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公开(公告)号：US06800783B2
公开(公告)日：2004-10-05
申请号：US10204619
申请日：2002-09-05
Applicant: Helmut Springer , Peter Lappe
Inventor： Helmut Springer , Peter Lappe
IPC: C07C51235
CPC classification number: C07C51/235 , Y02P20/582 , C07C53/126 , C07C53/124
Abstract: The invention relates to a method for the synthesis of aliphatic carboxylic acids by the catalytic oxidation of aldehydes with oxygen, or oxygen-containing gas mixtures. Metals of groups 5 11 of the periodic table of elements, or the compounds thereof are used as catalyst, in amounts of up to 5 ppm, based upon the amount of aldehyde used.
Abstract translation: 本发明涉及通过用氧或含氧气体混合物催化氧化醛来合成脂族羧酸的方法。 基于元素周期表的第5组11的金属或其化合物，以所使用的醛的量为基准，最多可用量为5ppm。
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22.发明授权Mixtures of isomeric pentanoic acids, esters prepared therefrom, and their use as lubricants 失效异构戊酸的混合物，由其制备的酯及其作为润滑剂的用途
公开(公告)号：US5410072A
公开(公告)日：1995-04-25
申请号：US311557
申请日：1994-09-23
Applicant: Helmut Bahrmann , Wolfgang Greb , Georg Dambkes , Peter Heymanns , Heinz Kalbfell , Peter Lappe , Helmut Springer , Eberhard von Mulmann , Jurgen Weber , Ernst Wiebus , Carl D. Frohning , Harald Kappesser
Inventor： Helmut Bahrmann , Wolfgang Greb , Georg Dambkes , Peter Heymanns , Heinz Kalbfell , Peter Lappe , Helmut Springer , Eberhard von Mulmann , Jurgen Weber , Ernst Wiebus , Carl D. Frohning , Harald Kappesser
IPC: B01J31/24 , C07B61/00 , C07C45/50 , C07C51/235 , C07C53/126 , C07C53/128 , C07C69/22 , C07C69/33 , C10M105/32 , C10M105/34 , C10M105/38 , C10M171/00 , C10N40/30 , C10N70/00
CPC classification number: C10M171/008 , C07C45/50 , C07C53/126 , C07C53/128 , C10M105/38 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2211/022 , C10M2211/06 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66
Abstract: Isomeric mixtures of pentanoic acids are prepared by subjecting butene-1/butene-2 mixtures to hydroformylation to form aldehyde mixtures, followed by oxidation of the aldehyde mixtures which have been separated off from the reaction product. The hydroformylation is carried out in a heterogeneous system in the presence of rhodium catalysts which are dissolved in water. The mixture of isomeric 5 carbon monocarboxylic acids produced, when esterified with polyhydric alcohols, yields mixtures of isomeric esters which are useful as lubricants for refrigerant compressors operated with chlorine-free, at least partly fluorinated hydrocarbons as the refrigerant.
Abstract translation: 戊烯的异构混合物是通过使丁烯-1 /丁烯-2混合物进行加氢甲酰化形成醛混合物，然后氧化从反应产物中分离的醛混合物来制备的。 加氢甲酰化在异相体系中在溶解在水中的铑催化剂存在下进行。 当用多元醇酯化时，产生异构体5碳一元羧酸的混合物产生异构酯的混合物，其可用作用于无氯，至少部分氟化的烃作为制冷剂的制冷剂压缩机的润滑剂。
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公开(公告)号：US5354911A
公开(公告)日：1994-10-11
申请号：US178634
申请日：1994-01-07
Applicant: Jurgen Weber , Peter Lappe , Helmut Springer
Inventor： Jurgen Weber , Peter Lappe , Helmut Springer
CPC classification number: C07C41/28
Abstract: A process for the preparation of ethers of the formula R.sup.1 --CR.sup.2 .dbd.CH--O--R.sup.3, in which R.sup.1 and R.sup.3 are each a radical having 1 to 6 carbon atoms and R.sup.2 is hydrogen or a radical having 1 to 2 carbon atoms, by reaction of a diacetal of the formula R.sup.1 --CHR.sup.2 --CH(--O--R.sup.3).sub.2 in the presence of a catalyst composed of an acid and an amine at elevated temperature in the liquid phase. The unsaturated ether of the above-mentioned formula is formed from the diacetal with elimination of an alcohol R.sup.3 --OH.
Abstract translation: 制备式R1-CR2 = CH-O-R3的醚的方法，其中R 1和R 3各自为具有1至6个碳原子且R 2为氢或具有1至2个碳原子的基团，通过 在液相中在升高的温度下，在由酸和胺组成的催化剂存在下，式R 1 -CH 2 -CH（-O-R 3）2的二缩醛的反应。 上述式的不饱和醚由二缩醛形成，除去醇R3-OH。
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24.发明授权Process for the recovery of rhodium from residues of the distillation of products of the oxo synthesis 失效用于从羰基合成产物的蒸馏残余物中回收铑的方法
公开(公告)号：US5264600A
公开(公告)日：1993-11-23
申请号：US855731
申请日：1992-03-20
Applicant: Peter Lappe , Helmut Springer
Inventor： Peter Lappe , Helmut Springer
IPC: B01J31/24 , B01J31/40 , B01J38/00 , B01J38/58 , C07B61/00 , C07C45/50 , C07C47/02 , C07C67/313 , C07C69/716 , C22B11/00 , C07F15/00
CPC classification number: B01J31/1845 , B01J31/185 , B01J31/24 , B01J31/2404 , B01J31/4046 , B01J38/58 , C07C45/50 , C07C67/293 , C07C67/54 , B01J2231/321 , B01J2531/822 , B01J31/04 , B01J31/26 , Y02P20/584
Abstract: Recovery of rhodium from the distillation residues from the crude products of oxo synthesis, the residue or the starting material containing the residue is treated with oxygen or an oxygen-containing gas in the presence of a monocarboxylic acid with 2 to 5 carbon atoms and of an alkali metal salt of a monocarboxylic acid with 2 to 5 carbon atoms. The rhodium is subsequently extracted with water as a water-soluble compound.
Abstract translation: 从含氧合成的粗产物的蒸馏残余物中回收铑，残余物或含有残余物的原料在具有2-5个碳原子的一元羧酸存在下用氧或含氧气体处理， 具有2至5个碳原子的一元羧酸的碱金属盐。 随后用水将铑作为水溶性化合物萃取。
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25.发明授权
公开(公告)号：US5072037A
公开(公告)日：1991-12-10
申请号：US632471
申请日：1990-12-21
Applicant: Jurgen Weber , Peter Lappe , Helmut Springer
Inventor： Jurgen Weber , Peter Lappe , Helmut Springer
IPC: B01J23/755 , C07B61/00 , C07C45/49 , C07C45/74 , C07C51/16 , C07C51/235 , C07C51/285 , C07C51/29 , C07C57/58
CPC classification number: C07C51/285 , C07C45/49 , C07C45/74 , C07C51/16 , C07C51/29
Abstract: A process for the preparation of 2-(4-chlorophenyl)-3-methylbutyric acid from 4-chlorobenzaldehyde by conversion of the benzaldehyde to 3-(4-chlorophenyl)-2-methylpropenal, 3-(4-chlorophenyl)-2-methylpropanol, 1-(4-chlorophenyl)-2-methylpropene-1, and 2-(4-chlorophenyl)-2-methylbutyraldehyde, and finally to the desired corresponding butyric acid.
Abstract translation: 通过将苯甲醛转化为3-（4-氯苯基）-2-甲基丙醛，3-（4-氯苯基）-2-甲基丙酸，由4-氯苯甲醛制备2-（4-氯苯基）-3-甲基丁酸的方法， 甲基丙醇，1-（4-氯苯基）-2-甲基丙烯-1和2-（4-氯苯基）-2-甲基丁醛，最后到所需的对应的丁酸。
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Patent Agency Ranking
公开(公告)号：US4918247A
公开(公告)日：1990-04-17
申请号：US361711
申请日：1989-05-26
Applicant: Norbert Breitkopf , Wolfgang Hofs , Heinz Kalbfell , Franz Thonnessen , Peter Lappe , Helmut Springer
Inventor： Norbert Breitkopf , Wolfgang Hofs , Heinz Kalbfell , Franz Thonnessen , Peter Lappe , Helmut Springer
Abstract: Preparation of 2,2-dimethylpropanediol-1,3 by the aldol addition of isobutyraldehyde and formaldehyde using tri-n-propylamine as a catalyst, followed by hydrogenation of the reaction mixture, and subsequent distillation of the hydrogenation product in the presence of isobutanol and water.
Abstract translation: 通过使用三正丙胺作为催化剂通过醛醇醛加成异丁醛和甲醛制备2,2-二甲基丙二醇-1,3-，随后氢化反应混合物，随后在异丁醇存在下蒸馏氢化产物， 水。
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公开(公告)号：US06696582B2
公开(公告)日：2004-02-24
申请号：US10204286
申请日：2002-09-10
Applicant: Helmut Springer , Peter Heymanns
Inventor： Helmut Springer , Peter Heymanns
IPC: C07C5116
CPC classification number: C07C51/235 , Y02P20/582 , C07C53/126
Abstract: The invention relates to a method for producing aliphatic carboxylic acids from aldehydes by means of oxidation with oxygen or gases containing oxygen. This novel process is carried out in at least two stages at different temperatures, preferably in the absence of catalysts.
Abstract translation: 本发明涉及通过氧气或含氧气体从醛制备脂族羧酸的方法。 该新方法在不同温度下进行至少两个阶段，优选在不存在催化剂的情况下进行。
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公开(公告)号：US4515986A
公开(公告)日：1985-05-07
申请号：US294114
申请日：1981-08-19
Applicant: Wolfgang Bernhagen , Volker Falk , Helmut Springer , Jurgen Weber , Ernst Wiebus , Claus Kniep
Inventor： Wolfgang Bernhagen , Volker Falk , Helmut Springer , Jurgen Weber , Ernst Wiebus , Claus Kniep
IPC: C07C223/02 , C07C85/00 , C07C85/18
CPC classification number: C07C221/00
Abstract: An improved process for preparing 3-dimethylamino-2,2-dimethylpropanal from isobutyraldehyde, dimethylamine and a source of formaldehyde is disclosed wherein the process is carried out at a pH value of 9 to 11.
Abstract translation: 公开了一种由异丁醛，二甲胺和甲醛源制备3-二甲基氨基-2,2-二甲基丙醛的改进方法，其中该方法在pH值为9至11的条件下进行。
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公开(公告)号：US4275242A
公开(公告)日：1981-06-23
申请号：US106314
申请日：1979-12-21
Applicant: Jurgen Weber , Wolfgang Bernhagen , Helmut Springer
Inventor： Jurgen Weber , Wolfgang Bernhagen , Helmut Springer
Abstract: A process for preparing 2-methylenealdehydes by reacting aldehydes with formaldehyde in the presence of enamines is disclosed.
Abstract translation: 公开了一种在烯胺存在下使醛与甲醛反应制备2-甲基醛的方法。
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公开(公告)号：US4270008A
公开(公告)日：1981-05-26
申请号：US83893
申请日：1979-10-11
Applicant: Jurgen Weber , Wolfgang Bernhagen , Helmut Springer
Inventor： Jurgen Weber , Wolfgang Bernhagen , Helmut Springer
IPC: A61K8/33 , A61Q13/00 , C07C41/28 , C07C43/15 , C07C45/00 , C07C45/51 , C07C47/21 , C07C67/00 , C11B9/00
CPC classification number: C11B9/0015 , C07C41/28 , C07C45/513 , C07C45/515 , C07C47/21 , Y02P20/582
Abstract: 2-Propyl-pent-4-en-1-al of the formula ##STR1## and a process for its preparation.
Abstract translation: 2-丙基 - 戊-4-烯-1-al及其制备方法。
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