SYSTEMS AND STRIPPABLE COATINGS FOR DECONTAMINATING STRUCTURES THAT INCLUDE POROUS MATERIAL
    24.
    发明申请
    SYSTEMS AND STRIPPABLE COATINGS FOR DECONTAMINATING STRUCTURES THAT INCLUDE POROUS MATERIAL 有权
    用于去除包括多孔材料的结构的系统和可剥离涂层

    公开(公告)号:US20100206345A1

    公开(公告)日:2010-08-19

    申请号:US12704409

    申请日:2010-02-11

    IPC分类号: B08B7/00 B08B3/04

    摘要: Methods of removing contaminant matter from porous materials include applying a polymer material to a contaminated surface, irradiating the contaminated surface to cause redistribution of contaminant matter, and removing at least a portion of the polymer material from the surface. Systems for decontaminating a contaminated structure comprising porous material include a radiation device configured to emit electromagnetic radiation toward a surface of a structure, and at least one spray device configured to apply a capture material onto the surface of the structure. Polymer materials that can be used in such methods and systems include polyphosphazine-based polymer materials having polyphosphazine backbone segments and side chain groups that include selected functional groups. The selected functional groups may include iminos, oximes, carboxylates, sulfonates, β-diketones, phosphine sulfides, phosphates, phosphites, phosphonates, phosphinates, phosphine oxides, monothio phosphinic acids, and dithio phosphinic acids.

    摘要翻译: 从多孔材料去除污染物质的方法包括将聚合物材料施加到污染的表面上,照射被污染的表面以引起污染物质的再分配,以及从表面除去至少一部分聚合物材料。 用于净化包括多孔材料的污染结构的系统包括被配置为朝向结构的表面发射电磁辐射的辐射装置和被配置为将捕获材料施加到结构的表面上的至少一个喷射装置。 可以用于这些方法和体系的聚合物材料包括具有多聚磷腈骨架链段的聚磷腈基聚合物材料和包括选定官能团的侧链基团。 所选择的官能团可以包括亚氨基,肟,羧酸盐,磺酸盐,二酮,硫化膦,磷酸盐,亚磷酸盐,膦酸盐,次膦酸盐,氧化膦,一硫次膦酸和二硫次膦酸。

    Polyphosphazine-based polymer materials
    25.
    发明授权
    Polyphosphazine-based polymer materials 有权
    聚合基膦基聚合物材料

    公开(公告)号:US07723463B2

    公开(公告)日:2010-05-25

    申请号:US11279414

    申请日:2006-04-12

    IPC分类号: C08G79/02

    摘要: Methods of removing contaminant matter from porous materials include applying a polymer material to a contaminated surface, irradiating the contaminated surface to cause redistribution of contaminant matter, and removing at least a portion of the polymer material from the surface. Systems for decontaminating a contaminated structure comprising porous material include a radiation device configured to emit electromagnetic radiation toward a surface of a structure, and at least one spray device configured to apply a capture material onto the surface of the structure. Polymer materials that can be used in such methods and systems include polyphosphazine-based polymer materials having polyphosphazine backbone segments and side chain groups that include selected functional groups. The selected functional groups may include iminos, oximes, carboxylates, sulfonates, β-diketones, phosphine sulfides, phosphates, phosphites, phosphonates, phosphinates, phosphine oxides, monothio phosphinic acids, and dithio phosphinic acids.

    摘要翻译: 从多孔材料去除污染物质的方法包括将聚合物材料施加到污染的表面上,照射被污染的表面以引起污染物质的再分配,以及从表面除去至少一部分聚合物材料。 用于净化包括多孔材料的污染结构的系统包括被配置为朝向结构的表面发射电磁辐射的辐射装置和被配置为将捕获材料施加到结构的表面上的至少一个喷射装置。 可以用于这些方法和体系的聚合物材料包括具有多聚磷腈骨架链段的聚磷腈基聚合物材料和包括选定官能团的侧链基团。 所选择的官能团可以包括亚氨基,肟,羧酸盐,磺酸盐,二酮,硫化膦,磷酸盐,亚磷酸盐,膦酸盐,次膦酸盐,氧化膦,一硫次膦酸和二硫次膦酸。

    Production of biodiesel using expanded gas solvents
    26.
    发明授权
    Production of biodiesel using expanded gas solvents 有权
    使用膨胀气体溶剂生产生物柴油

    公开(公告)号:US07514575B2

    公开(公告)日:2009-04-07

    申请号:US11123607

    申请日:2005-05-06

    IPC分类号: C11C1/00 C11C3/00

    摘要: A method of producing an alkyl ester. The method comprises providing an alcohol and a triglyceride or fatty acid. An expanding gas is dissolved into the alcohol to form a gas expanded solvent. The alcohol is reacted with the triglyceride or fatty acid in a single phase to produce the alkyl ester. The expanding gas may be a nonpolar expanding gas, such as carbon dioxide, methane, ethane, propane, butane, pentane, ethylene, propylene, butylene, pentene, isomers thereof, and mixtures thereof, which is dissolved into the alcohol. The gas expanded solvent may be maintained at a temperature below, at, or above a critical temperature of the expanding gas and at a pressure below, at, or above a critical pressure of the expanding gas.

    摘要翻译: 一种制备烷基酯的方法。 该方法包括提供醇和甘油三酯或脂肪酸。 将膨胀气体溶解到醇中以形成气体膨胀溶剂。 醇与甘油三酯或脂肪酸在单相中反应以产生烷基酯。 膨胀气体可以是溶解在醇中的非极性膨胀气体,例如二氧化碳,甲烷,乙烷,丙烷,丁烷,戊烷,乙烯,丙烯,丁烯,戊烯,其异构体及其混合物。 气体膨胀溶剂可以保持在膨胀气体的临界温度以下,低于或等于膨胀气体的临界压力或高于膨胀气体的临界压力的压力的温度以下。

    Method for making an energetic material
    27.
    发明授权
    Method for making an energetic material 失效
    制作精力充沛的材料的方法

    公开(公告)号:US07345208B2

    公开(公告)日:2008-03-18

    申请号:US11231142

    申请日:2005-09-19

    申请人: Robert V. Fox

    发明人: Robert V. Fox

    IPC分类号: C07C205/06 C06B25/08

    摘要: A method for making trinitrotoluene is described, and which includes the steps of providing a source of aqueous nitric acid having a concentration of less than about 95% by weight; mixing a surfactant with the source of aqueous nitric acid so as to dehydrate the aqueous nitric acid to produce a source of nitronium ions; providing a supercritical carbon dioxide environment; providing a source of an organic material to be nitrated to the supercritical carbon dioxide environment; and controllably mixing the source or nitronium ions with the supercritical carbon dioxide environment to nitrate the organic material and produce trinitrotoluene.

    摘要翻译: 描述了制备三硝基甲苯的方法,其包括以下步骤:提供浓度小于约95重量%的硝酸水溶液源; 将表面活性剂与硝酸水溶液混合以使硝酸水溶液脱水以产生硝鎓离子源; 提供超临界二氧化碳环境; 提供要对超临界二氧化碳环境进行硝化的有机材料的来源; 并将可控地将源或硝鎓离子与超临界二氧化碳环境混合,使有机物硝酸化并产生三硝基甲苯。

    Method for destroying halocarbon compositions using a critical solvent
    28.
    发明授权
    Method for destroying halocarbon compositions using a critical solvent 失效
    使用临界溶剂破坏卤代烃组合物的方法

    公开(公告)号:US06984768B2

    公开(公告)日:2006-01-10

    申请号:US10152599

    申请日:2002-05-21

    IPC分类号: A62D3/00

    CPC分类号: A62D3/34 A62D3/37 A62D2101/22

    摘要: A method for destroying halocarbons. Halocarbon materials are reacted in a dehalogenation process wherein they are combined with a solvent in the presence of a catalyst. A hydrogen-containing solvent is preferred which functions as both a solvating agent and hydrogen donor. To augment the hydrogen donation capacity of the solvent if needed (or when non-hydrogen-containing solvents are used), a supplemental hydrogen donor composition may be employed. In operation, at least one of the temperature and pressure of the solvent is maintained near, at, or above a critical level. For example, the solvent may be in (1) a supercritical state; (2) a state where one of the temperature or pressure thereof is at or above critical; or (3) a state where at least one of the temperature and pressure thereof is near-critical. This system provides numerous benefits including improved reaction rates, efficiency, and versatility.

    摘要翻译: 一种破坏卤代烃的方法。 卤代烃材料在脱卤方法中反应,其中它们在催化剂存在下与溶剂组合。 优选含氢溶剂,其既用作溶剂化剂又可用作氢供体。 为了增加溶剂的氢气供应能力(如果需要的话)(或者当使用不含氢的溶剂时),可以使用补氢供体组合物。 在操作中,溶剂的温度和压力中的至少一个保持接近,等于或高于临界水平。 例如,溶剂可以是(1)超临界状态; (2)其温度或压力之一处于或超过临界状态; 或(3)至少其中一个温度和压力接近临界的状态。 该系统提供了许多好处,包括提高反应速率,效率和多功能性。