-05

申请人： Toshio Isozaki ,  Kouji Satou ,  Takayoshi Tanaka

发明人： Toshio Isozaki ,  Kouji Satou ,  Takayoshi Tanaka

IPC分类号： C08K3/30 ,  C08L83/04 ,  C08L69/00 ,  C08K3/34 ,  C08K3/08 ,  C08K3/22 ,  B29C45/00

CPC分类号： C08L83/10 ,  B29C45/0013 ,  B29K2069/00 ,  B29K2105/0026 ,  B29K2995/0026 ,  C08K3/22 ,  C08K3/346 ,  C08K7/14 ,  C08K9/02 ,  C08L69/00 ,  C08L83/04 ,  C08L83/00

摘要： Provided are: a polycarbonate resin composition which is excellent in mechanical properties, physical properties, optical properties, and flame retardancy, including: a composition formed of an aromatic polycarbonate resin (A) and a glass filler (B) having a difference in refractive index of 0.002 or less from the aromatic polycarbonate resin; glossy particles (C-1) having an average particle diameter of 10 μm or more and less than 50 μm; glossy particles (C-2) having an average particle diameter of 50 to 300 μm; and a silicone compound (D) having a reactive functional group; a polycarbonate resin molded article obtained by molding the polycarbonate resin composition; and a method of producing a polycarbonate resin molded article, involving subjecting the polycarbonate resin composition to injection molding at a mold temperature of 120° C. or higher.

摘要翻译： 提供：具有优异的机械性能，物理性能，光学性质和阻燃性的聚碳酸酯树脂组合物，包括：由芳族聚碳酸酯树脂（A）和折射率差的玻璃填料（B）组成的组合物 为0.002以下; 平均粒径为10μm以上且小于50μm的光泽粒子（C-1） 平均粒径为50〜300μm的光泽粒子（C-2） 和具有反应性官能团的硅氧烷化合物（D） 通过将聚碳酸酯树脂组合物成型得到的聚碳酸酯树脂成形品; 以及聚碳酸酯树脂成型体的制造方法，其特征在于，在120℃以上的模具温度下进行聚碳酸酯树脂组合物的注射成型。

公开(公告)号：US20100267880A1

公开(公告)日：2010-10-21

申请号：US12747704

申请日：2008-12-04

申请人： Toshio Isozaki ,  Kouji Satou ,  Takayoshi Tanaka

发明人： Toshio Isozaki ,  Kouji Satou ,  Takayoshi Tanaka

IPC分类号： C08K3/40 ,  C08K3/30 ,  C08K3/22 ,  B29C45/00 ,  C08K3/08

CPC分类号： C08L69/00 ,  C08K3/40 ,  C08K5/098 ,  C08K7/14 ,  C08K9/02 ,  C08L83/04 ,  C08L83/00

摘要： Provided is a polycarbonate resin composition which contains specific amounts of a glass filler and glossy particles, which can be molded into an article in which no difference in lightness is visually observed between the left side and the right side of the weld line, and which has excellent optical properties and flame retardancy. The polycarbonate resin composition contains: a composition formed of an aromatic polycarbonate resin (A) and a glass filler (B) having a difference in refractive index 0.002 or less from the aromatic polycarbonate resin of; glossy particles (C-1) having an average particle diameter of 10 μm or more and less than 50 μm; glossy particles (C-2) having an average particle diameter of 50 to 300 μm; a silicone compound (D) having a reactive functional group; and an organic alkali metal salt compound and/or an organic alkali earth metal salt compound (E). Also provided are a polycarbonate resin molded article produced by molding the resin composition, and a method of producing a polycarbonate resin molded article, which is characterized by involving subjecting the resin composition to an injection molding at a mold temperature of 120° C. or higher.

摘要翻译： 提供一种聚碳酸酯树脂组合物，其含有特定量的玻璃填料和光泽性颗粒，其可以模制成在焊接线的左侧和右侧之间目视观察到亮度不同的制品，并且具有 优异的光学性能和阻燃性。 聚碳酸酯树脂组合物含有：由芳香族聚碳酸酯树脂（A）和玻璃填料（B）组成的组合物，其与芳香族聚碳酸酯树脂的折射率差为0.002以下。 平均粒径为10μm以上且小于50μm的光泽粒子（C-1） 平均粒径为50〜300μm的光泽粒子（C-2） 具有反应性官能团的硅氧烷化合物（D） 和有机碱金属盐化合物和/或有机碱土金属盐化合物（E）。 还提供了通过模塑树脂组合物制备的聚碳酸酯树脂模制品，以及聚碳酸酯树脂模塑制品的制备方法，其特征在于包括在120℃或更高的模具温度下对树脂组合物进行注塑 。

公开(公告)号：US20100256279A1

公开(公告)日：2010-10-07

申请号：US12739548

申请日：2008-10-07

申请人： Toshio Isozaki ,  Kouji Satou

发明人： Toshio Isozaki ,  Kouji Satou

IPC分类号： C08K5/00 ,  B28B1/24

CPC分类号： C08J5/00 ,  B29C45/0001 ,  B29K2069/00 ,  C08J2369/00 ,  C08K3/40 ,  C08K5/0041 ,  C08K5/098 ,  C08K5/5425 ,  C08K7/14 ,  C08L69/00 ,  C08L83/04 ,  C08L83/00

摘要： Disclosed are a polycarbonate resin composition comprising, with respect to 100 parts by mass of a composition composed of (A) 60 to 90 parts by mass of an aromatic polycarbonate resin and (B) 40 to 10 parts by mass of a glass filler having a refractive index smaller or larger than a refractive index of the aromatic polycarbonate resin by 0.002 or less, (C) 0.05 to 2.0 parts by mass of a silicone compound having a reactive functional group, (D) 0.03 to 1.0 part by mass of an organic alkali metal salt compound and/or an organic alkaline earth metal salt compound, (E) 0.05 to 7.0 parts by mass of glossy particles, and (F) 0.0001 to 3 parts by mass of a colorant, a polycarbonate resin molded article obtained by molding the composition, and a method for producing the molded article by molding the polycarbonate resin composition. Provided are a polycarbonate resin composition containing a glass filler, which is excellent in transparency, strength, and heat resistance, and provided with high flame retardancy, a polycarbonate resin molded article obtained by molding the resin composition, and a method of producing the molded article.

摘要翻译： 公开了一种聚碳酸酯树脂组合物，其包含相对于100质量份由（A）60〜90质量份的芳香族聚碳酸酯树脂构成的组合物和（B）40〜10质量份的具有 折射率小于或大于芳族聚碳酸酯树脂的折射率为0.002以下，（C）0.05〜2.0质量份具有反应性官能团的硅氧烷化合物，（D）0.03〜1.0质量份有机 碱金属盐化合物和/或有机碱土金属盐化合物，（E）0.05〜7.0质量份光泽性颗粒，（F）0.0001〜3质量份着色剂，通过成型得到的聚碳酸酯树脂成型体 该组合物和通过模制聚碳酸酯树脂组合物来制造模制品的方法。 提供一种含有玻璃填料的聚碳酸酯树脂组合物，其透明性，强度和耐热性优异，并且具有高阻燃性，通过模塑该树脂组合物而获得的聚碳酸酯树脂模制品，以及制备该模制品的方法 。

公开(公告)号：US06455659B1

公开(公告)日：2002-09-24

申请号：US09462103

申请日：2000-01-13

申请人： Itaru Kuramoto ,  Yutaka Obata ,  Tsuyoshi Ota ,  Toshio Isozaki

发明人： Itaru Kuramoto ,  Yutaka Obata ,  Tsuyoshi Ota ,  Toshio Isozaki

IPC分类号： C08F11006

CPC分类号： C08F10/06 ,  C08F110/06 ,  Y10S526/943 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/26

摘要： Provided is a crystalline polypropylene of which the 0° C. soluble content, &agr; (% by weight), as measured through programmed-temperature fractionation and the molecular weight, Mp, for the peak in the molecular weight distribution curve as measured through gel permeation chromatography satisfy the relationship of the following formula (1): &agr;≦−0.42×ln(Mp)+7.3  (1), and the melting point, Tm (° C.), as measured through differential scanning calorimetry and Mp satisfy the relationship of the following formula (2): Tm>1.85×ln(Mp)+144.5  (2). Also provided are moldings and films of the crystalline polypropylene. The crystalline polypropylene and its moldings and films are highly rigid and have good heat resistance and good scratch resistance.

摘要翻译： 提供了一种结晶聚丙烯，其通过程序温度分馏测定的0℃可溶性成分α（重量％），分子量分布曲线中通过凝胶渗透色谱法测定的分子量分子量Mp 满足以下公式（1）的关系：通过差示扫描量热法测定的熔点Tm（℃）和Mp满足下式（2）的关系：还提供了结晶 聚丙烯。 结晶聚丙烯及其模制品和膜具有高刚性并具有良好的耐热性和良好的抗划伤性

公开(公告)号：US06204215B1

公开(公告)日：2001-03-20

申请号：US09200851

申请日：1998-11-30

申请人： Yasunori Kadoi ,  Tsuyoshi Ota ,  Toshio Isozaki ,  Kiyokazu Katayama ,  Takanori Sadashima

发明人： Yasunori Kadoi ,  Tsuyoshi Ota ,  Toshio Isozaki ,  Kiyokazu Katayama ,  Takanori Sadashima

IPC分类号： B01J03104

CPC分类号： C08F10/00 ,  C08F4/651

摘要： Provided are a solid catalyst component for olefin polymerization and a catalyst comprising the component for olefin polymerization, in which the electron donor is free from the problem of lacking in safety and sanitation, and is inexpensive and easy to produce, and which exhibit high activity in producing olefin polymers with high stereospecificity, and also a method for producing olefin polymers in the presence of the catalyst. The solid catalyst component comprises titanium, magnesium and an electron donor compound of formula (I): wherein R1 and R2 each represent a linear or branched hydrocarbon residue having from 1 to 20 carbon atoms; R3 represents an alicyclic hydrocarbon residue having from 3 to 20 carbon atoms; and n represents an integer of from 1 to 10. The solid catalyst component is combined with an organic aluminium compound to prepare a catalyst, which is used in producing olefin polymers.

摘要翻译： 提供了用于烯烃聚合的固体催化剂组分和包含用于烯烃聚合的组分的催化剂，其中电子给体没有安全和卫生缺乏的问题，并且便宜并且易于生产，并且其表现出高的活性 制备具有高立体定向性的烯烃聚合物，以及在催化剂存在下生产烯烃聚合物的方法。 固体催化剂组分包括钛，镁和式（I）的电子给体化合物：其中R 1和R 2各自表示具有1至20个碳原子的直链或支链烃残基; R3表示具有3至20个碳原子的脂环族烃残基; n表示1〜10的整数。将固体催化剂成分与有机铝化合物结合，制备用于制造烯烃聚合物的催化剂。

公开(公告)号：US08338513B2

公开(公告)日：2012-12-25

申请号：US12739548

申请日：2008-10-07

申请人： Toshio Isozaki ,  Kouji Satou

发明人： Toshio Isozaki ,  Kouji Satou

IPC分类号： C08K5/42 ,  C08K3/40

CPC分类号： C08J5/00 ,  B29C45/0001 ,  B29K2069/00 ,  C08J2369/00 ,  C08K3/40 ,  C08K5/0041 ,  C08K5/098 ,  C08K5/5425 ,  C08K7/14 ,  C08L69/00 ,  C08L83/04 ,  C08L83/00

摘要： Disclosed are a polycarbonate resin composition comprising, with respect to 100 parts by mass of a composition composed of (A) 60 to 90 parts by mass of an aromatic polycarbonate resin and (B) 40 to 10 parts by mass of a glass filler having a refractive index smaller or larger than a refractive index of the aromatic polycarbonate resin by 0.002 or less, (C) 0.05 to 2.0 parts by mass of a silicone compound having a reactive functional group, (D) 0.03 to 1.0 part by mass of an organic alkali metal salt compound and/or an organic alkaline earth metal salt compound, (E) 0.05 to 7.0 parts by mass of glossy particles, and (F) 0.0001 to 3 parts by mass of a colorant, a polycarbonate resin molded article obtained by molding the composition, and a method for producing the molded article by molding the polycarbonate resin composition. Provided are a polycarbonate resin composition containing a glass filler, which is excellent in transparency, strength, and heat resistance, and provided with high flame retardancy, a polycarbonate resin molded article obtained by molding the resin composition, and a method of producing the molded article.

摘要翻译： 公开了一种聚碳酸酯树脂组合物，其包含相对于100质量份由（A）60〜90质量份的芳香族聚碳酸酯树脂构成的组合物和（B）40〜10质量份的具有 折射率小于或大于芳族聚碳酸酯树脂的折射率为0.002以下，（C）0.05〜2.0质量份具有反应性官能团的硅氧烷化合物，（D）0.03〜1.0质量份有机 碱金属盐化合物和/或有机碱土金属盐化合物，（E）0.05〜7.0质量份光泽性颗粒，（F）0.0001〜3质量份着色剂，通过成型得到的聚碳酸酯树脂成型体 该组合物和通过模制聚碳酸酯树脂组合物来制造模制品的方法。 提供一种含有玻璃填料的聚碳酸酯树脂组合物，其透明性，强度和耐热性优异，并且具有高阻燃性，通过模塑该树脂组合物而获得的聚碳酸酯树脂模制品，以及制备该模制品的方法 。

公开(公告)号：US08143330B2

公开(公告)日：2012-03-27

申请号：US12747704

申请日：2008-12-04

申请人： Toshio Isozaki ,  Kouji Satou ,  Takayoshi Tanaka

发明人： Toshio Isozaki ,  Kouji Satou ,  Takayoshi Tanaka

IPC分类号： C08K9/02

CPC分类号： C08L69/00 ,  C08K3/40 ,  C08K5/098 ,  C08K7/14 ,  C08K9/02 ,  C08L83/04 ,  C08L83/00

摘要： Provided is a polycarbonate resin composition which contains specific amounts of a glass filler and glossy particles, which can be molded into an article in which no difference in lightness is visually observed between the left side and the right side of the weld line, and which has excellent optical properties and flame retardancy. The polycarbonate resin composition contains: a composition formed of an aromatic polycarbonate resin (A) and a glass filler (B) having a difference in refractive index 0.002 or less from the aromatic polycarbonate resin of; glossy particles (C-1) having an average particle diameter of 10 μm or more and less than 50 μm; glossy particles (C-2) having an average particle diameter of 50 to 300 μm; a silicone compound (D) having a reactive functional group; and an organic alkali metal salt compound and/or an organic alkali earth metal salt compound (E). Also provided are a polycarbonate resin molded article produced by molding the resin composition, and a method of producing a polycarbonate resin molded article, which is characterized by involving subjecting the resin composition to an injection molding at a mold temperature of 120° C. or higher.

摘要翻译： 提供一种聚碳酸酯树脂组合物，其含有特定量的玻璃填料和光泽性颗粒，其可以模制成在焊接线的左侧和右侧之间目视观察到亮度不同的制品，并且具有 优异的光学性能和阻燃性。 聚碳酸酯树脂组合物含有：由芳香族聚碳酸酯树脂（A）和玻璃填料（B）组成的组合物，其与芳香族聚碳酸酯树脂的折射率差为0.002以下。 平均粒径为10μm以上且小于50μm的光泽粒子（C-1） 平均粒径为50〜300μm的光泽粒子（C-2） 具有反应性官能团的硅氧烷化合物（D） 和有机碱金属盐化合物和/或有机碱土金属盐化合物（E）。 还提供了通过模塑树脂组合物制备的聚碳酸酯树脂模制品，以及聚碳酸酯树脂模塑制品的制备方法，其特征在于包括在120℃或更高的模具温度下对树脂组合物进行注塑 。

公开(公告)号：US20110028634A1

公开(公告)日：2011-02-03

申请号：US12745170

申请日：2008-10-31

申请人： Toshio Isozaki ,  Kouji Satou ,  Takayoshi Tanaka

发明人： Toshio Isozaki ,  Kouji Satou ,  Takayoshi Tanaka

IPC分类号： C08K3/40 ,  B29C45/00

CPC分类号： B29C45/0013 ,  B29C45/0005 ,  C08K3/40 ,  C08K5/0041 ,  C08K5/1345 ,  C08K5/526 ,  C08K5/5425 ,  C08K7/14 ,  C08K7/20 ,  C08L69/00 ,  C08L83/10 ,  C08L83/00 ,  C08L2666/18

摘要： Provided are a polycarbonate resin composition which includes a specific amount of a glass filler and a specific amount of a glossy particle and is excellent in optical characteristics and flame retardancy, and in which difference in brightness between a left half and a right half of a weld line of a molded product is not visually observed, a polycarbonate resin molded article, and a method for producing the polycarbonate resin molded article. The polycarbonate resin composition includes, with respect to 100 parts by mass of a composition composed of (A) more than 90 parts by mass and 99 parts by mass or less of an aromatic polycarbonate resin containing 10 to 40 parts by mass of a polycarbonate-polyorganosiloxane copolymerized resin and (B) 1 part by mass or more and less than 10 parts by mass of a glass filler having a difference in a refractive index of 0.002 or less from the aromatic polycarbonate resin, (C) 0.01 to 3.0 parts by mass of a glossy particle and (D) 0.05 to 2.0 parts by mass of a silicone compound having a reactive functional group.

摘要翻译： 提供一种聚碳酸酯树脂组合物，其包含特定量的玻璃填料和特定量的光泽颗粒，并且具有优异的光学特性和阻燃性，并且其中焊接的左半部分和右半部分之间的亮度差 未观察到模制品的生产线，聚碳酸酯树脂模制品，以及聚碳酸酯树脂模塑制品的制造方法。 聚碳酸酯树脂组合物中，相对于100质量份由（A）大于90质量份组成的组合物和99质量份以下的含有10〜40质量份聚碳酸酯类的芳香族聚碳酸酯树脂， 聚有机硅氧烷共聚树脂和（B）1质量份以上且小于10质量份的来自芳族聚碳酸酯树脂的折射率为0.002以下的玻璃填料，（C）0.01〜3.0质量份 的（D）0.05〜2.0质量份具有反应性官能团的硅氧烷化合物。

公开(公告)号：US20090286892A1

公开(公告)日：2009-11-19

申请号：US12299335

申请日：2007-05-10

申请人： Toshio Isozaki

发明人： Toshio Isozaki

IPC分类号： C08J11/04

CPC分类号： C08J11/06 ,  B29B17/00 ,  B29B17/02 ,  B29B2017/0203 ,  B29B2017/0279 ,  B29B2017/0282 ,  B29B2017/0296 ,  B29K2069/00 ,  B29L2017/005 ,  C08J2369/00 ,  G11B7/2534 ,  G11B7/26 ,  Y02W30/62 ,  Y02W30/622 ,  Y02W30/701 ,  Y10T428/31504 ,  Y10T428/31507

摘要： A method for manufacturing a recycled polycarbonate raw material for a flame retardant resin composition from discarded and/or recovered optical discs using a polycarbonate resin as a substrate material, and includes (a) a step to identify if 2,2-bis(4-hydroxyphenyl)propane as a divalent phenol of the polycarbonate resin raw material is polymerized as the sole raw material in the polycarbonate resin as the substrate material of the discarded and/or recovered optical discs and (b) a step to remove impurities by a chemical treatment by separating only the discarded and/or recovered optical discs, wherein the polycarbonate resin is identified as polymerized by using 2,2-bis(4-hydroxyphenyl)propane as the sole raw material. Accordingly, used optical discs using a PC resin as a substrate material and discarded optical discs as substandard articles in a manufacturing step can be reused as a raw material for a flame retardant polycarbonate resin composition by treating with a method at low cost and a low environmental load.

摘要翻译： 一种使用聚碳酸酯树脂作为基材从废弃和/或回收的光盘制造用于阻燃树脂组合物的再循环聚碳酸酯原料的方法，包括（a）鉴定2,2-双（4- 羟基苯基）丙烷作为聚碳酸酯树脂原料的二价苯酚作为唯一的原料聚合在作为废弃和/或回收光盘的基材的聚碳酸酯树脂中，（b）通过化学处理除去杂质的步骤 通过仅分离丢弃和/或回收的光盘，其中通过使用2,2-双（4-羟基苯基）丙烷作为唯一原料，将聚碳酸酯树脂鉴定为聚合。 因此，在制造工序中使用PC树脂作为基板材料和废弃光盘的使用的光盘可以通过以低成本和低环境的方法进行处理而被重新用作阻燃聚碳酸酯树脂组合物的原料 加载。