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公开(公告)号：US20150158799A1
公开(公告)日：2015-06-11
申请号：US14368523
申请日：2012-12-20
Applicant: SHELL OIL COMPANY
Inventor： Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
IPC: C07C29/141 , C07C45/50
CPC classification number: C07C29/141 , C07C1/20 , C07C1/22 , C07C4/06 , C07C29/16 , C07C45/505 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2529/40 , C07C2529/83 , C07C2529/84 , C07C2529/85 , Y02P30/42
Abstract: The present invention provides a process for the production of alcohols, which process comprises the steps of: (a) reacting an oxygenate and/or olefinic feed in a reactor in the presence of a molecular sieve catalyst to form an effluent comprising olefins, comprising propylene; (b) separating the effluent comprising olefins as obtained in step (a) into at least a first olefinic product fraction comprising propylene and a second olefinic product fraction; (c) subjecting at least part of the first olefinic product fraction as obtained in step (b) to a hydroformylation process to form aldehydes; (d) hydrogenating at least part of the aldehydes as obtained in step (c) to form alcohols; (e) separating at least part of the alcohols as obtained in step (d) into at least a first product fraction of alcohols and a second product fraction of alcohols; and (f) recycling at least part of the first or second product fraction of alcohols to step (a).
Abstract translation: 本发明提供了一种生产醇的方法，该方法包括以下步骤：（a）在分子筛催化剂存在下使反应器中的含氧化合物和/或烯烃进料反应，以形成包含烯烃的流出物，其包含丙烯 ; （b）将步骤（a）中获得的包含烯烃的流出物分离成至少包含丙烯和第二烯属产物馏分的第一烯烃产物级分; （c）将步骤（b）中获得的至少部分第一烯属产物级分进行加氢甲酰化过程以形成醛; （d）氢化步骤（c）中获得的至少部分醛以形成醇; （e）将步骤（d）中获得的至少一部分醇分离成至少第一产物级分的醇和第二产物级分的醇; 和（f）将至少部分第一或第二产物级分的醇再循环到步骤（a）。
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22.发明申请公开(公告)号：US20140357919A1
公开(公告)日：2014-12-04
申请号：US14360855
申请日：2012-11-28
Inventor： Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
CPC classification number: B01J29/90 , B01D53/1493 , B01D53/28 , B01D2252/2023 , B01D2256/12 , B01J29/40 , B01J29/85 , B01J38/12 , C07C1/20 , C07C1/22 , C07C4/06 , C07C2523/02 , C07C2523/04 , C07C2529/40 , C07C2529/70 , Y02P20/584 , Y02P30/42 , C07C11/02
Abstract: The present invention relates to a process for the oxidative regeneration of a deactivated catalyst comprising molecular sieve to provide a regenerated molecular sieve catalyst, wherein said deactivated catalyst is from one or both of an oxygenate to olefin process and a olefin cracking process, said regeneration process comprising at least the steps of providing a regeneration gas stream comprising oxidant; treating the regeneration gas stream with a liquid adsorbent stream comprising an ethylene glycol in a contaminant absorption zone to remove at least a part of one or more of any water, any alkali metal ion and any alkaline earth metal ion present in the regeneration gas stream to provide a treated regeneration gas stream comprising oxidant; regenerating a deactivated catalyst comprising molecular sieve with the treated regeneration gas stream to provide a regenerated catalyst comprising regenerated molecular sieve.
Abstract translation: 本发明涉及包含分子筛的失活催化剂的氧化再生方法，以提供再生分子筛催化剂，其中所述失活催化剂是含氧化合物与烯烃方法中的一种或两种以及烯烃裂解方法，所述再生过程 至少包括提供包含氧化剂的再生气流的步骤; 在污染物吸收区中用包含乙二醇的液体吸附剂流处理再生气流，以将再生气流中存在的任何水，任何碱金属离子和任何碱土金属离子中的一种或多种中的一种或多种除去至 提供包含氧化剂的经处理的再生气流; 使经处理的再生气流再生包含分子筛的失活催化剂以提供包含再生分子筛的再生催化剂。
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23.发明授权Process for the preparation of an olefinic product comprising ethylene and/or propylene 有权制备包含乙烯和/或丙烯的烯烃产物的方法公开(公告)号：US08895792B2
公开(公告)日：2014-11-25
申请号：US14136047
申请日：2013-12-20
Applicant: Shell Oil Company
Inventor： Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
CPC classification number: C07C1/22 , C07C1/20 , C07C11/04 , C07C11/06 , C07C29/74 , C07C29/76 , C07C31/04 , C07C2529/40 , C07C2529/70 , C07C2529/83 , C07C2529/84 , C07C2529/85 , Y02P30/42 , C07C11/02
Abstract: An oxygenate to olefins (OTO) process, comprising the steps of: (i) purifying an oxygenate feedstream comprising one or more ionic contaminants by contacting the feedstream with a membrane, resulting in the formation of a retentate and a permeate separated by the membrane, which permeate is a purified oxygenate stream which contains a lower ionic contaminant concentration than the original oxygenate feedstream; (ii) introducing the purified oxygenate stream into an oxygenate to olefins reaction zone; and (iii) contacting the purified oxygenate stream with a molecular sieve catalyst in the oxygenate to olefins reaction zone to form a product stream comprising olefins.
Abstract translation: 一种含氧化合物至烯烃（OTO）方法，包括以下步骤：（i）通过使进料流与膜接触，纯化含有一种或多种离子污染物的含氧物原料流，导致形成由膜分离的渗余物和渗透物， 该渗透物是纯化的含氧化合物流，其含有比原始含氧化合物进料流更低的离子污染物浓度; （ii）将纯化的含氧物流引入含氧化合物至烯烃反应区; 和（iii）将纯化的含氧物流与含氧化合物中的分子筛催化剂接触到烯烃反应区，以形成包含烯烃的产物流。
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公开(公告)号：US09878963B2
公开(公告)日：2018-01-30
申请号：US14655345
申请日：2013-12-24
Applicant: SHELL OIL COMPANY
Inventor： Antonius Gijsbertus Johannes Kloth , Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
CPC classification number: C07C1/20 , C07C7/005 , C07C2529/00 , Y02P30/42 , Y02P30/48 , C07C11/04 , C07C11/06
Abstract: The invention relates to process for the preparation of an olefinic product comprising ethylene and/or propylene from an oxygenate, the process comprising the following steps: a) an oxygenate conversion step wherein a gaseous effluent comprising olefins and a water-soluble oxygenate is obtained; b) separation of water from the effluent; c) compression of the effluent; d) acid gas removal from the compressed gaseous effluent obtained in step c), wherein the compressed gaseous effluent is treated with a caustic solution in a caustic tower; and e) separating the olefinic product from the gaseous effluent treated in step d), wherein, in a final stage in the caustic tower, water-depleted compressed gaseous effluent is treated with a water stream that is essentially free of water-soluble oxygenate and a spent water stream comprising caustic and water-soluble oxygenate is obtained, which spent water stream is withdrawn from the process.
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公开(公告)号：US09828312B2
公开(公告)日：2017-11-28
申请号：US14439249
申请日：2013-10-29
Applicant: SHELL OIL COMPANY
Inventor： Antonius Gijsbertus Johannes Kloth , Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
CPC classification number: C07C7/11 , C07C1/20 , C07C7/09 , Y02P30/42 , Y02P30/464 , Y02P30/48 , C07C11/04 , C07C11/06
Abstract: The invention removes oxygenate from an olefin rich gas stream, the process comprising: (a) reacting an oxygenate, in a reaction zone in the presence of a molecular sieve catalyst, at a temperature from 350 to 1000° C., to produce an effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; (b) cooling the effluent stream and contacting it with a first aqueous stream in a quench zone to produce an aqueous stream and an olefin rich gas stream; (c) compressing the olefin rich gas stream in one or more compressors in series to produce a compressed gas stream, (d) cooling the compressed gas stream and separating condensed material from said gas stream after each of the one or more compressors.
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Patent Agency Ranking
公开(公告)号：US09828306B2
公开(公告)日：2017-11-28
申请号：US14439292
申请日：2013-10-29
Applicant: SHELL OIL COMPANY
Inventor： Antonius Gijsbertus Johannes Kloth , Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
Abstract: The invention provides a process for preparing an olefin, comprising: (a) reacting an oxygenate, in a reaction zone in the presence of a molecular sieve catalyst, at a temperature from 350 to 1000° C., to produce a effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; (b) cooling the reaction effluent stream by an indirect heat exchange to a temperature greater than the dew point temperature of effluent stream; (c) further rapidly cooling the effluent stream to a temperature lower than the dew point temperature of the effluent stream by direct injection of an aqueous liquid into the effluent stream, to form a quench effluent stream; and (d) passing the quench effluent stream into a quench tower and contacting the quench effluent stream with a second aqueous liquid in the presence of at least one set of internals, to produce a quench tower gaseous stream comprising the olefin.
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公开(公告)号：US09505670B2
公开(公告)日：2016-11-29
申请号：US14655348
申请日：2013-12-24
Applicant: SHELL OIL COMPANY
Inventor： Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
Abstract: The invention relates to a process for the preparation of an olefinic product comprising ethylene and/or propylene from an oxygenate comprising: a) an oxygenate conversion step wherein a gaseous effluent comprising olefins is obtained; b) separation of water from the effluent; c) compression of the effluent; d) acid gas removal from the effluent wherein the water-depleted compressed gaseous effluent is treated with a caustic solution in a caustic tower and a non-aqueous liquid stream comprising one or more aromatic C7+ hydrocarbons is added to the caustic solution to control the formation of red oil; and e) separating the olefinic product from the gaseous effluent treated in step d).
Abstract translation: 本发明涉及一种从含氧化合物制备包含乙烯和/或丙烯的烯烃产物的方法，包括：a）含氧化合物转化步骤，其中获得包含烯烃的气态流出物; b）将水从流出物中分离出来; c）流出物的压缩; d）从流出物中除去酸性气体，其中将贫水的压缩气体流出物用苛性塔中的苛性碱溶液和包含一种或多种芳族C 7 +烃的非水液体流加入到苛性碱溶液中以控制形成 的红油; 和e）从在步骤d）中处理的气态流出物中分离烯烃产物。
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公开(公告)号：US20150299067A1
公开(公告)日：2015-10-22
申请号：US14439267
申请日：2013-10-29
Applicant: SHELL OIL COMPANY
Inventor： Antonius Gijsbertus Johannes Kloth , Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
CPC classification number: C07C1/20 , C07C4/06 , C10G45/08 , C10G45/12 , C10G65/12 , C10G2300/1011 , C10G2300/104 , C10G2300/1044 , C10G2300/1051 , C10G2300/1059 , C10G2300/1081 , C10G2300/1085 , C10G2400/02 , C10G2400/20 , C10G2400/22 , Y02P30/42 , C07C11/02
Abstract: The invention provides a process for the preparation of an olefinic product, comprising:(a) reacting an oxygenate feedstock, in a reaction zone in the presence of a molecular sieve catalyst, at a temperature from 350 to 1000° C., to produce a reaction effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; (b) cooling the reaction effluent stream by means of an indirect heat exchange to a temperature greater than the dew point temperature of reaction effluent stream; (c) further rapidly cooling the reaction effluent stream to a temperature lower than the dew point temperature of the reaction effluent stream by direct injection of an aqueous liquid into the reaction effluent stream, to form a first quench effluent stream; and (d) separating the first quench effluent stream into a first liquid quench effluent stream and a first gaseous quench effluent stream, comprising the olefinic product.
Abstract translation: 本发明提供了制备烯烃产物的方法，包括：（a）在分子筛催化剂存在下，在350-1000℃的温度下使反应区中的含氧原料反应，以产生 反应流出物流，至少包含含氧化合物，烯烃，水和酸性副产物; （b）通过间接热交换将反应流出物流冷却至大于反应流出物流的露点温度的温度; （c）通过将水性液体直接注入反应流出物流中，将反应流出物流进一步快速冷却到低于反应流出物流的露点温度的温度，形成第一骤冷流出物流; 和（d）将第一骤冷流出物流分离成第一液体骤冷流出物流和包含烯烃产物的第一气态骤冷流出物流。
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29.发明申请公开(公告)号：US20150291487A1
公开(公告)日：2015-10-15
申请号：US14439242
申请日：2013-10-29
Applicant: SHELL OIL COMPANY
Inventor： Jeroen Van Westrenen
CPC classification number: C07C2/867 , C07C1/20 , C07C7/14891 , C07C29/10 , C07C41/06 , C07C45/29 , C07C45/38 , C07C2529/40 , C07C2529/70 , Y02P30/42 , C07C11/02 , C07C11/04 , C07C11/06 , C07C11/09 , C07C11/08 , C07C11/18 , C07C43/046 , C07C31/04 , C07C47/04
Abstract: The invention relates to a process for preparing ethylene, propylene and isoprene from an oxygenate, the process comprising the following steps: a) contacting the oxygenate with a molecular sieve-comprising catalyst, at a temperature in the range of from 350 to 1000° C. to produce an oxygenate conversion effluent comprising ethylene, propylene and C4+ hydrocarbons including C4+ paraffins and C4+ olefins including isobutene; b) subjecting the oxygenate conversion effluent to one or more separation steps such that at least an olefin product stream comprising ethylene and/or propylene, and a stream comprising C4 hydrocarbons including butane, n-butenes and isobutene, are obtained; c) reacting at least part of the isobutene with formaldehyde to produce isoprene.
Abstract translation: 本发明涉及从含氧化合物制备乙烯，丙烯和异戊二烯的方法，该方法包括以下步骤：a）使含氧化合物与含分子筛的催化剂在350-1000℃的温度下接触 以产生包含乙烯，丙烯和包括C 4+链烷烃和C 4+烯烃的C 4+烃（包括异丁烯）的含氧化合物转化流出物; b）使含氧化合物转化流出物经受一个或多个分离步骤，使得至少包含乙烯和/或丙烯的烯烃产物流和包含丁烷，正丁烯和异丁烯的C 4烃的流; c）使至少部分异丁烯与甲醛反应产生异戊二烯。
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公开(公告)号：US09133077B2
公开(公告)日：2015-09-15
申请号：US13727826
申请日：2012-12-27
Applicant: SHELL OIL COMPANY
Inventor： Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
CPC classification number: C07C1/22 , C07C1/20 , C07C4/06 , C07C2529/40 , C07C2529/70 , Y02P30/42 , C07C11/04
Abstract: A process for the preparation of an olefin product comprising ethylene, which process comprises the steps of: a) converting an oxygenate feedstock in an oxygenate-to-olefins conversion system, comprising a reaction zone in which an oxygenate feedstock is contacted with an oxygenate conversion catalyst under oxygenate conversion conditions, to obtain a conversion effluent comprising ethylene and/or propylene; b) separating at least a portion of the propylene from the conversion effluent to form a propylene stream; c) separating the remainder of the olefins from the conversion effluent; and d) recycling at least a portion of the propylene stream to step a).
Abstract translation: 一种制备包含乙烯的烯烃产物的方法，该方法包括以下步骤：a）将含氧化合物 - 烯烃转化体系中的含氧化合物原料转化，其包含其中含氧化合物原料与含氧化合物转化率接触的反应区 催化剂，以获得包含乙烯和/或丙烯的转化流出物; b）从转化流出物中分离至少一部分丙烯以形成丙烯料流; c）从转化流出物中分离剩余的烯烃; 和d）将至少一部分丙烯流再循环到步骤a）。
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