公开(公告)号：US4916195A

公开(公告)日：1990-04-10

申请号：US199265

申请日：1988-05-09

申请人： Akihiro Kanakura ,  Yoshio Eguchi ,  Ryuzo Mizuguchi ,  Mitsuhiro Takarada ,  Yoshio Okamura ,  Hideyuki Itoh

发明人： Akihiro Kanakura ,  Yoshio Eguchi ,  Ryuzo Mizuguchi ,  Mitsuhiro Takarada ,  Yoshio Okamura ,  Hideyuki Itoh

IPC分类号： C08G77/06 ,  C08G77/28 ,  C08G77/38 ,  C08G77/388 ,  C08G77/42

CPC分类号： C08G77/42

摘要： The invention concerns a novel process for the preparation of poly(N-acylethyleneimine) grafted polysiloxanes comprising sulfo-esterifying all or part of alcoholic hydroxyl groups of a hydroxy containing polysiloxane and conducting, in said sulfo-esterification reaction mixture, ring-opening polymerization of a 2-oxazoline compound. The present process can afford the desired poly(N-acylethyleneimine) grafted polysiloxane in a higher reaction yield.

公开(公告)号：US5157086A

公开(公告)日：1992-10-20

申请号：US721830

申请日：1991-06-26

申请人： Akihiro Kanakura ,  Yoshio Eguchi ,  Ryuzo Mizuguchi ,  Mitsuhiro Takarada ,  Yoshio Okamura ,  Hideyuki Itoh

发明人： Akihiro Kanakura ,  Yoshio Eguchi ,  Ryuzo Mizuguchi ,  Mitsuhiro Takarada ,  Yoshio Okamura ,  Hideyuki Itoh

IPC分类号： C08G77/42

CPC分类号： C08G77/42

摘要： The invention concerns a novel process for the preparation of poly(N-acylethyleneimine) grafted poysiloxanes comprising sulfoesterifying all or part of alcoholic hydroxyl groups of a hydroxy containing polysiloxane and conducting, in said sulfoesterification reaction mixture, ring-opening polymerization of a 2-oxazoline compound. The present process can afford the desired poly(N-acylethyleneimine) grafted polysiloxane in a higher reaction yield. The invention also provides novel poly(N-acylethyleneimine) grafted polysiloxanes.

摘要翻译： 本发明涉及一种制备聚（N-烷基亚乙基亚胺）接枝聚硅氧烷的新方法，其包括将含羟基聚硅氧烷的全部或部分醇羟基磺化，并在所述磺化酯化反应混合物中导入2-恶唑啉的开环聚合 复合。 本方法可以以更高的反应产率提供所需的聚（N-烷基亚乙基亚胺）接枝的聚硅氧烷。 本发明还提供了新的聚（N-酰基亚乙基亚胺）接枝的聚硅氧烷。

公开(公告)号：US5066720A

公开(公告)日：1991-11-19

申请号：US313231

申请日：1989-02-21

申请人： Hiroharu Ohsugi ,  Akihiro Kanakura ,  Hirotoshi Umemoto ,  Yoshio Okamura ,  Mitsuhiro Takarada ,  Kenji Yamamoto

发明人： Hiroharu Ohsugi ,  Akihiro Kanakura ,  Hirotoshi Umemoto ,  Yoshio Okamura ,  Mitsuhiro Takarada ,  Kenji Yamamoto

IPC分类号： C08L83/06 ,  C09D133/06 ,  C09D183/06 ,  C09D201/06

CPC分类号： C09D183/06 ,  C09D133/06 ,  C09D201/06 ,  C08L83/06

摘要： A resinous composition for coating use comprising(a) 3 to 70% by weight of organopolysiloxane represented by the formula:R.sup.1.sub.n R.sup.2.sub.m SiO.sub.(4-n-m)/2 wherein R.sup.1 represents hydrogen, allyloxy group, an alkoxy group having 1 to 20 carbon atoms, an aryl group, methyl group, or an organic group having 2 to 100 carbon atoms; R.sup.2 is a hydroxyl group bearing organic group having 2 to 100 carbon atoms; m and n each represents a positive number fulfilling the requirements of 0

公开(公告)号：US4888406A

公开(公告)日：1989-12-19

申请号：US135302

申请日：1987-12-21

申请人： Hiroharu Ohsugi ,  Yoshio Eguchi ,  Satoshi Urano ,  Ryuzo Mizuguchi ,  Mitsuhiro Takarada

发明人： Hiroharu Ohsugi ,  Yoshio Eguchi ,  Satoshi Urano ,  Ryuzo Mizuguchi ,  Mitsuhiro Takarada

IPC分类号： C08F30/08 ,  C08F8/42 ,  C08F220/10 ,  C08F220/18 ,  C08F230/08

CPC分类号： C08F8/42 ,  C08F230/08

摘要： A novel class of polymerizable monomers containing silicons represented by the formula: ##STR1## wherein R.sup.1 represents a substituted or unsubstituted monovalent hydrocarbon residue; R.sup.2 represents an alkylene attached to silicon atom and selected from an unsubstituted alkylene, a substituted alkylene, an unsubstituted alkylene containing hetero atoms or a substituted alkylene containing hetero atoms; m and n each represents a positive number which will fulfil the requirement of 2.ltoreq.m+n.ltoreq.4; R.sup.3 is hydrogen or methyl; A is a direct bond, ##STR2## or a substituted or unsubstituted phenylene; B is ##STR3## R.sup.4 and R.sup.5 each represents an alkylene, providing that when A represents ##STR4## m+n is 2. The invention also provides a preparation method thereof.

公开(公告)号：US5416147A

公开(公告)日：1995-05-16

申请号：US165803

申请日：1993-12-14

申请人： Mitsuhiro Takarada ,  Yuji Yoshikawa ,  Hiroharu Ohsugi ,  Yoshio Eguchi

发明人： Mitsuhiro Takarada ,  Yuji Yoshikawa ,  Hiroharu Ohsugi ,  Yoshio Eguchi

IPC分类号： C08K5/56 ,  C08K5/00 ,  C08L33/00 ,  C08L33/04 ,  C08L63/00 ,  C08L67/00 ,  C08L67/06 ,  C08L83/04 ,  C08L83/05 ,  C08L83/07 ,  C08L83/10 ,  C08L101/00 ,  C08K5/098 ,  C08K5/04

CPC分类号： C08L67/06 ,  C08K5/0025 ,  C08L101/00 ,  C08L63/00 ,  C08L83/10

摘要： A blend of (A) an acrylic, polyester or epoxy resin having at least two alkenyl or alkynyl groups in a molecule, (B) an organic silicon compound having at least two hydrogen atoms each directly attached to a silicon atom in a molecule, and (C) a hydrosilylaion catalyst is blended with (D) an organic iron or aluminum compound to form a hydrosilylative composition. Component (D) scavenges a catalyst poison, permitting components (A) and (B) to undergo hydrosilylation reaction with the aid of catalyst (C).

摘要翻译： （A）在分子中具有至少两个烯基或炔基的丙烯酸，聚酯或环氧树脂的共混物，（B）具有至少两个氢原子的有机硅化合物，每个氢原子分别直接连接到分子中的硅原子，以及 （C）将氢化甲硅烷基化催化剂与（D）有机铁或铝化合物混合以形成氢化硅烷化组合物。 组分（D）清除催化剂毒物，允许组分（A）和（B）借助催化剂（C）进行氢化硅烷化反应。

公开(公告)号：US5068301A

公开(公告)日：1991-11-26

申请号：US404544

申请日：1989-09-08

申请人： Yoshio Okamura ,  Mitsuhiro Takarada ,  Yoshiteru Kobayashi ,  Tadashi Takahashi

发明人： Yoshio Okamura ,  Mitsuhiro Takarada ,  Yoshiteru Kobayashi ,  Tadashi Takahashi

IPC分类号： C09D183/04 ,  G03G9/113

CPC分类号： G03G9/1137 ,  C09D183/04 ,  G03G9/1136

摘要： A coating composition to form a coat on the surface of electrophotographic carrier which imparts excellent durability, moisture resistance and flowability to the carrier comprises:(A) 100 parts by weight of an organopolysiloxane of the general formula;R.sub.a X.sub.b SiO.sub.(4-(a+b))/z wherein R represents a substituted or unsubstituted hydrocarbon residue; X represents a hydroxyl group, or a hydrolizable group; "a" is a number in the range of 0.8

摘要翻译： 赋予载体优异的耐久性，耐湿性和流动性的电子照相载体表面上形成涂层的涂料组合物包括：（A）100重量份的通式的有机聚硅氧烷; RaXbSiO（4-（a + b））/ z其中R表示取代或未取代的烃残基; X表示羟基或可水解基团; “a”是在0.8

公开(公告)号：US5248750A

公开(公告)日：1993-09-28

申请号：US783973

申请日：1991-10-29

申请人： Mitsuhiro Takarada ,  Yuji Yoshikawa ,  Kenichi Isobe

发明人： Mitsuhiro Takarada ,  Yuji Yoshikawa ,  Kenichi Isobe

IPC分类号： C08G77/14 ,  C08G77/12 ,  C08G77/20 ,  C08G77/22 ,  C08G77/38

CPC分类号： C08G77/38 ,  C08G77/12 ,  C08G77/20

摘要： Organopolysiloxanes having two different functional groups selected from the group consisting of 3-glycidoxy-propyl, 2-(3',4'-epoxycyclohexyl)ethyl, 3-hydroxypropyl, 3-(2'-hydroxyethoxy)propyl, 3-acryloxypropyl, and 3-methacryloxypropyl groups are more compatible with organic resins and more effective for tailoring the organic resins. They are produced by hydrosilylation of organohydrogenpolysiloxanes with functional group-containing alkenes.

公开(公告)号：US20060000356A1

公开(公告)日：2006-01-05

申请号：US10531719

申请日：2003-11-26

申请人： Yasuyoshi Tomoe ,  Makoto Shimizu ,  Mitsuhiro Takarada ,  Teruki Ikeda ,  Yoshitaka Aoki

发明人： Yasuyoshi Tomoe ,  Makoto Shimizu ,  Mitsuhiro Takarada ,  Teruki Ikeda ,  Yoshitaka Aoki

IPC分类号： B01D53/14

CPC分类号： C10L3/102 ,  B01D19/0409 ,  B01D53/1456 ,  B01D53/1493 ,  C10L3/10 ,  C23F11/06 ,  B01D19/0413

摘要： A method for removing an acidic gas from a raw gas containing the acid gas by contacting the raw gas with an aqueous alkanol amine solution, characterized in that a composition comprising an organopolysiloxane containing a polyoxyalkylene group and a fine silica powder is caused to be present. In some embodiments, a composition comprising the above-mentioned organopolysiloxane and a fine silica powder is added appropriately according to the state of foaming in an acidic gas removing reaction system from the outside of the system, or use is made of an alkanol amine containing in advance a composition comprising the above-mentioned organopolysiloxane and a fine silica powder. In preferred embodiments, the fine silica powder has a specific surface area of 50 m2/g or more, and/or the composition comprising the above-mentioned organopolysiloxane and a fine silica powder is used in an amount of 0.1 to 5000 ppm relative to the alkanol amine. As a further embodiment, a method for removing an acidic gas from a raw gas by contacting the raw gas with an aqueous alkanol amine solution containing 40 mass % or more of an alkanol amine, characterized in that a composition comprising the above-mentioned organopolysiloxane and a fine silica powder is caused to be present in an amount of 0.1 to 5000 ppm relative to the alkanol amine.

摘要翻译： 使原料气体与烷醇胺溶液接触，从含有酸性气体的原料气体中除去酸性气体的方法，其特征在于，含有含有聚氧化烯基的有机聚硅氧烷和二氧化硅微粉末的组合物存在。 在一些实施方案中，包含上述有机聚硅氧烷和二氧化硅细粉末的组合物根据酸性气体除去反应体系中的发泡状态从系统外部适当添加，或者使用含有 推进包含上述有机聚硅氧烷和二氧化硅微粉的组合物。 在优选的实施方案中，二氧化硅微粉的比表面积为50m 2 / g以上，和/或包含上述有机聚硅氧烷和二氧化硅微粉的组合物的用量 相对于链烷醇胺为0.1〜5000ppm。 作为另一实施方案，通过使原料气体与含有40质量％以上的链烷醇胺的烷醇胺水溶液接触，从原料气体中除去酸性气体的方法，其特征在于，含有上述有机聚硅氧烷和 相对于链烷醇胺，二氧化硅微粉末的存在量为0.1〜5000ppm。

公开(公告)号：US5567561A

公开(公告)日：1996-10-22

申请号：US300011

申请日：1994-09-02

申请人： Yuji Yoshikawa ,  Mitsuhiro Takarada

发明人： Yuji Yoshikawa ,  Mitsuhiro Takarada

IPC分类号： C08G77/24 ,  C09D183/04 ,  C09D183/08 ,  G03G9/113

CPC分类号： C08G77/24 ,  C09D183/08 ,  G03G9/1136 ,  G03G9/1138 ,  Y10T428/2995

摘要： Coating agents for electrophotography carriers are disclosed which are resistant to wear, peel-off, cracks, and prevent the occurrence of a spent phenomenon, and which possess a durability for a long period of use and a superior stability in the carrier charge characteristics. The coating provides long lifetime electrophotography carriers which possess reduced temperature dependency and improved stability in the carrier charge characteristics.The coating agents for the electrophotography carrier are characterized by having an organopolysiloxane expressed by the formula below as a main component:R.sub.a.sup.f R.sub.b.sup.1 Si(OR.sup.2).sub.c O.sub.(4-(a+b+c))/2IwhereinR.sup.f is C.sub.p F.sub.2p+1 Q;p is 1-12;Q is a bivalent organic group with 2-12 carbon atoms;R.sup.1 is alkyl with 1-12 carbon atoms or phenyl;R.sup.2 is H or alkyl with 1-6 carbon atoms; anda, b and c are numbers satisfying the following conditions:0

摘要翻译： 公开了耐磨损，剥离，裂纹，防止出现现象的电子照相载体用涂料，其具有长时间使用的耐久性和载体电荷特性优异的稳定性。 涂层提供长寿命的电子照相载体，其具有降低的温度依赖性和改善载体电荷特性的稳定性。 电子照相载体的涂层剂的特征在于具有由下式表示的有机聚硅氧烷作为主要成分：RafRb1Si（OR2）cO（4-（a + b + c））/ 2I，其中Rf为CpF2p + 1Q; p为1-12; Q是具有2-12个碳原子的二价有机基团; R1是具有1-12个碳原子的烷基或苯基; R2是H或具有1-6个碳原子的烷基; 和a，b和c是满足以下条件的数字：0 和0

公开(公告)号：US5457166A

公开(公告)日：1995-10-10

申请号：US278193

申请日：1994-07-21

申请人： Yuji Yoshikawa ,  Tadashi Takahashi ,  Mitsuhiro Takarada

发明人： Yuji Yoshikawa ,  Tadashi Takahashi ,  Mitsuhiro Takarada

IPC分类号： C08G63/695 ,  C08G77/445 ,  C09D183/10 ,  C08F20/00

CPC分类号： C09D183/10 ,  C08G63/6954 ,  C08G77/445

摘要： A process for preparing a polyester-modified silicone resin comprises mixing an alkoxysilane and/or its hydrolyzate, i.e. an alkoxysiloxane, and a polyester resin having at least two hydroxyl groups in the molecule, and subjecting the mixture to hydrolysis and polycondensation reactions in the presence of an acid catalyst. This process is performed by a continuous one-stage reaction sequence including hydrolysis, polycondensation and modification and is simplified. A composition comprising the polyester-modified silicone resin is also described. The composition comprising organozinc compounds along with the modified silicone resin is significantly improved in heat resistance and color-difference.

摘要翻译： 制备聚酯改性有机硅树脂的方法包括在分子中混合烷氧基硅烷和/或其水解产物，即烷氧基硅氧烷和具有至少两个羟基的聚酯树脂，并在该存在下使混合物进行水解和缩聚反应 的酸催化剂。 该方法通过包括水解，缩聚和改性的连续一步反应顺序进行，并被简化。 还描述了包含聚酯改性的有机硅树脂的组合物。 包含有机锌化合物以及改性有机硅树脂的组合物的耐热性和色差显着提高。