Propylene resin foam particles and foam particle molded article

    公开(公告)号:US10336880B2

    公开(公告)日:2019-07-02

    申请号:US15542261

    申请日:2015-01-09

    Abstract: Provided is an expanded propylene resin bead including a core layer in a foamed state, which includes a propylene-based resin composition (a) satisfying the following (i) and (ii); and a cover layer which includes an olefin-based resin (b) satisfying the following (iii) or (iv): (i) the propylene-based resin composition (a) is a mixture of 65% by weight to 98% by weight of a propylene-based resin (a1) having a melting point of 145° C. to 165° C. and a flexural modulus of 1,200 MPa or more and 35% by weight to 2% by weight of a propylene-based resin (a2) having a melting point of 100° C. to 145° C. and a flexural modulus of 800 MPa to 1,200 MPa; (ii) a difference in a melting point between the resin (a1) and the resin (a2) is 5° C. to 25° C.; (iii) the olefin-based resin (b) is a crystalline olefin-based resin having a melting point (TmB) that is lower than a melting point (TmA) of the composition (a) and being in a relation of (0° C.

    POLYOLEFIN RESIN FOAM PARTICLES, FOAM-PARTICLE MOULDED BODY, AND COMPOSITE STACKED BODY INCLUDING SAID MOULDED BODY
    25.
    发明申请
    POLYOLEFIN RESIN FOAM PARTICLES, FOAM-PARTICLE MOULDED BODY, AND COMPOSITE STACKED BODY INCLUDING SAID MOULDED BODY 审中-公开
    聚烯烃树脂泡沫颗粒,泡沫塑料体,以及复合层压体,包括模压体

    公开(公告)号:US20170009038A1

    公开(公告)日:2017-01-12

    申请号:US14914598

    申请日:2015-03-20

    Abstract: The present invention relates to polyolefin resin expanded beads containing multi-layer expanded beads containing a core layer in a foamed state containing a polyolefin resin and a cover layer coated on the core layer, the cover layer containing a mixed resin of a polyolefin resin (A) and at least one resin (B) selected from a polystyrene resin and a polyester resin, and the mixed resin having a weight ratio (A/B) of the polyolefin resin (A) and the resin (B) of from 15/85 to 90/10, and a composite laminated body using an expanded beads molded body thereof, and the expanded beads molded body is excellent in solvent resistance and also excellent in adhesiveness to a thermosetting resin on the surface of the molded body, and can provide a composite laminated body excellent in productivity with a thermosetting resin.

    Abstract translation: 本发明涉及含有多层发泡珠粒的聚烯烃树脂发泡珠,该多层发泡珠含有包含聚烯烃树脂的发泡状态的核心层和涂覆在芯层上的覆盖层,该覆盖层含有聚烯烃树脂(A )和至少一种选自聚苯乙烯树脂和聚酯树脂的树脂(B),聚烯烃树脂(A)和树脂(B)的重量比(A / B)为15/85 90/10以及使用其发泡珠粒成型体的复合层压体,发泡珠成型体的耐溶剂性优异,且与成型体的表面的热固性树脂的粘合性优异,可以提供 复合层叠体,其热固性树脂的生产率优异。

    Polycarbonate resin foamed blow-molded article and process for producing same
    26.
    发明授权
    Polycarbonate resin foamed blow-molded article and process for producing same 有权
    聚碳酸酯树脂发泡吹塑制品及其制备方法

    公开(公告)号:US09259874B2

    公开(公告)日:2016-02-16

    申请号:US13571718

    申请日:2012-08-10

    CPC classification number: B29C49/04 B29C49/0005 B29K2069/00 B29K2105/04

    Abstract: A process for producing a foamed blow-molded article, including melting and mixing a branched polycarbonate resin having a specific polystyrene equivalent weight average molecular weight, a specific weight average absolute molecular weight and a relatively high terminal hydroxyl group content, a linear polycarbonate resin having specific polystyrene equivalent weight average molecular weight, a specific weight average absolute molecular weight and a relatively low terminal hydroxyl group content and a branching agent to obtain a polycarbonate resin “A”, mixing the polycarbonate resin “A” with a blowing agent to obtain a foamable molten resin composition, extruding the foamable molten resin composition to obtain a foamed parison, and blow-molding the foamed parison.

    Abstract translation: 一种生产发泡吹塑制品的方法,包括熔融和混合具有特定聚苯乙烯换算重均分子量,比重重量平均绝对分子量和相对高的末端羟基含量的支链聚碳酸酯树脂,具有 特定的聚苯乙烯换算的重均分子量,比重的平均绝对分子量和相对低的末端羟基含量和支化剂,得到聚碳酸酯树脂“A”,将聚碳酸酯树脂“A”与发泡剂混合,得到 可发泡熔融树脂组合物,挤出可发泡熔融树脂组合物以获得发泡型坯,并吹塑发泡型坯。

    POLYLACTIC ACID-BASED RESIN EXPANDED BEADS AND MOLDED ARTICLE THEREOF
    27.
    发明申请
    POLYLACTIC ACID-BASED RESIN EXPANDED BEADS AND MOLDED ARTICLE THEREOF 审中-公开
    基于聚氨酯的树脂膨胀珠及其成型品

    公开(公告)号:US20160032070A1

    公开(公告)日:2016-02-04

    申请号:US14881800

    申请日:2015-10-13

    Abstract: Polylactic acid-based resin expanded beads obtained by releasing a softened, pressurized foamable resin composition, which has a polylactic acid-based resin and a physical blowing agent, to a low pressure atmosphere to foam and expand the resin composition, where the polylactic acid-based resin satisfies the conditions (1) to (3) shown below, and exhibits excellent secondary expansion properties and fusion bonding properties. A polylactic acid-based resin expanded beads molded article obtained by in-mold molding of the polylactic acid-based resin expanded beads exhibits excellent mechanical properties. MT≦30 mN  (1) log MT≦0.93 log η−1.75  (2) CT1/2≧600 sec  (3) where MT represents a melt tension [mN] at 190° C., η represents a melt viscosity [Pa·s] at 190° C. and a shear speed of 20 sec−1, and CT1/2 represents a half crystallization time [sec] at 110° C.

    Abstract translation: 通过将具有聚乳酸类树脂和物理发泡剂的软化的加压发泡树脂组合物释放到低压气氛中以使树脂组合物发泡和膨胀而获得的聚乳酸类树脂发泡珠粒,其中聚乳酸 - 基于树脂的树脂满足下述条件(1)至(3),并且显示出优异的二次膨胀性和熔融粘合性。 通过聚乳酸类树脂发泡粒子的模内成型得到的聚乳酸类树脂发泡粒子成型体的机械特性优异。 MT≦̸ 30mN(1)log MT≦̸ 0.93log&eegr; -1.75(2)CT1 /2≥600秒(3)其中MT表示在190℃下的熔体张力[mN] 表示190℃下的熔融粘度[Pa·s],剪切速度为20秒-1,CT1 / 2表示110℃下的半结晶时间[秒]。

    Method for producing polypropylene-based resin foamed blow-molded article
    28.
    发明授权
    Method for producing polypropylene-based resin foamed blow-molded article 有权
    聚丙烯系树脂发泡吹塑制品的制造方法

    公开(公告)号:US09217067B2

    公开(公告)日:2015-12-22

    申请号:US13636743

    申请日:2011-02-10

    Abstract: Provided is a method that can improve formability and blow moldability of a foamed parison as compared with conventional production method and can produce a polypropylene-based resin foamed blow-molded article having excellent uniformity of wall thickness over a wide range of its density. The method comprises kneading a polypropylene-based resin with a physical foaming agent, extruding the thus obtained foamable molten resin through a die to obtain a foamed parison in a softened state, placing the foamed parison between molds and then blow-molding the foamed parison and is characterized in that the polypropylene-based resin comprises a polypropylene-based resin (A) satisfying specific requirements (1) to (3) and a polypropylene-based resin (B) satisfying a specific requirement (4), when the polypropylene-based resins (A) and (B) are each subjected to dynamic viscoelasticity measurement in which an oscillation strain is applied thereto at a temperature of 190° C., and that the mixing ratio by weight (A:B) of the resin (A) to the resin (B) is in the range of 100:0.5 to 100:5.

    Abstract translation: 本发明提供一种能够提高发泡型坯的成形性和吹塑成形性的方法,与现有的制造方法相比,可以制造在其密度范围宽的壁厚均匀性优异的聚丙烯系树脂发泡吹塑成形品。 该方法包括将聚丙烯基树脂与物理发泡剂捏合,将由此获得的可发泡熔融树脂通过模具挤出以获得处于软化状态的发泡型坯,将发泡型坯放置在模具之间,然后吹塑成型发泡型坯, 其特征在于,聚丙烯类树脂包含满足特定要求(1)〜(3)的聚丙烯类树脂(A)和满足特定要求(4)的聚丙烯类树脂(B),当聚丙烯系树脂 树脂(A)和(B)各自经受在190℃的温度下施加振动应变的动态粘弹性测量,并且树脂(A)的混合比例(A:B) 与树脂(B)的摩尔比在100:0.5至100:5的范围内。

    Polylactic resin expanded beads and molded article of the expanded beads
    29.
    发明授权
    Polylactic resin expanded beads and molded article of the expanded beads 有权
    聚乳酸树脂发泡珠粒和发泡珠粒的成型制品

    公开(公告)号:US09206296B2

    公开(公告)日:2015-12-08

    申请号:US13696856

    申请日:2011-03-24

    Abstract: An expanded bead of a polylactic acid resin, having an exterior surface, a surface region including the entire exterior surface and having a weight of one-sixth to one-fourth the weight of the expanded bead, and a center region located inside the surface region and having a weight of one-fifth to one-third the weight of the expanded bead, wherein the expanded bead, the surface region and the center region, after having been subjected to a pretreatment including a heat treatment at 110° C. for 120 minutes followed by cooling at a cooling speed of 2° C./min, have endothermic calorific values of (Br:endo), (Brs:endo) and (Brc:endo), respectively, when measured by heat flux differential scanning calorimetry at a heating speed of 2° C./min in accordance with JIS K7122 (1987), and wherein (Br:endo) is greater than 25 J/g and (Brs:endo) is smaller than (Brc:endo) and is not smaller than 0 J/g.

    Abstract translation: 具有外表面的聚乳酸树脂的膨胀珠粒,包括整个外表面的表面积,其重量是发泡珠粒重量的六分之一至四分之一,以及位于表面区域内的中心区域 并且具有发泡珠重量的五分之一至三分之一的重量,其中经过包括在110℃热处理的预处理后的发泡珠粒,表面区域和中心区域为120 分钟,然后以2℃/分钟的冷却速度冷却,当通过热通量差示扫描量热法测定时,分别具有(Br:endo),(Brs:endo)和(Brc:endo)的吸热热值 根据JIS K7122(1987)的加热速度为2℃/分钟,其中(Br:endo)大于25J / g,(Brs:endo)小于(Brc:endo),并且不是 小于0J / g。

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