公开(公告)号：US5227447A

公开(公告)日：1993-07-13

申请号：US925194

申请日：1992-08-06

申请人： Shinichi Sato ,  Takashi Matsuda ,  Toshio Takago

发明人： Shinichi Sato ,  Takashi Matsuda ,  Toshio Takago

IPC分类号： C08G77/08

CPC分类号： C08G77/08

摘要： The process for preparing a high molecular weight organopolysiloxane comprises subjecting a hydroxyl-containing organosiloxane, as a starting material, to a dehydration condensation reaction in the presence of an acidic compound selected from the acidic compounds represented by the following general formulas (1) and (2): ##STR1## wherein in the formulas n is an integer of from 1 to 10, k is an integer of from 0 to 8, and 1 and m are each an integer of 0 or above, with 1+m being in the range from 1 to 10. The process is advantageous over the conventional methods in that compounds having toxicity or the like are neither used nor by-produced. The process also has the merit of easy control of the molecular weight of the intended organopolysiloxane.

摘要翻译： 制备高分子量有机聚硅氧烷的方法包括在选自下列通式（1）和（I）表示的酸性化合物的酸性化合物存在下，使含羟基的有机硅氧烷作为起始原料进行脱水缩合反应， 2）：（1）（2）其中，在式中，n是1至10的整数，k是0至8的整数，并且1和m各自为整数0或 其中1 + m在1至10的范围内。该方法优于常规方法，因为具有毒性等的化合物既不使用也不再生产。 该方法还具有易于控制目标有机聚硅氧烷的分子量的优点。

公开(公告)号：US5214177A

公开(公告)日：1993-05-25

申请号：US769483

申请日：1991-10-01

申请人： Masayuki Oyama ,  Toshio Takago ,  Hideki Fujii ,  Hitoshi Kinami

发明人： Masayuki Oyama ,  Toshio Takago ,  Hideki Fujii ,  Hitoshi Kinami

IPC分类号： C07F7/12

CPC分类号： C07F7/12

摘要： Fluorinated organic silicon compound of the general formula: ##STR1## wherein R is an alkyl group having 1 to 6 carbon atoms, n is an integer of from 1 to 6, and m is equal to 1, 2 or 3 are novel and useful as treating agents and intermediates for the synthesis of fluorinated cyclic organic silicon compounds. The fluorinated organic silicon compounds are prepared by reacting a chlorosilane with a fluorinated olefin.

摘要翻译： 具有以下通式的氟化有机硅化合物：其中R是具有1至6个碳原子的烷基，n是1至6的整数，m等于1,2或3是新的 并且可用作合成氟化环状有机硅化合物的处理剂和中间体。 氟化有机硅化合物通过氯硅烷与氟化烯烃反应制备。

公开(公告)号：US4985526A

公开(公告)日：1991-01-15

申请号：US518220

申请日：1990-05-03

申请人： Hirofumi Kishita ,  Kouichi Yamaguchi ,  Toshio Takago

发明人： Hirofumi Kishita ,  Kouichi Yamaguchi ,  Toshio Takago

IPC分类号： C08L83/07 ,  C08G77/24 ,  C08L83/05 ,  C08L83/08 ,  C08L83/12

CPC分类号： C08L83/08 ,  C08G77/24 ,  C08L83/12

摘要： A curable silicone composition comprising;(a) an organopolysiloxane having at least two silicon-bonded C.sub.2 to C.sub.8 alkenyl groups and containing a particular silicon-bonded fluorine-containing substituent;(b) an organohydrogenpolysiloxane having at least three silicon-bonded hydrogen atoms and a particular silicon-bonded fluorine-containing substituent; and(c) a catalyst; the proportion of said silicon-bonded hydrogen atoms in Component (b) to said silicon-bonded alkenyl groups in Component (a) being at least 0.5. This composition can form a film, on various substrates, having good release properties, water repellency and oil repellency.

公开(公告)号：US5580992A

公开(公告)日：1996-12-03

申请号：US396619

申请日：1995-03-01

申请人： Yasuo Tarumi ,  Hirofumi Kishita ,  Toshio Takago

发明人： Yasuo Tarumi ,  Hirofumi Kishita ,  Toshio Takago

IPC分类号： C07D321/08

CPC分类号： C07D321/08

摘要： A fluorine-containing compound represented by the following general formula (1): ##STR1## wherein A represents a group --CH.sub.2 --CH.dbd.CH.sub.2 or a group ##STR2## in which R represents a hydrogen atom or an alkyl group. The compound is useful as an intermediate for producing various compounds and can introduce perfluorocyclic ether groups into various polymers to give such properties as chemical resistance, water repellency, oil repellency, and weather resistance to the polymers.

摘要翻译： 由以下通式（1）表示的含氟化合物：其中A表示基团-CH 2 -CH = CH 2或基团R 1，其中R表示氢原子或烷基。 该化合物可用作生产各种化合物的中间体，并可将全氟醚基团引入各种聚合物中，以提供耐化学性，拒水性，拒油性和耐候性的性能。

公开(公告)号：US5126420A

公开(公告)日：1992-06-30

申请号：US562318

申请日：1990-08-03

申请人： Shinichi Satoh ,  Toshio Takago ,  Hitoshi Kinami

发明人： Shinichi Satoh ,  Toshio Takago ,  Hitoshi Kinami

IPC分类号： C08L83/06 ,  C08K5/5419 ,  C08K5/5425 ,  C08L83/04

CPC分类号： C08K5/5425 ,  Y10S528/901

摘要： A mixture of (A) a diorganopolysiloxane end-blocked with a hydroxyl group, (B) an .alpha.,.beta.-substituted vinyloxysilane, or a hydrolyzate thereof, and (C) a perfluorocarboxylic acid derivative provides an RTV organopolysiloxane composition which is stable and non-corrosive to metal.

摘要翻译： 端基封端的（A）二羟基有机聚硅氧烷，（B）α，β-取代的乙烯基氧基硅烷或其水解产物和（C）全氟羧酸衍生物的混合物提供了一种稳定和非稳定的RTV有机聚硅氧烷组合物， 腐蚀金属。

公开(公告)号：US5523441A

公开(公告)日：1996-06-04

申请号：US383376

申请日：1995-02-03

申请人： Hirofumi Kishita ,  Noriyuki Koike ,  Hideyoshi Yanagisawa ,  Toshio Takago

发明人： Hirofumi Kishita ,  Noriyuki Koike ,  Hideyoshi Yanagisawa ,  Toshio Takago

IPC分类号： C07F7/18 ,  C07F7/10

CPC分类号： C07F7/1836

摘要： Disclosed is a novel polyfluorocarbon group-containing alkoxy silane compound useful as a silane coupling agent as represented by the general formulaA--R.sub.f --(--CH.sub.2 --).sub.n --NH--R.sup.1 --SiR.sub.3,in which each R is, independently from the others, a monovalent hydrocarbon group having 1 to 10 carbon atoms or an alkoxy group having 1 to 6 carbon atoms with the proviso that at least one of the three groups denoted by R is an alkoxy group, R.sup.1 is a divalent hydrocarbon group having 1 to 10 carbon atoms, A is a monovalent group selected from the class consisting of a hydrogen atom, a fluorine atom, an aminomethyl group and a 2-aminoethyl group, R.sub.f is a polyfluorinated alkylene group with 1 to 20 carbon atoms or a polyfluorinated etherified alkylene group with 2 to 20 carbon atoms having at least one oxygen atom between two carbon atoms of an alkylene group forming an ether linkage, at least two of the hydrogen atoms therein being substituted by fluorine atoms, and the subscript n is 1 or 2.

摘要翻译： 公开了一种新型的含有氟代烃基的烷氧基硅烷化合物，其可用作通式A-Rf - （ - CH2-）n-NH-R1-SiR3所示的硅烷偶联剂，其中每个R独立于其它 ，具有1-10个碳原子的一价烃基或具有1至6个碳原子的烷氧基，条件是由R表示的三个基团中的至少一个是烷氧基，R 1是具有1至10个碳原子的二价烃基 碳原子，A为选自氢原子，氟原子，氨基甲基和2-氨基乙基的一价基团，Rf为碳原子数1〜20的多氟化亚烷基或多氟化醚化亚烷基 具有2至20个碳原子，在形成醚键的亚烷基的两个碳原子之间具有至少一个氧原子，其中至少两个氢原子被氟原子取代，并且下标n为1或2。

公开(公告)号：US5227502A

公开(公告)日：1993-07-13

申请号：US922424

申请日：1992-07-31

申请人： Toshio Takago ,  Hiroshi Inomata ,  Yasuo Tarumi ,  Hiromasa Yamaguchi ,  Kenichi Fukuda

发明人： Toshio Takago ,  Hiroshi Inomata ,  Yasuo Tarumi ,  Hiromasa Yamaguchi ,  Kenichi Fukuda

IPC分类号： C07D303/22 ,  C07F7/18 ,  C08G65/22

CPC分类号： C07D303/22 ,  C07F7/182 ,  C08G65/226

摘要： Novel fluorinated unsaturated glycidyl ethers are prepared by reacting 1,1,1-trifluoro-2-trifluoromethyl-3-buten-2-ol or 1,1,1-trifluoro-2-trifluoromethyl-4-propen-2-ol with chloromethyloxirane in the presence of onium salts. The fluorinated unsaturated glycidyl ethers are, in turn, subject to addition reaction with hydrosilanes in the presence of transition metal catalysts, obtaining novel silicon-modified glycidyl ethers or fluorinated organic silicon compounds.

公开(公告)号：US4652663A

公开(公告)日：1987-03-24

申请号：US862676

申请日：1986-05-13

申请人： Toshio Takago ,  Yasushi Yamamoto ,  Koichi Yamaguchi ,  Hideto Kato

发明人： Toshio Takago ,  Yasushi Yamamoto ,  Koichi Yamaguchi ,  Hideto Kato

IPC分类号： C08K5/5475 ,  C07F7/02 ,  C07F7/12 ,  C07F7/18 ,  C08K5/49 ,  C08K5/5419 ,  C08K5/5425 ,  C08K5/5435 ,  C08L27/12 ,  C07F7/08 ,  C07F7/10 ,  C07D303/02

CPC分类号： C07F7/025 ,  C07F7/1836

摘要： A class of novel organosilane compounds are disclosed as represented by the general formulaRSi(OCH.sub.2 CF.sub.3).sub.3,in which R is an atom or group selected from the class consisting of a hydrogen atom, unsaturated monovalent aliphatic hydrocarbon groups having from 2 to 20 carbon atoms, monovalent aryl groups and monovalent organic groups having from 3 to 20 carbon atoms and containing at least one hetero atom, i.e. an atom other than carbon and hydrogen atoms, such as oxygen, halogens, sulfur and nitrogen, the said hetero atom-containing organic group being bonded to the silicon atom through a carbon-to-silicon linkage. Several particular compounds belonging to the class were synthesized and identified.

摘要翻译： 公开了一类由通式RSi（OCH2CF3）3表示的新型有机硅烷化合物，其中R是选自氢原子，具有2至20个碳原子的不饱和一价脂族烃基的原子或基团 具有3至20个碳原子并含有至少一个杂原子的单价芳基和一价有机基团，即除碳和氢原子之外的原子，如氧，卤素，硫和氮，所述含杂原子的有机物 基团通过碳 - 硅键连接到硅原子上。 合成并鉴定了属于该类的几种特定化合物。

公开(公告)号：US5414119A

公开(公告)日：1995-05-09

申请号：US203250

申请日：1994-03-01

申请人： Yasuo Tarumi ,  Noriyuki Koike ,  Toshio Takago

发明人： Yasuo Tarumi ,  Noriyuki Koike ,  Toshio Takago

IPC分类号： C07C59/60 ,  C07C51/58

CPC分类号： C07C59/60

摘要： Hexafluoropropylene oxide (HFPO) compounds, including polymers, expressed by the general chemical formula (1) below: ##STR1## wherein R.sup.1 is a single bond, an alkylene group of 1 to 10 carbon atoms, or said alkylene group in which a part of, or all of, the hydrogen atoms are substituted by fluorine atoms, Rf is a fluorine atom, a perfluoroalkyl group of 1 to 10 carbon atoms, or a perfluoroalkyl ether group, and n is 0 or an integer of at least 1. A manufacturing method for the HFPO compounds which is characterized by the reaction between hexafluoropropylene oxide and a vinyl group containing compound, expressed by the general chemical formula (2) below: ##STR2## wherein R.sup.1 and Rf are same as above. The compounds have utility as important intermediate raw materials for the production of novel functional silicone compounds having HFPO polymer units.

摘要翻译： 由下列通式（1）表示的六氟环氧丙烷（HFPO）化合物，包括聚合物：其中R 1为单键，1至10个碳原子的亚烷基或所述亚烷基，其中 一部分或全部氢原子被氟原子取代，Rf为氟原子，1-10个碳原子的全氟烷基或全氟烷基醚基，n为0或至少为1的整数 以下通式（2）表示的特征在于六氟环氧丙烷与含乙烯基的化合物反应的HFPO化合物的制造方法：其中R1和Rf与上述相同。 该化合物可用作生产具有HFPO​​聚合物单元的新型功能硅氧烷化合物的重要中间体原料。

公开(公告)号：US5278340A

公开(公告)日：1994-01-11

申请号：US903967

申请日：1992-06-26

申请人： Noriyuki Koike ,  Masayuki Oyama ,  Toshio Takago

发明人： Noriyuki Koike ,  Masayuki Oyama ,  Toshio Takago

IPC分类号： C08G65/00 ,  C07C43/12 ,  C07C51/58 ,  C07C59/135 ,  C07C59/315 ,  C08G65/22 ,  C08G65/32 ,  C07C51/04

CPC分类号： C08G65/226 ,  C07C59/135 ,  C07C59/315

摘要： Oligohexafluoropropylene oxide derivatives represented by the general formula (I): ##STR1## wherein R.sub.f represents a perfluoroalkyl group having 1 to 10 carbon atoms and n is an integer of 0 to 100 or the general formula (II): ##STR2## wherein R.sub.f ' represents a perfluoroalkylene group having 2 to 10 carbon atoms and a and b are each independently an integer of 0 to 20. These compounds are novel and are useful as intermediates for synthesizing iodine-containing oligohexafluoropropylene oxides useful as raw materials for fluororesins, fluororubbers, and fluorine-containing surfactants.

摘要翻译： 由通式（I）表示的低聚六氟环氧丙烷衍生物：（*化学结构*）（I）其中，Rf表示碳原子数1〜10的全氟烷基，n表示0〜100的整数或通式（II）： （*化学结构*）（II）其中Rf'表示具有2〜10个碳原子的全氟亚烷基，a和b各自独立地为0〜20的整数。这些化合物是新的，可用作合成含碘的中间体 可用作氟树脂，氟​​橡胶和含氟表面活性剂的原料的低聚六氟环氧丙烷。