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公开(公告)号：US06239236B1
公开(公告)日：2001-05-29
申请号：US09663335
申请日：2000-09-18
IPC分类号： C08F444
摘要： The invention relates to solid catalyst components for the polymerization of olefins CH2═CHR, in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Ti, Mg, halogen and an electron donor compound selected from cyanoesters of formula (I): wherein R1 is a C1-C20 linear or branched alkyl, alkenyl, cycloalkyl, cycloalkylalkyl, alkylcycloalkyl, aryl, arylalkyl or alkylaryl group; n is 0, 1, 2 or 3; R2, R3, R4 and R5 are independently selected from hydrogen or C1-C20 linear or branched alkyl, alkenyl, cycloalkyl, cycloalkylalkyl, alkylcycloalkyl, aryl, arylalkyl or alkylaryl groups; two or more of R2 and R3, and R4 and R5, can be joined to form a cycle. Said catalyst components when used in the polymerization of olefins are characterized by an excellent response to hydrogen and capability to produce polymers with broad Molecular Weight Distribution.
摘要翻译： 本发明涉及用于烯烃CH 2 = CHR（其中R是氢或具有1-12个碳原子的烃基）的聚合的固体催化剂组分，其包含Ti，Mg，卤素和选自式（I）的氰酯的电子给体化合物 ）：其中R1是C1-C20直链或支链烷基，烯基，环烷基，环烷基烷基，烷基环烷基，芳基，芳基烷基或烷基芳基; n为0,1,2或3; R 2，R 3，R 4和R 5独立地选自氢或C 1 -C 20直链或支链烷基，烯基，环烷基，环烷基烷基，烷基环烷基，芳基，芳基烷基或烷基芳基; R2和R3中的两个或更多个，以及R4和R5可以连接形成一个循环。 当用于烯烃聚合时，所述催化剂组分的特征在于对氢的优异响应和产生具有宽分子量分布的聚合物的能力。
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公开(公告)号：US07098164B2
公开(公告)日：2006-08-29
申请号：US10506176
申请日：2003-02-28
CPC分类号： C08F10/00 , C08F110/06 , C08F210/16 , C08F2/40 , C08F2/002 , C08F4/651 , C08F4/6492 , C08F2500/12 , C08F2500/15 , C08F2500/17 , C08F210/08
摘要： A process for the (co) polymerization of olefins of formula CH2═CHR wherein R is a hydrogen atom, a methyl or an ethyl radical, carried out in the presence of a system comprising (a) solid catalyst component comprising a compound of Ti or V not containing Metal-π bonds, Mg, halogen and optionally an electron donor compound; (b) an Al-alkyl compound; and (c) one or more non-polymerizing olefins in an amount up to 1.2% by mol with respect to the total olefins present in the reactor.
摘要翻译： 一种使式CH 2 -CHR的烯烃（共）聚合的方法，其中R是氢原子，甲基或乙基，在包含（a）固体的体系存在下进行 催化剂组分，其包含不含金属-I键的Ti或V的化合物，Mg，卤素和任选的电子给体化合物; （b）Al-烷基化合物; 和（c）相对于存在于反应器中的总烯烃，至多1.2摩尔％的量的一种或多种非聚合烯烃。
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公开(公告)号：US07005487B2
公开(公告)日：2006-02-28
申请号：US10486876
申请日：2003-06-23
申请人： Giulio Balbontin , Giampiero Morini
发明人： Giulio Balbontin , Giampiero Morini
IPC分类号： C08F4/42 , C08F210/00
CPC分类号： C08F110/06 , C08F4/025 , C08F4/651 , C08F4/6541 , C08F2500/12 , C08F2500/04 , C08F4/6545
摘要： A solid catalyst component for the polymerization of olefins, comprising: an inert porous support, Mg, Ti, halogen and an electron donor selected from succinates of formula (I) wherein the radicals R1 and R2 equal to or different form each other, are hydrocarbon groups, the radicals R3, R4, R5 and R6, equal to or different from each other, are hydrogen or hydrocarbon groups.
摘要翻译： 一种用于烯烃聚合的固体催化剂组分，包括：惰性多孔载体，Mg，Ti，卤素和选自式（I）的琥珀酸盐的电子给体，其中基团R 1和R 0 > 2 相同或不同，是烃基，基团R 3，R 4，R 5和 R 6彼此相同或不同，为氢或烃基。
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公开(公告)号：US06841632B2
公开(公告)日：2005-01-11
申请号：US10344616
申请日：2002-06-10
IPC分类号： C08F4/654 , C07C43/10 , C07C43/115 , C07C43/12 , C08F4/651 , C08F10/00 , C08F110/06 , C08F4/42
CPC分类号： C08F4/651 , C07C43/10 , C07C43/115 , C07C43/126 , C08F110/06 , C08F2500/12 , C08F2500/17
摘要： Solid catalyst components comprising Ti,Mg, halogen and internal electron-donor compound selected from the 1,3-diethers of formula (I) in which R is a C1-C10 alkyl group, R1 is a linear or branched primary alkyl radical having at least three carbon atoms, optionally containing a heteroatom, and R2 is a secondary alkyl or cycloalkyl radicals different from i-propyl, optionally containing a heteroatom. The catalysts obtained by using as internal electron-donor compound the said 1,3-diethers display in the (co)polymerization of olefins an excellent balance of activity and stereospecificity that cannot be reached with the ethers known in the art.
摘要翻译： 包含Ti，Mg，卤素和选自式（I）的1,3-二醚的固体催化剂组分，其中R是C1-C10烷基，R1是直链或支链的伯烷基，其具有 至少三个碳原子，任选地含有杂原子，并且R 2是不同于任选含有杂原子的异丙基的仲烷基或环烷基。 通过使用作为内部电子给体化合物获得的催化剂，所述1,3-二醚在烯烃的（共）聚合中显示出与本领域已知的醚不能达到的活性和立体特异性的极好的平衡。
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公开(公告)号：US06689850B2
公开(公告)日：2004-02-10
申请号：US10455899
申请日：2003-06-06
IPC分类号： C08F4649
CPC分类号： C08F10/06 , C07C69/63 , C08F4/6365 , C08F4/651
摘要： The present invention relates to a process for the polymerization of olefins using catalyst components and catalysts obtained therefrom comprising Ti, Mg, halogen and an electron donor compound selected from heteroatoms containing esters of malonic acids. The catalysts are particularly suitable for the sterospecific polymermerization of olefins having high isotactic index expressed in terms of high xylene insolubility.
摘要翻译： 本发明涉及一种使用催化剂组分和由其获得的催化剂聚合烯烃的方法，其包含Ti，Mg，卤素和选自含有丙二酸酯的杂原子的电子给体化合物。 催化剂特别适用于以高二甲苯不溶性表示的具有高全同立构指数的烯烃的固相特异性聚酯化。
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公开(公告)号：US06395670B1
公开(公告)日：2002-05-28
申请号：US09306532
申请日：1999-05-06
IPC分类号： B01J3100
CPC分类号： C08F10/00 , C08F4/651 , C08F4/6494 , C08F4/6543
摘要： The present invention relates to catalyst components for the polymerization of olefins having Mg, Ti, halogen and at least two internal electron donor compounds, said catalyst components characterized by the fact that at least one of the electron donor compounds is selected from ethers containing two or more ether groups which are further characterized by the formation of complexes with anhydrous magnesium dichloride in an amount less than 60 mmoles per 100 g of MgCl2 and by the failure of entering into substitution reactions with TiCl4 or by reacting in that way for less than 50% by moles, and at least another electron donor compound selected from esters of mono or polycarboxylic acids. Said catalyst components are able to produce propylene polymers which, for high values of xylene insolubility, show a broad range of isotacticity.
摘要翻译： 本发明涉及用于聚合具有Mg，Ti，卤素和至少两种内部电子给体化合物的烯烃的催化剂组分，所述催化剂组分的特征在于至少一种电子给体化合物选自含有两个或多个 更多的醚基团，其进一步的特征在于与无水二氯化镁形成配合物，其量小于60毫摩尔/ 100g MgCl 2，并且通过与TiCl 4进行取代反应或通过以这种方式反应少于50％ 和至少另一种选自单羧酸或多元羧酸的电子给体化合物。 所述催化剂组分能够生产丙烯聚合物，其对于高二甲苯不溶性值显示出广泛的全同立构规整度。
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公开(公告)号：US6048818A
公开(公告)日：2000-04-11
申请号：US94309
申请日：1998-06-09
CPC分类号： C08F10/00
摘要： The present invention relates to a solid catalyst component for the polymerization of olefins CH.sub.2 .dbd.CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising a titanium compound, having at least a Ti-halogen bond and an electron donor compound supported on a Mg halide, in which said electron donor compound is selected from esters of malonic acids of formula (I): ##STR1## wherein R.sub.1 is a C.sub.5 -C.sub.20 linear or branched alkyl, a C.sub.5 -C.sub.20 cycloalkyl, a C.sub.7 -C.sub.20 arylalkyl or alkylaryl group; R.sub.2 and R.sub.3, equal to or different from each other, are C.sub.1 -C.sub.3 alkyl, cycloalkyl. Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give high yields and polymers having high insolubility in xylene.
摘要翻译： 本发明涉及一种用于烯烃CH 2 = CHR的聚合的固体催化剂组分，其中R是氢或具有1-12个碳原子的烃基，其包含至少具有Ti-卤素键的钛化合物和电子给体 负载在卤化镁上的化合物，其中所述电子给体化合物选自式（I）的丙二酸的酯：其中R1是C5-C20直链或支链烷基，C5-C20环烷基，C7-C20芳烷基或 烷基芳基 R2和R3彼此相同或不同，为C1-C3烷基，环烷基。 当用于烯烃聚合，特别是丙烯时，所述催化剂组分能够产生高产率和在二甲苯中具有高不溶性的聚合物。
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28.发明授权Process for the preparation of a solid catalyst component suitable for the polymerization of olefins which includes at least two additions of an electron donor 失效制备适用于烯烃聚合的固体催化剂组分的方法，其包括至少两种电子给体的添加物
公开(公告)号：US5723400A
公开(公告)日：1998-03-03
申请号：US603962
申请日：1996-02-20
CPC分类号： C08F10/00
摘要： Process for the preparation of a solid catalyst component for olefins polymerization including (1) a magnesium halide in active form, (2) a titanium compound, and (3) an electron-donor compound selected from particular 1,3-diethers, the process being carried out by reaction between the compounds from (1) to (3), and including at least two additions of electron-donor (3) in the following order: a) one addition prior to or during a reaction with the titanium compound or with a halogenated compound, and then b) one addition prior to or during a further reaction with the titanium compound.
摘要翻译： 制备用于烯烃聚合的固体催化剂组分的方法，包括（1）活性形式的卤化镁，（2）钛化合物和（3）选自特定1,3-二醚的电子给体化合物，该方法 通过来自（1）至（3）的化合物之间的反应进行，并且按以下顺序包括至少两个电子给体（3）的添加：a）在与钛化合物反应之前或期间， 与卤代化合物反应，然后b）在与钛化合物进一步反应之前或期间进行一次加料。
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公开(公告)号：US07223712B2
公开(公告)日：2007-05-29
申请号：US10971227
申请日：2004-10-22
IPC分类号： B01J31/02
CPC分类号： C08F4/651 , C07C43/10 , C07C43/115 , C07C43/126 , C08F110/06 , C08F2500/12 , C08F2500/17
摘要： An internal electron-donor compound selected from the 1,3-diethers of formula (I) in which R is a C1–C10 alkyl group, R1 is a linear or branched primary alkyl radical having at least three carbon atoms, optionally containing a heteroatom, and R2 is a secondary alkyl or cycloalkyl radicals different from i-propyl, optionally containing a heteroatom.
摘要翻译： 选自式（I）的1,3-二醚的内电子给体化合物，其中R是C 1 -C 10烷基，R 1， 1是具有至少三个碳原子的直链或支链伯烷基，任选地含有杂原子，R 2是不同于异丙基的仲烷基或环烷基，任选含有 杂原子。
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公开(公告)号：US07169871B2
公开(公告)日：2007-01-30
申请号：US10965543
申请日：2004-10-14
申请人： Giampiero Morini , Giulio Balbontin
发明人： Giampiero Morini , Giulio Balbontin
IPC分类号： C08F110/06
CPC分类号： C08F10/00 , C08F4/651 , C08F4/6545
摘要： The present invention relates to propylene polymers made by using catalyst components for the polymerization of olefins comprising Mg, Ti, halogen and at least two electron donor compounds, said catalyst component being characterized by the fact that at least one of the electron donor compounds, present in an amount from 20 to 50% by mol with respect to the total amount of donors, is selected from esters of succinic acids which are not extractable, under the conditions described below, for more than 25% by mol and at least another electron donor compound which is extractable, under the same conditions, for more than 35%. The said catalyst component are capable to give polymers with high xylene insolubility, high stereoblock content and broad MWD suitable for making the polymers usable in the BOPP sector.
摘要翻译： 本发明涉及通过使用催化剂组分制备的丙烯聚合物，其用于包含Mg，Ti，卤素和至少两种电子给体化合物的烯烃的聚合，所述催化剂组分的特征在于至少一种电子给体化合物存在 相对于供体总量为20至50摩尔％的量选自不可提取的琥珀酸的酯，在下述条件下，超过25摩尔％，并且至少另一种电子给体 在相同条件下可提取35％以上的化合物。 所述催化剂组分能够产生具有高二甲苯不溶性，高立体嵌段含量和宽MWD的聚合物，其适用于使聚合物可用于BOPP部分。
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