Abstract:
Provided is a non-aqueous electrolyte secondary battery having excellent properties even at low temperatures. The non-aqueous electrolyte secondary battery comprises: an electrode assembly including a positive electrode plate and a negative electrode plate; a non-aqueous electrolyte; an exterior body having an opening, and accommodating the electrode assembly and the non-aqueous electrolyte; and a sealing plate for sealing the opening of the exterior body, wherein the negative electrode plate has a negative electrode core and a negative electrode active material layer formed on the negative electrode core, and the non-aqueous electrolyte contains a non-aqueous solvent, the non-aqueous solvent containing 50-80 vol % of a chain carbonate with respect to the non-aqueous solvent, and containing, as the chain carbonate, 30-40 vol % of dimethyl carbonate, 3-8 vol % of propylene carbonate, and 2-5 vol % of methyl propionate with respect to the non-aqueous solvent.
Abstract:
A battery pack includes a plurality of prismatic secondary batteries with spacers each interposed therebetween. The prismatic secondary batteries each include a flat wound electrode body that is formed by winding a positive electrode plate and a negative electrode plate with a separator interposed therebetween; a prismatic outer body that houses the wound electrode body; and a sealing plate that seals an opening of the flat wound electrode body. The wound electrode body has a wound positive electrode core-exposed portion at one end portion and a wound negative electrode core-exposed portion at the other end portion. A positive electrode current collector is joined to the positive electrode core-exposed portion to form a positive electrode-joined portion, and a negative electrode current collector is joined to the negative electrode core-exposed portion to form a negative electrode-joined portion.
Abstract:
A nonaqueous electrolyte secondary battery includes a prismatic housing having an opening and a sealing member sealing the opening. The prismatic housing contains a flat-wound electrode assembly and a nonaqueous electrolyte. The flat-wound electrode assembly includes a positive electrode and a negative electrode. The positive electrode includes a positive electrode substrate and a positive electrode active material mixture layer formed on the positive electrode substrate. The positive electrode active material mixture layer contains lithium carbonate and lithium phosphate. The nonaqueous electrolyte contains lithium fluorosulfonate.
Abstract:
Provided is a method of manufacturing a nonaqueous electrolyte secondary battery. The method includes: forming an electrode assembly including a positive electrode plate and a negative electrode plate disposed with a separator interposed therebetween; arranging the electrode assembly and a nonaqueous electrolyte containing LiBOB (lithium bis(oxalato)borate) and LiPF2O2 (lithium difluorophosphate) inside an outer body; and configuring the concentration of the LiBOB to be larger than that of the LiPF2O2 and to be smaller than that of the LiPF2O2 by charge and discharge.
Abstract translation:提供一种制造非水电解质二次电池的方法。 该方法包括:形成电极组件,该电极组件包括:正极板和设置有间隔件的负极板; 将电极组件和含有LiBOB(双(草酸)硼酸锂)和LiPF 2 O 2(二氟磷酸锂)的非水电解质放置在外体内; 并且将LiBOB的浓度配置为大于LiPF 2 O 2的浓度,并且通过充放电比LiPF 2 O的浓度小。
Abstract:
To provide with high productivity a non-aqueous electrolyte secondary battery having high capacity and superior low temperature characteristics.The present invention is a non-aqueous electrolyte secondary battery including a positive electrode and a non-aqueous electrolyte containing a non-aqueous solvent, the non-aqueous electrolyte secondary battery characterized in that the non-aqueous solvent includes 30 to 70 vol % ethylene carbonate at 25° C. and 1 atm, the non-aqueous electrolyte includes a total of 0.01 to 0.10 mol/L lithium difluorophosphate and/or lithium monofluorophosphate, and the packing density of the positive electrode active material layer is from 2.0 to 2.8 g/ml.
Abstract:
Each prismatic cell is provided with a rolled electrode assembly, and the rolled electrode assembly has a flat section with a flat outer peripheral surface and two curved sections with a curved outer peripheral surface. Each spacer has a substrate and multiple ribs protruding on at least one side of the substrate, and the ribs are formed so as to face the flat section of the rolled electrode assembly and extend in a direction substantially perpendicular to the rolling axis of the rolled electrode assembly. The ribs have a length of 60 to 100 when the height of the flat section of the rolled electrode assembly is represented by 100, and the relationship 2≤B/A≤10 is satisfied where A is the width of the ribs and B is the distance between adjoining ribs.
Abstract:
A non-aqueous electrolyte secondary battery including a positive electrode core; a positive electrode plate having a positive electrode active material layer formed on the positive electrode core; a negative electrode plate; a flat wound electrode assembly in which the positive electrode plate and the negative electrode plate are wound with a separator therebetween; and a non-aqueous electrolyte, wherein the positive electrode active material is a manganese-containing lithium transition metal composite oxide, the BET specific surface area of the positive electrode active material is 2.0-3.0 m2/g, the total surface area of the positive electrode active material contained in the positive electrode active material layer is 70-90 m2, and the value of A/B is 0.03-0.09 (μmol/m2), where A (μmol) is the total amount of FSO3 contained in the non-aqueous electrolyte, and B (m2) is the total area of the positive electrode active material contained in the positive electrode active material layer.
Abstract:
A nonaqueous electrolyte secondary battery according to an embodiment of the present disclosure includes a separator which contains a first region located in a flat part of an electrode body and second regions located in a pair of curved parts, the ratio (B/A) of the air permeability (B) in each of the second regions to the air permeability (A) in the first region being 0.5 or more and 0.9 or less. Further, in a section passing through the center in the axial direction of the electrode body and being perpendicular to the axial direction, the ratio (SB/SA) of the sectional area (SB) of the pair of curved parts to the sectional area (SA) of the flat part is 0.28 or more and 0.32 or less.
Abstract:
A method for manufacturing a nonaqueous electrolyte secondary battery which includes an electrode assembly, a housing with an opening and contains the electrode assembly, and a sealing member sealing the opening, the electrode assembly comprising a positive electrode and a negative electrode. The positive electrode includes a positive electrode active material, lithium carbonate, and lithium phosphate, the negative electrode comprising a negative electrode active material. The method includes placing the electrode assembly in the housing, and placing a nonaqueous electrolyte containing lithium fluorosulfonate in the housing.
Abstract:
A battery pack includes a plurality of prismatic secondary batteries with spacers each interposed therebetween. The prismatic secondary batteries each include a flat wound electrode body that is formed by winding a positive electrode plate and a negative electrode plate with a separator interposed therebetween; a prismatic outer body that houses the wound electrode body; and a sealing plate that seals an opening of the flat wound electrode body. The wound electrode body has a wound positive electrode core-exposed portion at one end portion and a wound negative electrode core-exposed portion at the other end portion. A positive electrode current collector is joined to the positive electrode core-exposed portion to form a positive electrode-joined portion, and a negative electrode current collector is joined to the negative electrode core-exposed portion to form a negative electrode-joined portion.