公开(公告)号：US20030118939A1

公开(公告)日：2003-06-26

申请号：US10040241

申请日：2001-11-09

Applicant: KODAK POLYCHROME GRAPHICS, L.L.C.

Inventor： Heidi Munnelly ,  Paul West

IPC: G03F007/031 ,  G03F007/033 ,  G03F007/032 ,  G03F007/11 ,  G03F007/30 ,  G03F007/38 ,  G03F007/40 ,  B41N001/08 ,  B41N001/14

CPC classification number: G03F7/031 ,  B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24

Abstract: The present invention provides an IR-sensitive composition, which includes: a polymeric binder; and a free radical polymerizable system consisting of: at least one component selected from unsaturated free radical polymerizable monomers, oligomers which are free radical polymerizable and polymers containing CnullC bonds in the backbone and/or in the side chain groups; and an initiator system, which includes: (a) at least one compound capable of absorbing IR radiation; (b) at least one compound capable of producing radicals; and (c) at least one carboxylic co-initiator, provided that the total acid number of the polymeric binder is 70 mg KOH/g or less. The present invention further provides a printing plate precursor, a process for preparing the printing plate and a method of producing an image.

Abstract translation: 本发明提供了一种IR敏感组合物，其包括：聚合物粘合剂; 和由以下组成的自由基可聚合体系：至少一种选自不饱和自由基可聚合单体的组分，可自由基聚合的低聚物和在主链和/或侧链基团中含有C = C键的聚合物; 和引发剂体系，其包括：（a）至少一种能够吸收IR辐射的化合物; （b）至少一种能够产生自由基的化合物; 和（c）至少一种羧酸共引发剂，条件是聚合物粘合剂的总酸值为70mg KOH / g或更低。 本发明还提供一种印版前体，一种制备印版的方法和一种制作图象的方法。

公开(公告)号：US06576397B2

公开(公告)日：2003-06-10

申请号：US09729350

申请日：2000-12-05

Applicant: Nobuyuki Kita ,  Kazuo Maemoto

Inventor： Nobuyuki Kita ,  Kazuo Maemoto

IPC: G03F7038

CPC classification number: B41C1/1016 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24

Abstract: A heat-sensitive lithographic printing plate precursor, comprising a support having a hydrophilic surface on which (1) a thermal polymerization layer comprising an aqueous alkali-soluble polymer having addition polymerizable unsaturated bonds at its side chains and a thermal polymerization initiator and (2) a water-soluble overcoat layer comprising a water-soluble polymer and a compound capable of converting light into heat are provided in this order.

Abstract translation: 一种热敏性平版印刷版原版，其特征在于，具有亲水性表面的载体，（1）热聚合层，其包含在侧链具有加聚性不饱和键的水溶性聚合物水溶性聚合引发剂和（2） 依次提供包含水溶性聚合物和能够将光转化成热的化合物的水溶性外涂层。

公开(公告)号：US20030073034A1

公开(公告)日：2003-04-17

申请号：US10109870

申请日：2002-03-29

Applicant: FUJI PHOTO FILM CO., LTD.

Inventor： Shiro Tan ,  Kazuo Fujita ,  Akira Nishioka

IPC: G03F007/027 ,  G03F007/038 ,  G03F007/039 ,  G03F007/09

CPC classification number: G03F7/033 ,  B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/12 ,  B41C2201/14 ,  B41C2210/02 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  G03F7/0046 ,  G03F7/0233 ,  Y10S430/111 ,  Y10S430/145

Abstract: A lithographic printing plate precursor comprises: a support; and an image-forming layer including a fluoroaliphatic group-containing copolymer, wherein the fluoroaliphatic group-containing copolymer contains a repeating unit corresponding to monomer (i) below and a repeating unit corresponding to monomer (ii) below: (i) a specified fluoroaliphatic group-containing monomer, and (ii) at least one of a poly(oxyalkylene) acrylate and a poly(oxyalkylene) methacrylate.

Abstract translation: 平版印刷版前体包括：载体; 以及包含含氟脂族基团的共聚物的成像层，其中含氟脂族基团的共聚物含有对应于下述单体（i）的重复单元和对应于下述单体（ii）的重复单元：（i）指定的氟代脂族基 含有基团的单体，和（ii）聚（氧化烯）丙烯酸酯和聚（氧化烯）甲基丙烯酸酯中的至少一种。

公开(公告)号：US20030054288A1

公开(公告)日：2003-03-20

申请号：US10146465

申请日：2002-05-16

Applicant: FUJI PHOTO FILM CO., LTD.

Inventor： Kazuto Shimada ,  Tadahiro Sorori ,  Morio Yagihara

IPC: G03F007/016 ,  G03F007/038

CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/04 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24 ,  B41M5/3333 ,  B41M5/368 ,  B41M5/465

Abstract: This invention describes a heat sensitive composition comprising: (A-I) a compound which is represented by the following general formula (I) and generates a radical when heated, and (B-I) a compound having physical and chemical properties that are changed irreversibly by a radical, RnullSO2nullMnullnullnullGeneral formula (I) wherein R represents an alkyl group or aryl group, and Mnull represents a counter cation selected from sulfonium, iodonium, diazonium, ammonium and azinium; and a negative planographic printing plate precursor which can be recorded by heat mode using this composition. This invention also describes a planographic printing plate precursor comprising a substrate having disposed thereon a photosensitive layer containing (C-II) a light-heat converting agent, (B-II) a compound having a polymerizable unsaturated group, and (A-II) an onium salt having at least two cation parts in one molecule.

Abstract translation: 本发明描述了一种热敏性组合物，其包含：（AI）由以下通式（I）表示的化合物，并在加热时产生自由基，（BI）具有由激进基团不可逆地改变的物理和化学性质的化合物 ，R-SO 2 -M +通式（I）其中R表示烷基或芳基，M +表示选自锍，碘，重氮，铵和吖嗪的抗衡阳离子; 以及可以使用该组合物通过热模式记录的负型平版印刷版原版。 本发明还描述了一种平版印刷版原版，其包括在其上设置有含有（C-II）光热转换剂（B-II）具有可聚合不饱和基团的化合物和（A-II） 在一个分子中具有至少两个阳离子部分的鎓盐。

公开(公告)号：US20030008239A1

公开(公告)日：2003-01-09

申请号：US09932975

申请日：2001-08-21

Inventor： Kazuhiro Fujimaki ,  Tadahiro Sorori ,  Keitaro Aoshima

IPC: G03F007/029 ,  G03F007/032

CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/266 ,  Y10S430/145 ,  Y10S430/146 ,  Y10S430/165

Abstract: A heat mode type negative image recording material is provided which comprises (A) a polymer compound that is insoluble in water but is soluble in an alkali aqueous solution and has at least one of groups represented by general formulae (1) to (3) on a side chain; (B) a photothermal conversion agent; and (C) an onium salt compound forming radicals by heat mode exposure with light that is capable of being absorbed by said photothermal conversion agent (B), said heat mode type negative image recording material being capable of recording an image by heat mode exposure. The general formulae are defined in the specification.

Abstract translation: 提供一种热模式型负型图像记录材料，其包括（A）不溶于水但可溶于碱性水溶液且具有至少一个由通式（1）至（3）表示的基团的聚合物化合物对 侧链 （B）光热转换剂; 和（C）通过用能够被所述光热转换剂（B）吸收的光进行热模式曝光而形成自由基的鎓盐化合物，所述加热模式型负型图像记录材料能够通过热模式曝光记录图像。 通式在本说明书中定义。

公开(公告)号：US06500599B1

公开(公告)日：2002-12-31

申请号：US09598444

申请日：2000-06-22

Applicant: Toshifumi Inno ,  Hiromichi Tachikawa

Inventor： Toshifumi Inno ,  Hiromichi Tachikawa

IPC: G03F711

CPC classification number: B41C1/1016 ,  B41C2201/02 ,  B41C2201/04 ,  B41C2201/14 ,  B41C2210/02 ,  B41C2210/08 ,  B41C2210/22 ,  B41C2210/24

Abstract: Disclosed are a lithographic printing plate precursor that can record images by laser beam scanning exposure based on digital signals and can be printed by easy development processing or development processing on a printing machine, comprising a support having thereon an ink-receptive light-heat conversion layer containing a compound converting laser light to heat and a hardened hydrophilic layer in this order, wherein a part of said light-heat conversion layer remains at a laser light-irradiated area of the lithographic printing plate precursor, and a plate-making method of a lithographic printing plate using the same.

Abstract translation: 公开了一种平版印刷版原版，其可以基于数字信号通过激光束扫描曝光来记录图像，并且可以通过在印刷机上进行简单的显影处理或显影处理来印刷，该印刷机包括其上具有吸墨光热转换层 其特征在于，所述光热转换层的一部分保持在所述平版印刷版原版的激光照射区域，并且其制造方法为 平版印刷版使用相同。

公开(公告)号：US20020189476A1

公开(公告)日：2002-12-19

申请号：US10087834

申请日：2002-03-05

Inventor： Keitaro Aoshima

IPC: B41N001/00 ,  B41N003/00

CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262

Abstract: A planographic printing plate precursor comprising: a substrate; a photosensitive layer disposed on the substrate, the photosensitive layer including a light-to-heat conversion agent and a compound, which is at least one of crosslinkable and polymerizable, with solubility of the photosensitive layer in an alkali developing solution being decreased by the effect of at least one of light and heat; and an overcoat layer including a polymer, which is hydrophobic and soluble in an aqueous alkali solution.

Abstract translation: 一种平版印刷版原版，包括：基片; 设置在基板上的感光层，包含光热转换剂和感光层在碱性显影液中的溶解度中的至少一种可交联和可聚合的感光层由于效果而降低 至少一种光和热; 以及包含疏水性且可溶于碱性水溶液的聚合物的保护层。

公开(公告)号：US06487969B2

公开(公告)日：2002-12-03

申请号：US09730058

申请日：2000-12-05

Applicant: Tu Vinh Chau ,  Jacek Paul Obuchowicz

Inventor： Tu Vinh Chau ,  Jacek Paul Obuchowicz

IPC: B41C110

CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/04 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/16 ,  B41C2210/24 ,  B41N3/00 ,  B41N3/034 ,  Y10S205/921

Abstract: A lithographic printing plate precursor comprises an electrochemically grained aluminium substrate, the grained surface of which is coated with a layer of gel-like amorphous colloidal oxides and hydroxides of aluminium and their hydrates incorporating metallic aluminium and inter-metallic aluminium alloys—generally at a level of below 5%—this layer being produced during the electrochemical graining process. The layer is typically present in an amount of from 0.1-20 g/m2 and at a layer thickness of 0.1-4.0 &mgr;m, the particle sizes in the said layer generally falling in the range of from 10 to 2000 nm. Methods are disclosed for the preparation of said precursors via the electrochemical graining of aluminium substrates. The invention provides lithographic printing plate precursors which may be imagewise exposed by means of a high intensity laser beam to provide printing plates showing high durability on press and giving images which show good resolution and are free from background staining.

Abstract translation: 平版印刷版前体包括电化学细粒的铝基底，其粗糙表面涂有凝胶状无定形胶体氧化物层和铝氢氧化物及其水合物，其结合金属铝和金属间铝合金 - 通常在一定水平上 在电化学磨粒过程中产生的低于5％的层。 该层的存在量通常为0.1-20g / m 2，层厚为0.1-4.0μm，所述层中的颗粒尺寸通常在10-2000nm的范围内。 公开了通过铝基板的电化学砂磨制备所述前体的方法。 本发明提供平版印刷版前体，其可以通过高强度激光束成像曝光，以提供在印刷机上显示出高耐久性的印版，并给出显示出良好分辨率且不含背景染色的图像。

公开(公告)号：US20020162469A1

公开(公告)日：2002-11-07

申请号：US10087401

申请日：2002-03-01

Applicant: Presstek, Inc.

Inventor： Gerald P. Harwood JR.

IPC: B41N003/00 ,  B41M005/00

CPC classification number: B41N1/083 ,  B41C1/1008 ,  B41C1/1016 ,  B41C1/1033 ,  B41C2201/02 ,  B41C2201/04 ,  B41C2201/14 ,  B41C2210/02 ,  B41C2210/20 ,  B41C2210/22 ,  B41C2210/24

Abstract: The present invention provides a printing member having a single radiation-absorptive multiphase layer over a substrate layer that may be imaged with or without ablation.

Abstract translation: 本发明提供了一种在衬底层上具有单一辐射吸收多相层的印刷部件，其可以在有或没有消融的情况下被成像。

公开(公告)号：US06468717B2

公开(公告)日：2002-10-22

申请号：US09779616

申请日：2001-02-09

Applicant: Nobuyuki Kita ,  Hisashi Hotta

Inventor： Nobuyuki Kita ,  Hisashi Hotta

IPC: G03F711

CPC classification number: B41C1/1016 ,  B41C2201/02 ,  B41C2201/10 ,  B41C2201/12 ,  B41C2201/14 ,  B41C2210/02 ,  B41C2210/08 ,  B41C2210/20 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  Y10S430/145

Abstract: A heat-sensitive lithographic printing plate precursor is disclosed, which comprises an aluminum support having provided thereon an ink-receptive layer and a hydrophilic layer containing a colloidal particle oxide or hydroxide of at least one element selected from the group consisting of beryllium, magnesium, aluminum, silicon, titanium, boron, germanium, tin, zirconium, iron, vanadium, antimony and transition metals, wherein at least one layer of the ink-receptive layer and the hydrophilic layer contains a compound capable of converting light into heat, the aluminum support has an anodic oxide film in an amount of 2 g/m2 or more, and the anodic oxide film has been subjected to sealing treatment at a sealing rate of 50% or more.

Abstract translation: 公开了一种热敏平版印刷版原版，其包括在其上设置有油墨接受层的铝支撑体和含有选自铍，镁，镁，镁，镁等的至少一种元素的胶体粒子氧化物或氢氧化物的亲水层， 铝，硅，钛，硼，锗，锡，锆，铁，钒，锑和过渡金属，其中至少一层油墨接收层和亲水层含有能够将光转化成热的化合物，铝 支撑体具有2g / m 2以上的阳极氧化膜，阳极氧化膜以50％以上的密封率进行密封处理。