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公开(公告)号：US20120156588A1
公开(公告)日：2012-06-21
申请号：US13307745
申请日：2011-11-30
CPC分类号： H01M8/103 , H01M8/1048 , H01M8/1051 , H01M8/106 , H01M8/1067 , Y02E60/521
摘要： The present invention relates to a membrane electrode assembly comprising at least two electrochemically active electrodes which are separated by at least one polymer electrolyte membrane, the aforementioned polymer electrolyte membrane having at least one reinforcement, wherein the reinforcement comprises at least one film which has holes through which the polymer electrolyte membrane is in contact with both electrochemically active electrodes.The membrane electrode assembly is suitable for applications in fuel cells, especially in high-temperature polymer electrolyte fuel cells.
摘要翻译： 本发明涉及一种膜电极组件，其包括由至少一个聚合物电解质膜隔开的至少两个电化学活性电极，上述聚合物电解质膜具有至少一个增强材料，其中该增强材料包括至少一个具有孔 聚合物电解质膜与两个电化学活性电极接触。 膜电极组件适用于燃料电池，特别是在高温聚合物电解质燃料电池中的应用。
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公开(公告)号：US20110311901A1
公开(公告)日：2011-12-22
申请号：US13115594
申请日：2011-05-25
申请人： Friederike Fleischhaker , Anna Cristadoro , Jörg Belack , Oliver Gronwald , Francisco Javier Lopez Villanueva , Bernd Bruchmann
发明人： Friederike Fleischhaker , Anna Cristadoro , Jörg Belack , Oliver Gronwald , Francisco Javier Lopez Villanueva , Bernd Bruchmann
CPC分类号： C08G73/18 , C08G73/0616 , C08G73/0627 , C08G73/0633 , C08L79/04 , H01M8/103 , H01M8/1051 , H01M8/1088 , H01M8/109 , H01M2008/1095 , Y02E60/521 , Y02P70/56 , C08L71/02
摘要： A process for preparing mechanically stabilized polyazoles, comprising the following steps: I) treating at least one polyazole having at least one amino group in a repeat unit with a solution comprising (i) at least one strong acid and (ii) at least one stabilizing reagent, the total content of stabilizing reagents in the solution being in the range from 0.01 to 30% by weight, II) performing the stabilization reaction directly and/or in a subsequent processing step by heating to a temperature greater than 25° C., using at least one high-functionality polyether as the stabilizing reagent. The polyazoles thus obtainable are notable especially for a high conductivity and a very good mechanical stability. They are therefore especially suitable for applications in fuel cells.
摘要翻译： 一种制备机械稳定化的多唑的方法，包括以下步骤：I）用包含（i）至少一种强酸和（ii）至少一种稳定的酸的溶液，在重复单元中处理至少一种具有至少一个氨基的聚唑 试剂，溶液中稳定试剂的总含量在0.01至30重量％的范围内，II）直接和/或在随后的加工步骤中通过加热至大于25℃的温度进行稳定化反应， 使用至少一种高官能度聚醚作为稳定剂。 因此获得的聚唑特别是对于高导电性和非常好的机械稳定性而言尤其如此。 因此，它们特别适用于燃料电池中的应用。
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23.发明授权Mechanically stabilized polyazoles comprising at least one polyvinyl alcohol 有权包含至少一种聚乙烯醇的机械稳定化的多唑类公开(公告)号：US09006339B2
公开(公告)日：2015-04-14
申请号：US13467485
申请日：2012-05-09
CPC分类号： C08G73/22 , C08G73/0616 , C08G73/0633 , C08G73/0694 , C08G73/08 , C08K3/24 , C08L79/04 , C08L79/06 , C08L29/04
摘要： A process for preparing mechanically stabilized polyazoles, comprising the following steps: I) treating at least one polyazole having at least one amino group in a repeat unit with a solution comprising (i) at least one strong acid and (ii) at least one stabilizing reagent, the total content of stabilizing reagents in the solution being in the range from 0.01 to 30% by weight, II) performing the stabilization reaction directly and/or in a subsequent processing step by heating to a temperature greater than 25° C., the stabilizing reagent used being at least one polyvinyl alcohol. The polyazoles thus obtainable are notable especially for a high conductivity and a very good mechanical stability. They are therefore especially suitable for applications in fuel cells.
摘要翻译： 一种制备机械稳定化的多唑的方法，包括以下步骤：I）用重复单元处理至少一种具有至少一个氨基的多唑，所述溶液包含（i）至少一种强酸和（ii）至少一种稳定的 试剂，溶液中稳定试剂的总含量在0.01至30重量％的范围内，II）直接和/或在随后的加工步骤中通过加热至大于25℃的温度进行稳定化反应， 使用的稳定剂为至少一种聚乙烯醇。 因此获得的聚唑特别是对于高导电性和非常好的机械稳定性而言尤其如此。 因此，它们特别适用于燃料电池中的应用。
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公开(公告)号：US08815467B2
公开(公告)日：2014-08-26
申请号：US13307690
申请日：2011-11-30
IPC分类号： H01M8/10
CPC分类号： H01M8/103 , C08J5/2206 , C08J2361/00 , H01M8/1032 , H01M8/1034 , H01M8/1041 , H01M8/1067 , H01M8/1069 , Y02P70/56
摘要： The present invention relates to a membrane electrode assembly comprising at least two electrochemically active electrodes separated by at least one polymer electrolyte membrane, the aforementioned polymer electrolyte membrane having fibrous reinforcing elements which at least partly penetrate the polymer electrolyte membrane, wherein at least some of the fibrous reinforcing elements have functional groups which have a covalent chemical bond between the fibers and the polymer of the polymer electrolyte membrane.The membrane electrode assembly is suitable for applications in fuel cells, especially in high-temperature polymer electrolyte fuel cells.
摘要翻译： 本发明涉及一种膜电极组件，其包括由至少一个聚合物电解质膜隔开的至少两个电化学活性电极，上述聚合物电解质膜具有至少部分地穿透聚合物电解质膜的纤维增强元件，其中至少一些 纤维增强元件具有在纤维和聚合物电解质膜的聚合物之间具有共价化学键的官能团。 膜电极组件适用于燃料电池，特别是在高温聚合物电解质燃料电池中的应用。
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25.发明申请COMPOSITE, ITS PRODUCTION AND ITS USE IN SEPARATORS FOR ELECTROCHEMICAL CELLS 审中-公开复合材料，其生产及其在电化学细胞分离器中的应用公开(公告)号：US20130189550A1
公开(公告)日：2013-07-25
申请号：US13748243
申请日：2013-01-23
申请人： Nicole Janssen , Arno Lange , Helmut Moehwald , Oliver Gronwald
发明人： Nicole Janssen , Arno Lange , Helmut Moehwald , Oliver Gronwald
IPC分类号： H01M2/16
CPC分类号： H01M2/1633 , H01M2/162 , H01M10/052
摘要： The present invention relates to a novel composite which comprises at least one base body composed of nonwoven as component (A), at least one nanocomposite as component (B), at least one polyether or at least one polyether-comprising radical as component (C) and optionally a lithium salt as component (D).The invention further relates to a process for producing the novel composite, its use in separators for electrochemical cells and also specific starting compounds which can be used for producing nanocomposites (B).
摘要翻译： 本发明涉及一种新型复合材料，它包括至少一种由非织造材料（A）组成的至少一个基体，至少一种作为组分（B）的纳米复合材料，至少一种聚醚或至少一种含聚醚的基团作为组分（C ）和任选的锂盐作为组分（D）。 本发明还涉及一种生产新型复合材料的方法，其用于电化学电池的分离器以及可用于生产纳米复合材料（B）的特定起始化合物。
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公开(公告)号：US08461296B2
公开(公告)日：2013-06-11
申请号：US13428074
申请日：2012-03-23
CPC分类号： C08G73/22 , C08G73/06 , C08G73/0616 , C08G73/0633 , C08G73/0694 , C08J5/2287 , C08J2379/04 , C08L79/04 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1044 , H01M8/1048 , H01M8/1051 , H01M8/1067 , H01M8/1088 , H01M8/109 , Y02P70/56
摘要： The invention relates to a process for preparing mechanically stabilized polyazole polymers. The process includes the steps of: a) producing a film comprising polyazoles with at least one amino group in a repeat unit, b) treating the film from step a) with a solution comprising (i) at least one acid and (ii) at least one stabilizing reagent, and c) performing the stabilization reaction in the membrane obtained in step directly or in a subsequent membrane processing step by heating to a temperature greater than 60° C. The stabilizing reagent contains at least one compound which has at least one aldehyde group and at least one hydroxyl group; or at least one hemiacetal group; or at least one acetal group. These polyazole polymer membranes have a high conductivity and a good mechanical stability and are suitable for applications in fuel cells.
摘要翻译： 本发明涉及制备机械稳定化的聚唑聚合物的方法。 该方法包括以下步骤：a）在重复单元中产生包含具有至少一个氨基的多唑类的膜，b）用包含（i）至少一种酸的溶液和（ii）在 至少一种稳定剂，以及c）通过加热到大于60℃的温度，在直接或随后的膜处理步骤中获得的膜中进行稳定化反应。稳定剂含有至少一种具有至少一种 醛基和至少一个羟基; 或至少一个半缩醛基团; 或至少一个缩醛基团。 这些聚唑聚合物膜具有高导电性和良好的机械稳定性，适用于燃料电池。
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公开(公告)号：US20120264030A1
公开(公告)日：2012-10-18
申请号：US13444235
申请日：2012-04-11
CPC分类号： H01M8/103 , B01D67/0002 , C08G73/06 , C08G73/22 , C08K3/32 , C08L79/04 , Y02E60/521
摘要： The present invention relates to improved membrane electrode assemblies and fuel cells with long lifetime, comprising two electrochemically active electrodes separated by a polymer electrolyte membrane based on polyoxazoles.
摘要翻译： 本发明涉及具有长寿命的改进的膜电极组件和燃料电池，其包括由基于聚恶唑的聚合物电解质膜隔开的两个电化学活性电极。
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公开(公告)号：US20120231365A1
公开(公告)日：2012-09-13
申请号：US13509432
申请日：2010-11-12
申请人： Oliver Gronwald , Jörg Belack , Jochen Baurmeister , Thomas Justus Schmidt , Seongwoo Choi , Jung Ock Park , Woo Sung Jeon , Jung Seok Yi
发明人： Oliver Gronwald , Jörg Belack , Jochen Baurmeister , Thomas Justus Schmidt , Seongwoo Choi , Jung Ock Park , Woo Sung Jeon , Jung Seok Yi
CPC分类号： H01M8/0291 , H01M8/0289 , H01M2008/1095 , Y02E60/50 , Y02P70/56
摘要： A method for the production of mechanically stabilized polyazole polymers, comprising the following steps: a) providing a membrane comprising i.) polyazoles with at least one amino group in a repeating unit except the ones obtainable by reacting aromatic and/or heteroaromatic diaminocarboxylic acids, ii.) at least one strong acid and iii.) at least one stabilizing reagent, the total content of stabilizing reagents in the membrane being within the range of from 0.01 to 30% by weight, b) performing the stabilization reaction in the membrane, immediately or in a subsequent processing step of the membrane, c) if appropriate, additionally doping the membrane obtained in accordance with step b) with a strong acid or concentrating the present strong acid further by removal of present water, wherein the stabilizing agent comprises at least one oxazine-based compound. The polyazole polymer membranes thus obtainable are in particular characterized by a high conductivity and a very good mechanical stability. Therefore, they are in particular suited for applications in fuel cells.
摘要翻译： 一种生产机械稳定化的聚唑聚合物的方法，包括以下步骤：a）提供一种膜，其包含i。）除了通过芳香族和/或杂芳族二氨基羧酸反应得到的重氮单元以外的至少一个氨基的多唑类， ii）至少一种强酸和iii）至少一种稳定剂，所述膜中的稳定剂的总含量在0.01至30重量％的范围内，b）在膜中进行稳定化反应， 立即或在随后的膜处理步骤中，c）如果合适，另外用强酸掺杂根据步骤b）获得的膜，或通过除去现有水进一步浓缩本发明的强酸，其中稳定剂包括 至少一种基于恶嗪的化合物。 因此可获得的聚唑聚合物膜的特征在于具有高导电性和非常好的机械稳定性。 因此，它们特别适用于燃料电池中的应用。
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公开(公告)号：US20120141908A1
公开(公告)日：2012-06-07
申请号：US13307690
申请日：2011-11-30
CPC分类号： H01M8/103 , C08J5/2206 , C08J2361/00 , H01M8/1032 , H01M8/1034 , H01M8/1041 , H01M8/1067 , H01M8/1069 , Y02P70/56
摘要： The present invention relates to a membrane electrode assembly comprising at least two electrochemically active electrodes separated by at least one polymer electrolyte membrane, the aforementioned polymer electrolyte membrane having fibrous reinforcing elements which at least partly penetrate the polymer electrolyte membrane, wherein at least some of the fibrous reinforcing elements have functional groups which have a covalent chemical bond between the fibers and the polymer of the polymer electrolyte membrane.The membrane electrode assembly is suitable for applications in fuel cells, especially in high-temperature polymer electrolyte fuel cells.
摘要翻译： 本发明涉及一种膜电极组件，其包括由至少一个聚合物电解质膜隔开的至少两个电化学活性电极，上述聚合物电解质膜具有至少部分地穿透聚合物电解质膜的纤维增强元件，其中至少一些 纤维增强元件具有在纤维和聚合物电解质膜的聚合物之间具有共价化学键的官能团。 膜电极组件适用于燃料电池，特别是在高温聚合物电解质燃料电池中的应用。
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公开(公告)号：US07473748B2
公开(公告)日：2009-01-06
申请号：US11038571
申请日：2005-01-21
IPC分类号： C08F12/30
摘要： A superacidic ester group is useful in the production of ionomers for polymer electrolyte fuel cells. A polymer is produced from said vinyl monomer. A process produces a polymer containing a superacidic group. The vinyl monomer contains a haloalkyl ester group of a superacid, wherein the number of carbon atoms of the haloalkyl ester group is no more than 10, and the halogen in the haloalkyl group is chlorine and/or fluorine. A polymer containing said vinyl monomer as a repeating unit can be converted to a polymer containing a superacid group using at least one procedure of 1) heat treating at 50°C. to 350°C., and 2) contacting with a protic compound.
摘要翻译： 超酸酯基团可用于生产用于聚合物电解质燃料电池的离聚物。 由所述乙烯基单体制备聚合物。 一种方法产生含有超酸性基团的聚合物。 乙烯基单体含有超酸的卤代烷基酯基，其中卤代烷基酯基的碳原子数不超过10，卤代烷基中的卤素是氯和/或氟。 含有所述乙烯基单体作为重复单元的聚合物可以使用至少一种在50℃下进行热处理的方法转化成含有超强酸基团的聚合物。 至350℃，和2）与质子化合物接触。
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