公开(公告)号：US20220403059A1

公开(公告)日：2022-12-22

申请号：US17777365

申请日：2020-11-05

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： DIEGO BRITA ,  GIANNI COLLINA ,  DANIELE EVANGELISTI ,  BENEDETTA GADDI ,  PIERO GESSI ,  GIAMPIERO MORINI ,  SILVIA SOFFRITTI ,  PAOLO VINCENZI

IPC: C08F4/602

Abstract: A process for preparing a catalyst component made from or containing Mg, Ti, and at least an electron donor compound (ID), including the steps of: (a) reacting a Mg based compound with a Ti compound, having at least a Ti—Cl bond, in an amount such that the Ti/Mg molar ratio is greater than 3 and at a temperature ranging from 0 to 150° C., thereby yielding an intermediate solid catalyst component containing Mg and Ti; and (b) contacting the intermediate solid catalyst component with a gaseous stream containing the electron donor compound (ID) in a gaseous dispersing medium, thereby yielding a final solid catalyst component having an ID/Ti molar ratio ranging from 0.5:1 to 20:1.

公开(公告)号：US20220396649A1

公开(公告)日：2022-12-15

申请号：US17776117

申请日：2020-11-03

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： NICOLO ARICH DE FINETTI ,  PIETRO BAITA ,  ANTONIO MAZZUCCO ,  ROBERTA PICA

IPC: C08F210/16

Abstract: A process for the continuous solution polymerization including the step of polymerizing a first olefin monomer of formula CH2═CHR1, wherein R1 is hydrogen or a hydrocarbon radical having from 1 to 8 carbon atoms with a second olefin monomer of formula CH2═CHR2, wherein R2 is a hydrocarbon radical having from 3 to 8 carbon atoms, in the presence of a polymerization catalyst and in the absence of an inert solvent, at a polymerization temperature (Tp) satisfying the following relationship: Tp≥Tm+20° C. wherein Tm is the melting temperature of the obtained polymer.

公开(公告)号：US11466107B2

公开(公告)日：2022-10-11

申请号：US16967587

申请日：2019-01-25

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Simona Guidotti ,  Dario Liguori ,  Giampiero Morini ,  Gianni Vitale

IPC: C08F4/02 ,  C08F4/20 ,  C08F4/646 ,  C08F110/06 ,  C08F4/657

Abstract: A solid catalyst component for the polymerization of olefins CH2═CHR, wherein R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, made from or containing Mg, Ti, Bi, a halogen and an electron donor.

公开(公告)号：US20220298343A1

公开(公告)日：2022-09-22

申请号：US17642277

申请日：2020-08-31

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： FABRIZIO PIEMONTESI ,  ALESSANDRO MIGNOGNA ,  DARIO LIGUORI ,  GIAMPIERO MORINI ,  GIANNI VITALE

IPC: C08L23/12

Abstract: A polypropylene composition made from or containing: A) from 60 to 90 wt %, based upon the total weight of the polypropylene composition, of a fraction insoluble in xylene at 25° C., is made from or containing more than 80% wt of propylene units, and B) from 10 to 40 wt %, based upon the total weight of the polypropylene composition, of a fraction soluble in xylene at 25° C. is made from or containing a copolymer of propylene and ethylene having an average content of ethylene derived units from 30.0 wt % to 55.0 wt %, wherein the fraction when subjected to GPC fractionation and continuous IR analysis for determining the ethylene content of the eluted fractions (GPC-IR analysis), shows that the content of ethylene increases along with the Mw for fractions having Mw higher than the average.

公开(公告)号：US20220298272A1

公开(公告)日：2022-09-22

申请号：US17642460

申请日：2020-08-27

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： FABRIZIO PIEMONTESI ,  ALESSANDRO MIGNOGNA ,  DARIO LIGUORI ,  GIAMPIERO MORINI ,  TIZIANO DALL'OCCO ,  GIANNI VITALE

IPC: C08F4/654 ,  C08F10/06

Abstract: A solid catalyst component for the polymerization of olefins made from or containing a magnesium halide, a titanium compound having at least a Ti-halogen bond, a first electron donor compound selected from 1,3 diethers (DE), and a second electron donor compound selected from dicarbamates (DC), wherein the first and second electron donor compounds are present in a molar ratio DE:DC ranging from 4.5:1 to 20:1.

公开(公告)号：US11407844B2

公开(公告)日：2022-08-09

申请号：US17312264

申请日：2019-12-03

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Alessandro Mignogna ,  Dario Liguori ,  Giampiero Morini ,  Gianni Vitale

IPC: C08F4/651 ,  C08F10/06 ,  C08F4/659

Abstract: A solid catalyst component for the polymerization of olefins made from or containing Mg, Ti, Cl and at least an electron donor compound which is the reaction product obtained by bringing into contact a Mg compound and a Ti compound having at least a Ti-halogen bond with an electron donor selected from diphenol derivatives.

公开(公告)号：US20220170162A1

公开(公告)日：2022-06-02

申请号：US17602369

申请日：2020-03-23

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Luca Lunghi ,  Maria Aranzazu Lujan Abarca ,  Alberto Foguet Roca

IPC: C23C18/16 ,  C23C18/31 ,  C25D5/14 ,  C08L23/12

Abstract: A method for the production of metal-plated articles, including the step of depositing an electrically-conductive metallic layer on a surface of an article comprising a polymer composition comprising by weight: a) 40-60% of a propylene homopolymer, or propylene copolymer containing up to 5% by weight of ethylene and/or another C4-C10 α-olefin, and having a melting temperature of 155° C. or higher and/or a fraction soluble in xylene at 25° C. of 10% by weight or less; b) 10-20% of an ethylene-based elastoplastic copolymer, optionally, a copolymer of ethylene with C4-C10 α-olefin; c) 2-6% of a styrene block copolymer; d) optionally, up to 3% of a propylene homopolymer having a Melt Flow Rate (230° C./2.16 kg) of 500 g/10 min. or more; e) 15-50% of a filler; and f) optionally, up to 6% of a color pigment.

公开(公告)号：US11319431B2

公开(公告)日：2022-05-03

申请号：US17253435

申请日：2019-06-19

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Takeshi Nakajima ,  Kazuhiko Sakai ,  Kunio Yamamoto ,  Masashi Uchida

IPC: C08L23/16 ,  C08L23/12

Abstract: A polypropylene composition made from or containing (i) component (1) made from or containing a propylene homopolymer or copolymer containing 0 to 0.5% by weight of an ethylene-derived unit; (ii) component (2) made from or containing an ethylene/propylene copolymer containing 15 to 30% by weight of an ethylene-derived unit; and (iii) 0.01 to 1.0 parts by weight of a crystal nucleating agent based on a total of 100 parts by weight of component (1) and component (2); wherein 1) the Mw/Mn value of xylene insolubles (XI) is in the range of 6 to 20, 2) the weight ratio of component (1) to component (2) is in the range of 82:18 to 90:10, 3) the intrinsic viscosity of xylene solubles (XSIV) is in the range of 2.5 to 3.4 dl/g, 4) the MFR (at 230° C. under a load of 2.16 kg) is in the range of 3 to 10 g/10 min.

公开(公告)号：US11319424B2

公开(公告)日：2022-05-03

申请号：US17015506

申请日：2020-09-09

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Diego Brita ,  Sheri E. Davis ,  Volker Fraaije ,  Simona Guidotti ,  Dario Liguori ,  Sandor Nagy ,  David L. Ramage ,  Shahram Mihan ,  Christopher D. Smith ,  Daniel F. White ,  Xueyong Yang

IPC: C08J11/16 ,  B01J21/16

Abstract: A method of depolymerizing plastics using a halloysite catalyst is described herein. The method reduces the energy required for the depolymerization process while achieving improved depolymerization results.

公开(公告)号：US20220112352A1

公开(公告)日：2022-04-14

申请号：US17450234

申请日：2021-10-07

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Sandor Nagy ,  Daniel F. White ,  Christopher D. Smith ,  David L. Ramage

IPC: C08J11/20

Abstract: Methods of depolymerizing polyolefin-based material into useful petrochemical products using styrene oligomers or polymers, and heat are described. The styrene oligomers or polymers improve the depolymerization reaction by decreasing the halftime for the depolymerization, which results in a higher depolymerization rate and a shorter residence time in the depolymerization unit, allowing for a predictable depolymerization reaction, and decreasing the branching or aromatic formations in the product.