公开(公告)号：US5658852A

公开(公告)日：1997-08-19

申请号：US449452

申请日：1995-05-24

申请人： Gerald J. Murphy ,  George A. Policello

发明人： Gerald J. Murphy ,  George A. Policello

IPC分类号： A01M1/20 ,  A01N25/02 ,  A01N25/04 ,  A01N25/10 ,  A01N25/30 ,  A01N55/00 ,  A01N55/10 ,  A01N61/02 ,  C07F7/18 ,  A01N25/24

CPC分类号： A01N55/00 ,  A01N25/30 ,  A01N61/02

摘要： Linear alkylsilicone compounds of the formula ##STR1## wherein x=0 to 20, preferably 0 to 10, most preferably 0 to 1; y=1 to 10, preferably 1 to 5, most preferably 1; and R is an alkyl or alkyl ester group containing 6 to 16 carbons, or cyclic alkylsilicone compounds of the formula ##STR2## where m is 0 to 4, preferably 0 to 2, most preferably 0, and n is 1 to 5, preferably 3 to 5, most preferably 4, provided that m+n=3 to 5, are adjuvants for agricultural applications of oil-containing compositions. Especially preferred alkylsilicone compounds have a degree of polymerization of .ltoreq.6 and an alkyl content of .ltoreq.50% by weight. The compounds potentiate spreading of mineral or vegetable oils or oil-containing emulsions in dormant spray oils, crop oil concentrates, pesticides, and the like on difficult-to wet surfaces such as waxy leaf cuticles and arthropod exoskeletons.

摘要翻译： 其中x = 0至20，优选0至10，最优选0至1的直链烷基硅氧烷化合物。 y = 1〜10，优选1〜5，最优选1; 和R为含有6至16个碳原子的烷基或烷基酯基，或式“IMAGE”的环烷基硅氧烷化合物，其中m为0至4，优选0至2，最优选0，n为1至5，优选3 至5，最优选4，条件是m + n = 3至5，是用于含油组合物的农业应用的佐剂。 特别优选的烷基硅氧烷化合物的聚合度为＆lt; 6＆gt;烷基含量为<50重量％。 这些化合物加强了在难以湿润的表面如蜡状叶片角质层和节肢动物外骨骼上的休眠喷雾油，作物油浓缩物，农药等中的矿物油或植物油或含油乳剂的铺展。

公开(公告)号：US5104647A

公开(公告)日：1992-04-14

申请号：US541958

申请日：1990-06-22

申请人： George A. Policello

发明人： George A. Policello

IPC分类号： A01N25/30 ,  C08L71/02 ,  C08L83/06 ,  C08L83/12

CPC分类号： C08L71/02 ,  A01N25/30 ,  C08L83/06 ,  C08L83/12

摘要： A surfactant mixture for use as a pesticide adjuvant comprising an organosilicone compound and a polyalkyleneoxide copolymer.

摘要翻译： 用作农药助剂的表面活性剂混合物，其包含有机硅氧烷化合物和聚环氧烷共聚物。

公开(公告)号：US5045225A

公开(公告)日：1991-09-03

申请号：US455875

申请日：1989-12-18

申请人： Michael P. Aronson ,  Samuel O. Lin ,  George A. Policello

发明人： Michael P. Aronson ,  Samuel O. Lin ,  George A. Policello

IPC分类号： B01D19/04 ,  C11D3/00

CPC分类号： C11D3/0026 ,  B01D19/0409

摘要： An antifoam composition and laundry detergent formulation including it. The antifoam composition comprises a selected alkylaminosilicone, finely divided filler particles and a hydrocarbon carrier oil. Optional ingredients include oil/water surfactants and silicone oils. The alkylaminosilicone reduces the surface tension of the hydrocarbon oil and renders the formulation self-hydrophobing.

摘要翻译： 包含它的消泡剂组合物和衣物洗涤剂制剂。 消泡剂组合物包含选择的烷基氨基硅氧烷，细分散的填料颗粒和烃载体油。 可选配成分包括油/水表面活性剂和硅油。 烷基氨基硅氧烷降低烃油的表面张力并使配方自我疏水。

公开(公告)号：US08470894B2

公开(公告)日：2013-06-25

申请号：US13251667

申请日：2011-10-03

申请人： Mark D. Leatherman ,  George A. Policello ,  Wenqing N. Peng ,  Liping Zheng ,  Roland Wagner ,  Suresh K. Rajaraman ,  Zijun Xia

发明人： Mark D. Leatherman ,  George A. Policello ,  Wenqing N. Peng ,  Liping Zheng ,  Roland Wagner ,  Suresh K. Rajaraman ,  Zijun Xia

IPC分类号： B01F3/08 ,  C07F7/10

CPC分类号： A01N25/30 ,  B01F17/0071 ,  C07F7/0838 ,  C11D3/3738 ,  C11D3/3742

摘要： The present invention provides for a composition comprising a siloxane having the formula: M1DM2 wherein M1=(R1)(R2)(R3)SiO1/2; M2=(R4)(R5)(R6)SiO1/2 and D=(R7)(Z)SiO2/2 where R1, R2, R3 R4, R5, R6 and R7 are each independently selected from the group consisting of 1 to 4 carbon monovalent hydrocarbon radicals, aryl, and a hydrocarbon group of 4 to 9 carbons containing an aryl group; Z is a pendant hydrophilic ionic group selected from the group consisting of R8—RA, R9-RC, and R10—RZ; RA being an anionic substituent, RC a cationic substituent or RZ a zwitterionic substituent on the D group wherein said siloxane has an enhanced resistance to hydrolysis at a pH below 6 or a pH above 7.5.

摘要翻译： 本发明提供包含具有下式的硅氧烷的组合物：M1DM2其中M1 =（R1）（R2）（R3）SiO1 / 2; M2 =（R4）（R5）（R6）SiO1 / 2和D =（R7）（Z）SiO2 / 2其中R1，R2，R3 R4，R5，R6和R7各自独立地选自1〜 4碳一价烃基，芳基和含有芳基的4至9个碳的烃基; Z是选自R8-RA，R9-RC和R10-RZ的侧链亲水离子基团; RA为阴离子取代基，RC为阳离子取代基或RZ为D基团上的两性离子取代基，其中所述硅氧烷在pH低于6或pH高于7.5时具有增强的水解抗性。

公开(公告)号：US08367740B2

公开(公告)日：2013-02-05

申请号：US12810967

申请日：2008-12-26

申请人： Mark D. Leatherman ,  George A. Policello ,  Wenqing N. Peng ,  Liping Zheng ,  Roland Wagner ,  Suresh K. Rajaraman ,  Xia Zijun

发明人： Mark D. Leatherman ,  George A. Policello ,  Wenqing N. Peng ,  Liping Zheng ,  Roland Wagner ,  Suresh K. Rajaraman ,  Xia Zijun

IPC分类号： B01F3/08 ,  C07F7/08

CPC分类号： A01N25/30 ,  B01F17/0071 ,  C07F7/0838 ,  C08G77/388 ,  C08G77/46 ,  C11D3/3738 ,  C11D3/3742

摘要： An asymmetric organomodified disiloxane surfactant having the formula: MM′ wherein M comprises branched hydrocarbon substituents and M′ comprises a cationic, anionic or zwitterionic substituent and a polyether substituent that may be combined as one moiety, wherein the disiloxane surfactant has an enhanced resistance to hydrolysis between a pH of about 3 to about 12.

摘要翻译： 具有下式的不对称有机改性二硅氧烷表面活性剂：其中M包含支链烃取代基，M'包含阳离子，阴离子或两性离子取代基和可以作为一个部分结合的聚醚取代基，其中二硅氧烷表面活性剂具有增强的抗水解性 在约3至约12的pH之间。

公开(公告)号：US08263669B2

公开(公告)日：2012-09-11

申请号：US12810976

申请日：2008-12-26

申请人： Mark D. Leatherman ,  George A. Policello ,  Wenging N. Peng ,  Liping Zheng ,  Roland Wagner ,  Suresh K. Rajaraman ,  Xia Zijun

发明人： Mark D. Leatherman ,  George A. Policello ,  Wenging N. Peng ,  Liping Zheng ,  Roland Wagner ,  Suresh K. Rajaraman ,  Xia Zijun

IPC分类号： B01F3/08 ,  C07F7/10

CPC分类号： A01N25/30 ,  B01F17/0071 ,  C07F7/0838 ,  C11D3/3738 ,  C11D3/3742

摘要： The present invention provides for a composition comprising a siloxane having the formula: M1D M2 wherein M1=(R1)(R2)(R3)SiO1/2; M2=(R4)(R5)(R6)SiO1/2 and D=(R7)(Z)SiO2/2 where R1, R2, R3 R4, R5, R6 and R7 are each independently selected from the group consisting of 1 to 4 carbon monovalent hydrocarbon radicals, aryl, and a hydrocarbon group of 4 to 9 carbons containing an aryl group; Z is a pendant hydrophilic ionic group selected from the group consisting of R8—RA, R9 Rc and R10—RZ; RA being an anionic substituent, Rc a cationic substituent or Rz a zwitterionic substituent on the D group wherein the composition is resistant to hydrolysis under either basic or acidic conditions.

摘要翻译： 本发明提供包含具有下式的硅氧烷的组合物：M1D M2其中M1 =（R1）（R2）（R3）SiO1 / 2; M2 =（R4）（R5）（R6）SiO1 / 2和D =（R7）（Z）SiO2 / 2其中R1，R2，R3 R4，R5，R6和R7各自独立地选自1〜 4碳一价烃基，芳基和含有芳基的4至9个碳的烃基; Z是选自R8-RA，R9Rc和R10-RZ的侧链亲水性离子基团; RA为阴离子取代基，Rc为阳离子取代基或Rz为D基团上的两性离子取代基，其中所述组合物在碱性或酸性条件下对水解具有抗性。

公开(公告)号：US08008231B2

公开(公告)日：2011-08-30

申请号：US11427961

申请日：2006-06-30

申请人： Mark D. Leatherman ,  George A. Policello ,  Suresh K. Rajaraman

发明人： Mark D. Leatherman ,  George A. Policello ,  Suresh K. Rajaraman

IPC分类号： A01N55/10

CPC分类号： C11D3/162 ,  A01N25/30 ,  A61K8/585 ,  A61K8/894 ,  A61K2800/31 ,  A61Q19/00 ,  C05D9/02 ,  C07F7/0838 ,  C08L83/04 ,  C09D163/00 ,  C09D167/00 ,  C09D167/08 ,  C05G3/06 ,  C08L2666/44 ,  C08L83/00

摘要： Compositions comprising an asymmetric disiloxane surfactant composition comprising a silicone composition comprising a silicone having the formula: MM′ where M or M′ comprises an alkylpolyalkyleneoxide bearing substituent selected from the group consisting of: R13(C2H4O)a(C3H6O)b(C4H8O)cR14 and R12SiR5R6(R13(C2H4O)a(C3H6O)b(C4H8O)cR14) that exhibit resistance to hydrolysis over a wide pH range.

摘要翻译： 包含不对称二硅氧烷表面活性剂组合物的组合物，其包含硅氧烷组合物，其包含具有下式的MM的硅氧烷，其中M或M'包含带有取代基的烷基聚环氧烷烃，所述取代基选自：R 13（C 2 H 4 O）a（C 3 H 6 O）b（C 4 H 8 O）c R 14 和在宽pH范围内表现出抗水解性的R12SiR5R6（R13（C2H4O）a（C3H6O）b（C4H8O）cR14）。

公开(公告)号：US20100215922A1

公开(公告)日：2010-08-26

申请号：US12712377

申请日：2010-02-25

申请人： Suresh K. Rajaraman ,  Eric R. Pohl ,  Mark D. Leatherman ,  George A. Policello

发明人： Suresh K. Rajaraman ,  Eric R. Pohl ,  Mark D. Leatherman ,  George A. Policello

IPC分类号： B32B3/10 ,  C08L83/02 ,  C08L53/00

CPC分类号： C09D11/02 ,  C07F7/081 ,  C08G65/3322 ,  C08G65/336 ,  C08L33/08 ,  C08L43/04 ,  C08L2205/05 ,  C09D7/65 ,  C09D11/102 ,  C09D171/02 ,  Y10T428/24802 ,  C08L2666/02

摘要： The present invention relates to coating and printing ink compositions containing silylated polyether compounds comprising a hydrolysis-resistant bis-silyl hydrocarbylene group. More particularly, the silylated polyether compound comprising a bis-silyl hydrocarbylene group provides to the coating and ink compositions formulation flexibility over the entire pH range, leveling-and-flow and surface wetting, and are non-reactive with the other components of the coating and ink compositions, thereby providing long-term shelf-stability of formulated coatings and inks. These coating and ink compositions containing silylated polyether compounds do not release silicone materials and thereby provide articles treated with these coatings and ink compositions with uniform appearance and gloss.

摘要翻译： 本发明涉及包含含有耐水解双甲硅烷基亚烃基的甲硅烷基化聚醚化合物的涂料和印刷油墨组合物。 更具体地，包含双甲硅烷基亚烃基的甲硅烷基化聚醚化合物在整个pH范围内赋予涂料和油墨组合物配方柔性，流平和流动和表面润湿，并且与涂层的其它组分不反应 和油墨组合物，从而提供配方涂料和油墨的长期储存稳定性。 含有甲硅烷基化聚醚化合物的这些涂料和油墨组合物不释放硅氧烷材料，从而提供用这些涂料处理的制品和具有均匀外观和光泽的油墨组合物。

公开(公告)号：US07645720B2

公开(公告)日：2010-01-12

申请号：US11301707

申请日：2005-12-13

申请人： Mark D. Leatherman ,  George A. Policello ,  Suresh K. Rajaraman

发明人： Mark D. Leatherman ,  George A. Policello ,  Suresh K. Rajaraman

IPC分类号： A01N25/04 ,  A01N25/16

CPC分类号： A61Q19/00 ,  A61K8/585 ,  C09D163/00 ,  C08L2666/44

摘要： Compositions comprising disiloxane surfactant compositions comprising a silicone composition comprising a silicone having the formula: MM′ where M=R1R2R3SiO1/2; M′=R4R5R6SiO1/2; with R1 selected from the group consisting of branched monovalent hydrocarbon radical of from 3 to 6 carbon atoms and R7, where R7 has the formula: R8R9R10SiR12 with R8, R9, and R10 each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 6 carbon atoms and monovalent aryl or alkaryl hydrocarbon radicals having from 6 to 13 carbon atoms and R12 is a divalent hydrocarbon radical having from 1 to 3 carbon atoms, R2 and R3 are each independently selected from the group of from 1 to 6 carbon atom monovalent hydrocarbon radicals or R1, with R4 an alkylpolyalkyleneoxide of the general formula: R13(C2H4O)a(C3H6O)b(C4H8O)cR14 where R13 is a divalent linear or branched hydrocarbon radical having the structure: —CH2—CH(R15)(R16)dO— where R15 is H or methyl; R16 is a divalent alkyl radical of 1 to 6 carbons where the subscript d may be 0 or 1; R14 is selected from the group consisting of H, monovalent hydrocarbon radicals of from 1 to 6 carbon atoms and acetyl where the subscripts a; b and c are zero or positive and satisfy the following relationships: 2≦a+b+c≦20 with a≧2, and R5 and R6 are each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 6 carbon atoms or R4 that exhibit resistance to hydrolysis over a wide pH range.

摘要翻译： 包含二硅氧烷表面活性剂组合物的组合物，其包含硅氧烷组合物，其包含具有式MM的其中M = R 1 R 2 R 3 SiO 1/2的硅氧烷; M'= R4R5R6SiO1 / 2; 其中R 1选自3至6个碳原子的支化一价烃基和R 7，其中R 7具有下式：R 8 R 9 R 10 SiR 12，其中R 8，R 9和R 10各自独立地选自具有1至 6个碳原子和具有6至13个碳原子的单价芳基或烷芳基烃基，R 12是具有1至3个碳原子的二价烃基，R 2和R 3各自独立地选自1至6个碳原子的单价 烃基或R 1，其中R 4是具有通式R 13（C 2 H 4 O）a（C 3 H 6 O）b（C 4 H 8 O）c R 14的烷基聚环氧烷，其中R 13是具有以下结构的二价直链或支链烃基：-CH 2 -CH（R 15） ）dO-，其中R 15是H或甲基; R16是1至6个碳的二价烷基，其中下标d可以是0或1; R 14选自H，1至6个碳原子的一价烃基和乙酰基，其中下标a; b和c为零或正，并且满足以下关系：2和R5和R6各自独立地选自具有1至6个碳原子的一价烃基或在宽pH范围内表现出抗水解性的R4。

公开(公告)号：US06593274B2

公开(公告)日：2003-07-15

申请号：US09812436

申请日：2001-03-20

申请人： George A. Policello

发明人： George A. Policello

IPC分类号： A01N6300

CPC分类号： C07F7/0838

摘要： The present invention teaches the composition of terminally modified, amino, polyether, siloxanes, known hereforth as amino siloxane alkokylates, and their use as adjuvants. The amino siloxane alkoxylates of the present invention enhance the efficacy of agrichemicals on plants as compared to conventional TSE's alone. The amino siloxane alkoxylates have at one end, an amine functionality and at the other end, a polyalkyleneoxide functionality.

摘要翻译： 本发明教导了末端改性的氨基，聚醚，硅氧烷（其在本文中称为氨基硅氧烷烷基酯）的组成及其作为佐剂的用途。 与单独的常规TSE相比，本发明的氨基硅氧烷烷氧基化物增强了农药对植物的功效。 氨基硅氧烷烷氧基化物在一端具有胺官能团，另一端具有聚亚烷基氧化物官能团。