摘要:
A lubrication composition providing excellent anti-wear protection for corrosion-resistant materials which comprises a major amount of a synthetic ester base oil, and a minor amount of a molybdenum compound and an anti-wear additive selected from the group consisting of 1,3,4-thiadiazole derivative as an anti-wear additive, the reaction products of 2,5-dimercapto-1,3,4-thiadiazole dimers and poly(ether)glycols, and 2,5-dimercapto-1,3,4-thiadiazole monomer and mixtures thereof. Also described is a method for imparting anti-wear properties to a corrosion resistant material, comprising using the lubricating composition of the invention.
摘要:
An additive for imparting antiwear properties to a lubricant composition is based on a combination of (1) an organo borate ester composition and (2) one or more sulfur- or phosphorus-containing compounds or a non-sulfur molybdenum compound. The sulfur- or phosphorus-containing compounds are dithiocarbamate, bisdithiocarbamate, 1,3,4-diathiazole, phosphorodithioate, phosphorodithioate esters, and the molybdenum compound is prepared by reacting (a) about 1.0 mole of fatty oil having 12 or more carbon atoms, (b) about 1.0 to 2.5 moles diethanolamine and (c) a molybdenum source.
摘要:
Lubricating compositions containing a major amount of a base oil and an effective amount of an additive component having at least one compound of formula (I): where R is one of the following radicals, methyl, ethyl, n-propyl, i-propyl or a combination thereof, and n=0-8. In a preferred embodiment, R is a methyl radical and n=2-3. The lubricating compositions provide improved lubricating performance, particularly by inhibiting oxidation and improving thermal stability.
摘要:
Disclosed are synergistic antioxidant compositions composed of (1) amine salts of alkyl phosphates and (2) ethylenediamine, ammonium or metal salts of alkylarylsulfonates.The antioxidant compositions are useful for formulating zinc-free antiwear hydraulic fluids and gear lubricating oils in conjunction with thiophosphate type antiwear agents, corrosion and rust inhibitors.
摘要:
A novel method is disclosed for preparation of bismuth dithiocarbamates by an exchange reaction between a bismuth carboxylate and a metal dithiocarbamate. The metal dithiocarbamate can be added to the reaction or prepared in situ by reacting a secondary amine and carbon disulfide in the presence of metal oxide, metal hydroxide or a tertiary amine. The reaction products are useful as extreme pressure additives when incorporated in lubricants.
摘要:
A novel method is disclosed for preparation of bismuth dithiocarbamates by an exchange reaction between a bismuth carboxylate and a metal dithiocarbamate. The metal dithiocarbamate can be added to the reaction or prepared in situ by reacting a secondary amine and carbon disulfide in the presence of metal oxide, metal hydroxide or a tertiary amine.The reaction products are useful as extreme pressure additives when incorporated in lubricants.
摘要:
Oxidative stability of petroleum motor fuel is improved by adding to the fuel an effective amount of heterocyclic molybdenum complex prepared by reacting (a) diol, amino or amino-alcohol compound and (b) a molybdenum source sufficient to yield about 2.0 to 20.0 percent of molybdenum based on the weight of the complex.
摘要:
Disclosed are novel compounds prepared by reacting 2,5-dimercapto-1,3,4-thiadiazole, aliphatic or aromatic aldehyde and aromatic amine in the molar ratio of 1:1:1 to 2:4:3. The 2,5-dimercapto-1,3,4-thiadiazole may be substituted in the 2-position by hydrocarbyl, terpene, polymeric and succinate residues. The compounds possess antiwear and antioxidant characteristics.
摘要:
Disclosed are novel compounds prepared by reacting 2,5-dimercapto-1,3,4-thiadiazole, aliphatic or aromatic aldehyde and alkylated phenol in the molar ratio of 1:1:1 to 2:2:1. The 2,5-dimercapto-1,3,4-thiadiazole may be substituted in the 2-position by terpene, polymeric and succinate residues. The compounds are effective antiwear agents and antioxidants when incorporated into lubricating compositions.