公开(公告)号：US4281670A

公开(公告)日：1981-08-04

申请号：US834645

申请日：1977-09-19

申请人： Uwe Heitmann ,  Joachim Buchegger ,  Werner Hinz

发明人： Uwe Heitmann ,  Joachim Buchegger ,  Werner Hinz

IPC分类号： A24C5/60 ,  B23K26/067 ,  B23K26/08

CPC分类号： B23K26/0676 ,  A24C5/606 ,  B23K26/067 ,  B23K26/0823

摘要： Webs which are to be converted into wrappers for filter rod sections, cigars, cigarillos or cigarettes, or the wrappers of such articles, are perforated by one or more laser beams in the machine wherein the articles are produced. The permeability of wrappers can be changed by increasing or reducing the number of holes and/or by increasing or reducing the size of holes in each wrapper. The permeability of the wrappers of finished articles is monitored and the intensity of laser beam or beams is automatically adjusted when the monitored permeability deviates from a desired value. The perforations are formed for the purpose of admitting cool atmospheric air which influences the quantity of nicotine and condensate in the column of smoke. The perforations are disposed close to or in the filter plugs of filter cigarettes, cigars or cigarillos, or close to one or both ends of each filter rod section or plain cigarette, depending on the length of such articles.

摘要翻译： 要转换成滤棒部分，雪茄，雪茄或香烟的包装纸或这些物品的包装纸的网由机器中的一个或多个激光束穿孔，其中制造物品。 可以通过增加或减少孔的数量和/或通过增加或减小每个包装纸中的孔的尺寸来改变包装纸的渗透性。 监测成品的包装纸的渗透性，并且当监测的渗透率偏离期望值时，激光束或束的强度被自动调节。 形成穿孔的目的是允许影响烟柱中烟碱和冷凝物的量的冷气氛。 根据这些制品的长度，穿孔靠近过滤器香烟，雪茄或雪茄的过滤嘴或靠近每个过滤杆部分或普通卷烟的一端或两端。

公开(公告)号：US4200179A

公开(公告)日：1980-04-29

申请号：US856571

申请日：1977-12-01

申请人： Werner Hinz

发明人： Werner Hinz

IPC分类号： A24C5/47 ,  B65G47/26

CPC分类号： A24C5/478

摘要： Apparatus for increasing the distance between pairs of coaxial plain cigarettes has a rotary drum-shaped conveyor with a rotor which carries two annuli of axially movable segment-shaped holders provided with peripheral flutes for plain cigarettes. A cam with two endless grooves cooperates with rollers followers which are affixed to shifting rods for the holders to move successive aligned holders nearer to each other during travel toward a first transfer station where the flutes receive plain cigarettes and to thereupon move the holders apart during travel toward a second transfer station where the cigarettes are transferred into the flutes of a rotary assembly conveyor and are spaced apart to an extent which suffices for insertion of filter mouthpieces of double unit length. The holders are guided by tie rods which are reciprocable in a collar of the rotor.

摘要翻译： 用于增加成对的同轴平卷烟之间的距离的装置具有带有转子的旋转鼓形输送机，该转子承载设置有用于普通香烟的周边槽纹的两个可轴向移动的节段状保持器的环。 具有两个环形凹槽的凸轮与辊跟随器配合，辊跟随器固定到用于保持器的移动杆上，用于在朝向第一转运站的第一转运站行进期间移动连续对齐的保持器，其中凹槽接收平卷烟并且随后在行进期间将保持器分开 朝向第二转运站，其中香烟被转移到旋转组件输送机的凹槽中，并且间隔开到足以插入双单元长度的过滤嘴的程度。 保持器由可在转子的轴环中往复运动的拉杆引导。

公开(公告)号：US4020973A

公开(公告)日：1977-05-03

申请号：US655548

申请日：1976-02-05

申请人： Werner Hinz

发明人： Werner Hinz

IPC分类号： A24C5/31 ,  A24C5/32 ,  A24C5/352 ,  A24C5/47 ,  B65H43/00

CPC分类号： A24C5/325 ,  A24C5/31

摘要： Apparatus for removing filter rod sections from a magazine in a filter cigarette making machine. The magazine has an outlet which receives a portion of a fluted drum so that, when the drum rotates, its flutes remove filter rod sections from the magazine. A yieldably mounted refuser roller is disposed between the drum and the magazine at the downstream side of the outlet to normally prevent the drum from removing sections which are not received in the flutes. If a section adheres to a section in a flute and displaces the refuser roller against the opposition of a spring, the roller or a lever for the roller actuates a switch which disengages a clutch serving to transmit torque to the drum and to other moving parts of the machine.

摘要翻译： 用于从过滤嘴卷烟机中的盒子上移除过滤棒部分的装置。 该杂志具有一个出口，该出口接收一个凹槽滚筒的一部分，使得当滚筒旋转时，其凹槽从该盒中取出过滤杆部分。 可靠地安装的重新定位辊设置在出口的下游侧的滚筒和料仓之间，以正常地防止滚筒除去未被接收在凹槽中的部分。 如果一个部分粘附在长槽中的部分并且使得重新定位辊抵靠弹簧的对立位置，则辊或用于辊的杠杆驱动开关，该开关使用于将扭矩传递到滚筒和其它运动部件的离合器 机器。

公开(公告)号：US06762278B2

公开(公告)日：2004-07-13

申请号：US10066855

申请日：2002-02-04

申请人： Werner Hinz ,  Edward Michael Dexheimer ,  Edward Bohres ,  Georg Heinrich Grosch

发明人： Werner Hinz ,  Edward Michael Dexheimer ,  Edward Bohres ,  Georg Heinrich Grosch

IPC分类号： C08G6434

CPC分类号： C08G18/44 ,  C08G18/7621 ,  C08G64/34 ,  C08G65/2603 ,  C08G65/2663 ,  C08G2101/0083

摘要： A method of forming a polyethercarbonate polyol using a multimetal cyanide compound is disclosed. The method includes providing a multimetal cyanide compound having a crystalline structure and a content of platelet-shaped particles of at least 30% by weight, based on the weight of the multimetal cyanide compound and further including at least two of the following components: an organic complexing agent, water, a polyether, and a surface-active substance. Then an alcohol initiator is reacted with at least one alkylene oxide and carbon dioxide under a positive pressure in the presence of the multimetal cyanide compound, thereby forming the polyethercarbonate polyol.

摘要翻译： 公开了使用多金属氰化合物形成聚醚碳酸酯多元醇的方法。 该方法包括提供具有基于多金属氰化合物的重量至少30重量％的晶体结构和片状颗粒的含量的多金属氰化合物，并且还包括以下组分中的至少两种：有机 络合剂，水，聚醚和表面活性物质。 然后在多金属氰化合物的存在下，在正压下使醇引发剂与至少一种烯化氧和二氧化碳反应，从而形成聚醚碳酸酯多元醇。

公开(公告)号：US5476969A

公开(公告)日：1995-12-19

申请号：US952376

申请日：1992-09-28

申请人： Werner Hinz ,  Stefan Adams ,  Ulrich Koehler ,  Christian Maletzko ,  Klaus Vorspohl ,  Ruth Zschiesche

发明人： Werner Hinz ,  Stefan Adams ,  Ulrich Koehler ,  Christian Maletzko ,  Klaus Vorspohl ,  Ruth Zschiesche

IPC分类号： C08G18/50 ,  C08G65/26 ,  C07C217/42

CPC分类号： C08G18/5021 ,  C08G65/2624 ,  C08G2101/0008 ,  C08G2101/0016 ,  C08G2101/0025 ,  C08G2101/0033 ,  C08G2101/0041

摘要： The invention relates to highly reactive polyoxyalkylene-polyols prepared by oxyalkylation of an initiator molecule containing, in bonded form, at least 2 reactive hydrogen atoms and at least one tertiary amino group bonded via a spacer bridge, which preferably comprises an alkylene radical having at least 3 carbon atoms, by means of at least one alkylene oxide, preferably ethylene oxide and/or 1,2-propylene oxide, to a process for the preparation of these polyoxyalkylene-polyols, and to their use for the production of compact or cellular, preferably flexible polyisocyanate polyaddition products.

摘要翻译： 本发明涉及通过包含键合形式的至少2个反应性氢原子和至少一个通过间隔桥连接的叔氨基的引发剂分子的烷氧基化制备的高反应性聚氧化烯多元醇，其优选包含至少具有至少 3个碳原子，通过至少一种烯化氧，优选环氧乙烷和/或1,2-环氧丙烷与制备这些聚氧化烯 - 多元醇的方法，以及它们用于生产紧密或细胞的， 优选柔性聚异氰酸酯加成产物。

公开(公告)号：US5374667A

公开(公告)日：1994-12-20

申请号：US24589

申请日：1993-03-01

申请人： Werner Hinz ,  Ruth Zschiesche ,  Heinz-Dieter Lutter ,  Bernd Bruchmann

发明人： Werner Hinz ,  Ruth Zschiesche ,  Heinz-Dieter Lutter ,  Bernd Bruchmann

IPC分类号： C08G18/10 ,  C08G18/48 ,  C08G18/76 ,  C08G18/80 ,  C08G18/00

CPC分类号： C08G18/8035 ,  C08G18/10 ,  C08G18/4837 ,  C08G18/7664 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083 ,  Y10S521/914

摘要： The invention provides a method for the preparation of fluorochlorohydrocarbon(FCHC)-free polyurethane soft (molded) foam materials with low density, by reactingA) liquid polyisocyanate mixtures containing bound urethane groups, containing 22 to 30 weight percent of NCO groups, which in turn are prepared by reacting a mixture of diphenylmethane-diisocyanate and polyphenyl-polymethylene-polyisocyanates (raw MDI) with at least one polyoxypropylene-polyoxyethylene-polyol with a functionality between 2.5 and 3.5, a hydroxyl number between 50 and 90 and a polymerized ethylene oxide group concentration ranging from more than 30 to less than 50 weight percent, relative to the weight of the polymerized ethylene oxide and 1,2 propylene oxide groups, or by reacting of 4,4'diphenylmethane-diisocyanate (MDI) or and MDI-isomeric mixture with the above-named polyoxypropylene-polyoxyethylene-polyol to an NCO-group-containing quasi-prepolymer, and diluting this quasi-prepolymer with raw-MDI, withB) higher-molecular polyhydroxyl compounds and, if appropriateC) low-molecular chain lengthening and/or cross-linkage-promoting materialsD) propellants,E) catalysts as well as if appropriate,F) auxiliary materials and/or additives, as well as the polyisocyanate mixtures modified with urethane groups (A) which are utilizable in accordance with the process of the invention.

摘要翻译： 本发明提供了一种通过使含有22-30％（重量）NCO基团的结合的氨基甲酸酯基团的液体多异氰酸酯混合物反应来制备低密度的氟氯烃（FCHC） - 软质（模塑）泡沫材料的方法， 通过使二苯基甲烷 - 二异氰酸酯和聚苯基 - 多亚甲基多异氰酸酯（原MDI）与至少一种官能度在2.5和3.5之间，羟基数在50和90之间的聚氧化丙烯 - 聚氧乙烯 - 多元醇与聚合的环氧乙烷 相对于聚合的环氧乙烷和1,2-环氧丙烷基团的重量，或通过4,4'-二苯基甲烷二异氰酸酯（MDI）或MDI异构体（MDI）的反应，组浓度范围从大于30至小于50重量％ 与上述聚氧丙烯 - 聚氧乙烯 - 多元醇的混合物与含有NCO基的准预聚物混合，并用B-MDI稀释该准预聚物，B） 高分子量多羟基化合物，如果合适C）低分子链延长和/或交联促进材料D）推进剂，E）催化剂以及适当的F）辅助材料和/或添加剂，以及 用氨基甲酸酯基团（A）改性的多异氰酸酯混合物，其可根据本发明的方法使用。

公开(公告)号：US5364852A

公开(公告)日：1994-11-15

申请号：US53759

申请日：1993-04-29

申请人： Werner Hinz ,  Christian Maletzko ,  Johannes Becker ,  Guenter Matzke

发明人： Werner Hinz ,  Christian Maletzko ,  Johannes Becker ,  Guenter Matzke

IPC分类号： C08G18/66 ,  C08G18/10 ,  C08G18/50 ,  C08G18/65 ,  C08G101/00 ,  C08J9/02 ,  C08J9/14 ,  C08J9/34 ,  C08G18/32 ,  C08G18/60

CPC分类号： C08G18/5024 ,  C08G18/10 ,  C08G18/5021 ,  C08G2101/00 ,  C08G2120/00

摘要： Compact or cellular elastomers containing urethane and urea groups are prepared by reactinga) at least one organic and/or modified organic polyisocyanateb) at least one N-propoxylated polyoxyalkylene-polyamine containing at least 50% of secondary amino groups or a mixture of said N-propoxylated polyoxyalkylene-polyamines and polyoxyalkylene-polyamines containing 2 to 4 primary amino groups and having a molecular weight of from 1000 to 8000,c) at least one alkyl-substituted aromatic polyamine having a molecular weight up to 500, in the presence or absence ofd) catalysts and, if desired,e) blowing agents,f) auxiliaries and/org) additives.

摘要翻译： 通过使a）至少一种有机和/或改性的有机多异氰酸酯b）至少一种含有至少50％的仲氨基的N-丙氧基化的聚氧化烯 - 多胺或所述的 含有2-4个伯氨基，分子量为1000-8000的N-丙氧基化聚亚烷基 - 多胺和聚氧化烯 - 多胺，c）至少一种分子量高达500的烷基取代的芳族多胺， 没有d）催化剂，如果需要，e）发泡剂，f）助剂和/或g）添加剂。

公开(公告)号：US5306798A

公开(公告)日：1994-04-26

申请号：US970749

申请日：1992-11-02

申请人： Peter Horn ,  Werner Hinz ,  Georg Knoblauch ,  Falko Ramsteiner ,  Gottfried Knorr

发明人： Peter Horn ,  Werner Hinz ,  Georg Knoblauch ,  Falko Ramsteiner ,  Gottfried Knorr

IPC分类号： A61L29/00 ,  A61F2/00 ,  A61L27/34 ,  A61M5/00 ,  B01D63/02 ,  C08G18/02 ,  C08G18/10 ,  C08G18/12 ,  C08G18/48 ,  C08G18/50 ,  C08G18/66 ,  C08G18/76 ,  C08G18/32

CPC分类号： C08G18/6696 ,  A61L27/34 ,  B01D63/023 ,  C08G18/12 ,  C08G18/4804 ,  C08G18/50

摘要： The invention relates to transparent, autoclavable, non-cytotoxic, essentially compact polyurethane embedding compositions which are prepared by reactinga) modified diphenylmethane diisocyanates withb) compounds with at least two reactive hydrogens, which contain or are composed ofb1) at least one polyether-polyol with an average functionality of from 3 to 8, a hydroxyl number of from 200 to 1000 and an alkali metal ion content of from 150 to 1200 ppm or, preferably, a mixture of (b1) and castor oil and/or at least one polyetherpolyol (b2) with a functionality of from 2 to 3, a hydroxyl number of from 90 to 200 and an alkali metal ion content of less than 10 ppm in the presence or absence ofc) catalysts and to a process for preparing the polyurethane embedding compositions and to the use thereof for articles used in medicine.

摘要翻译： 本发明涉及通过使a）改性二苯基甲烷二异氰酸酯与b）化合物与至少两种反应性氢反应而制备的透明，高压灭菌，非细胞毒性，基本上致密的聚氨酯嵌入组合物，其含有或由b1组成的至少一种聚醚 - 多元醇，平均官能度为3至8，羟值为200至1000，碱金属离子含量为150至1200ppm，或优选（b1）和蓖麻油的混合物和/或至少 在c）催化剂存在或不存在下，一种聚醚多元醇（b2）的官能度为2至3，羟值为90至200，碱金属离子含量小于10ppm，并且制备聚氨酯 包埋组合物及其在医药中使用的制品的用途。

公开(公告)号：US4827947A

公开(公告)日：1989-05-09

申请号：US158306

申请日：1988-02-19

申请人： Werner Hinz

发明人： Werner Hinz

IPC分类号： A24C5/60 ,  B23K26/08

CPC分类号： B23K26/0823 ,  A24C5/606

摘要： Successive filter cigarettes of unit length or multiple unit length are transported sidways on a first drum-shaped conveyor which cooperates in a filter tipping machine with a second drum-shaped conveyor to rotate successive cigarettes about their respective axes so that the rotating cigarettes come to a temporary halt in a predetermined portion of their path. Such cigarettes are acted upon the two or more laser beams or light beams which are equidistant from and angularly offset relative to each other in the circumferential direction of the cigarette which rotates about its axis so that a circumferentially complete portion of the rotating cigarette is acted upon by radiation while the cigarette completes a fraction of one revolution, namely an angle of 360 degrees divided by the number of beams. The first conveyor has peripheral advancing surfaces for individual cigarettes, and the length of each advancing surface in the circumferential direction of the first conveyor equals the circumferential length of a cigarette divided by the number of beams. The mutual spacing of cigarettes on the first conveyor is less than the mutual spacing of cigarettes on a conveyor which feeds successive untreated cigarettes to the first conveyor ahead of the rolling station and on a conveyor which receives successive treated cigarettes from the first conveyor downstream of the rolling station.

摘要翻译： 单位长度或多个单位长度的连续过滤嘴香烟在第一个鼓形输送机上运输，在第二个鼓形输送机上，该过滤嘴香烟与一个第二鼓形输送机在一个过滤嘴连接机器中配合，以使连续的香烟围绕其各自的轴旋转，从而使旋转的香烟进入 在其路径的预定部分暂时停止。 这种香烟作用在两根或多根激光束或光束上，这些激光束或光束在香烟的圆周方向上相对于彼此等距离并且沿角度偏移，该卷烟的圆周方向绕其轴线旋转，使得旋转香烟的周向完整部分作用在 通过辐射，而香烟完成了一圈的一分之一，即360度的角度除以光束的数量。 第一输送机具有用于单个香烟的周边前进表面，并且第一输送机的圆周方向上的每个前进表面的长度等于香烟的圆周长度除以梁的数量。 香烟在第一输送机上的相互间距小于输送机上的香烟的相互间隔，该输送机将连续未经处理的香烟供给到轧制站前面的第一输送机，以及在从第一输送机下游的第一输送机接收连续处理的香烟的输送机上 滚动站。

公开(公告)号：US06806348B2

公开(公告)日：2004-10-19

申请号：US10364788

申请日：2003-02-11

申请人： Werner Hinz ,  Edward Michael Dexheimer

发明人： Werner Hinz ,  Edward Michael Dexheimer

IPC分类号： C08G600

CPC分类号： B01J27/28 ,  B01J27/26 ,  B01J38/62 ,  C08G65/2663 ,  C08G65/2696 ,  C08G65/30 ,  C08G65/32 ,  Y02P20/582 ,  Y02P20/584

摘要： A method of removing and reclaiming a double metal cyanide (DMC) catalyst from a polyol is disclosed. A polymeric acid that is soluble in the polyol is introduced into the polyol during or after the polymerization reaction. The polymeric acid reacts with the double metal cyanide catalyst thereby causing the double metal cyanide catalyst and the polymeric acid to form an agglomeration in the polyol. The agglomeration is easily separated from the polyol via filtration, for example. The recovered agglomerated DMC catalyst can then be reconstituted using an acid solution.