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21.发明授权
公开(公告)号：US4916195A
公开(公告)日：1990-04-10
申请号：US199265
申请日：1988-05-09
申请人： Akihiro Kanakura , Yoshio Eguchi , Ryuzo Mizuguchi , Mitsuhiro Takarada , Yoshio Okamura , Hideyuki Itoh
发明人： Akihiro Kanakura , Yoshio Eguchi , Ryuzo Mizuguchi , Mitsuhiro Takarada , Yoshio Okamura , Hideyuki Itoh
IPC分类号： C08G77/06 , C08G77/28 , C08G77/38 , C08G77/388 , C08G77/42
CPC分类号： C08G77/42
摘要： The invention concerns a novel process for the preparation of poly(N-acylethyleneimine) grafted polysiloxanes comprising sulfo-esterifying all or part of alcoholic hydroxyl groups of a hydroxy containing polysiloxane and conducting, in said sulfo-esterification reaction mixture, ring-opening polymerization of a 2-oxazoline compound. The present process can afford the desired poly(N-acylethyleneimine) grafted polysiloxane in a higher reaction yield.
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公开(公告)号：US4888406A
公开(公告)日：1989-12-19
申请号：US135302
申请日：1987-12-21
IPC分类号： C08F30/08 , C08F8/42 , C08F220/10 , C08F220/18 , C08F230/08
CPC分类号： C08F8/42 , C08F230/08
摘要： A novel class of polymerizable monomers containing silicons represented by the formula: ##STR1## wherein R.sup.1 represents a substituted or unsubstituted monovalent hydrocarbon residue; R.sup.2 represents an alkylene attached to silicon atom and selected from an unsubstituted alkylene, a substituted alkylene, an unsubstituted alkylene containing hetero atoms or a substituted alkylene containing hetero atoms; m and n each represents a positive number which will fulfil the requirement of 2.ltoreq.m+n.ltoreq.4; R.sup.3 is hydrogen or methyl; A is a direct bond, ##STR2## or a substituted or unsubstituted phenylene; B is ##STR3## R.sup.4 and R.sup.5 each represents an alkylene, providing that when A represents ##STR4## m+n is 2. The invention also provides a preparation method thereof.
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公开(公告)号：US5916980A
公开(公告)日：1999-06-29
申请号：US943158
申请日：1997-10-03
申请人： Noriyoshi Ogawa , Jun Tajima , Mitsuhiro Takarada , Masaki Tanaka
发明人： Noriyoshi Ogawa , Jun Tajima , Mitsuhiro Takarada , Masaki Tanaka
IPC分类号： C08G64/18 , C08G77/448 , C08J5/18 , C08L69/00 , C08G64/00
CPC分类号： C08J5/18 , C08G64/186 , C08G77/448 , C08L69/00 , C08J2369/00
摘要： A polycarbonate polymer and resin composition having excellent transparency and abrasion resistance, comprising a mixture of (i) a polycarbonate polymer having a repeating unit having a specific grafted polysiloxane structure, and (ii) from 0 to 20 wt % of a diorganopolysiloxane. The polycarbonate polymer is obtained by reacting (a) a specific polysiloxane compound and (b) a specific bisphenol compound with (c) a carbonate ester forming compound.
摘要翻译： 具有优异的透明性和耐磨性的聚碳酸酯聚合物和树脂组合物，包含（i）具有特定接枝聚硅氧烷结构的重复单元的聚碳酸酯聚合物和（ii）0-20重量％的二有机聚硅氧烷的混合物。 聚碳酸酯聚合物通过（a）特定的聚硅氧烷化合物和（b）特定的双酚化合物与（c）形成碳酸酯的化合物反应而获得。
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24.发明授权Coating composition for carriers for use in electrophotography and carriers using the same 失效用于电子照相用载体的涂料组合物及其使用的载体
公开(公告)号：US5468825A
公开(公告)日：1995-11-21
申请号：US185354
申请日：1994-01-24
IPC分类号： C09D183/04 , G03G9/113 , C08G77/08
CPC分类号： G03G9/1136 , C09D183/04 , Y10S528/901
摘要： A coating composition for carriers which are adapted for use in electrophotography is described. The composition comprises an organopolysiloxane of the following average unit formula (1)R.sup.1.sub.a Si(OR.sup.2).sub.b O.sub.[4-(a+b)]/2 (1)wherein R.sup.1 represents an alkyl group having from 1 to 10 carbon atoms or a phenyl group, R.sup.2 represents a hydrogen atom or an alkyl, alkenyl or alkoxyalkyl group, each having from 1 to 10 carbon atoms for the alkyl and alkenyl and from 2 to 10 carbon atoms for the alkoxyalkyl, a is a value of 0.8.ltoreq.a.ltoreq.1.8, b is a value of 0
摘要翻译： 描述适用于电子照相术的用于载体的涂料组合物。 该组合物包含以下平均单元式（1）的有机聚硅氧烷：R1aSi（OR2）bO [4-（a + b）] / 2（1）其中R1表示具有1-10个碳原子的烷基或苯基 ，R2表示氢原子或烷基，烯基或烷氧基烷基，其烷基和烯基具有1-10个碳原子，对于烷氧基烷基具有2至10个碳原子，a为0.8 < /=1.8，b为0
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25.发明授权Curable resin composition comprising a silicone resin having epoxy and phenyl groups in the molecule and a vinyl polymer having a group reactive with the epoxy group 失效可固化树脂组合物包含分子中具有环氧基和苯基的有机硅树脂和具有与环氧基反应的基团的乙烯基聚合物
公开(公告)号：US5464901A
公开(公告)日：1995-11-07
申请号：US210401
申请日：1994-03-18
申请人： Yuji Yoshikawa , Mitsuhiro Takarada
发明人： Yuji Yoshikawa , Mitsuhiro Takarada
IPC分类号： C08G59/40 , C08G59/20 , C08G59/42 , C08G59/50 , C08G81/02 , C08L57/00 , C08L63/00 , C08L83/06 , C09D163/00 , C09D183/06 , C08L83/04
摘要： A curable resin composition comprises (A) a silicone resin having epoxy and phenyl groups and at least two hydrolyzable silyl groups and/or silanol groups in one molecule, (B) a vinyl polymer having a group or groups reactive with the epoxy group in the ingredient (A), and (C) a condensation catalyst for the silicone resin.
摘要翻译： 一种可固化树脂组合物包含（A）具有环氧基和苯基的硅氧烷树脂和一个分子中的至少两个可水解甲硅烷基和/或硅烷醇基团，（B）具有与环氧基反应的基团的乙烯基聚合物 成分（A）和（C）硅氧烷树脂的缩合催化剂。
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公开(公告)号：US5416147A
公开(公告)日：1995-05-16
申请号：US165803
申请日：1993-12-14
IPC分类号： C08K5/56 , C08K5/00 , C08L33/00 , C08L33/04 , C08L63/00 , C08L67/00 , C08L67/06 , C08L83/04 , C08L83/05 , C08L83/07 , C08L83/10 , C08L101/00 , C08K5/098 , C08K5/04
CPC分类号： C08L67/06 , C08K5/0025 , C08L101/00 , C08L63/00 , C08L83/10
摘要： A blend of (A) an acrylic, polyester or epoxy resin having at least two alkenyl or alkynyl groups in a molecule, (B) an organic silicon compound having at least two hydrogen atoms each directly attached to a silicon atom in a molecule, and (C) a hydrosilylaion catalyst is blended with (D) an organic iron or aluminum compound to form a hydrosilylative composition. Component (D) scavenges a catalyst poison, permitting components (A) and (B) to undergo hydrosilylation reaction with the aid of catalyst (C).
摘要翻译： （A）在分子中具有至少两个烯基或炔基的丙烯酸，聚酯或环氧树脂的共混物，（B）具有至少两个氢原子的有机硅化合物，每个氢原子分别直接连接到分子中的硅原子，以及 （C）将氢化甲硅烷基化催化剂与（D）有机铁或铝化合物混合以形成氢化硅烷化组合物。 组分（D）清除催化剂毒物，允许组分（A）和（B）借助催化剂（C）进行氢化硅烷化反应。
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27.发明授权
公开(公告)号：US5157086A
公开(公告)日：1992-10-20
申请号：US721830
申请日：1991-06-26
申请人： Akihiro Kanakura , Yoshio Eguchi , Ryuzo Mizuguchi , Mitsuhiro Takarada , Yoshio Okamura , Hideyuki Itoh
发明人： Akihiro Kanakura , Yoshio Eguchi , Ryuzo Mizuguchi , Mitsuhiro Takarada , Yoshio Okamura , Hideyuki Itoh
IPC分类号： C08G77/42
CPC分类号： C08G77/42
摘要： The invention concerns a novel process for the preparation of poly(N-acylethyleneimine) grafted poysiloxanes comprising sulfoesterifying all or part of alcoholic hydroxyl groups of a hydroxy containing polysiloxane and conducting, in said sulfoesterification reaction mixture, ring-opening polymerization of a 2-oxazoline compound. The present process can afford the desired poly(N-acylethyleneimine) grafted polysiloxane in a higher reaction yield. The invention also provides novel poly(N-acylethyleneimine) grafted polysiloxanes.
摘要翻译： 本发明涉及一种制备聚（N-烷基亚乙基亚胺）接枝聚硅氧烷的新方法，其包括将含羟基聚硅氧烷的全部或部分醇羟基磺化，并在所述磺化酯化反应混合物中导入2-恶唑啉的开环聚合 复合。 本方法可以以更高的反应产率提供所需的聚（N-烷基亚乙基亚胺）接枝的聚硅氧烷。 本发明还提供了新的聚（N-酰基亚乙基亚胺）接枝的聚硅氧烷。
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公开(公告)号：US5134191A
公开(公告)日：1992-07-28
申请号：US478522
申请日：1990-02-12
IPC分类号： C09D183/04 , C09D183/06
CPC分类号： C09D183/04 , C09D183/06
摘要： A hard coating composition comprising an epoxy group-containing organic silicon compound and inorganic submicron particles such as silica sol is curable with a minimal amount of an antimony compound as the curing catalyst. The composition is thus stable during shelf storage and can be cured to a plastic optical article as a mar resistant hard coating film.
摘要翻译： 包含含环氧基的有机硅化合物和无机亚微米颗粒如硅溶胶的硬涂层组合物可用最少量的锑化合物作为固化催化剂固化。 因此，组合物在储存期间是稳定的，并且可以固化成塑料光学制品作为耐腐蚀性硬涂膜。
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公开(公告)号：US5068301A
公开(公告)日：1991-11-26
申请号：US404544
申请日：1989-09-08
IPC分类号： C09D183/04 , G03G9/113
CPC分类号： G03G9/1137 , C09D183/04 , G03G9/1136
摘要： A coating composition to form a coat on the surface of electrophotographic carrier which imparts excellent durability, moisture resistance and flowability to the carrier comprises:(A) 100 parts by weight of an organopolysiloxane of the general formula;R.sub.a X.sub.b SiO.sub.(4-(a+b))/z wherein R represents a substituted or unsubstituted hydrocarbon residue; X represents a hydroxyl group, or a hydrolizable group; "a" is a number in the range of 0.8
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30.发明授权Alkoxysilylated acrylic or vinylic resin containing primer compositions 失效含有底漆组合物的烷氧基甲硅烷基化丙烯酸或乙烯基树脂
公开(公告)号：US5025049A
公开(公告)日：1991-06-18
申请号：US530596
申请日：1990-05-30
申请人： Mitsuhiro Takarada , Kazuharu Sato
发明人： Mitsuhiro Takarada , Kazuharu Sato
IPC分类号： C09D5/00 , C08J7/04 , C08L33/06 , C08L43/04 , C09D133/06 , C09D143/04 , C09J5/02 , C09J11/06 , C09J201/00
CPC分类号： C09D133/06 , C09D143/04 , C08L33/06 , C08L43/04
摘要： A primer composition dilluted with a suitable organic solvent comprising (A) an organic copolymer comprising an alkoxysilylated monomer, vinyl acetate and other monomers copolymerizable therewith, (B) a polyalkyl (meth)acrylate, (C) a crosslinking agent for said copolymer (A), and (D) an ultraviolet absorber. This primer composition is a very effective primer in forming an organopolysiloxane coating layer excellent in adhesion, endurance, weathering resistance of the surface of a molded article of a thermoplastic resin.
摘要翻译： 一种用合适的有机溶剂稀释的底漆组合物，其包含（A）包含烷氧基甲硅烷基化单体，乙酸乙烯酯和可与其共聚的其它单体的有机共聚物，（B）聚（甲基）丙烯酸烷基酯，（C）所述共聚物的交联剂 ），（D）紫外线吸收剂。 该底漆组合物是形成热塑性树脂的成型体的表面的粘合性，耐久性，耐候性优异的有机聚硅氧烷涂层的非常有效的底漆。
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