摘要:
It is an object to provide a cathode for a secondary lithium battery in which adhesiveness and flexibility thereof are simultaneously achieved and the thickness thereof is made large, and the secondary lithium ion battery that has a large capacity and is excellent in safety and cycle life using the cathode.The cathode includes a current collector and a cathode mixture layer formed on the surface of the current collector. The cathode mixture layer is formed by stacking two layers one on another, each of which contains a cathode active material, a conductive material and a binder, and the cathode active material contains a lithium-containing composite oxide that forms a polyanion. Of the two layers, the binder that composes a first layer that is in contact with the current collector contains a polymer formed by polymerizing at least one of monomers consisting of a monomer derived from 1-olefin and a monomer derived from a vinyl compound; and the binder that forms a second layer formed on the first layer contains a fluorine resin.
摘要:
A lithium ion secondary battery according to the present invention uses a cathode material obtained by mixing a first cathode active substance represented by a compositional formula: Lix1Nia1Mnb1COc1O2 (in which 0.2≦x1≦1.2, 0.6≦a1≦0.9, 0.05≦b1≦0.3, 0.05≦c1≦0.3, and a1+b1+c1=1.0); and a second cathode active substance represented by a compositional formula: Lix2Nia2Mnb2COc2MdO2 (in which 0.2≦x2≦1.2, 0.7≦a2≦0.9, 0.05≦b2≦0.3, 0.05≦c2≦0.3, M=Mo, W, 0≦d≦0.06, and a2+b2+c2+d=1.0).
摘要:
A superconductive material has the formula(Tl.sub.1-X1-X2 Pb.sub.X1 Bi.sub.X2).sub..alpha. (Sr.sub.1-X3 Ba.sub.X3).sub..beta. Ca.sub..gamma. Cu.sub..delta. O.sub..xi.where0.ltoreq.X1.ltoreq.0.80.ltoreq.X2.ltoreq.0.50.ltoreq.X3.ltoreq.1.00.7.ltoreq..alpha..ltoreq.1.51.4.ltoreq..beta..ltoreq.3.00.7.ltoreq..gamma..ltoreq.4.51.4.ltoreq..delta..ltoreq.64.5.ltoreq..xi..ltoreq.170
摘要:
A superconductive material has the formula(Tl.sub.1-X1-x2 Pb.sub.X1 Bi.sub.X2).sub..alpha. (Sr.sub.1-X3 Ba.sub.X3).sub..beta. Ca.sub..gamma. Cu.sub..delta. O.sub..zeta.where0.ltoreq.X1.ltoreq.0.80.ltoreq.X2.ltoreq.0.50.ltoreq.X3.ltoreq.1.00.7.ltoreq..alpha..ltoreq.1.51.4.ltoreq..beta..ltoreq.3.00.7.ltoreq..gamma..ltoreq.4.51.4.ltoreq..delta..ltoreq.64.5.ltoreq..zeta..ltoreq.170
摘要:
A cathode material with excellent capacity and output characteristics and safety, and a lithium ion secondary battery using the same is provided. The invention relates to a cathode material which includes a mixture of a cathode active material having a large primary particle size with excellent capacity characteristics and represented by the composition formula: Lix1Nia1Mnb1Coc1O2, where 0.2≦x1≦1.2, 0.6≦a1, 0.05≦b1≦0.3, 0.05≦c1≦0.3, and another cathode active material having a small primary particle size with excellent output characteristics and represented by the composition formula: Lix2Nia2Mnb2Coc2O2, where 0.2≦x2≦1.2, a2≦0.5, 0.05≦b2≦0.5, 0.05≦c2≦0.5. The invention also relates to a lithium ion secondary battery using the cathode material.
摘要:
This invention provides a positive electrode material having high capacity and safety, and a lithium ion secondary battery using the positive electrode material, the lithium ion secondary battery using a positive electrode active substance comprising a first transition metal oxide represented by the compositional formula: Lix1Nia1Mnb1Coc1Md1O2; a second transition metal oxide represented by the compositional formula: Lix2Nia2Mnb2Coc2Md2O2; and a third transition metal oxide represented by the compositional formula: Lix3Nia3Mnb3Coc3Md3O2; in which a3
摘要:
The present invention provides superconductors capable of being used at temperatures to which the superconductor can be cooled in liquid nitrogen and of carrying current in a high critical current density in a magnetic field, and superconducting apparatuses employing the superconductors and more advantageous in costs than the conventional superconducting apparatuses. A superconducting wire is formed by combining a metallic body of a cubic aggregate structure and an oxide superconducting substance. The present invention provides superconductors, superconducting wires, superconducting magnets and applied superconducting apparatuses having a high superconducting critical current density. The applied super conducting apparatuses employing the superconductors or the superconducting wires in accordance with the present invention are able to operate when cooled in liquid nitrogen-and can be manufactured at costs lower than those of the conventional superconducting apparatuses.
摘要:
A positive electrode active material for a lithium ion battery includes a material represented by chemical formula LiMPO4 where M includes at least one of iron, manganese, cobalt, and nickel. Particles of the positive electrode active material have a diameter d in the range of 10 nm to 200 nm, the diameter d being determined by observation under a transmission electron microscope. A ratio d/D of the diameter d to a crystallite diameter D is in the range of 1 to 1.35, the crystallite diameter D being determined from a half width measured by X-ray diffraction. The positive electrode active material is coated with carbon, an amount of the carbon being in the range of 1 weight percent to 10 weight percent.
摘要:
A high safety cathode active material having large capacity, suppressing deterioration in storage at high temperature, and ensuring thermal stability in a charged state is provided. A cathode active material represented by a composition formula of LixNiaMnbCocM1dM2eO2 where M1 is at least one or more kinds of elements selected from the group consisting of Al, Ti, and Mg; M2 is at least one or more kinds of elements selected from the group consisting of Mo, W, and Nb; 0.2≦x≦1.2; 0.6≦a≦0.8; 0.05≦b≦0.3; 0.05≦c≦0.3; 0.02≦d≦0.04; 0.02≦e≦0.06; and a+b+c+d+e=1.0 is used.
摘要翻译:提供了一种具有大容量的高安全性的正极活性物质,能够抑制高温储存的劣化,并且能够确保充电状态下的热稳定性。 一种由组合式LixNiaMnbCocM1dM2eO2表示的正极活性物质,其中M1是选自Al,Ti和Mg中的至少一种或多种元素; M2是选自Mo,W和Nb中的至少一种以上的元素; 0.2≦̸ x≦̸ 1.2; 0.6≦̸ a≦̸ 0.8; 0.05≦̸ b≦̸ 0.3; 0.05≦̸ c≦̸ 0.3; 0.02≦̸ d≦̸ 0.04; 0.02≦̸ e≦̸ 0.06; 并且使用a + b + c + d + e = 1.0。
摘要:
It is an object to provide a cathode for a secondary lithium battery in which adhesiveness and flexibility thereof are simultaneously achieved and the thickness thereof is made large, and the secondary lithium ion battery that has a large capacity and is excellent in safety and cycle life using the cathode.The cathode includes a current collector and a cathode mixture layer formed on the surface of the current collector. The cathode mixture layer is formed by stacking two layers one on another, each of which contains a cathode active material, a conductive material and a binder, and the cathode active material contains a lithium-containing composite oxide that forms a polyanion. Of the two layers, the binder that composes a first layer that is in contact with the current collector contains a polymer formed by polymerizing at least one of monomers consisting of a monomer derived from 1-olefin and a monomer derived from a vinyl compound; and the binder that forms a second layer formed on the first layer contains a fluorine resin.