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    Catalytic oxidation and oxidative dehydrogenation using metal-compound-loaded, deboronated hams-1b crystalline borosilicate molecular sieve compositions
    21.
    发明授权
    Catalytic oxidation and oxidative dehydrogenation using metal-compound-loaded, deboronated hams-1b crystalline borosilicate molecular sieve compositions 失效
    使用金属化合物负载的脱硼火山-1b结晶硼硅酸盐分子筛组合物的催化氧化和氧化脱氢

    公开(公告)号：US5324702A

    公开(公告)日：1994-06-28

    申请号：US991113

    申请日：1992-12-16

    申请人： Jin S. Yoo ,  Mark S. Kleefisch ,  John A. Donohue

    发明人： Jin S. Yoo ,  Mark S. Kleefisch ,  John A. Donohue

    IPC分类号： B01J29/86 ,  B01J37/06 ,  B01J21/00 ,  B01J37/00

    CPC分类号： B01J37/06 ,  B01J29/86

    摘要： Compositions comprising certain metal-containing materials distributed interactively on a deboronated HAMS-1B crystalline borosilicate molecular sieve which are useful for catalytically oxidizing or oxidatively dehydrogenating organic compounds such as alkanes, aromatics, and alkyl-substituted aromatics are described. Alkanes are oxidatively dehydrogenated to olefins, and an aromatic compound such as benzene can be oxidized by nitric and/or nitrous oxide to largely phenol or largely nitrobenzene depending upon the oxidation temperature. When the compound is a methylaromatic, oxidation produces an aromatic aldehyde. Alkyl groups larger than methyl oxidatively dehydrogenate to alkenyl groups. The compositions can be used in a process to separate p-xylene from a mixture of its isomers based upon the ability of the compositions, which preferably comprise a iron molybdenum material interactively distributed on a deboronated HAMS-1B crystalline borosilicate molecular sieve, to selectively oxidize the p-xylene to an aldehyde or dialdehyde while not substantially oxidizing the ortho and metaxylene isomers. Such partially oxidized mixtures of p-xylene are useful to make TPAA or as feeds to a water-based, further oxidation to make terephthalic acid. Carbon dioxide used as a carrier gas with a methylaromatic feed to the oxidation catalyst is shown to have a beneficial effect on yield and selectivity.

    摘要翻译： 描述了包含某些含金属材料的组合物交互地分布在脱硼的HAMS-1B结晶硼硅酸盐分子筛上，其可用于催化氧化或氧化脱氢有机化合物如烷烃，芳族化合物和烷基取代的芳族化合物。 烷烃被氧化脱氢成烯烃，芳族化合物如苯可以根据氧化温度被硝酸和/或一氧化二氮氧化成大部分苯酚或大部分硝基苯。 当化合物是甲基芳族化合物时，氧化产生芳族醛。 大于甲基的烷基氧化脱氢成烯基。 基于组合物的能力，组合物可用于从其异构体的混合物中分离对二甲苯的方法，该组合物优选包含交联分布在脱硼的HAMS-1B结晶硼硅酸盐分子筛上的铁钼材料，以选择性氧化 对二甲苯变成醛或二醛，而基本上不氧化邻位和间二甲苯异构体。 这种部分氧化的对二甲苯的混合物可用于制备TPAA或作为进料进行水基的进一步氧化以制备对苯二甲酸。 用作载气的二氧化碳与甲基芳族化合物进入氧化催化剂显示对产率和选择性具有有益的影响。

    Tin-containing composition and use
    23.
    发明授权
    Tin-containing composition and use 失效
    含锡成分及用途

    公开(公告)号：US5059740A

    公开(公告)日：1991-10-22

    申请号：US555768

    申请日：1990-06-25

    申请人： Mark P. Kaminsky ,  Mark S. Kleefisch ,  Gerry W. Zajac

    发明人： Mark P. Kaminsky ,  Mark S. Kleefisch ,  Gerry W. Zajac

    IPC分类号： B01J23/14 ,  C07C2/84

    CPC分类号： B01J23/14 ,  C07C2/84 ,  C07C2523/02 ,  C07C2523/10 ,  C07C2523/14 ,  Y10S585/934

    摘要： A tin-containing composition is provided, the composition having a tin Auger line transition wherein the ratio of the area of the M.sub.5 N.sub.4,5 N.sub.4,5 transition peak at 424.5 eV.+-.1 eV, having a 6 eV FWHM, to the area of M.sub.4 N.sub.4,5 N.sub.4,5 transition peak at 430.5 eV.+-.1 eV is at least 10 to 1. Additional such tin-containing compositions, including catalyst compositions are also provided as are methods for converting feedstock alkanes containing from 1 to 4 carbon atoms to higher molecular weight hydrocarbons using such catalyst compositions.

    摘要翻译： 提供含锡组合物，组合物具有锡俄歇线转变，其中具有6eV FWHM的具有6eV FWHM的M5N4,5N4,5转变峰的面积与M4N4的面积的比值为424.5eV +/- 1eV 在430.5eV +/- 1eV下的5N4.5转变峰为至少10:1。还提供另外的这种含锡组合物，包括催化剂组合物，其方法是将含有1至4个碳原子的原料烷烃转化为更高分子量 使用这种催化剂组合物的重量烃。

    Tin-containing composition and use
    27.
    发明授权
    Tin-containing composition and use 失效
    含锡成分及用途

    公开(公告)号：US4971940A

    公开(公告)日：1990-11-20

    申请号：US382477

    申请日：1989-07-19

    申请人： Mark P. Kaminsky ,  Mark S. Kleefisch ,  Gerry W. Zajac

    发明人： Mark P. Kaminsky ,  Mark S. Kleefisch ,  Gerry W. Zajac

    IPC分类号： C10G2/00 ,  B01J23/14 ,  C07C2/84

    CPC分类号： B01J23/14 ,  C07C2/84 ,  C07C2523/02 ,  C07C2523/10 ,  C07C2523/14

    摘要： A tin-containing composition is provided, the composition having a tin Auger line transition wherein the ratio of the area of the M.sub.5 N.sub.4,5 N.sub.4,5 transition peak at 424.5 eV.+-.leV, having a 6 eV FWHM, to the area of M.sub.4 N.sub.4,5 N.sub.4,5 transition peak at 430.5 eV.+-.1eV is at least 10 to 1. Additional such tin-containing compositions, including catalyst compositions are also provided as are methods for converting feedstock alkanes containing from 1 to 4 carbon atoms to higher molecular weight hydrocarbons using such catalyst compositions.

    摘要翻译： 提供含锡组合物，该组合物具有锡俄歇线转变，其中具有6eV FWHM的424.5eV +/- leV的M5N4,5N4,5转变峰的面积与M4N4的面积的比率， 在430.5eV +/- 1eV下的5N4.5转变峰至少为10:1。还提供了另外的这种含锡组合物，包括催化剂组合物，如将含有1至4个碳原子的原料烷烃转化为较高分子量烃的方法 使用这种催化剂组合物。