Use of polyaspartic acid in detergents and cleaners
    22.
    发明授权
    Use of polyaspartic acid in detergents and cleaners 失效
    在洗涤剂和清洁剂中使用聚天冬氨酸

    公开(公告)号:US5770553A

    公开(公告)日:1998-06-23

    申请号:US646263

    申请日:1996-05-20

    摘要: The use of polyaspartic acid prepared by polycondensation of aspartic acid in the presence of phosphoric acid in a molar ratio of from 1:0.05 to 1:10 at temperatures of at least 120.degree. C. to give polysuccinimide, and subsequent hydrolysis of the polysuccinimide with bases to give at least partially neutralized polyaspartic acid, as additive to detergents and cleaners in amounts of from 0.1 to 10% by weight, and detergents and cleaners which contain polyaspartic acids prepared in the presence of phosphoric acid.

    摘要翻译: PCT No.PCT / EP94 / 04057 Sec。 371日期:1996年5月20日 102(e)日期1996年5月20日PCT 1994年12月6日PCT PCT。 WO95 / 16020PC PCT出版物 日期:1995年6月15日使用通过在磷酸存在下天冬氨酸以1:0.05至1:10的摩尔比在至少120℃的温度下缩聚制备的聚天冬氨酸,得到聚琥珀酰亚胺,随后 用碱进行聚琥珀酰亚胺的水解,得到至少部分中和的聚天冬氨酸,其量为0.1至10重量%的洗涤剂和清洁剂的添加剂,以及含有在磷酸存在下制备的聚天冬氨酸的洗涤剂和清洁剂。

    Polymers containing polyacetal blocks, their preparation and their use
    23.
    发明授权
    Polymers containing polyacetal blocks, their preparation and their use 失效
    含聚缩醛嵌段的聚合物,其制备及其用途

    公开(公告)号:US5756594A

    公开(公告)日:1998-05-26

    申请号:US934084

    申请日:1997-09-19

    摘要: Polymers which contain polyacetal blocks are obtainable by polymerizing carboxylates containing aldehyde groups in the presence of initiators and reacting the polymers with at least bifunctional crosslinking agents in the presence of acids or Lewis acids and, if required hydrolyzing the ester groups present as polymerized units, process for the preparation of the polymers containing polyacetal blocks by polymerizing carboxylates containing aldehyde groups in the presence of initiators and reacting the resulting polyacetals containing terminal hydroxyl groups with at least bifunctional crosslinking agents in the presence of acids or Lewis acids, and the use of the resulting polymers as additives in phosphate-free and reduced phosphate detergents and cleaning agents, as scale inhibitors and as dispersants for pigments.

    摘要翻译: 含有聚缩醛嵌段的聚合物可以通过在引发剂的存在下聚合含有醛基的羧酸盐并在酸或路易斯酸存在下使聚合物与至少两官能交联剂反应,并且如果需要,水解作为聚合单元存在的酯基, 在含有聚缩醛嵌段的聚合物的制备中,在引发剂的存在下聚合含有醛基的羧酸酯,并在酸或路易斯酸的存在下使含有末端羟基的所得聚缩醛与至少两官能交联剂反应, 聚合物作为添加剂,在无磷酸盐和还原性磷酸盐洗涤剂和清洁剂中作为阻垢剂和作为颜料的分散剂。

    Block copolyacetals, preparation thereof and use thereof in detergents
and cleaners
    27.
    发明授权
    Block copolyacetals, preparation thereof and use thereof in detergents and cleaners 失效
    封闭共聚缩醛,其制备方法及其在洗涤剂和清洁剂中的应用

    公开(公告)号:US5466762A

    公开(公告)日:1995-11-14

    申请号:US397051

    申请日:1995-03-13

    摘要: There are described block copolyacetals obtainable by cationically initiated polyaddition of(A) polyacetals containing acetaldehyde acetal units and having at least 2 OH groups in the molecule and(B) polyacetals containing acetaldehyde acetal units and having at least 2 vinyl ether groups in the molecule.in a molar ratio of (A):(B) of from 2:1 to 1:2, processes for preparing the block copolyacetals by cationically initiated polyaddition of (A) and (B), and the use of the block polyacetals as additament to reduced-phosphate and phosphate-free detergents and cleaners and as low-foam surfactants in dishwashing compositions.

    摘要翻译: 描述了通过阳离子引发的(A)含有乙醛缩醛单元的聚缩醛并且在分子中具有至少2个OH基团并且(B)含有乙醛缩醛单元的聚缩醛并且在分子中具有至少2个乙烯基醚基团的聚缩醛获得的嵌段共聚缩醛。 (A):(B)的摩尔比为2:1至1:2,通过(A)和(B)的阳离子引发加聚制备嵌段共聚缩醛的方法,以及嵌段聚缩醛作为添加剂的用途 至减少磷酸盐和无磷酸盐的洗涤剂和清洁剂以及作为洗碗组合物中的低泡表面活性剂。