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    Method for preparing carboxylic acids by palladium carbonylation
    21.
    发明授权
    Method for preparing carboxylic acids by palladium carbonylation 失效
    通过羰基化羰基制备羧酸的方法

    公开(公告)号：US06946574B2

    公开(公告)日：2005-09-20

    申请号：US10451662

    申请日：2001-12-21

    Applicant: Jean-Pierre Simonato ,  Pascal Metivier

    Inventor： Jean-Pierre Simonato ,  Pascal Metivier

    IPC: C07B61/00 ,  C07C51/14 ,  C07C53/126 ,  C07C57/03 ,  C07C57/02

    CPC classification number: C07C51/14 ,  C07C57/03

    Abstract: The present invention relates to a process for the preparation of β- or γ-unsaturated or saturated carboxylic acids.It relates more particularly to the hydroxycarbonylation of an organic compound comprising a conjugated unsaturation, such as butadiene, by the action of carbon monoxide and water in the presence of a palladium-based catalyst. The carboxylic acids thus obtained are preferably pentenoic acids. According to the invention, the reaction medium after the end of the hydroxycarbonylation stage is treated with hydrogen to reduce the palladium present in the 2+ oxidation state to palladium in the zero oxidation state and the precipitated palladium is recovered.

    Abstract translation: 本发明涉及一种制备β-或γ-不饱和或饱和羧酸的方法。 更具体地涉及在钯基催化剂存在下，通过一氧化碳和水的作用，包括共轭不饱和键的有机化合物如丁二烯的羟基羰基化。 由此得到的羧酸优选为戊烯酸。 根据本发明，羟基羰基化阶段结束后的反应介质用氢气处理以将存在于2+氧化态的钯以零氧化态还原成钯，并回收沉淀的钯。

    Recovering/recycling nitric acid from dinitration process streams comprising HNO3/dinitro compounds
    22.
    发明授权
    Recovering/recycling nitric acid from dinitration process streams comprising HNO3/dinitro compounds 失效
    从包含HNO3 /二硝基化合物的二硝化工艺流中回收/再循环硝酸

    公开(公告)号：US06191325B1

    公开(公告)日：2001-02-20

    申请号：US09130348

    申请日：1998-08-13

    Applicant: Philippe Marion ,  Pascal Metivier

    Inventor： Philippe Marion ,  Pascal Metivier

    IPC: C07C20500

    CPC classification number: C07C201/16 ,  C07C201/08 ,  C07C205/06

    Abstract: Dinitro aromatic compounds are improvedly prepared by reacting an aromatic compound with a nitric acid nitrating agent and thence separating the nitrating acid from the process stream thus formed, the process stream containing said at least one dinitro aromatic compound and also having a fraction of the nitrating acid dissolved therein, the subject process also comprising (a) distilling/stripping nitric acid from said process stream, (b) recovering nitric acid from the top of the distillation/stripping vessel and recycling same to the nitration reaction and (c) washing the process stream which contains the at least one dinitro aromatic compound, but having the nitric acid removed therefrom.

    Abstract translation: 二硝基芳族化合物通过使芳族化合物与硝酸硝化剂反应，然后从所形成的工艺流中分离硝酸而改进制备，所述工艺流含有所述至少一种二硝基芳族化合物，并且还含有一部分硝酸 本方法还包括（a）从所述工艺流中蒸馏/除去硝酸，（b）从蒸馏/汽提容器的顶部回收硝酸并将其再循环到硝化反应，和（c）洗涤该过程 其含有至少一种二硝基芳族化合物，但其中除去硝酸。

    Method for preparing a 4-hydroxybenzaldehyde and derivatives
    23.
    发明授权
    Method for preparing a 4-hydroxybenzaldehyde and derivatives 失效
    4-羟基苯甲醛及其衍生物的制备方法

    公开(公告)号：US06184421B2

    公开(公告)日：2001-02-06

    申请号：US09308065

    申请日：1999-05-13

    Applicant: Pascal Metivier

    Inventor： Pascal Metivier

    IPC: C07C4538

    CPC classification number: C07C45/676 ,  C07C39/11 ,  C07C41/30 ,  C07C45/38 ,  C07C51/235 ,  C07C47/58 ,  C07C47/575 ,  C07C65/21 ,  C07C43/23

    Abstract: The present invention concerns a process for the preparation of a 4-hydroxybenzaldehyde and its derivatives. More particularly, the invention concerns the preparation of 3-methoxy-4-hydroxybenzaldehyde and 3-ethoxy-4-hydroxybenzaldehyde, respectively known as vanillin and ethylvanillin. The process for the preparation of a 4-hydroxybenzaldehyde and its derivatives is characterized in that it consists of selectively oxidising, to a carboxy group, the group in the 2 position with respect to the hydroxyl group, present in the phenolic compounds in a mixture comprising at least a phenolic compound (A) carrying formyl and/or hydroxymethyl groups in the 2 and 4 position, a phenolic compound (B) carrying a formyl or hydroxymethyl group in the 4 position, a phenolic compound (C) carrying a formyl or hydroxymethyl group in the 2 position, resulting in a mixture comprising a 3-carboxy-4-hydroxybenzaldehyde, a 4-hydroxybenzaldehyde and a 2-hydroxybenzoic acid, which then undergoes a decarboxylation operation to produce the 4-hydroxybenzaldehyde and a phenol which can optionally be recycled.

    Abstract translation: 本发明涉及一种制备4-羟基苯甲醛及其衍生物的方法。 更具体地，本发明涉及3-甲氧基-4-羟基苯甲醛和3-乙氧基-4-羟基苯甲醛的制备，分别称为香草醛和乙基香兰素。 制备4-羟基苯甲醛及其衍生物的方法的特征在于，它包括以相对于羟基的2位选择性氧化羧基，所述基团存在于酚类化合物中，所述混合物包含 至少在2位和4位含有甲酰基和/或羟甲基的酚类化合物（A），4位上带有甲酰基或羟甲基的酚类化合物（B），含有甲酰基或羟甲基的酚类化合物（C） 组成2位，得到包含3-羧基-4-羟基苯甲醛，4-羟基苯甲醛和2-羟基苯甲酸的混合物，然后进行脱羧操作以产生4-羟基苯甲醛和可以任选地为 回收。

    Process for the preparation of 3-carboxy-4-hydroxybenzaldehides and derivatives thereof
    24.
    发明授权
    Process for the preparation of 3-carboxy-4-hydroxybenzaldehides and derivatives thereof 失效
    3-羧基-4-羟基苯甲醛及其衍生物的制备方法

    公开(公告)号：US5783737A

    公开(公告)日：1998-07-21

    申请号：US776343

    申请日：1997-01-24

    Applicant: Pascal Metivier

    Inventor： Pascal Metivier

    IPC: B01J23/42 ,  B01J23/44 ,  C07B61/00 ,  C07C45/38 ,  C07C45/65 ,  C07C45/67 ,  C07C47/575 ,  C07C47/58 ,  C07C51/255 ,  C07C65/30 ,  C07C201/12 ,  C07C205/61 ,  C07C45/00

    CPC classification number: C07C45/676 ,  C07C45/38 ,  C07C51/255

    Abstract: The present invention concerns a process for the preparation of 3-carboxy-4-hydroxybenzaldehydes and derivatives thereof from phenolic compounds carrying formyl and/or hydroxymethyl groups in the 2 and 4 positions. The invention also concerns the preparation of 4-hydroxybenzaldehydes from 3-carboxy-4-hydroxybenzaldehydes. More particularly, the invention concerns the preparation of 3-methoxy-4-hydroxybenzaldehyde and 3-ethoxy-4-hydroxybenzaldehyde, respectively known as "vanillin" and "ethylvanillin". The process for the preparation of 3-carboxy-4-hydroxybenzaldehyde is characterized in that the group in the 2 position in a phenolic compound carrying formyl and/or hydroxymethyl groups in the 2 and 4 positions is selectively oxidized to a carboxy group, and optionally a hydroxymethyl group in the 4 position is selectively oxidized to a formyl group. A successive decarboxylation step for a 3-carboxy-4-hydroxybenzaldehyde produces a 4-hydroxybenzaldehyde.

    Abstract translation: PCT No.PCT / FR96 / 00779 Sec。 371日期1997年1月24日 102（e）日期1997年1月24日PCT提交1996年5月24日PCT公布。 出版物WO96 / 37454 日期：1996年11月28日本发明涉及在2位和4位含有甲酰基和/或羟甲基的酚类化合物制备3-羧基-4-羟基苯甲醛及其衍生物的方法。 本发明还涉及从3-羧基-4-羟基苯甲醛制备4-羟基苯甲醛。 更具体地，本发明涉及3-甲氧基-4-羟基苯甲醛和3-乙氧基-4-羟基苯甲醛的制备，分别称为“香草醛”和“乙基香兰素”。 3-羧基-4-羟基苯甲醛的制备方法的特征在于，在2位和4位上带有甲酰基和/或羟甲基的酚类化合物中2位的基团被选择性氧化成羧基， 4位的羟甲基被选择性氧化成甲酰基。 3-羧基-4-羟基苯甲醛的连续脱羧步骤产生4-羟基苯甲醛。

    Cyclic (poly)glycerol sulphates and preparation and use thereof
    25.
    发明授权
    Cyclic (poly)glycerol sulphates and preparation and use thereof 有权
    环状（聚）甘油硫酸盐及其制备和用途

    公开(公告)号：US09371306B2

    公开(公告)日：2016-06-21

    申请号：US14356512

    申请日：2011-11-10

    Applicant: Pascal Metivier ,  Yan Zhao ,  Zhaoyu Fan ,  Chenjiang Zhu

    Inventor： Pascal Metivier ,  Yan Zhao ,  Zhaoyu Fan ,  Chenjiang Zhu

    IPC: C07D327/10

    CPC classification number: C07D327/10

    Abstract: The present invention relates to novel cyclic sulphates of (poly)glycerol, particularly to the novel compound of 4-(hydroxymethyl)-1,3,2-dioxathiolane-2,2-dioxide. The present invention also relates to the preparation process of the cyclic sulphate compounds, and to the use thereof as an intermediate to prepare green surfactants containing sulphate groups.

    Abstract translation: 本发明涉及（聚）甘油的新型环状硫酸盐，特别涉及4-（羟甲基）-1,3,2-二氧杂环戊烷-2,2-二氧化物的新化合物。 本发明还涉及环硫酸酯化合物的制备方法，以及作为制备含有硫酸酯基团的绿色表面活性剂的中间体的用途。

    Secure control system for opening locking devices by encrypted acoustic accreditations
    28.
    发明授权
    Secure control system for opening locking devices by encrypted acoustic accreditations 有权
    通过加密声学认证打开锁定装置的安全控制系统

    公开(公告)号：US08565725B2

    公开(公告)日：2013-10-22

    申请号：US13386232

    申请日：2010-07-16

    Applicant: Pascal Metivier

    Inventor： Pascal Metivier

    IPC: H04M1/66

    CPC classification number: G07C9/00182 ,  G07C9/00904 ,  G07C2009/00642 ,  G07C2009/00801

    Abstract: The invention relates to a system implements a mobile phone (20) available to a user (18) authorized to open a lock (22). A remote management site (10) includes a database (12) of locks and authorized users identified by the mobile phone number thereof, as well as a generator (14) of accreditation data. The accreditations are encrypted acoustic accreditations in the form of single-use audio signals, capable of enabling the opening of locks that are indexed in the database. The system includes means for securely transmitting the encrypted acoustic accreditations from the management site to the mobile phone of the corresponding authorized user via a mobile network operator (16). The lock (22) includes an electroacoustic transducer that is capable of sensing the acoustic accreditations reproduced by the telephone placed beforehand near the lock, as well as a means for recognizing, analyzing, and authenticating the sensed acoustic accreditations, and controlling the unlocking of the mechanical members upon recognizing a compliant accreditation.

    Abstract translation: 本发明涉及一种系统，其实现了授权打开锁（22）的用户（18）可用的移动电话（20）。 远程管理站点（10）包括由其移动电话号码识别的锁和授权用户的数据库（12）以及认证数据的发生器（14）。 认证是一次性音频信号形式的加密声学认证，能够打开在数据库中编入索引的锁。 该系统包括用于经由移动网络运营商（16）将来自管理站点的加密的声学认证安全地传送到相应的授权用户的移动电话的装置。 锁（22）包括电声换能器，其能够感测由预先在锁附近放置的电话再现的声学认证，以及用于识别，分析和认证感测到的声学认证的手段，以及控制解锁 机械成员认可合规认证。

    Purification of mixtures of nitroaromatic compounds by removing nitrocresols therefrom
    30.
    发明授权
    Purification of mixtures of nitroaromatic compounds by removing nitrocresols therefrom 失效
    通过从其中除去硝基酚来净化硝基芳族化合物的混合物

    公开(公告)号：US5874654A

    公开(公告)日：1999-02-23

    申请号：US934115

    申请日：1997-09-19

    Applicant: Antoinette Gacon-Camoz ,  Pascal Metivier

    Inventor： Antoinette Gacon-Camoz ,  Pascal Metivier

    IPC: C07C201/16

    CPC classification number: C07C201/16

    Abstract: Environmentally-polluting nitrocresol values are removed from admixtures of nitroaromatic compounds comprised thereof, notably the media of nitration of aromatic compounds by reacting same with aqueous HNO.sub.3 /H.sub.2 SO.sub.4, by first intimately contacting such nitroaromatic compound admixtures with an oxidizing agent comprising hydrogen peroxide, javelle water, or mixture thereof, and thereafter with a neutralizing agent; the nitroaromatic aromatic compounds thus purified are conveniently catalytically hydrogenated into aromatic amines.

    Abstract translation: 通过首先使这种硝基芳族化合物外加剂与包含过氧化氢，悬浮液的氧化剂紧密接触，从而与其组成的硝基芳族化合物的混合物，特别是芳族化合物硝化的介质从HNO 3 / H 2 SO 4水溶液中除去环境污染的硝基甲酚值 ，或其混合物，然后用中和剂; 如此纯化的硝基芳族芳族化合物方便地催化氢化成芳族胺。

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