Abstract:
Alloy particles for negative electrode active material are proposed, which can impart anti-oxidation property to Si-containing alloy particles, and suppress oxidation of the negative electrode active material due to electrolyte at a considerably high level. A negative electrode material of secondary battery is achieved by a negative electrode material of secondary battery which is capable of intercalating and de-intercalating lithium and which consists of alloy particles including a silicon phase, a metal phase and bismuth, in which a crystallite size of the silicon phase is 10 nm or smaller, and the metal phase includes at least one kind of metal alloying with silicon but not with lithium, and the negative electrode material includes primary particles formed at least by the silicon and the metals.
Abstract:
The present invention relates to a method for preparing an anode active material, comprising (S1) forming a shell being a coating layer comprising a carbon material on the surface of a core comprising silicon oxide particles, to obtain a silicon oxide-carbon composite having a core-shell structure; (S2) mixing the silicon oxide-carbon composite with an oxygen-containing lithium salt, followed by heat treatment to produce a silicon oxide-lithium alloy, thereby obtaining a (SiOx—Liy)—C (0
Abstract:
Disclosed is an electrode active material for a lithium secondary battery including a first material including a carbon material, a second material of a nanostructure formed on the first material, the second material including at least one selected from a metal and a metalloid capable of reversibly alloying with lithium, and a third material present on a surface of at least one of the first material and the second material to control a side reaction with an electrolyte solution, an electrode including the electrode active material, and a lithium secondary battery having the electrode.
Abstract:
A negative electrode including: a negative electrode current collector; and a negative electrode active material layer on at least one surface of the negative electrode current collector. The negative electrode is pre-lithiated and the negative electrode active material layer includes a silicon-based material and a carbonaceous material. In addition, a graphene sheet having 2 layers to 15 layers is on the negative electrode active material layer. The negative electrode is advantageous in terms of storage and safety. A lithium secondary battery using the negative electrode shows reduced initial irreversibility, and thus provides increased efficiency.
Abstract:
Provided is a negative electrode active material including secondary particles assembled from silicon composite primary particles represented by Mg—SiOx (0
Abstract:
A negative electrode for a lithium secondary battery (and a lithium secondary battery including the same) including: a negative electrode current collector; a first negative electrode mixture layer present on at least one surface of the negative electrode current collector and including a first carbonaceous negative electrode active material, a first polymer binder and a first conductive material; a second negative electrode mixture layer present on a top surface of the first negative electrode mixture layer and including a silicon-based negative electrode active material, a second polymer binder and a second conductive material; and a third negative electrode mixture layer present on a top surface of the second negative electrode mixture layer and including a second carbonaceous negative electrode active material, a third polymer binder and a third conductive material.
Abstract:
The present invention provides an anode active material and a method for preparing the same, wherein the anode active material has a core-shell structure having formula (MOx-Liy)-C (here, M is a metal (or metalloid), x is greater than 0 and less than 1.5, and y is greater than 0 and less than 4) and including a core part containing an alloy of a metal (or metalloid) oxide-Li (MOx-Liy) and a shell part containing a carbon material coated on a surface of the core part, wherein the shell part contains lithium in an amount less than 5 atm % in the surface and the inner portion thereof. The anode active material can provide high capacity, excellent cycle characteristics, excellent volume expansion control capability, and high initial efficiency.
Abstract:
Disclosed herein is a non-carbon-based anode active material for lithium secondary batteries, including: a core containing silicon (Si); and silicon nanoparticles formed on the surface of the core. The non-carbon-based anode active material is advantageous in that the increase in the volume expansion during charging-discharging can be prevented by the application of silicon nanoparticles, and in that SiOx(x
Abstract:
The present disclosure relates to an anode active material comprising a composite of a core-shell structure, a lithium secondary battery comprising the same, and a method of manufacturing the anode active material. According to an aspect of the present disclosure, there is provided an anode active material of a core-shell structure comprising a core including alloyed (quasi)metal oxide-Li (MOx—Liy) and a shell including a carbon material coated on a surface of the core. According to another aspect of the present disclosure, there is provided a method of manufacturing the anode active material of the core-shell structure. According to an aspect of the present disclosure, an anode active material with high capacity, excellent cycle characteristics and volume expansion control capacity, and high initial efficiency is provided.
Abstract:
Disclosed herein is a non-carbon-based anode active material for lithium secondary batteries, including: a core containing silicon (Si); and silicon nanoparticles formed on the surface of the core. The non-carbon-based anode active material is advantageus in that the increase in the volume expansion during charging-discharging can be prevented by the application of silicon nanoparticles, and in that SiOx(x