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1.发明授权1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers 失效1,3-二醚和用于烯烃聚合的组分和催化剂，其含有所述二醚公开(公告)号：US07049377B1
公开(公告)日：2006-05-23
申请号：US08603497
申请日：1996-02-20
IPC分类号： C08F4/44
CPC分类号： C08F10/00 , C07C41/16 , C07C43/162 , C07C2601/10 , C07C2602/08 , C07C2603/18 , C07C2603/24 , C07C2603/28 , C07D311/82 , C07F7/081 , C08F110/06 , C08F4/651 , C08F4/6494 , C08F2500/12 , C08F2500/17
摘要： Cyclopolyenic 1,3-diethers wherein the carbon atom in position 2 belongs to a particular cyclic or polycyclic structure containing two or three unsaturations, solid catalyst components and catalysts therefrom, the catalysts comprising the reaction product of: i. a solid catalyst component containing an internal donor; ii. an Al-alkyl compound, and optionally iii. an external donor; the internal donor and/or the external donor being cyclopolyenic 1,3-diethers. The catalysts are useful for the polymerization of alpha-olefins.
摘要翻译： 其中位置2的碳原子属于特定的含有两个或三个不饱和的环状或多环结构的环多烯1,3-二醚，固体催化剂组分和催化剂，所述催化剂包含以下反应产物： 含有内给体的固体催化剂组分; ii。 烷基铝化合物，和任选的iii。 外部供体; 内给体和/或外供体是环多取代1,3-二醚。 该催化剂可用于α-烯烃的聚合。
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2.发明授权Process for the preparation of a solid catalyst component suitable for the polymerization of olefins which includes at least two additions of an electron donor 失效制备适用于烯烃聚合的固体催化剂组分的方法，其包括至少两种电子给体的添加物
公开(公告)号：US5723400A
公开(公告)日：1998-03-03
申请号：US603962
申请日：1996-02-20
CPC分类号： C08F10/00
摘要： Process for the preparation of a solid catalyst component for olefins polymerization including (1) a magnesium halide in active form, (2) a titanium compound, and (3) an electron-donor compound selected from particular 1,3-diethers, the process being carried out by reaction between the compounds from (1) to (3), and including at least two additions of electron-donor (3) in the following order: a) one addition prior to or during a reaction with the titanium compound or with a halogenated compound, and then b) one addition prior to or during a further reaction with the titanium compound.
摘要翻译： 制备用于烯烃聚合的固体催化剂组分的方法，包括（1）活性形式的卤化镁，（2）钛化合物和（3）选自特定1,3-二醚的电子给体化合物，该方法 通过来自（1）至（3）的化合物之间的反应进行，并且按以下顺序包括至少两个电子给体（3）的添加：a）在与钛化合物反应之前或期间， 与卤代化合物反应，然后b）在与钛化合物进一步反应之前或期间进行一次加料。
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公开(公告)号：US07022640B2
公开(公告)日：2006-04-04
申请号：US10876576
申请日：2004-06-28
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , C07C41/16 , C07C43/162 , C07C2601/10 , C07C2602/08 , C07C2603/18 , C07C2603/24 , C07C2603/28 , C07D311/82 , C07F7/081 , C08F110/06 , C08F4/651 , C08F4/6494 , C08F2500/12 , C08F2500/17
摘要： Cyclopolyenic 1,3-diethers wherein the carbon atom in position 2 belongs to a particular cyclic or polycyclic structure containing two or three unsaturations, solid catalyst components and catalysts therefrom, the catalysts comprising the reaction product of: i. a solid catalyst component containing an internal donor; ii. an Al-alkyl compound, and optionally iii. an external donor; the internal donor and/or the external donor being cyclopolyenic 1,3-diethers. The catalysts are useful for the polymerization of alpha-olefins.
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公开(公告)号：US5552359A
公开(公告)日：1996-09-03
申请号：US391327
申请日：1995-02-21
申请人： Giampiero Morini , Luisa Barino , Raimondo Scordamaglia , Elisabetta Barbassa , Giovanni Baruzzi
发明人： Giampiero Morini , Luisa Barino , Raimondo Scordamaglia , Elisabetta Barbassa , Giovanni Baruzzi
IPC分类号： C08F4/647 , C07C211/11 , C07C211/25 , C07C211/27 , C08F4/60 , C08F4/649 , C08F4/651 , C08F4/654 , C08F10/00 , B01J31/00
CPC分类号： C08F10/00 , C07C211/11 , C07C211/25 , C07C211/27 , C07C2101/14 , C07C2101/16
摘要： Disclosed are catalyst components for the polymerization of olefins which include magnesium halide in active form, and, supported thereon, a titanium halide or titanium halogen alcoholate and an electron-donor compound selected from the group diamines of formula ##STR1## wherein the radicals R.sub.1 to R.sub.10 are the same or different and are hydrogen or C.sub.1 -C.sub.18 hydrocarbon radicals, with the proviso that at least one of the R.sub.7 and R.sub.8 radicals and at least one of the R.sub.9 and R.sub.10 radicals are not hydrogen. Also, disclosed are catalysts obtained from the catalyst components and an Al-alkyl compound, as well as catalysts obtained by reaction of an Al-alkyl compound and a diamine of formula (I) with a solid catalyst component including a titanium halide or a titanium halogen alcoholate, and an electron-donor compound having particular characteristics of extractability with Al-triethyl, supported on magnesium halide in active form.
摘要翻译： 公开了用于烯烃聚合的催化剂组分，其包括活性形式的卤化镁，并且在其上负载有卤化钛或卤化钛卤化物，以及选自式（I）的二胺的电子给体化合物，其中 基团R 1至R 10相同或不同，为氢或C 1 -C 18烃基，条件是R 7和R 8基团中的至少一个和R 9和R 10基团中的至少一个不是氢。 还公开了由催化剂组分和Al-烷基化合物获得的催化剂，以及由烷基铝化合物和式（I）的二胺与固体催化剂组分反应获得的催化剂，所述固体催化剂组分包括卤化钛或钛 卤素醇化物，和具有萃取性的具有特征的三乙基铝的电子给体化合物，负载在活性形式的卤化镁上。
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5.发明授权Catalyst component and catalyst for the polymerization of alpha-olefins to stereoregular polymers having narrow molecular weight distribution 失效用于将α-烯烃聚合成具有窄分子量分布的立体规则聚合物的催化剂组分和催化剂
公开(公告)号：US4980329A
公开(公告)日：1990-12-25
申请号：US353223
申请日：1989-05-15
CPC分类号： C08F10/00
摘要： Disclosed is a component for a catalyst for the polymerization of alpha-olefins to stereoregular polymers having narrow molecular weight distribution. The product is formed by the reaction of a solid catalyst-forming component comprising (1) a Ti compound having at least one Ti-halogen bond and (2) optionally, an electron-donor compound, supported on an anhydrous Mg dihalide in active form, with certain amounts of an organic compound (AH) containing at least one active hydrogen atom, in the presence of a liquid medium which is inert with respect to the Ti compound and the other components of the catalyst component, and which has a dielectric constant greater than 2 at 20.degree. C.Catalysts comprising the reaction product of the solid catalyst component prepared as above described, with an Al-alkyl compound and an electron-donor compound are also disclosed.
摘要翻译： 公开了用于将α-烯烃聚合成具有窄分子量分布的立体规则聚合物的催化剂的组分。 该产物是由固体催化剂形成组分反应形成的，该组分包含（1）具有至少一个Ti-卤素键的Ti化合物和（2）任选的电子给体化合物，负载在活性形式的无水Mg二卤化物上 在一定量的含有至少一个活性氢原子的有机化合物（AH）的存在下，相对于Ti化合物和催化剂组分的其它组分是惰性的，并且具有介电常数 在20℃下大于2的催化剂也包括如上所述制备的固体催化剂组分与烷基铝化合物和电子给体化合物的反应产物。
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公开(公告)号：US4129559A
公开(公告)日：1978-12-12
申请号：US626289
申请日：1975-10-28
摘要： Disclosed are reverse osmosis anisotropic gel-type membranes having the structure: ##STR1## WHEREIN N IS A WHOLE NUMBER; A is a divalent group derived from piperazine and having the structure: ##STR2## WHEREIN X IS 0 TO 8 AND R is an alkyl group, and Q is at least two divalent organic groups selected from the group consisting of: ##STR3## wherein Y is O or S, ##STR4## Also disclosed are processes for preparing such membranes.
摘要翻译： 公开了具有以下结构的反渗透各向异性凝胶型膜：（AQ）n WHEREIN N是全数; A是衍生自哌嗪的二价基团，其结构如下：其中X为0至8，R为烷基，Q为至少两个选自以下的二价有机基团：其中Y 是O或S，
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公开(公告)号：US20050049371A1
公开(公告)日：2005-03-03
申请号：US10497000
申请日：2002-11-22
IPC分类号： C08F2/34 , C08F4/02 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/18 , C08L23/10 , C08L23/12 , C08L23/16 , C08F4/44
CPC分类号： C08F210/18 , C08F4/65912 , C08F4/65927 , C08F110/06 , C08L23/10 , C08L23/16 , C08L2203/14 , C08F4/65916 , C08F4/027 , C08L2666/06 , C08F2500/17 , C08F2500/18 , C08F2500/24 , C08F2500/20 , C08F210/06 , C08F232/00 , C08F2500/25 , C08F2500/21
摘要： A process for the preparation of heterophasic elastomeric polymer comprising the step of polymerizing ethylene, an alpha-olefin CH2=CHL, where L is an alkyl, cycloalkyl or aryl radical with 1-10 carbon atoms and a non-conjugated diene in the presence of a catalyst system comprising a transition metal catalyst component supported on a porous alpha-olefin polymer, characterized in that at least part of the diene is impregnated on the porous alpha-olefin polymer.
摘要翻译： 一种用于制备多相弹性体聚合物的方法，包括聚合乙烯，α-烯烃CH 2 = CHL的步骤，其中L是具有1-10个碳原子的烷基，环烷基或芳基和非共轭二烯，在存在 包含负载在多孔α-烯烃聚合物上的过渡金属催化剂组分的催化剂体系，其特征在于至少部分二烯浸渍在多孔α-烯烃聚合物上。
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公开(公告)号：US06716940B1
公开(公告)日：2004-04-06
申请号：US10070120
申请日：2002-02-28
IPC分类号： C08F442
CPC分类号： C08F10/00 , C08F4/6426
摘要： Catalyst system for the polymerization of olefins CH2═CHR, wherein R is hydrogen or a hydrocarbon radical having 1-12 carbon atoms, comprising the product of the reaction between (a) a solid catalyst component comprising Mg, Ti, and halogen, (b) dimethylaluminium chloride (DMAC) and (c) an alkylaluinium compound, in which the molar ratio between (b) and (c) is lower than 10. This kind of catalyst system is particularly suitable for the preparation of copolymers of ethylene with &agr;-olefins due to its high capacity for incorporating the comonomer while at the same time maintaining high yields.
摘要翻译： 用于烯烃CH 2 = CHR（其中R是氢或具有1-12个碳原子的烃基）聚合的催化剂体系包括（a）包含Mg，Ti和卤素的固体催化剂组分（b ）二甲基氯化铝（DMAC）和（c）（b）和（c）之间的摩尔比低于10的烷基铝化合物。这种催化剂体系特别适用于制备乙烯与α- 烯烃，因为它具有高的并入共聚单体的能力，同时保持高产率。
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公开(公告)号：US5902163A
公开(公告)日：1999-05-11
申请号：US854196
申请日：1997-05-09
摘要： A debris shedding buoy having a float body with a top and a bottom is provided. The buoy includes a slide rail, adapted for slidable engagement to a mooring line, is attached to the bottom of the float body. The slide rail is located in a generally centered position beneath the float body and is oriented in a first direction. A rudder device is affixed to the float body and adapted to produce a stabilizing force to maintain the float body in a quasi stable orientation with respect to a current direction, with the first direction being generally aligned to the current direction. Debris lodging against the float body overcomes the stabilizing force produced by the rudder device, causing the float body to rotate from the quasi stable orientation to a second orientation to shed the debris whereupon the float body rotates back to the quasi stable orientation.
摘要翻译： 提供具有顶部和底部的浮体的碎屑脱落浮标。 浮子包括适于滑动接合到系泊线的滑轨，附接到浮体的底部。 滑轨位于浮子体下方的大致中心位置并且沿第一方向定向。 方向舵装置固定在浮子体上并适于产生稳定力，以使浮体相对于电流方向保持在准稳定的方位，而第一方向大致与电流方向对准。 靠在浮体上的碎屑克服了由舵装置产生的稳定力，导致浮体从准稳定方向旋转到第二方位，从而使浮体转动回到准稳定方向。
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公开(公告)号：US5557025A
公开(公告)日：1996-09-17
申请号：US675229
申请日：1991-03-26
申请人： Luciano Noristi , Giovanni Baruzzi
发明人： Luciano Noristi , Giovanni Baruzzi
CPC分类号： C08F10/00
摘要： A process for preparing hyperpure propylene (co)polymers comprising polymerizing the monomer(s) in liquid monomer in the presence of a catalyst obtained by reacting an Al-trialkyl compound with a solid catalyst component comprising magnesium dihalide in active form, having supported thereon a titanium chloride or chloroalcoholate, and an ether having the general formula: ##STR1## where R and R" are the same or different and are C.sub.2-18 alkyl, C.sub.3-18 cycloalkyl, C.sub.6-18 aryl, C.sub.7-18 arylalkyl or alkylaryl radicals.
摘要翻译： 一种制备超纯丙烯（共）聚合物的方法，包括在通过使三烷基铝化合物与包含活性形式的二卤化镁的固体催化剂组分反应获得的催化剂存在下使液体单体聚合的单体，其上负载有 氯化钛或氯代醇化物，以及具有以下通式的醚：其中R和R“相同或不同，为C2-18烷基，C3-18环烷基，C6-18芳基，C7-18 芳基烷基或烷基芳基。
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