Silver halide photographic material

    公开(公告)号:US4767692A

    公开(公告)日:1988-08-30

    申请号:US484

    申请日:1987-01-05

    摘要: A novel silver halide photographic material is provided comprising a support and at least one silver halide photographic emulsion layer formed thereon and containing in said photographic emulsion layer or at least one hydrophilic colloid layer a compound represented by formula (I): ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and each represents a hydrogen atom, an aliphatic residual group, an aromatic residual group, or a heterocyclic residual group; R.sup.3 represents a hydrogen atom or an aliphatic residual group; L.sub.1 represents a divalent aliphatic group, a divalent aromatic group, or a divalent heterocyclic group; L.sub.2 represents --O--, --CONR--, --NRCO--, --SO.sub.2 NR--, --NRSO.sub.2 --, --OCO--, --COO--, --S--, --NR--, --CO--, --SO--, --SO.sub.2 --, --OCOO--, --NRCONR'--, --NRCOO--, --OCONR--, or --NRSO.sub.2 NR'-- (in which R and R' each represents a hydrogen atom, an alkyl group or an aryl group); l and m each represents an integer of 1 or 2; n represents an integer of 0 or 1; and A represents a residual group which is obtained by removing hydrogen atoms from Ar or B in a compound represented by formula (II), provided that when m=1, one hydrogen atom is removed; when m=2, two hydrogen atoms are removed: ##STR2## wherein Ar represents an aryl group; B represents a formyl group, an acyl group, an alkyl or arylsulfonyl group, an alkyl or arylsulfinyl group, a carbamoyl group, a sulfamoyl group, an alkoxy or aryloxycarbonyl group, a sulfinamoyl group, an alkoxysulfonyl group, a thioacyl group, a thiocarbamoyl group, or a heterocyclic group; and R.sub.0 and R.sub.00 each represents a hydrogen atom or one of R.sub.0 and R.sub.00 represents a hydrogen atom and the other represents a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group or a substituted or unsubstituted acyl group, with the proviso that B, R.sub.00 and the nitrogen atom to which B and R.sub.00 are bonded may together form a partial structure of hydrazone (--N.dbd.C

    Silver halide photographic materials containing a blocked photographic
reagent
    22.
    发明授权
    Silver halide photographic materials containing a blocked photographic reagent 失效
    含有封闭照相试剂的卤化银照相材料

    公开(公告)号:US4659651A

    公开(公告)日:1987-04-21

    申请号:US753847

    申请日:1985-07-11

    摘要: A silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer having associated therewith at least one blocked photographic reagent represented by formula (I) or (II); ##STR1## wherein, A represents a moiety of a photographic reagent or a moiety of a precursor of a photographic reagent bonded to the ring containing Z through a hetero atom; Y.sup.1, and Y.sup.2 and Y.sup.3 each represents a hydrogen atom or a substituent, or Y.sup.1 and Y.sup.3 in formula (I) together form a ring; Z represents an atomic group necessary for forming a carbon ring or a heterocyclic ring; and n represents 1 or 2.The silver halide photographic material is stable under storage conditions.

    摘要翻译: 一种卤化银照相材料,其包含其上具有至少一种感光卤化银乳剂层的载体,所述感光卤化银乳剂层具有至少一种由式(I)或(II)表示的封闭照相试剂。 (II)其中,A表示通过杂原子键合到含有Z的环的照相试剂或照相试剂的前体的部分的部分; Y1,Y2和Y3各自表示氢原子或取代基,或式(I)中的Y1和Y3一起形成环; Z表示形成碳环或杂环所必需的原子团; 并且n表示1或2.卤化银照相材料在储存条件下是稳定的。

    Silver halide diffusion transfer using plural cyclic imide silver halide
solvents
    23.
    发明授权
    Silver halide diffusion transfer using plural cyclic imide silver halide solvents 失效
    使用多种环状酰亚胺卤化银溶剂进行卤化银扩散转移

    公开(公告)号:US4624911A

    公开(公告)日:1986-11-25

    申请号:US706532

    申请日:1985-02-27

    CPC分类号: G03C8/365

    摘要: A method for image formation by a diffusion transfer process including developing an imagewise light-exposed light-sensitive silver halide emulsion layer in the presence of a developing agent, a silver halide solvent and an alkali, wherein at least two cyclic imide compounds represented by the formula: ##STR1## wherein Z represents an atomic group necessary to form a 5- or 6-membered imido ring containing from 1 to 3 nitrogen atoms, are used as the silver halide solvent is disclosed. Images obtained by the method are stable during storage over a long period of time.

    摘要翻译: 一种通过扩散转移法形成图像的方法,包括在显影剂,卤化银溶剂和碱的存在下显影成像曝光的感光卤化银乳剂层,其中至少两种由 公开:其中Z表示形成含有1至3个氮原子的5-或6-元亚胺基所必需的原子团的式(I)化合物用作卤化银溶剂。 通过该方法获得的图像在长时间的储存期间是稳定的。

    Silver halide color photographic light-sensitive material
    25.
    发明授权
    Silver halide color photographic light-sensitive material 失效
    卤化银彩色摄影感光材料

    公开(公告)号:US4444870A

    公开(公告)日:1984-04-24

    申请号:US415295

    申请日:1982-09-07

    CPC分类号: G03C7/3275 Y10S525/902

    摘要: A silver halide color photographic light-sensitive material comprising a support having thereon a layer containing at least one copolymer coupler latex having a layered structure capable of forming a dye upon coupling with an oxidation product of an aromatic primary amine developing agent. The polymer coupler latex having a layered structure has an exceptionally good color forming property and is capable of forming a dye with a high yield and without the formation of undesired stains and fogs. The silver halide color photographic light-sensitive material containing the polymer coupler latex has good film strength and a reduced layer thickness and provides a color image having an improved sharpness. A method of forming a color image using the silver halide color photographic light-sensitive material is also disclosed.

    摘要翻译: 一种卤化银彩色摄影感光材料,其包括其上具有包含至少一种具有能与芳族伯胺显影剂的氧化产物偶合形成染料的层状结构的共聚物成色胶乳的层的载体。 具有层状结构的聚合物成色剂胶乳具有非常好的成色性,能够以高产率形成染料,并且不形成不期望的污渍和雾。 含有聚合物偶联胶乳的卤化银彩色照相感光材料具有良好的膜强度和降低的层厚度,并提供了具有改善的清晰度的彩色图像。 还公开了使用卤化银彩色照相感光材料形成彩色图像的方法。

    Silver halide photographic light-sensitive material
    26.
    发明授权
    Silver halide photographic light-sensitive material 失效
    卤化银照相感光材料

    公开(公告)号:US4296200A

    公开(公告)日:1981-10-20

    申请号:US177337

    申请日:1980-08-12

    摘要: A silver halide photographic light-sensitive material containing a colorless photographic cyan color forming coupler having, in a position for coupling with an oxidation product of an aromatic primary amine developing agent, a coupling-off group represented by the formula (I):--O--R--S--R.sub.1 (I)wherein R represents a substituted alkylene group or an unsubstituted or substituted alkenylene group, and said alkylene group or alkenylene group may be straight or branched chain; and R.sub.1 represents a substituted or unsubstituted alkyl group, an alkenyl group, an aralkyl group, an aralkenyl group, a cycloalkyl group or a heterocyclic group and said alkyl group, alkenyl group, aralkyl group and aralkenyl group may be straight or branched chain; and said heterocyclic group being connected with a thio group at the position of a carbon atom of the heterocyclic group.

    摘要翻译: 含有无色摄影青色成色剂的卤化银照相感光材料,其具有与芳族伯胺显影剂的氧化产物偶联的位置,式(I)表示的偶合离去基团:-OR -R1(I)其中R表示取代的亚烷基或未取代或取代的亚烯基,所述亚烷基或亚烯基可以是直链或支链的; R1表示取代或未取代的烷基,烯基,芳烷基,芳烯基,环烷基或杂环基,所述烷基,烯基,芳烷基和芳烯基可以是直链或支链的; 并且所述杂环基与杂环基的碳原子上的硫基连接。

    Silver halide photographic light-sensitive material
    27.
    发明授权
    Silver halide photographic light-sensitive material 失效
    卤化银照相感光材料

    公开(公告)号:US4264722A

    公开(公告)日:1981-04-28

    申请号:US093965

    申请日:1979-11-14

    CPC分类号: G03C7/30523

    摘要: A silver halide photographic light-sensitive material containing a colorless photographic cyan color-forming coupler having, in a position for coupling with an oxidation product of an aromatic primary amine developing agent, an eliminatable group represented by the following formula (I):--O--(R.sub.1 O).sub.x (R.sub.2 O).sub.y R.sub.3 (I)wherein R.sub.1 and R.sub.2 each represents a substituted or unsubstituted alkylene group which may be branched provided that R.sub.1 is not substituted with an aryl group at the carbon atom adjacent to the oxygen atom bonded to the coupling position, R.sub.3 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a cycloalkyl group, an aryl group, or a cyan coupler residue, x represents a positive integer, and y represents 0 or a positive integer.

    摘要翻译: 含有无色摄影青色成色剂的卤化银摄影感光材料,其具有与芳族伯胺显影剂的氧化产物偶联的位置,由下式(I)表示的可消除基团:-O - (R 1 O)x(R 2 O)y R 3(I)其中R 1和R 2各自表示可以被支化的取代或未取代的亚烷基,条件是R 1不与在与该键合的氧原子相邻的碳原子上的芳基取代 R 3表示氢原子,取代或未取代的烷基,环烷基,芳基或青色成色剂残基,x表示正整数,y表示0或正整数。

    Silicon-containing compound, composition containing said compound, and insulating material
    28.
    发明授权
    Silicon-containing compound, composition containing said compound, and insulating material 失效
    含硅化合物,含有所述化合物的组合物和绝缘材料

    公开(公告)号:US07534904B2

    公开(公告)日:2009-05-19

    申请号:US11138352

    申请日:2005-05-27

    IPC分类号: C07F7/18

    CPC分类号: C07F7/1804

    摘要: A composition for forming an insulating film comprising at least one of a compound represented by formula (1), a hydrolysate of the compound represented by formula (1) and a condensate of the compound represented by formula (1): AnSiX(4-n)  (1) wherein n represents an integer of from 1 to 3; A represents an optionally substituted group containing a cage structure formed by 11 or more carbon atoms, and when n represents an integer of 2 or 3, A's are mutually same or different; and X represents a hydrolyzable group, and when n represents an integer of 1 or 2, X's are mutually same or different.

    摘要翻译: 一种用于形成绝缘膜的组合物,其包含由式(1)表示的化合物,由式(1)表示的化合物的水解产物和由式(1)表示的化合物的缩合物中的至少一种:&lt; -formulae description =“In-line Formulas”end =“lead”?> AnSiX(4-n)(1)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中n 表示1〜3的整数, A表示含有由11个或更多个碳原子形成的笼状结构的任选取代的基团,当n表示2或3的整数时,A相互相同或不同; X表示可水解基团,当n表示1或2的整数时,X相同或不同。

    Photosensitive composition and planographic printing plate precursor
    30.
    发明授权
    Photosensitive composition and planographic printing plate precursor 失效
    光敏组合物和平版印刷版前体

    公开(公告)号:US06908727B2

    公开(公告)日:2005-06-21

    申请号:US10796973

    申请日:2004-03-11

    摘要: This invention describes a heat sensitive composition comprising: (A-I) a compound which is represented by the following general formula (I) and generates a radical when heated, and (B-I) a compound having physical and chemical properties that are changed irreversibly by a radical, R—SO2−M+  General formula (I) wherein R represents an alkyl group or aryl group, and M+ represents a counter cation selected from sulfonium, iodonium, diazonium, ammonium and azinium; and a negative planographic printing plate precursor which can be recorded by heat mode using this composition. This invention also describes a planographic printing plate precursor comprising a substrate having disposed thereon a photosensitive layer containing (C-II) a light-heat converting agent, (B-II) a compound having a polymerizable unsaturated group, and (A-II) an onium salt having at least two cation parts in one molecule.

    摘要翻译: 本发明描述了一种热敏性组合物,其包含:(AI)由以下通式(I)表示并在加热时产生自由基的化合物和(BI)具有由激进基团不可逆地改变的物理和化学性质的化合物 ,<?in-line-formula description =“In-line Formulas”end =“lead”?> R-SO <2> >通式(I)<?in-line-formula description =“In-line formula”end =“tail”?>其中R表示烷基或芳基,M + 选自锍,碘鎓,重氮,铵和氮鎓的抗衡阳离子; 以及可以使用该组合物通过热模式记录的负型平版印刷版原版。 本发明还描述了一种平版印刷版原版,其包括在其上设置有含有(C-II)光热转换剂(B-II)具有可聚合不饱和基团的化合物和(A-II) 在一个分子中具有至少两个阳离子部分的鎓盐。