公开(公告)号：US06242159B1

公开(公告)日：2001-06-05

申请号：US09464201

申请日：1999-12-15

申请人： Deborah Jane Firth ,  Mark John Spowage ,  Christopher David McCullough ,  Kevin Barry Ray

发明人： Deborah Jane Firth ,  Mark John Spowage ,  Christopher David McCullough ,  Kevin Barry Ray

IPC分类号： G03F730

CPC分类号： B41C1/1008 ,  B41C1/1016 ,  B41C2210/04 ,  B41C2210/14 ,  B41C2210/16 ,  B41C2210/22 ,  G03F7/016

摘要： There is described a method of preparing a water-less lithographic printing form using a precursor which includes a support having a coating thereon comprising a diazo salt formed from an aromatic diazonium compound and an abhesive counter anionic moiety, the method comprising heat mode imaging the precursor and processing the imaged percursor on press by the application of printing ink to remove the abhesive products of the imaging so that areas of the precursor which have been imaged are ink-accepting.

摘要翻译： 描述了使用前体制备无水平版印刷版的方法，所述前体包括其上具有涂层的载体，其上包含由芳族重氮化合物形成的重氮盐和抗反阴离子部分，所述方法包括对所述前体进行加热模式成像 并且通过施加印刷油墨来处理成像的压痕物，以去除成像的粘合产物，使得已经被成像的前体的区域是油墨接受的。

公开(公告)号：US6085655A

公开(公告)日：2000-07-11

申请号：US365127

申请日：1999-07-30

申请人： Mark A. Harris ,  David B. Bailey

发明人： Mark A. Harris ,  David B. Bailey

IPC分类号： B41C1/10 ,  B41N1/00 ,  B41N1/14 ,  G03F7/075

CPC分类号： B41C1/1041 ,  B41C1/1033 ,  B41N1/003 ,  B41C1/1008 ,  B41C2210/02 ,  B41C2210/04 ,  B41C2210/16

摘要： A lithographic imaging member, such as a printing plate, has a support having thereon an ink-accepting melanophilic layer and an ink-rejecting siloxane surface melanophobic layer. Within the printing plate is a photothermal conversion material capable of converting irradiation, such as IR radiation, to heat in exposed regions. Also within one of the layers is a compound that upon imaging releases a moiety that facilitates degradation of the surface melanophobic layer. The released moiety can be fluoride ion or a fluoride ion-containing compound. In some imaging members, a barrier layer may be interposed between the two other layers. Such imaging members can be digitally imaged and used for printing without post-imaging processing.

摘要翻译： 诸如印版的平版印刷成像构件具有其上具有接受油墨的亲水层和拒油硅氧烷表面黑素抑制层的载体。 在印版内是能够将辐射如IR辐射转换成暴露区域的热的光热转换材料。 在一个层内也是化合物，其在成像时释放​​促进表面黑素抑制层降解的部分。 释放的部分可以是氟离子或含氟离子的化合物。 在一些成像构件中，可以在两个其它层之间插入阻挡层。 这样的成像构件可以被数字成像并用于不进行后置成像处理的打印。

公开(公告)号：US6058841A

公开(公告)日：2000-05-09

申请号：US318881

申请日：1999-05-26

申请人： Kevin Barry Ray ,  Christopher David McCullough

发明人： Kevin Barry Ray ,  Christopher David McCullough

IPC分类号： B41C1/10 ,  G03F7/075

CPC分类号： B41C1/1075 ,  B41C1/1008 ,  G03F7/0752 ,  G03F7/0755 ,  B41C2210/04 ,  B41C2210/16

摘要： A formulation comprising a heat sensitive cross-linkable ink and carbon black is coated over substantially the entirety of an ink-repellent/ink-releasing surface of a printing cylinder of a printing press by heating the formulation and/or the outer surface of the printing cylinder so that the formulation adheres to the cylinder to provide a continuous coating thereon. The coated printing cylinder is then allowed to cool to ambient temperature whereafter it can be imaged using a digitally controlled laser. The imaged printing cylinder may be developed during press start up by application of waterless ink over the cylindter surface in order to remove the non-imaged areas comprising non-cross-linked ink. After completion of printing, the printing cylinder can be cleaned by using an appropriate solvent to solubilize the cross-linked ink in the imaged areas and subsequently re-used.

摘要翻译： 包含热敏交联油墨和炭黑的配方通过加热印刷机的配方和/或外表面而涂覆在印刷机的印刷滚筒的基本上全部的防墨/油墨释放表面上 使得制剂粘附到圆筒上以在其上提供连续的涂层。 然后将涂覆的印刷滚筒冷却至环境温度，之后可以使用数字控制的激光成像。 成像的印刷滚筒可以在印刷机启动期间通过在圆柱形表面上施加无水墨水来显影，以便去除包括非交联墨水的非成像区域。 打印完成后，可以使用合适的溶剂清洗印刷滚筒，以便将成像区域中的交联墨水溶解并随后重新使用。

公开(公告)号：US6014929A

公开(公告)日：2000-01-18

申请号：US36881

申请日：1998-03-09

申请人： Gary Ganghui Teng

发明人： Gary Ganghui Teng

IPC分类号： B41C1/10 ,  B41N1/08 ,  B41N3/03 ,  B41N3/04 ,  G03F7/11

CPC分类号： B41C1/1016 ,  B41N1/08 ,  B41C2201/04 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/08 ,  B41C2210/16 ,  B41C2210/24 ,  B41N3/036 ,  B41N3/04

摘要： This invention discloses lithographic printing plates having a thin releasable interlayer interposed between a rough and/or porous substrate and a radiation-sensitive layer. The radiation-sensitive layer is bonded to the rough and/or porous substrate through mechanical interlocking. Insertion of a thin releasable interlayer in such a configuration minimizes cross-contamination between the substrate and the radiation-sensitive layer, protects the substrate from attack by environmental species and reduces ink scumming tendency of the plates while still allowing good bonding between the substrate and the radiation-sensitive layer.

摘要翻译： 本发明公开了具有介于粗糙和/或多孔基底和辐射敏感层之间的薄的可释放夹层的平版印刷版。 辐射敏感层通过机械互锁结合到粗糙和/或多孔基底上。 以这种构造插入薄的可剥离中间层使得基底和辐射敏感层之间的交叉污染最小化，保护基底免受环境物质的侵蚀并且降低了印版的油墨浮渣倾向，同时仍然允许基材和 辐射敏感层。

公开(公告)号：US5992322A

公开(公告)日：1999-11-30

申请号：US928202

申请日：1997-09-12

申请人： Howard A. Fromson ,  Robert F. Gracia ,  Steven A. Rubin

发明人： Howard A. Fromson ,  Robert F. Gracia ,  Steven A. Rubin

IPC分类号： G03F7/11 ,  B05D5/04 ,  B41C1/10 ,  B41M5/36 ,  B41N1/14 ,  G03F1/00 ,  G03F1/68 ,  G03F7/00 ,  G03F7/075

CPC分类号： B41C1/1066 ,  B41C1/1008 ,  B41C2210/04 ,  B41C2210/16 ,  B41M5/368 ,  G03F7/0752

摘要： A substrate is coated with a first material which is soluble in a first solvent, whereupon a second material which is strongly adherent to the first material and insoluble in the first solvent is selectively applied by an ink jet printer. The substrate is then developed in the first solvent to establish the image. In a preferred embodiment the substrate is hydrophilic, the first material is a negative working photosensitive material, and the second material is a transparent adhesive, which permits curing the first material by exposure to actinic light after the development step. The adhesive is then removed. In an embodiment directed to a waterless plate the substrate includes a surface coating of silicone, and the first material is a primer which promotes adhesion of a second material in the form of an oleophilic adhesive which is selectively applied. The primer is then developed to expose the silicone on the non-image areas. The ink carrying image areas are formed by the adhesive, which in this embodiment is not removed.

摘要翻译： 基材涂覆有可溶于第一溶剂的第一材料，于是通过喷墨打印机选择性地施加与第一种材料牢固粘附并且不溶于第一种溶剂的第二种材料。 然后将基底在第一溶剂中显影以建立图像。 在优选的实施方案中，基底是亲水的，第一种材料是负性感光材料，第二种材料是透明粘合剂，其允许在显影步骤后暴露于光化光下固化第一种材料。 然后去除粘合剂。 在针对无水板的实施例中，基底包括硅树脂的表面涂层，并且第一材料是促进被选择性施加的亲油性粘合剂形式的第二材料的粘附的底漆。 然后开发底漆以在非图像区域上暴露硅树脂。 载墨图像区域由粘合剂形成，该粘合剂在该实施例中不被去除。

公开(公告)号：US5908705A

公开(公告)日：1999-06-01

申请号：US812900

申请日：1997-03-10

申请人： My T. Nguyen ,  Hui Zhu ,  S. Peter Pappas ,  Ken-ichi Shimazu ,  Robert Hallman

发明人： My T. Nguyen ,  Hui Zhu ,  S. Peter Pappas ,  Ken-ichi Shimazu ,  Robert Hallman

IPC分类号： B41M1/08 ,  B41C1/10 ,  B41N1/14 ,  B41N1/04 ,  B41N3/03

CPC分类号： B41C1/1033 ,  B41C1/1008 ,  B41C2210/02 ,  B41C2210/16 ,  B41C2210/24 ,  B41C2210/26 ,  B41C2210/264 ,  B41C2210/266 ,  Y10T428/31692 ,  Y10T428/31797 ,  Y10T428/31855

摘要： Lithographic plate compositions and a method for their production have been discovered that are especially useful in conjunction with digitally controlled lasers to directly construct printable images on lithographic plates. The plates comprise a substrate and an ablatable polymeric coating on the substrate where the ablatable, imageable coating is prepared by in situ or solution polymerization of conjugated monomers deposited on the plate by vapor deposition or in solution. Examples of such monomers are thiophene, pyrrole and aniline.

摘要翻译： 已经发现了平版印刷版组合物及其生产方法，其特别适用于数字控制激光器，以直接构建平版印刷版上的可印刷图像。 这些板包括基材和可消融的聚合物涂层，其中可消融的可成像涂层通过原位沉淀或通过气相沉积或溶液沉积在板上的共轭单体的溶液聚合来制备。 这些单体的实例是噻吩，吡咯和苯胺。

公开(公告)号：US5871883A

公开(公告)日：1999-02-16

申请号：US757814

申请日：1996-11-27

申请人： Tsumoru Hirano ,  Toshifumi Inno

发明人： Tsumoru Hirano ,  Toshifumi Inno

IPC分类号： G03F7/004 ,  B41C1/055 ,  B41C1/10 ,  B41N1/00 ,  B41N1/14 ,  G03F7/00 ,  G03F7/075

CPC分类号： B41C1/1033 ,  B41N1/003 ,  B41C2210/16 ,  G03F7/0752

摘要： A lithographic printing plate precursor requiring no fountain solution possible to conduct heat mode recording by a laser beam and excellent in image reproducibility and scratch resistance, which comprises a support having provided thereon a light-heat conversion layer containing a compound converting a laser beam to heat and a silicone rubber layer in this order, wherein the light-heat conversion layer contains an addition polymer having a group capable of reacting with a silicone crosslinking agent at a side chain thereof, and the addition polymer reacts with a silicone crosslinking agent contained in the silicone rubber layer when the silicone rubber layer is formed by coating and drying.

摘要翻译： 不需要润版液的平版印刷版原版可以通过激光束进行热模式记录，并且具有优异的图像再现性和耐擦伤性，其包括在其上设置有包含将激光束转换成热的化合物的光热转换层的支撑体 和硅橡胶层，其中所述光热转换层含有具有能够在侧链与硅氧烷交联剂反应的基团的加成聚合物，并且所述加成聚合物与所述硅氧烷交联剂 硅橡胶层通过涂布和干燥形成硅橡胶层。

公开(公告)号：US5378580A

公开(公告)日：1995-01-03

申请号：US59283

申请日：1993-05-11

申请人： Luc Leenders

发明人： Luc Leenders

IPC分类号： B41C1/055 ,  B41C1/10 ,  B41M5/24 ,  B41M5/382 ,  B41M5/40 ,  B41M5/46 ,  B41M5/50 ,  B41M5/52 ,  B41N1/00 ,  B41N3/03 ,  G03F7/30 ,  G03F7/36

CPC分类号： B41M5/46 ,  B41C1/1033 ,  B41N1/003 ,  B41N3/03 ,  B41C2210/16 ,  B41M5/24 ,  B41M5/465 ,  Y10S430/145 ,  Y10S430/146

摘要： The present invention provides a method for making a lithographic printing plate requiring no dampening liquid comprising the steps of:image-wise exposing using a laser beam a heat mode recording material comprising on a support having an oleophilic surface (i) a recording layer having a thickness of not more than 3 .mu.m and containing a substance capable of converting the laser beam radiation into heat and (ii) a cured oleophobic surface layer and wherein said recording layer and oleophobic surface layer may be the same layer;rubbing the exposed heat mode recording material thereby removing said oleophobic surface layer in the exposed areas so that the underlying oleophilic surface is exposed andavoiding the swelling of said oleophobic surface layer by carrying out said rubbing without the use of a liquid or with the use of a non-solvent for said oleophobic surface layer.

摘要翻译： 本发明提供一种制备不需要润版液的平版印刷版的方法，包括以下步骤：使用激光束成像曝光包括在具有亲油表面的载体上的加热模式记录材料（i）具有 厚度不大于3μm，并且含有能够将激光束辐射转化成热的物质和（ii）固化的疏油表面层，并且其中所述记录层和疏油表面层可以是相同的层; 摩擦暴露的热模式记录材料，从而去除暴露区域中的疏油表面层，使得下面的亲油表面暴露，并且通过在不使用液体的情况下进行所述摩擦而避免所述疏油表面层的溶胀，或者使用 所述疏油表面层的非溶剂。

公开(公告)号：US4064312A

公开(公告)日：1977-12-20

申请号：US558616

申请日：1975-03-14

申请人： Richard G. Crystal

发明人： Richard G. Crystal

IPC分类号： B41N1/00 ,  G03F7/00 ,  G03G9/09 ,  G03G13/28 ,  B32B9/04

CPC分类号： G03G13/286 ,  B41N1/003 ,  G03G9/0926 ,  B41C2210/16 ,  Y10S428/908 ,  Y10T428/31507 ,  Y10T428/31663 ,  Y10T428/31667 ,  Y10T428/31681 ,  Y10T428/31703 ,  Y10T428/31739 ,  Y10T428/31786 ,  Y10T428/31797

摘要： A process for preparing a waterless lithographic printing master is provided. A suitable substrate, which is preferably ink accepting is first coated with a curable silicone which is curable at low or elevated temperature and a second different curable silicone deposited on said first silicone which can be preferentially cured at a lower temperature without curing the first silicone and which second silicone contains, in addition to its own catalyst, an amount of high temperature curing catalyst sufficient to cure the underlying silicone. The surface silicone is then preferentially cured at least on its surface to render it nontacky, but not the underlying silicone. A particulate image pattern is deposited on the surface cured silicone which pattern comprises a material which selectively inactivates the curing catalyst and combines with the catalyst to degrade the cured silicone below said image pattern at elevated temperature, the underlying silicone cured in the nonimaged areas to an elastomeric ink releasable condition, as well as the surface layer to the extent that it was not previously rendered ink releasing, and the particulate image pattern and preferably the degraded and uncured silicones removed beneath said pattern to reveal the ink accepting substrate in image configuration.

摘要翻译： 提供了一种制备无水平版印刷母版的方法。 首先涂覆可接受的油墨的合适的基材，其可在低或高温下可固化的可固化硅酮和沉积​​在所述第一硅氧烷上的第二种不同的可固化硅氧烷，其可以在较低温度下优先固化，而不固化第一硅氧烷， 除了其自身的催化剂之外，第二硅氧烷还含有足以固化下面的硅氧烷的一定量的高温固化催化剂。 然后表面硅氧烷至少在其表面上固化，使其不粘附，而不是下面的硅氧烷。 颗粒图像图案沉积在表面固化的硅树脂上，其图案包括选择性地使固化催化剂失活并与催化剂结合的材料，以在升高的温度下降解所述图像图案下的固化的硅氧烷，在非成像区域中固化的底层硅氧烷 弹性体油墨可释放状态，以及表面层到其以前未被释放的油墨的程度，并且颗粒图像图案，优选地，在所述图案下方去除了劣化和未固化的硅氧烷以在图像构造中露出受墨基板。

公开(公告)号：US3961947A

公开(公告)日：1976-06-08

申请号：US408222

申请日：1973-10-19

申请人： John B. Wells

发明人： John B. Wells

IPC分类号： B41N1/00 ,  G03G13/28 ,  G03F7/02

CPC分类号： B41N1/003 ,  G03G13/286 ,  B41C2210/16

摘要： A novel method of preparing a waterless lithographic master and a method of printing therefrom are provided. To prepare the printing master, a suitable ink accepting substrate such as aluminum, paper or plastic, is coated with a silicone gum curing catalyst, preferably suspended in a hydrophilic binder. A barrier fusable particulate hydrophobic image pattern is then deposited on said coated substrate and fused to mask said curing catalyst in the image areas. The substrate is then coated with an uncured silicone gum, preferably as an aqueous emulsion so that the gum does not adhere to the hydrophobic image pattern. The silicone gum is then cured in the nonimage areas to selectively provide ink receptive image areas and ink releasing nonimage areas. The method of printing comprises the additional steps of applying ink to the imaged master and contacting the inked master with an image receiving surface to thereby transfer the inked image.

摘要翻译： 提供一种制备无水平版印刷母版的新方法及其印刷方法。 为了制备印刷母版，合适的油墨接收基材如铝，纸或塑料涂覆有优选悬浮在亲水性粘合剂中的硅橡胶固化催化剂。 然后将可屏蔽的可熔融颗粒疏水图像图案沉积在所述涂覆的基底上并熔融以掩蔽图像区域中的所述固化催化剂。 然后将基底用未固化的硅橡胶胶，优选作为水性乳液涂覆，使得胶不粘附到疏水图像图案上。 然后在非图像区域中固化硅胶，以选择性地提供墨接受图像区域和墨水释放非图像区域。 印刷方法包括将油墨施加到成像的母版并使着墨的母版与图像接收表面接触从而转印上色的图像的附加步骤。