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21.发明申请Ultrafine polyactic acid fibers and fiber structure, and process for their production 审中-公开超细聚乳酸纤维和纤维结构，及其生产工艺公开(公告)号：US20070172651A1
公开(公告)日：2007-07-26
申请号：US10592760
申请日：2005-03-03
IPC分类号： D02G3/00
CPC分类号： D01D5/0038 , D01F6/625 , D01F6/84 , Y10T428/2929
摘要： A fiber structure is obtained by spinning of a solution of an L-lactic acid condensate and a D-lactic acid condensate by electrospinning. It is possible to provide a fiber structure comprising fibers with extremely small fiber diameters, as well as excellent heat resistance and biodegradability.
摘要翻译： 通过静电纺丝将L-乳酸缩合物和D-乳酸缩合物的溶液旋转来获得纤维结构体。 可以提供包含具有极小纤维直径的纤维的纤维结构，以及优异的耐热性和生物降解性。
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公开(公告)号：US06646060B1
公开(公告)日：2003-11-11
申请号：US09743408
申请日：2001-01-10
IPC分类号： C08G6948
CPC分类号： C08L67/02 , C08G73/1082 , C08L79/08 , Y10T428/31721
摘要： A resin composition containing a mixture produced by blending a crystalline polyamide expressed e.g. by formula (1) (in the formula, R1 is a bivalent organic aromatic group or aliphatic group having a carbon number of 2 to 30, optionally having substituent and optionally containing non-reactive groups such as ether group and aromatic group in the main chain, and Ar1 is an aromatic residue having a carbon number of 6 to 45 and optionally having substituent) with a thermoplastic polyester. The resin composition has excellent mechanical characteristics such as high elastic modulus, flow properties and heat-resistance and is suitable as a material for an electronic part for surface mounting.
摘要翻译： 一种树脂组合物，其含有通过将结晶聚酰胺共混而制得的混合物， 通式（1）（式中，R 1为二价有机芳香族基团或碳数为2〜30的脂肪族基，任选具有取代基且任选地含有非反应性基团，例如主链中的醚基和芳香族基团 ，Ar 1为碳原子数为6〜45，可以具有取代基的芳香族残基）与热塑性聚酯。 树脂组合物具有优异的机械特性，例如高弹性模量，流动性和耐热性，并且适合作为用于表面安装的电子部件的材料。
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公开(公告)号：US20130296790A1
公开(公告)日：2013-11-07
申请号：US13881322
申请日：2011-10-24
申请人： Koichi Masaoka , Keizo Ikari , Takashi Oda , Katsunori Kobayashi , Hidetoshi Hamamoto , Masaki Ishibashi , Kiyotsuna Toyohara
发明人： Koichi Masaoka , Keizo Ikari , Takashi Oda , Katsunori Kobayashi , Hidetoshi Hamamoto , Masaki Ishibashi , Kiyotsuna Toyohara
IPC分类号： A61M37/00
CPC分类号： A61M37/0015 , A61M2037/0023 , A61M2037/0053 , A61M2037/0061
摘要： Provided are a microneedle and a microneedle array which have both aspects of safety and easiness to use and can administer a predetermined dose of a medical agent without causing a pain by smoothly running into the skin surface layer of a patient, the microneedle comprising a frustum and a forward end portion thereon, having a forward end apex angle in the range of 15 to 60° and a forward end diameter in the range of 1 to 20 μm and satisfying the following expression (1), H/D≧5 (1) (H: Height of the whole, D: Diameter of bottom surface of the frustum).
摘要翻译： 提供了一种微针和微针阵列，其具有安全性和易于使用的两个方面，并且可以通过平滑地进入患者的皮肤表面层而施加预定剂量的药剂而不引起疼痛，所述微针包括截头锥体和 其前端部具有15-60°的前端顶角和1〜20μm的前端直径，满足下式（1）：H / D> = 5（1 ）（H：整体高度，D：截头锥体底面的直径）。
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公开(公告)号：US20110160364A1
公开(公告)日：2011-06-30
申请号：US12375347
申请日：2007-07-26
申请人： Kiyotsuna Toyohara , Takaaki Matsuda , Keiichiro Ino , Yuichi Matsuno , Fumitaka Kondo , Jitsuo Oda
发明人： Kiyotsuna Toyohara , Takaaki Matsuda , Keiichiro Ino , Yuichi Matsuno , Fumitaka Kondo , Jitsuo Oda
CPC分类号： C08L67/02 , C08K3/013 , C08K5/523 , C08K5/527 , C08L67/025 , C08L67/04 , C08L2666/18
摘要： To provide a resin composition having high heat resistance with a high melting point and excellent melt stability and hydrolysis resistance, a molded article of the resin composition and a method of manufacturing the resin composition; the resin composition comprises an aromatic polyester (component A) having a butylene terephthalate skeleton as the main constituent unit and polylactic acid (component B) having a melting point of 190° C. or higher.
摘要翻译： 为了提供具有高熔点的高耐热性和优异的熔体稳定性和耐水解性的树脂组合物，该树脂组合物的模塑制品和该树脂组合物的制造方法; 树脂组合物包含具有对苯二甲酸丁二醇酯骨架作为主要构成单元的芳族聚酯（组分A）和熔点为190℃或更高的聚乳酸（组分B）。
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公开(公告)号：US20100227963A1
公开(公告)日：2010-09-09
申请号：US12161295
申请日：2007-01-17
申请人： Katsuhiko Hironaka , Fumitaka Kondo , Keiichiro Ino , Yuichi Matsuno , Kiyotsuna Toyohara , Hirotaka Suzuki
发明人： Katsuhiko Hironaka , Fumitaka Kondo , Keiichiro Ino , Yuichi Matsuno , Kiyotsuna Toyohara , Hirotaka Suzuki
CPC分类号： C08L69/00 , C08K3/013 , C08K3/34 , C08K5/51 , C08L23/02 , C08L25/04 , C08L67/02 , C08L67/04 , C08L2666/18
摘要： There are provided a resin composition comprising a polylactic acid which (i) comprises a poly-L-lactic acid (component B-1) and a poly-D-lactic acid (component B-4), (ii) has a weight ratio of the component B-1 to the component B-4 (component B-1/component B-4) of 10/90 to 90/10, and (iii) shows a proportion of melt peaks at 195° C. or higher to all melt peaks in a temperature rising process in measurement by a differential scanning calorimeter (DSC) of at least 20%; a molded article of the resin composition; and methods for producing the resin composition and the molded article.
摘要翻译： 提供了包含聚乳酸的树脂组合物，（i）包含聚-L-乳酸（组分B-1）和聚-D-乳酸（组分B-4），（ii）具有重量比 的组分B-1与组分B-4（组分B-1 /组分B-4）的比例为10/90至90/10，和（iii）显示195℃或更高至 通过差示扫描量热计（DSC）测量的升温过程中所有熔体峰值至少为20％; 树脂组合物的模塑制品; 以及树脂组合物和成型体的制造方法。
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公开(公告)号：US20100222486A1
公开(公告)日：2010-09-02
申请号：US12734196
申请日：2008-10-15
摘要： The object of this invention is to provide a resin composition that contains a polymer obtained from biomass resources and constitutes molded articles excellent in heat resistance, mechanical properties and durable stability, this invention including a resin composition comprising (i) a resin component containing 95 to 5% by weight of an aromatic polycarbonate (component A) and 5 to 95% by weight of polylactic acid (component B), (ii) 0.001 to 10 parts by weight, per 100 parts by weight of the resin component, of a phosphoric ester metal salt (component C), and (iii) 0.01 to 5 parts by weight, per 100 parts by weight of the polylactic acid (component B), of a terminal blocker (component F), the stereo-complex crystal content (X) of the following expression (I) being 80% or more, X (%)={ΔHb/(ΔHa+ΔHb)}×100 (I) wherein ΔHa and ΔHb are a melting enthalpy (ΔHa) of a crystal melting point that appears at lower than 190° C. and a melting enthalpy (ΔHb) of a crystal melting point that appears at 190° C. or higher but less than 250° C., respectively, in a temperature-elevation process by a differential scanning calorimeter (DSC), and molded articles thereof.
摘要翻译： 本发明的目的是提供一种含有由生物质资源获得的聚合物的树脂组合物，并且构成耐热性，机械性能和耐久稳定性优异的成型体，本发明包括树脂组合物，其包含（i）含有95〜 5重量％的芳族聚碳酸酯（组分A）和5至95重量％的聚乳酸（组分B），（ii）每100重量份树脂组分0.001至10重量份的磷酸 酯组分C）和（iii）每100重量份聚乳酸（组分B），末端阻断剂（组分F），立体络合物结晶含量（X）为0.01〜5重量份 （I）为80％以上，X（％）= {＆Dgr; Hb /（＆Dgr; Ha +＆Dgr; Hb）}×100（I）其中＆Dgr; Ha和＆Dgr; Hb为熔融 焓（＆Dgr; Ha）的晶体熔点低于190℃，熔融焓（＆Dgr; Hb）为 通过差示扫描量热计（DSC）在升温过程中分别出现在190℃以上但小于250℃的晶体熔点，以及其成型体。
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公开(公告)号：US20090234094A1
公开(公告)日：2009-09-17
申请号：US12089322
申请日：2006-10-04
申请人： Hirotaka Suzuki , Kiyotsuna Toyohara , Shin To
发明人： Hirotaka Suzuki , Kiyotsuna Toyohara , Shin To
IPC分类号： C08G63/08
CPC分类号： C08L67/04 , C08K3/30 , C08K5/098 , C08L2205/02 , C08L2666/18
摘要： A composition which comprises polylactide and has excellent heat stability, color and hydrolytic resistance. The composition comprises (i) polylactide, (ii) a metal catalyst and (iii) a hypophosphorous acid-based deactivator or a metaphosphoric acid-based deactivator.
摘要翻译： 包含聚丙交酯并具有优异的热稳定性，颜色和耐水解性的组合物。 组合物包含（i）聚丙交酯，（ii）金属催化剂和（iii）次磷酸基失活剂或基于偏磷酸的失活剂。
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公开(公告)号：US07365148B2
公开(公告)日：2008-04-29
申请号：US10560934
申请日：2004-06-14
IPC分类号： C08G64/00
CPC分类号： C08G64/183 , C08G64/0208
摘要： A polycarbonate containing an ether diol residue producible from a polysaccharide and expressed by the following formula (1), and a diol residue expressed by the following formula (2) —O—(CmH2m)—O— (2) (here, m is an integer of 2 to 12), wherein said ether diol residue amounts to 65-98 wt. % of all the diol residues, and having a glass transition temperature of 90° C. or higher.
摘要翻译： 含有可由多糖生成并由下式（1）表示的醚二醇残基的聚碳酸酯和由下式（2）表示的二醇残基<？in-line-formula description =“In-line Formulas”end = “（”）“ - O-（C m H 2 m） - O-（2）<？在线公式描述=”在线公式“结束 =“尾”→（这里，m为2〜12的整数），其中所述醚二醇残基为65-98重量％。 所有二醇残基的百分比，玻璃化转变温度为90℃以上。
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29.发明申请Microorganism capable of degrading aromatic polyester and method of degrading aromatic polyester using the same 失效能够降解芳香族聚酯的微生物和使用其降解芳香族聚酯的方法公开(公告)号：US20060228792A1
公开(公告)日：2006-10-12
申请号：US10568754
申请日：2004-08-19
申请人： Kohei Oda , Yoshiharu Kimura , Kazumi Hiraga , Yasuhito Maeda , Kiyotsuna Toyohara , Hiroyoshi Minematsu
发明人： Kohei Oda , Yoshiharu Kimura , Kazumi Hiraga , Yasuhito Maeda , Kiyotsuna Toyohara , Hiroyoshi Minematsu
CPC分类号： C08J11/18 , C08J2367/02 , C12R1/41 , Y02W30/706
摘要： A microorganism which belongs to the genus Rhizobium and has the ability of degrading an aromatic polyester, and a method of degrading an aromatic polyester by using the microorganism. According to this method, the aromatic polyester can be degraded safely and relatively swiftly at a low cost.
摘要翻译： 属于根瘤菌属并具有降解芳族聚酯的能力的微生物，以及使用该微生物降解芳香族聚酯的方法。 根据该方法，芳香族聚酯可以以低成本安全且相对迅速地降解。
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公开(公告)号：US20060149024A1
公开(公告)日：2006-07-06
申请号：US10560934
申请日：2004-06-14
IPC分类号： C08G64/00
CPC分类号： C08G64/183 , C08G64/0208
摘要： A polycarbonate containing an ether diol residue producible from a polysaccharide and expressed by the following formula (1), and a diol residue expressed by the following formula (2) —O—(CmH2m)—O— (2) (here, m is an integer of 2 to 12), wherein said ether diol residue amounts to 65-98 wt. % of all the diol residues, and having a glass transition temperature of 90° C. or higher.
摘要翻译： 含有可由多糖生成并由下式（1）表示的醚二醇残基的聚碳酸酯和由下式（2）表示的二醇残基<？in-line-formula description =“In-line Formulas”end = “（”）“ - O-（C m H 2 m） - O-（2）<？在线公式描述=”在线公式“结束 =“尾”→（这里，m为2〜12的整数），其中所述醚二醇残基为65-98wt。 所有二醇残基的百分比，玻璃化转变温度为90℃以上。
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