Abstract:
A nonaqueous electrolyte secondary battery according to an embodiment of the present disclosure includes a negative electrode mixture layer which contains a first region located in a flat part of an electrode body and second regions located in a pair of curved parts of the electrode body, the ratio (B/A) of the packing density (B) in each of the second regions to the packing density (A) in the first region being 0.75 or more and 0.95 or less. Further, in a section passing through the center in the axial direction of the electrode body and being perpendicular to the axial direction, the ratio (SB/SA) of the sectional area (SB) of the pair of curved parts to the sectional area (SA) of the flat part is 0.28 or more and 0.32 or less.
Abstract:
A method for manufacturing a nonaqueous electrolyte secondary battery which includes an electrode assembly, a housing with an opening and contains the electrode assembly, and a sealing member sealing the opening, the electrode assembly comprising a positive electrode and a negative electrode. The positive electrode includes a positive electrode active material, lithium carbonate, and lithium phosphate, the negative electrode comprising a negative electrode active material. The method includes placing the electrode assembly in the housing, and placing a nonaqueous electrolyte containing lithium fluorosulfonate in the housing.
Abstract:
A non-aqueous electrolyte secondary battery of one example according to an embodiment has an output of 1,000 W or more. An electrode body includes a protective layer which contains an insulating inorganic compound and which is provided on at least one surface of a positive electrode, a negative electrode, and a separator, and has a heat capacity per unit battery capacity of 16 J/K·Ah or more. The positive electrode has a surface resistance of 0.5 to 40Ω.
Abstract:
A nonaqueous electrolyte secondary battery includes: an electrode assembly including positive and negative electrode plates; a nonaqueous electrolyte; an outer body; and a current interruption mechanism being provided on at least one of a conductive pathway between the positive electrode plate and a positive electrode external terminal and a conductive pathway between the negative electrode plate and a negative electrode external terminal. The nonaqueous electrolyte contains an overcharge inhibitor. The positive electrode active material layer has a specific surface area of 1.3 m2/g or less. The positive electrode active material layer has a total surface area of 41 m2/g or less with respect to the total mass of the overcharge inhibitor in the nonaqueous electrolyte. Thus the battery can increase a battery internal pressure inside the outer body in a short period of time to activate the current interruption mechanism to interrupt the conductive pathway if the battery is overcharged.
Abstract:
A stacked electrode assembly is arranged inside an aluminum laminated outer body. At least one of a positive electrode terminal and a negative electrode terminal satisfies Formula (1) below. A nonaqueous electrolyte contains LiBOB and/or a boron-containing substance derived from LiBOB. The battery has a capacity of 10 Ah or larger. The sectional area of the terminal (mm2)/a current value of 1.0 It (A)≦0.3 (mm2/A) (1)
Abstract:
Provided is a method of manufacturing a nonaqueous electrolyte secondary battery. The method includes: forming an electrode assembly including a positive electrode plate and a negative electrode plate disposed with a separator interposed therebetween; arranging the electrode assembly and a nonaqueous electrolyte containing LiBOB (lithium bis(oxalato)borate) and LiPF2O2 (lithium difluorophosphate) inside an outer body; and configuring the concentration of the LiBOB to be larger than that of the LiPF2O2 and to be smaller than that of the LiPF2O2 by charge and discharge.
Abstract translation:提供一种制造非水电解质二次电池的方法。 该方法包括:形成电极组件,该电极组件包括:正极板和设置有间隔件的负极板; 将电极组件和含有LiBOB(双(草酸)硼酸锂)和LiPF 2 O 2(二氟磷酸锂)的非水电解质放置在外体内; 并且将LiBOB的浓度配置为大于LiPF 2 O 2的浓度,并且通过充放电比LiPF 2 O的浓度小。
Abstract:
A nonaqueous electrolyte secondary battery includes a current interruption mechanism in at least one of a conductive pathway from the positive electrode sheet to the outside of the outer body and a conductive pathway from the negative electrode sheet to the outside of the outer body. The current interruption mechanism interrupts electric current when the pressure in the outer body exceeds a predetermined value. The nonaqueous electrolyte contains an overcharge inhibitor. The overcharge inhibitor is contained in an amount of 3.0% or more and 4.5% or less with respect to the spatial volume in the outer body in terms of volume ratio. The nonaqueous electrolyte secondary battery has excellent output characteristics in a low temperature condition and can sufficiently ensure reliability even when the battery is overcharged through two-step charging in a low temperature condition.
Abstract:
A non-aqueous electrolyte secondary battery including a positive electrode core; a positive electrode plate having a positive electrode active material layer formed on the positive electrode core; a negative electrode plate; a flat wound electrode assembly in which the positive electrode plate and the negative electrode plate are wound with a separator therebetween; and a non-aqueous electrolyte, wherein the positive electrode active material is a manganese-containing lithium transition metal composite oxide, the BET specific surface area of the positive electrode active material is 2.0-3.0 m2/g, the total surface area of the positive electrode active material contained in the positive electrode active material layer is 70-90 m2, and the value of A/B is 0.03-0.09 (μmol/m2), where A (μmol) is the total amount of FSO3 contained in the non-aqueous electrolyte, and B (m2) is the total area of the positive electrode active material contained in the positive electrode active material layer.
Abstract:
A non-aqueous electrolyte secondary battery comprises: a positive electrode core; a positive electrode plate having a positive electrode active material layer which is formed on the positive electrode core and contains a positive electrode active material; a negative electrode core; a negative electrode plate having a negative electrode active material layer which is formed on the negative electrode core and contains a negative electrode active material; a separator disposed between the positive and negative electrode plates; and a non-aqueous electrolytic solution, wherein the non-aqueous electrolytic solution contains lithium bis(oxalate) borate, and the value of A/B is 2-11, where A (μmol) is the total amount of lithium bis(oxalate) borate contained in the non-aqueous electrolytic solution, and B(m2) is the total area of the negative electrode active material contained in the region of the negative electrode active material layer facing the positive electrode active material layer with the separator therebetween.
Abstract:
A nonaqueous electrolyte secondary battery includes a prismatic housing having an opening and a sealing member sealing the opening. The prismatic housing contains a flat-wound electrode assembly and a nonaqueous electrolyte. The flat-wound electrode assembly includes a positive electrode and a negative electrode. The positive electrode includes a positive electrode substrate and a positive electrode active material mixture layer formed on the positive electrode substrate. The positive electrode active material mixture layer contains lithium carbonate and lithium phosphate. The nonaqueous electrolyte contains lithium fluorosulfonate.