摘要:
The present invention provides a lithium secondary battery having great capacity density per volume and weight. The lithium secondary battery contains a positive electrode having Li—Bi alloy or Li—Sb alloy as a positive electrode active material, a negative electrode and a non-aqueous electrolyte.
摘要:
A rechargeable lithium battery has a positive electrode, a negative electrode and a non-aqueous electrolyte. The active material of the positive or negative electrode is tungsten complex sulfide, either with or without addition of lithium thereto. The tungsten complex sulfide contains tungsten, sulfur and at least one transition metal selected from Cu, V, Cr, Mn, Fe, Co and Ni, and has substantially the same crystal structure as WS2.
摘要:
A method of manufacturing an electrode active material particle for a rechargeable battery wherein a layer of an active material capable of being alloyed with Li is formed on a surface of a metal particle incapable of being alloyed with Li and then a heat treatment is conducted to diffuse the active material into the metal particle so that the resulting active material particle has a concentration profile in which a concentration of a metal element of the metal particle decreases from an interior toward the surface.
摘要:
In a lithium secondary battery of this invention, the negative electrode uses, as an active material, an alloy including an A phase of a first intermetallic compound (A), and a B phase of a second intermetallic compound (B) having the same constituent elements as and a different composition from the first intermetallic compound (A) and/or a C phase consisting of one of the constituent elements of the first intermetallic compound (A), and at least one of the A phase, the B phase and the C phase is capable of electrochemically absorbing and discharging lithium ions. Thus, the lithium secondary battery can exhibit good charge-discharge cycle performance.
摘要:
A non-aqueous electrolyte battery according to the invention includes a positive electrode using a lithium-metal compound oxide as a positive electrode material, a negative electrode and a non-aqueous electrolyte solution, the battery employing a positive electrode material composed of the lithium-metal compound oxide which contains at least Ni, Co and Mn, and has a peak with a full width at half maximum of not greater than 0.22.degree. in a range of 2.theta.=18.71.+-.0.25.degree. as measured by the powder X-ray diffraction analysis using a Cu-K.alpha. X-ray source or employing a positive electrode material composed of a lithium-metal compound oxide which contains at least Ni, Co and Mn, and a non-aqueous electrolyte solution which includes a solvent containing ethylene carbonate and a solute containing at least one type of fluorine-containing compound.
摘要:
A lithium secondary battery comprising a nonaqueous electrolyte obtained by dissolving an electrolytic salt in a solvent, a negative electrode comprising a negative electrode material and a positive electrode comprising a positive electrode active material, the electrolytic salt comprising: at least one electrolytic salt A selected from the group consisting of LiPF.sub.6, LiAsF.sub.6, LiSbF.sub.6, LiBF.sub.4, LiBiF.sub.4, LiAlF.sub.4, LiGaF.sub.4, LiInF.sub.4 and LiClO.sub.4, and at least one electrolytic salt B selected from the group consisting of LiN(C.sub.n F.sub.2n+1 SO.sub.2).sub.2 wherein n is an integer of 1, 2, 3 or 4 and LiC(C.sub.m F.sub.2m+1 SO.sub.2).sub.3 wherein m is an integer of 1, 2, 3 or 4. The battery is superior in the aspects of storage characteristic in a charged condition.
摘要:
In a lithium secondary battery provided with a positive electrode, a negative electrode, and a non-aqueous electrolyte, a tungsten oxide W20O58 or W18O49, or the tungsten oxide to which lithium is added, or a tungsten composite oxide comprising a tungsten oxide containing at least one type of metal element selected from the group consisting of Mn, Cu, V, Cr, Fe, Co, and Ni and having a W20O58-type or W18O49-type crystal structure or the tungsten composite oxide to which lithium is added is used as a positive electrode active material for said positive electrode or a negative electrode active material for said negative electrode.
摘要:
The present invention provides an improved electrode material for a lithium secondary battery to provide a lithium secondary battery that is light in weight and has high energy density. Sulfur and a catalyst material such as active carbon, and the like, that reduces activation energy of an addition reaction of lithium to sulfur and allows the reaction to occur at not greater than 60° C., are included in the electrode material.
摘要:
A non-aqueous battery with improved volume energy density and enhanced load characteristics is made available even when using olivine-type lithium phosphate as a positive electrode active material.The non-aqueous electrolyte battery of the present invention is provided with a positive electrode (1) containing lithium iron phosphate as a positive electrode active material, a negative electrode (2), and a non-aqueous electrolyte (4). In the positive electrode (1), a positive electrode active material-containing layer that is made of the positive electrode active material, a conductive agent, and a binder agent is formed on a positive electrode current collector. The positive electrode current collector has a thickness of less than 20 μm and its surface that is in contact with the positive electrode active material-containing layer has a mean surface roughness Ra of greater than 0.026.
摘要:
In a non-aqueous electrolyte battery provided with a positive electrode, a negative electrode, and a non-aqueous electrolyte using an organic solvent, at least one type of ferrite, FeS2, and a transition metal oxide (except for LiCoO2) having crystal structure of space group R3m is used as a positive electrode material for a positive electrode, and a negative electrode material containing lithium is used for a negative electrode.
摘要翻译:在使用有机溶剂的正极,负极和非水电解质的非水电解质电池中,至少一种铁氧体FeS 2 O 3和过渡金属氧化物 (具有空间群R3m的晶体结构的LiCoO 2 2除外)用作正极的正极材料,负极使用含有锂的负极材料。