公开(公告)号：US09017639B2

公开(公告)日：2015-04-28

申请号：US13554127

申请日：2012-07-20

申请人： Xiang-Ming He ,  Li Wang ,  Jian-Jun Li ,  Jian-Wei Guo ,  Wen-Ting Sun ,  Jian-Guo Ren

发明人： Xiang-Ming He ,  Li Wang ,  Jian-Jun Li ,  Jian-Wei Guo ,  Wen-Ting Sun ,  Jian-Guo Ren

IPC分类号： C01B31/02 ,  B82Y40/00 ,  B82Y30/00 ,  C01B31/04 ,  C25B1/00 ,  H01M4/587

CPC分类号： C01B31/0469 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/19 ,  C25B1/00 ,  H01M4/587

摘要： In the method for making graphene, an electrolyte solution is formed by dissolving an electrolyte lithium salt in an organic solvent. Lithium ions are separated out from the electrolyte lithium salt in the electrolyte solution. Metal lithium and graphite are disposed in the electrolyte solution, and the metal lithium and the graphite are in contact with each other. In the electrolyte solution, lithium ions and organic solvent molecules jointly insert between adjacent layers of the graphite to form a graphite intercalation compound. The graphene is peeled off from the graphite intercalation compound.

摘要翻译： 在制造石墨烯的方法中，通过将电解质锂盐溶解在有机溶剂中形成电解质溶液。 从电解液中的电解质锂盐中分离出锂离子。 金属锂和石墨配置在电解液中，金属锂和石墨彼此接触。 在电解液中，锂离子和有机溶剂分子在相邻的石墨层之间共同插入以形成石墨插层化合物。 石墨烯从石墨插层化合物上剥离出来。

公开(公告)号：US08623965B2

公开(公告)日：2014-01-07

申请号：US13051131

申请日：2011-03-18

申请人： Xiang-Ming He ,  Li Wang ,  Wei-Hua Pu ,  Wen-Ting Sun ,  Jian-Jun Li

发明人： Xiang-Ming He ,  Li Wang ,  Wei-Hua Pu ,  Wen-Ting Sun ,  Jian-Jun Li

IPC分类号： C08F8/34 ,  H01M4/137 ,  C08F8/42 ,  C08F20/44

CPC分类号： H01M4/608 ,  H01M10/0525

摘要： The present disclosure relates to a sulfurized polyacrylonitrile and a lithium-ion battery cathode active material. The sulfurized polyacrylonitrile includes a structural unit. A general molecular formula of the structural unit is C3HNSn, in which n is a positive integer. The lithium-ion battery cathode active material includes sulfurized polyacrylonitrile and a sulfurized polyacrylonitrile with inserted ions.

摘要翻译： 本发明涉及硫化聚丙烯腈和锂离子电池正极活性物质。 硫化聚丙烯腈包括结构单元。 结构单元的一般分子式是C3HNSn，其中n是正整数。 锂离子电池正极活性物质包括硫化聚丙烯腈和带有插入离子的硫化聚丙烯腈。

公开(公告)号：US08273829B2

公开(公告)日：2012-09-25

申请号：US13051123

申请日：2011-03-18

申请人： Xiang-Ming He ,  Li Wang ,  Wei-Hua Pu ,  Wen-Ting Sun ,  Jian-Jun Li

发明人： Xiang-Ming He ,  Li Wang ,  Wei-Hua Pu ,  Wen-Ting Sun ,  Jian-Jun Li

IPC分类号： C08F6/06 ,  C08F20/44

CPC分类号： H01M4/137 ,  C08F8/48 ,  H01M4/1399 ,  H01M4/604 ,  H01M10/052 ,  C08F120/44

摘要： The present disclosure relates to a method for making a conjugated polymer. In the method, polyacrylonitrile, a solvent, and a catalyst are provided. The polyacrylonitrile is dissolved in the solvent to form a polyacrylonitrile solution. The catalyst is uniformly dispersed into the polyacrylonitrile solution. The polyacrylonitrile solution with the catalyst is heated to induce a cyclizing reaction of the polyacrylonitrile, thereby forming a conjugated polymer solution with conjugated polymer.

摘要翻译： 本发明涉及制备共轭聚合物的方法。 在该方法中，提供聚丙烯腈，溶剂和催化剂。 将聚丙烯腈溶解在溶剂中以形成聚丙烯腈溶液。 催化剂均匀分散在聚丙烯腈溶液中。 将具有催化剂的聚丙烯腈溶液加热以引起聚丙烯腈的环化反应，从而与共轭聚合物形成共轭聚合物溶液。

公开(公告)号：US08372919B2

公开(公告)日：2013-02-12

申请号：US13051117

申请日：2011-03-18

申请人： Xiang-Ming He ,  Li Wang ,  Wei-Hua Pu ,  Wen-Ting Sun ,  Jian-Jun Li

发明人： Xiang-Ming He ,  Li Wang ,  Wei-Hua Pu ,  Wen-Ting Sun ,  Jian-Jun Li

IPC分类号： C08F8/34 ,  C08F8/48

CPC分类号： C08F8/34 ,  C08F8/48 ,  C08F120/44

摘要： In a method for making sulfurized polyacrylonitrile, polyacrylonitrile, a first solvent, a catalyst, and sulfur or sodium thiosulfate are provided. The polyacrylonitrile is dissolved in the first solvent to form a polyacrylonitrile solution. The catalyst is uniformly dispersed in the polyacrylonitrile solution. The polyacrylonitrile solution with the catalyst is heated to induce a cyclizing reaction of the polyacrylonitrile, thereby forming a first conjugated polymer solution with a conjugated polymer. The sulfur or sodium thiosulfate is uniformly mixed with the conjugated polymer to form a mixture. The mixture is heated to form sulfurized polyacrylonitrile.

摘要翻译： 在制备硫化聚丙烯腈的方法中，提供聚丙烯腈，第一溶剂，催化剂和硫代硫代硫酸钠。 将聚丙烯腈溶解在第一溶剂中以形成聚丙烯腈溶液。 催化剂均匀分散在聚丙烯腈溶液中。 加热具有催化剂的聚丙烯腈溶液引起聚丙烯腈的环化反应，由此与共轭聚合物形成第一共轭聚合物溶液。 将硫或硫代硫酸钠与共轭聚合物均匀混合以形成混合物。 将混合物加热以形成硫化聚丙烯腈。

公开(公告)号：US08450605B2

公开(公告)日：2013-05-28

申请号：US13051148

申请日：2011-03-18

申请人： Xiang-Ming He ,  Li Wang ,  Wei-Hua Pu ,  Wen-Ting Sun ,  Jian-Jun Li

发明人： Xiang-Ming He ,  Li Wang ,  Wei-Hua Pu ,  Wen-Ting Sun ,  Jian-Jun Li

IPC分类号： C08F6/06 ,  C08F20/44 ,  H01L51/44 ,  H01L51/46 ,  H01L51/48

CPC分类号： H01L51/004 ,  C08F8/48 ,  H01L51/424 ,  C08F120/44

摘要： The present disclosure relates to a method for making a conjugated polymer. In the method, polyacrylonitrile, a solvent, and a catalyst are provided. The polyacrylonitrile is dissolved in the solvent to form a polyacrylonitrile solution. The catalyst is uniformly dispersed into the polyacrylonitrile solution. The polyacrylonitrile solution with the catalyst is heated to induce a cyclizing reaction of the polyacrylonitrile, thereby forming a conjugated polymer solution with the conjugated polymer dissolved therein.

摘要翻译： 本发明涉及制备共轭聚合物的方法。 在该方法中，提供聚丙烯腈，溶剂和催化剂。 将聚丙烯腈溶解在溶剂中形成聚丙烯腈溶液。 催化剂均匀分散在聚丙烯腈溶液中。 将具有催化剂的聚丙烯腈溶液加热以引起聚丙烯腈的环化反应，从而形成共轭聚合物溶液，其中共轭聚合物溶解在其中。

公开(公告)号：US09362016B2

公开(公告)日：2016-06-07

申请号：US13553931

申请日：2012-07-20

申请人： Jian-Gang Li ,  Xiang-Ming He ,  Jian-Jun Li ,  Jian Gao ,  Li Wang

发明人： Jian-Gang Li ,  Xiang-Ming He ,  Jian-Jun Li ,  Jian Gao ,  Li Wang

IPC分类号： H01B1/08 ,  H01M4/00 ,  C01G53/00 ,  H01M4/04 ,  H01M4/1391 ,  H01M4/36 ,  H01M4/505 ,  H01M4/62

CPC分类号： H01B1/08 ,  C01G53/54 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/80 ,  C01P2006/40 ,  H01M4/0471 ,  H01M4/1391 ,  H01M4/366 ,  H01M4/505 ,  H01M4/62 ,  Y02E60/122 ,  Y02P70/54

摘要： A cathode active material of a lithium ion battery includes a number of LiNi0.5Mn1.5O4 particles and an AlF3 layer coated on a surface of the LiNi0.5Mn1.5O4 particles. A method for making the cathode active material is provided. In the method, a number of LiNi0.5Mn1.5O4 particles are provided. The LiNi0.5Mn1.5O4 particles are added to a trivalent aluminum source solution to form a solid-liquid mixture. A fluorine source solution is put into the solid-liquid mixture to react and form an AlF3 layer coated on the surface of the LiNi0.5Mn1.5O4 particles. The coated LiNi0.5Mn1.5O4 particles are heat treated to form the cathode active material. A lithium ion battery including the cathode active material is also provided.

摘要翻译： 锂离子电池的正极活性物质包括多个LiNi 0.5 Mn 1.5 O 4颗粒和涂覆在LiNi0.5Mn1.5O4颗粒表面上的AlF 3层。 提供了制造阴极活性材料的方法。 在该方法中，提供了许多LiNi 0.5 Mn 1.5 O 4颗粒。 将LiNi0.5Mn1.5O4颗粒加入到三价铝源溶液中以形成固液混合物。 将氟源溶液放入固液混合物中反应并形成涂覆在LiNi0.5Mn1.5O4颗粒表面上的AlF3层。 涂覆的LiNi0.5Mn1.5O4颗粒被热处理以形成阴极活性材料。 还提供了包括阴极活性材料的锂离子电池。

公开(公告)号：US09159988B2

公开(公告)日：2015-10-13

申请号：US13719993

申请日：2012-12-19

申请人： Xiang-Ming He ,  Jian-Jun Li ,  Li Wang ,  Jian Gao

发明人： Xiang-Ming He ,  Jian-Jun Li ,  Li Wang ,  Jian Gao

IPC分类号： C23C26/00 ,  H01M4/04 ,  H01M4/66 ,  H01M4/133

CPC分类号： H01M4/0404 ,  H01M4/0409 ,  H01M4/133 ,  H01M4/663 ,  H01M4/667 ,  Y02E60/122 ,  Y02P70/54

摘要： A method for making a current collector of an electrochemical battery is disclosed. In the method, a current collecting metal substrate and a solid graphite source are provided. A graphite/graphene layer is formed on at least one surface of the current collecting metal substrate, by rubbing the at least one surface of the current collecting metal substrate with the solid graphite source. A method for making an electrode of an electrochemical battery is also disclosed.

摘要翻译： 公开了一种用于制造电化学电池的集电器的方法。 在该方法中，提供集电金属基板和固体石墨源。 通过用固体石墨源摩擦集电金属基板的至少一个表面，在集电金属基板的至少一个表面上形成石墨/石墨烯层。 还公开了一种用于制造电化学电池的电极的方法。

公开(公告)号：US09815914B2

公开(公告)日：2017-11-14

申请号：US13652807

申请日：2012-10-16

申请人： Li Wang ,  Xiang-Ming He ,  Jian-Jun Li ,  Jian Gao ,  Chang-Yin Jiang

发明人： Li Wang ,  Xiang-Ming He ,  Jian-Jun Li ,  Jian Gao ,  Chang-Yin Jiang

IPC分类号： H01M10/056 ,  C08F2/48 ,  H01M10/0565 ,  C08F222/10 ,  C08F220/28 ,  H01M10/052

CPC分类号： C08F2/48 ,  C08F222/1006 ,  C08F2220/286 ,  H01M10/052 ,  H01M10/0565 ,  H01M2300/0082

摘要： A solid electrolyte includes an interpenetrating polymer network and a lithium salt dispersed in the interpenetrating polymer network. The interpenetrating polymer network includes CH2—CH2On segments, and is formed by polymerizing a first monomer R1—OCH2—CH2—OnR2, a second monomer R3—OCH2—CH2—OmR4 and an initiator. Each “R1”, “R2” and “R3” includes —C═C— group or —C≡C— group. The “R4 . . . ” includes an alkyl group or a hydrogen atom. The “m” and “n” are integer. Molecular weights of the first monomer and the second monomer are more than or equal to 100, and less than or equal to 800. The first monomer is less than or equal to 50% of the second monomer by weight. The lithium salt is less than or equal to 10% the second monomer by weight. A lithium based battery using the solid electrolyte is also provided.

公开(公告)号：US09250297B2

公开(公告)日：2016-02-02

申请号：US13675028

申请日：2012-11-13

申请人： Xiang-Ming He ,  Jian-Jun Li ,  Li Wang ,  Jian Gao

发明人： Xiang-Ming He ,  Jian-Jun Li ,  Li Wang ,  Jian Gao

IPC分类号： G01N27/416 ,  G01R31/36

CPC分类号： G01R31/3627

摘要： A method for testing a lithium ion battery is disclosed. An under-test lithium ion battery including a cathode active material is provided. A reference voltage value is set according to the cathode active material. The under-test lithium ion battery is over charged, while an actual voltage change of the under-test lithium ion battery is tested during the over charging. A maximum voltage value is recorded before a first decrease in the actual voltage change of the under-test lithium ion battery during the over charging. The maximum voltage value is compared with the reference voltage value. A method for evaluating a safety of a lithium ion battery is also disclosed.

摘要翻译： 公开了一种锂离子电池的测试方法。 提供了包含正极活性物质的未被测试的锂离子电池。 根据阴极活性物质设定基准电压值。 未充分测试的锂离子电池过电压，而在过充电期间测试未测试锂离子电池的实际电压变化。 在过充电期间，被测试锂离子电池的实际电压变化的第一次降低之前记录最大电压值。 将最大电压值与参考电压值进行比较。 还公开了一种用于评估锂离子电池的安全性的方法。

公开(公告)号：US08889293B2

公开(公告)日：2014-11-18

申请号：US13652610

申请日：2012-10-16

申请人： Xiang-Ming He ,  Li Wang ,  Jian-Jun Li ,  Jian Gao ,  Wen-Ting Sun

发明人： Xiang-Ming He ,  Li Wang ,  Jian-Jun Li ,  Jian Gao ,  Wen-Ting Sun

IPC分类号： H01M4/60

CPC分类号： H01M4/137 ,  H01M4/131 ,  H01M4/136 ,  H01M4/5825 ,  H01M4/608 ,  H01M10/0525

摘要： A lithium ion battery includes a cathode electrode, an anode electrode, and an electrolyte. The anode electrode is spaced from the cathode electrode. The anode electrode includes an anode active material. The anode active material includes sulfur grafted poly(pyridinopyridine). The sulfur grafted poly(pyridinopyridine) includes a poly(pyridinopyridine) matrix and sulfur dispersed in the poly(pyridinopyridine) matrix. The electrolyte is located between the cathode electrode and the anode electrode.

摘要翻译： 锂离子电池包括阴极电极，阳极电极和电解质。 阳极与阴极隔开。 阳极电极包括阳极活性材料。 阳极活性材料包括硫接枝的聚（吡啶并吡啶）。 硫接枝的聚（吡啶并吡啶）包括分散在聚（吡啶并吡啶）基质中的聚（吡啶并吡啶）基质和硫。 电解质位于阴极和阳极之间。