公开(公告)号：US20080241704A1

公开(公告)日：2008-10-02

申请号：US10592702

申请日：2005-03-18

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

IPC分类号： H01M10/40

CPC分类号： H01M10/0567 ,  H01M4/1391 ,  H01M4/587 ,  H01M10/0525 ,  H01M2300/0025

摘要： The present invention provides a lithium secondary battery having excellent battery characteristics such as battery cycling property, electrical capacity and storage property.The present invention relates to a nonaqueous electrolytic solution for lithium secondary batteries in which an electrolyte salt is dissolved in a nonaqueous solvent, the nonaqueous electrolytic solution comprising a formic ester compound having a specific structure in an amount of 0.01 to 10% by weight of the nonaqueous electrolytic solution, and a lithium secondary battery using the same.

摘要翻译： 本发明提供具有优异的电池特性如锂电池循环特性，电容量和储存性能的锂二次电池。 本发明涉及一种锂二次电池的非水电解液，其中电解质盐溶解在非水溶剂中，该非水电解液包含具有特定结构的甲酸酯化合物，其量为0.01-10重量％ 非水电解液和使用其的锂二次电池。

公开(公告)号：US08404390B2

公开(公告)日：2013-03-26

申请号：US12596300

申请日：2008-04-15

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Yoshihiro Ushigoe ,  Manabu Takase ,  Kazuyuki Kawabe

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Yoshihiro Ushigoe ,  Manabu Takase ,  Kazuyuki Kawabe

IPC分类号： H01M6/16

CPC分类号： C07C317/08 ,  C07C317/18 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0569 ,  H01M10/4235 ,  Y02T10/7011

摘要： The present invention provides (1) a sulfone compounds having a propargyl group, (2) a nonaqueous electrolytic solution for lithium secondary batteries, which comprises an electrolyte salt dissolved in a nonaqueous solvent and contains a sulfone compound having a specific structure that has an SO2 group with a propargyl group or a vinyl group bonding thereto, in an amount of from 0.01 to 10% by weight of the nonaqueous electrolytic solution, and which can prevent gas generation and is excellent in battery characteristics such as cycle property and the like, and (3) a lithium secondary battery comprising a positive electrode, a negative electrode and a nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, wherein the nonaqueous electrolytic solution contains a sulfone compound having a specific structure, in an amount of from 0.01 to 10% by weight of the nonaqueous electrolytic solution.

摘要翻译： 本发明提供（1）具有炔丙基的砜化合物，（2）锂二次电池用非水电解液，其包含溶解在非水溶剂中的电解质盐，并含有具有SO 2的特定结构的砜化合物 与非水电解液的重量比为0.01〜10重量％的炔丙基或与其结合的乙烯基，能够防止气体产生，并且电池特性如循环特性等优异， （3）一种锂二次电池，其包含正极，负极和溶解在非水溶剂中的电解质盐的非水电解液，其中所述非水电解液含有特定结构的砜化合物，其量为0.01 至10重量％的非水电解液。

公开(公告)号：US20120301797A1

公开(公告)日：2012-11-29

申请号：US13576182

申请日：2011-02-02

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo

IPC分类号： H01M10/056 ,  C07C309/70 ,  C07C309/68 ,  C07C309/67

CPC分类号： H01M10/0567 ,  C07C309/67 ,  C07F9/113 ,  C07F9/327 ,  H01M10/052 ,  H01M2300/0025 ,  Y02E60/122 ,  Y02T10/7011

摘要： The present invention provides an excellent nonaqueous electrolytic solution capable of improving low-temperature and high-temperature cycle properties and load characteristics after high-temperature charging storage, an electrochemical element using it, and an alkynyl compound used for it.The nonaqueous electrolytic solution of the present invention comprises containing at least one alkynyl compound represented by the following general formula (I) in an amount of from 0.01 to 10% by mass in the nonaqueous electrolytic solution. R1(O)n—X1—R2  (I) (In the formula, X1 represents a group —C(═O)—, a group —C(═O)—C(═O)—, a group —S(═O)2—, a group —P(═O) (—R3)—, or a group —X2—S(═O)2O—. R1 represents an alkenyl group, a formyl group, an alkyl group, an acyl group, an arylcarbonyl, an alkanesulfonyl group, an alkynyloxysulfonyl group, an arylsulfonyl group, a dialkylphosphoryl group, an alkyl(alkoxy)phosphoryl group, or a dialkoxyphosphoryl group; R2 represents an alkynyl group or an alkynyloxy group; R3 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, or an aryloxy group; n indicates 0 or 1.

摘要翻译： 本发明提供一种能够提高高温充电保存后的低温高温循环性能和负载特性的优异的非水电解液，使用它的电化学元件和用于其的炔基化合物。 本发明的非水电解液在非水电解液中含有0.01〜10质量％的由通式（I）表示的至少一种炔基化合物。 R 1（O）n -X 1 -R 2（I）（式中，X1表示-C（= O） - 基，-C（= O）-C（= O） - 基，-S（ = O）2-，基团-P（= O）（-R 3） - 或基团-X 2 -S（= O）2 O-，R 1表示链烯基，甲酰基，烷基，酰基 基团，芳基羰基，烷磺酰基，炔氧基磺酰基，芳基磺酰基，二烷基磷酰基，烷基（烷氧基）磷酰基或二烷氧基磷酰基; R2表示炔基或炔氧基; R3表示烷基， 烯基，炔基，芳基，烷氧基，烯氧基，炔氧基或芳氧基; n表示0或1。

公开(公告)号：US08163427B2

公开(公告)日：2012-04-24

申请号：US10564852

申请日：2004-07-16

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

IPC分类号： H01M6/16

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/133 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M4/661 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/4235 ,  H01M2004/021 ,  H01M2300/0025 ,  H01M2300/0091

摘要： A non-aqueous electrolytic solution is advantageously used in preparation of a lithium secondary battery excellent in cycle characteristics. In the non-aqueous electrolytic solution for a lithium secondary battery, an electrolyte salt is dissolved in a non-aqueous solvent. The non-aqueous electrolytic solution further contains a vinylene carbonate compound in an amount of 0.01 to 10 wt. %, and an alkyne compound in an amount of 0.01 to 10 wt. %.

摘要翻译： 非水电解液有利地用于制备循环特性优异的锂二次电池。 在锂二次电池用非水电解液中，将电解质盐溶解在非水溶剂中。 非水电解液还含有碳酸亚乙烯酯化合物，其量为0.01〜10重量％。 ％，炔化合物的量为0.01〜10重量％。 ％。

公开(公告)号：US08026000B2

公开(公告)日：2011-09-27

申请号：US11656486

申请日：2007-01-23

申请人： Masato Iwanaga ,  Yukihiro Oki ,  Koji Abe ,  Kazuhiro Miyoshi

发明人： Masato Iwanaga ,  Yukihiro Oki ,  Koji Abe ,  Kazuhiro Miyoshi

IPC分类号： H01M6/04

CPC分类号： H01M10/0567 ,  H01M4/131 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0569 ,  H01M2300/004

摘要： A nonaqueous electrolyte secondary battery of the invention has a positive electrode having a positive electrode active material, a negative electrode, and a nonaqueous electrolyte having electrolyte salt in a nonaqueous solvent. The electric potential of the positive electrode active material is 4.4 to 4.6 V relative to lithium, and the nonaqueous electrolyte contains a compound expressed by structural formula (I) below. The quantity of compound added is preferably 0.1% to 2% by mass. Also, the positive electrode active material preferably comprises a mixture of a lithium-cobalt composite oxide which is LiCoO2 containing at least both zirconium and magnesium and a lithium-manganese-nickel composite oxide that has a layer structure and contains at least both manganese and nickel. Thanks to such structure, a nonaqueous electrolyte secondary battery can be provided that is charged to charging termination potential of 4.4 to 4.6 V relative to lithium and that has enhanced overcharging safety.[Chemical Formula 1]

摘要翻译： 本发明的非水电解质二次电池具有正极，具有正极活性物质，负极和非水电解质，在非水溶剂中具有电解质盐。 正极活性物质的电位相对于锂为4.4〜4.6V，非水电解质含有下述结构式（I）表示的化合物。 化合物的添加量优选为0.1质量％〜2质量％。 此外，正极活性物质优选包含锂 - 钴复合氧化物的混合物，其为至少含有锆和镁的两种LiCoO 2和具有层结构并且至少包含锰和镍两者的锂锰镍复合氧化物的混合物 。 由于这样的结构，可以提供非水电解质二次电池，其相对于锂充电至4.4至4.6V的充电终止电位，并且具有增强的过充电安全性。 [化学式1]

公开(公告)号：US07767343B2

公开(公告)日：2010-08-03

申请号：US10563124

申请日：2005-02-18

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Yasufumi Takahashi ,  Hiroyuki Fujimoto ,  Akira Kinoshita ,  Shingo Tode ,  Ikuro Nakane ,  Shin Fujitani

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Yasufumi Takahashi ,  Hiroyuki Fujimoto ,  Akira Kinoshita ,  Shingo Tode ,  Ikuro Nakane ,  Shin Fujitani

IPC分类号： H01M4/58 ,  H01M6/16

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/485 ,  H01M4/525 ,  H01M4/587 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2010/4292 ,  H01M2300/0025

摘要： A nonaqueous electrolyte secondary battery including a negative electrode containing a graphite material as the negative active material, a positive electrode containing lithium cobalt oxide as a main component of the positive active material and a nonaqueous electrolyte solution, the battery being characterized in that the lithium cobalt oxide contains a group IVA element and a group IIA element of the periodic table, the nonaqueous electrolyte solution contains 0.2-1.5% by weight of a sulfonyl-containing compound and preferably further contains 0.5-4% by weight of vinylene carbonate.

摘要翻译： 包含含有作为负极活性物质的石墨材料的负极，含有钴酸锂作为正极活性物质的主要成分的正极和非水电解液的非水电解质二次电池，其特征在于，所述锂钴 氧化物含有元素周期表IVA族元素和IIA族元素，非水电解质溶液含有0.2-1.5重量％的含磺酰基化合物，优选还含有0.5-4重量％的碳酸亚乙烯酯。

公开(公告)号：US20060177742A1

公开(公告)日：2006-08-10

申请号：US10564852

申请日：2004-07-16

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

IPC分类号： H01M10/40

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/133 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M4/661 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/4235 ,  H01M2004/021 ,  H01M2300/0025 ,  H01M2300/0091

摘要： A non-aqueous electrolytic solution is advantageously used in preparation of a lithium secondary battery excellent in cycle characteristics. In the non-aqueous electrolytic solution for a lithium secondary battery, an electrolyte salt is dissolved in a non-aqueous solvent. The non-aqueous electrolytic solution further contains a vinylene carbonate compound in an amount of 0.01 to 10 wt. %, and an alkyne compound in an amount of 0.01 to 10 wt. %.

摘要翻译： 非水电解液有利地用于制备循环特性优异的锂二次电池。 在锂二次电池用非水电解液中，将电解质盐溶解在非水溶剂中。 非水电解液还含有碳酸亚乙烯酯化合物，其量为0.01〜10重量％。 ％，炔化合物的量为0.01〜10重量％。 ％。

公开(公告)号：US09240614B2

公开(公告)日：2016-01-19

申请号：US13701193

申请日：2011-06-03

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Shoji Shikita ,  Kei Shimamoto

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Shoji Shikita ,  Kei Shimamoto

IPC分类号： H01M10/0567 ,  H01G11/58 ,  H01M10/0569 ,  H01M10/052 ,  H01M10/0566

CPC分类号： H01M10/0567 ,  H01G11/58 ,  H01M10/052 ,  H01M10/0566 ,  H01M10/0569 ,  H01M2300/0025 ,  Y02E60/122 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022

摘要： The present invention provides a nonaqueous electrolytic solution which can improve the electrochemical characteristics in a broad temperature range, an electrochemical element produced by using the same and a sulfonic ester compound having a branched structure which is used for the same.The present invention relates to a nonaqueous electrolytic solution prepared by dissolving an electrolyte salt in a nonaqueous solvent, which comprises a sulfonic ester compound represented by the following Formula (I) in an amount of 0.001 to 5% by mass of the nonaqueous electrolytic solution: (wherein R represents an alkyl group or an aryl group; A represents a >CH group or a >SiZ group (Z represents an alkyl group or an aryl group); X represents an alkyl group, a cycloalkyl group or an aryl group; Y represents a cycloalkyl group, a -L1CHRaOSO2Rb group or a —Si(Rc)(Rd)OSO2Rb group; W represents 1 or 2; Ra represents an alkyl group; Rb, Rc and Rd represent an alkyl group or an aryl group; L1 represents an alkylene group in which at least one hydrogen atom may be substituted with —OSO2Re (Re has the same meaning as that of R), a divalent linkage group containing at least one ether bond or a single bond).

摘要翻译： 本发明提供一种可以提高宽温度范围内的电化学特性的非水电解液，使用该电解质的电化学元件和具有分支结构的磺酸酯化合物。 本发明涉及通过将电解质盐溶解在非水溶剂中而制备的非水电解液，该非水溶剂包含以下式（I）表示的磺酸酯化合物：非水电解液的0.001〜5质量％ （其中R表示烷基或芳基; A表示> CH基或> SiZ基（Z表示烷基或芳基）; X表示烷基，环烷基或芳基; Y 表示环烷基，-L1CHRaOSO2Rb基或-Si（Rc）（Rd）OSO2Rb基; W表示1或2; Ra表示烷基; Rb，Rc和Rd表示烷基或芳基; L1表示 其中至少一个氢原子可以被-OSO 2 Re取代的亚烷基（Re具有与R相同的含义），含有至少一个醚键或单键的二价连接基团）。

公开(公告)号：US08568932B2

公开(公告)日：2013-10-29

申请号：US12064181

申请日：2006-08-10

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Chisen Hashimoto ,  Masahide Kondo

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Chisen Hashimoto ,  Masahide Kondo

IPC分类号： H01M6/16

CPC分类号： H01M10/0525 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0037 ,  H01M2300/004 ,  H01M2300/0042

摘要： The present invention provides a nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, containing 0.01% to 30% by weight of a 1,2-cyclohexanediol derivative having a specific structure; and a lithium secondary battery using the nonaqueous electrolytic solution. The lithium secondary battery exhibits excellent battery characteristics such as electrical capacity, cycle property, and storage property and can maintain excellent long-term battery performance.

摘要翻译： 本发明提供一种非水电解液，其中电解质盐溶解在非水溶剂中，其含有0.01重量％至30重量％的具有特定结构的1,2-环己二醇衍生物; 以及使用非水电解液的锂二次电池。 锂二次电池具有优异的电池特性，例如电容，循环特性和存储性能，并且可以保持优异的长期电池性能。

公开(公告)号：US20120183864A1

公开(公告)日：2012-07-19

申请号：US13430791

申请日：2012-03-27

申请人： Koji ABE ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

发明人： Koji ABE ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

IPC分类号： H01M10/056

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/133 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M4/661 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/4235 ,  H01M2004/021 ,  H01M2300/0025 ,  H01M2300/0091

摘要： A non-aqueous electrolytic solution is advantageously used in preparation of a lithium secondary battery excellent in cycle characteristics. In the non-aqueous electrolytic solution for a lithium secondary battery, an electrolyte salt is dissolved in a non-aqueous solvent. The non-aqueous electrolytic solution further contains a vinylene carbonate compound in an amount of 0.01 to 10 wt. %, and an alkyne compound in an amount of 0.01 to 10 wt. %.

摘要翻译： 非水电解液有利地用于制备循环特性优异的锂二次电池。 在锂二次电池用非水电解液中，将电解质盐溶解在非水溶剂中。 非水电解液还含有碳酸亚乙烯酯化合物，其量为0.01〜10重量％。 ％，炔化合物的量为0.01〜10重量％。 ％。