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公开(公告)号：US12049659B2
公开(公告)日：2024-07-30
申请号：US17297225
申请日：2019-11-26
Applicant: SHELL OIL COMPANY
Inventor： Carolina Botella-Franco , Sivakumar Sadasivan Vijayakumari , Robert Lawrence Blackbourn , Paul Richard Weider , Ye-Mon Chen , Yi Liang , Daniel Gagne , Ashley Villarreal Baugh
CPC classification number: C12P7/10
Abstract: Methods for production of ethanol, distiller's corn oil, and enhanced co-products are disclosed. Methods include obtaining a mixture of one or more co-products of an alcohol production process, which may include wet cake, performing hydrolysis of polysaccharides in the mixture to generate fermentable sugars, fermenting the fermentable sugars in the mixture to produce alcohol, distilling the mixture to remove alcohol from the mixture thereby producing alcohol-containing distillate and enhanced whole stillage, removing released oil from the fermented mixture before distillation and/or from the enhanced whole stillage after distillation, and recovering enhanced wet distiller's grains, enhanced thin stillage, and/or enhanced dried distiller's grains. Compositions disclosed herein include enhanced dried distiller's grains having a crude protein content of at least 45% on a dry weight basis and having a total fat content of less than 10% on a dry weight basis.
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公开(公告)号：US10696549B2
公开(公告)日：2020-06-30
申请号：US15318987
申请日：2015-06-29
Applicant: SHELL OIL COMPANY
Inventor： Sivakumar Sadasivan Vijayakumari , Parag Kotak , Arjan Allert Jonckers , Hubert Willem Schenck , Julie Hélène Emond Duncan , Eduardo Jorge Festa Pereira Ribeiro
IPC: C01B3/12 , B01D53/047
Abstract: The present invention relates to a process for processing a gas mixture comprising methane, carbon dioxide, carbon monoxide, hydrogen, nitrogen, argon and traces of olefins and oxygenates. Methane, carbon dioxide and carbon monoxide, and optionally hydrogen, can be recovered from the gas mixture in a very efficient way.
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公开(公告)号：US09902660B2
公开(公告)日：2018-02-27
申请号：US15103006
申请日：2013-12-13
Applicant: SHELL OIL COMPANY
Inventor： Antonius Gijsbertus Johannes Kloth , Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
CPC classification number: C07C1/20 , B01D17/045 , C07C2529/00 , C07C2529/40 , C07C2529/70 , C10G3/42 , Y02P30/42 , C07C11/04 , C07C11/02 , C07C11/06
Abstract: The invention provides a process for the preparation of an olefinic product, the process comprising the steps of: (a) reacting an oxygenate feedstock, comprising oxygenate, in an oxygenate reaction zone in the presence of a catalyst comprising a molecular sieve, at a temperature in the range of from 350 to 1000° C., to produce a reaction effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; (b) cooling the reaction effluent stream by means of an indirect heat exchange to provide a cooled reaction effluent stream at a temperature greater than the dew point temperature of reaction effluent stream; (c) passing the cooled reaction effluent stream into a quench tower and contacting the cooled reaction effluent stream with a first aqueous liquid in the presence of at least one set of quench tower internals, to produce a quench tower gaseous stream comprising the olefinic product and a quench tower liquid stream comprising condensed material; and (d) separating the quench tower liquid stream into a hydrocarbon quench tower liquid stream and an aqueous quench tower liquid stream in the presence of one or more coalescers.
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公开(公告)号：US20150291484A1
公开(公告)日：2015-10-15
申请号：US14439292
申请日：2013-10-29
Applicant: SHELL OIL COMPANY
Inventor： Antonius Gijsbertus Johannes Kloth , Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
Abstract: The invention provides a process for preparing an olefin, comprising: (a) reacting an oxygenate, in a reaction zone in the presence of a molecular sieve catalyst, at a temperature from 350 to 1000° C., to produce a effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; (b) cooling the reaction effluent stream by an indirect heat exchange to a temperature greater than the dew point temperature of effluent stream; (c) further rapidly cooling the effluent stream to a temperature lower than the dew point temperature of the effluent stream by direct injection of an aqueous liquid into the effluent stream, to form a quench effluent stream; and (d) passing the quench effluent stream into a quench tower and contacting the quench effluent stream with a second aqueous liquid in the presence of at least one set of internals, to produce a quench tower gaseous stream comprising the olefin.
Abstract translation: 本发明提供了一种制备烯烃的方法，包括：（a）使反应区中的含氧化合物在分子筛催化剂存在下，在350至1000℃的温度下反应，以产生流出物流，其包含 至少含氧化合物，烯烃，水和酸性副产物; （b）通过间接热交换将反应流出物流冷却至大于流出物流的露点温度的温度; （c）通过将水性液体直接注入流出物流中，将流出物流进一步快速冷却至低于流出物流的露点温度的温度，以形成骤冷流出物流; 和（d）将骤冷流出物流送入淬火塔并在至少一组内部存在下使骤冷流出物流与第二含水液体接触，以产生包含该烯烃的骤冷塔气流。
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公开(公告)号：US09067861B1
公开(公告)日：2015-06-30
申请号：US14368523
申请日：2012-12-20
Applicant: SHELL OIL COMPANY
Inventor： Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
IPC: C07C29/16 , C07C29/141 , C07C45/50 , C07C1/22
CPC classification number: C07C29/141 , C07C1/20 , C07C1/22 , C07C4/06 , C07C29/16 , C07C45/505 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2529/40 , C07C2529/83 , C07C2529/84 , C07C2529/85 , Y02P30/42
Abstract: The present invention provides a process for the production of alcohols, which process comprises the steps of: (a) reacting an oxygenate and/or olefinic feed in a reactor in the presence of a molecular sieve catalyst to form an effluent comprising olefins, comprising propylene; (b) separating the effluent comprising olefins as obtained in step (a) into at least a first olefinic product fraction comprising propylene and a second olefinic product fraction; (c) subjecting at least part of the first olefinic product fraction as obtained in step (b) to a hydroformylation process to form aldehydes; (d) hydrogenating at least part of the aldehydes as obtained in step (c) to form alcohols; (e) separating at least part of the alcohols as obtained in step (d) into at least a first product fraction of alcohols and a second product fraction of alcohols; and (f) recycling at least part of the first or second product fraction of alcohols to step (a).
Abstract translation: 本发明提供了一种生产醇的方法，该方法包括以下步骤：（a）在分子筛催化剂存在下使反应器中的含氧化合物和/或烯烃进料反应，以形成包含烯烃的流出物，其包含丙烯 ; （b）将步骤（a）中获得的包含烯烃的流出物分离成至少包含丙烯和第二烯属产物馏分的第一烯烃产物级分; （c）将步骤（b）中获得的至少部分第一烯属产物级分进行加氢甲酰化过程以形成醛; （d）氢化步骤（c）中获得的至少部分醛以形成醇; （e）将步骤（d）中获得的至少一部分醇分离成至少第一产物级分的醇和第二产物级分的醇; 和（f）将至少部分第一或第二产物级分的醇再循环到步骤（a）。
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Patent Agency Ranking
公开(公告)号：US09834488B2
公开(公告)日：2017-12-05
申请号：US14439389
申请日：2013-10-29
Applicant: SHELL OIL COMPANY
Inventor： Antonius Gijsberius Johannes Kloth , Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
CPC classification number: C07C1/20 , C07C4/04 , C07C2529/40 , C10G3/49 , C10G9/00 , C10G2400/20 , Y02P30/42 , C07C11/02
Abstract: The invention provides a process for the preparation of an olefinic product, the comprising: (a) reacting an oxygenate to produce an effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; (b) cooling the effluent stream by means of an indirect heat exchange to a temperature greater than the dew point temperature of effluent stream; (c) further rapidly cooling the effluent stream to a temperature at or lower than the dew point temperature of the reaction effluent stream by direct injection of a first aqueous liquid into the effluent stream, to form a quench effluent stream; (d) separating the first quench effluent stream into a liquid quench stream and a gaseous quench stream; and passing the gaseous quench stream into a quench tower and contacting the gaseous quench stream with a second aqueous liquid, to produce a quench tower gaseous stream comprising the olefinic product.
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公开(公告)号：US09682342B2
公开(公告)日：2017-06-20
申请号：US14758449
申请日：2013-12-31
Applicant: SHELL OIL COMPANY
Inventor： Sivakumar Sadasivan Vijayakumari
CPC classification number: B01D53/047 , B01D53/0423 , B01D2253/102 , B01D2253/104 , B01D2253/106 , B01D2253/108 , B01D2253/116 , B01D2256/10 , B01D2256/16 , B01D2256/20 , B01D2256/245 , B01D2257/102 , B01D2257/108 , B01D2257/502 , B01D2257/504 , B01D2259/40013 , B01D2259/40028 , B01D2259/40043 , B01D2259/40049 , B01D2259/402 , B01D2259/4141 , C01B3/56 , C01B2203/0205 , C01B2203/0244 , C01B2203/025 , C01B2203/062 , C10G2/32 , C10G2/50 , C10G70/047 , C10G2300/1022 , C10K1/32 , Y02C10/08 , Y02P20/152
Abstract: This invention concerns a method for recovering carbon monoxide and carbon dioxide from Fischer-Tropsch off-gas by feeding Fischer-Tropsch off-gas through a column comprising an adsorbent bed, and discharging effluent, optionally rinsing the column and the adsorbent bed by feeding carbon dioxide and discharging effluent until at least 60% of the carbon monoxide that was present in the bed is discharged, pressurizing the column and adsorbent bed with carbon dioxide, rinsing the column and the adsorbent bed by feeding carbon dioxide, until at least 60% of the methane and optionally an amount equal to at least 50% of the carbon dioxide present at the commencement of this rinsing step is discharged, rinsing the column and adsorbent bed by feeding a mixture of hydrogen and nitrogen, pressurizing the column and adsorbent bed by feeding a mixture of hydrogen and nitrogen. With this method a feed comprising at least 50 vol % carbon monoxide can be produced. Furthermore, methane and carbon dioxide at a high pressure can be recovered from the Fischer-Tropsch gas. This can be fed to a gasifier or a reformer. In a preferred embodiment a gas comprising at least 80 vol % hydrogen is produced as well.
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公开(公告)号：US20150291488A1
公开(公告)日：2015-10-15
申请号：US14439249
申请日：2013-10-29
Applicant: SHELL OIL COMPANY
Inventor： Antonius Gijsbertus Johannes Kloth , Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
CPC classification number: C07C7/11 , C07C1/20 , C07C7/09 , Y02P30/42 , Y02P30/464 , Y02P30/48 , C07C11/04 , C07C11/06
Abstract: The invention removes oxygenate from an olefin rich gas stream, the process comprising: (a) reacting an oxygenate, in a reaction zone in the presence of a molecular sieve catalyst, at a temperature from 350 to 1000° C., to produce an effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; (b) cooling the effluent stream and contacting it with a first aqueous stream in a quench zone to produce an aqueous stream and an olefin rich gas stream; (c) compressing the olefin rich gas stream in one or more compressors in series to produce a compressed gas stream, (d) cooling the compressed gas stream and separating condensed material from said gas stream after each of the one or more compressors.
Abstract translation: 本发明从富烯烃气流中除去含氧化合物，该方法包括：（a）在分子筛催化剂存在下，在反应区中，在350-1000℃的温度下使含氧化合物反应，以产生流出物 至少包含含氧化合物，烯烃，水和酸性副产物; （b）冷却流出物流并将其与骤冷区中的第一含水流接触以产生含水物流和富烯烃气流; （c）串联压缩一个或多个压缩机中的富烯烃气流以产生压缩气流，（d）冷却压缩气流，并在每个一个或多个压缩机之后从所述气流中分离冷凝材料。
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公开(公告)号：US20150148574A1
公开(公告)日：2015-05-28
申请号：US14368516
申请日：2012-12-20
Inventor： Leslie Andrew Chewter , Timothy Michael Nisbet , Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
CPC classification number: C07C1/20 , C07C4/04 , C07C4/06 , C07C2529/40 , C07C2529/70 , Y02P30/42 , C07C11/02
Abstract: A process for the preparation of an olefin product, which process comprises the steps of: a) converting an oxygenate feedstock in an oxygenate-to-olefins conversion system, comprising a reaction zone in which an oxygenate feedstock is contacted with an oxygenate conversion catalyst under oxygenate conversion conditions, to obtain a conversion effluent comprising olefins and paraffins; b) separating at least a portion of the paraffins from the conversion effluent to form a paraffin stream; and c) recycling at least a portion of the paraffin stream to step a).
Abstract translation: 一种制备烯烃产物的方法，该方法包括以下步骤：a）将含氧化合物 - 烯烃转化体系中的含氧化合物原料转化，其包含其中含氧化合物原料与含氧化合物转化催化剂接触的反应区， 含氧化合物转化条件，以获得包含烯烃和链烷烃的转化流出物; b）将至少一部分链烷烃与转化流出物分离以形成链烷烃流; 和c）将至少一部分石蜡流循环至步骤a）。
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公开(公告)号：US09012694B2
公开(公告)日：2015-04-21
申请号：US14368569
申请日：2012-12-21
Applicant: Shell Oil Company
Inventor： Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
CPC classification number: C07C45/50 , C01B3/16 , C07C1/20 , C07C1/22 , C07C4/06 , C07C29/14 , C07C29/141 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2529/40 , C07C2529/83 , C07C2529/84 , C07C2529/85 , Y02P30/42 , C07C11/06 , C07C11/04 , C07C31/12 , C07C47/02
Abstract: The present invention provides a process for the production of aldehydes and/or alcohols, which process comprises the steps of: (a) reacting an oxygenate and/or olefinic feed in a reactor in the presence of a molecular sieve catalyst to form an effluent comprising olefins, comprising propylene; (b) separating the effluent comprising olefins as obtained in step (a) into at least a first olefinic product fraction comprising propylene and a second olefinic product fraction; (c) subjecting at least part of the first olefinic product fraction as obtained in step (b) to a hydroformylation process to form aldehydes; (d) separating at least part of the aldehydes as obtained in step (c) into at least a first product fraction of aldehydes and a second product fraction of aldehydes; and (e) hydrogenating at least part of the aldehydes in the first and/or second product fraction of aldehydes as obtained in step (d) to form a first product fraction of alcohols and/or a second product fraction of alcohols; (f) recycling at least part of the first and/or second product fraction of alcohols obtained in step (e) to step (a).
Abstract translation: 本发明提供了一种生产醛和/或醇的方法，该方法包括以下步骤：（a）在分子筛催化剂存在下使反应器中的含氧化合物和/或烯烃进料反应形成流出物，其包含 烯烃，包括丙烯; （b）将步骤（a）中获得的包含烯烃的流出物分离成至少包含丙烯和第二烯属产物馏分的第一烯烃产物级分; （c）将步骤（b）中获得的至少部分第一烯属产物级分进行加氢甲酰化过程以形成醛; （d）将步骤（c）中获得的至少一部分醛分离成至少醛的第一产物级分和醛的第二产物级分; 和（e）将步骤（d）中获得的醛的第一和/或第二产物级分中的至少部分醛氢化以形成醇的第一产物级分和/或醇的第二产物级分; （f）将步骤（e）中获得的醇的第一和/或第二产物馏分的至少一部分再循环到步骤（a）。
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