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    Synthesis of metal compounds under carbothermal conditions
    34.
    发明授权
    Synthesis of metal compounds under carbothermal conditions 有权
    在碳热条件下合成金属化合物

    公开(公告)号：US08163430B2

    公开(公告)日：2012-04-24

    申请号：US11161156

    申请日：2005-07-25

    Applicant: Jeremy Barker ,  Yazid Saidi ,  Ming Dong ,  Jeffrey Swoyer

    Inventor： Jeremy Barker ,  Yazid Saidi ,  Ming Dong ,  Jeffrey Swoyer

    IPC: H01M8/10

    CPC classification number: H01M4/5825 ,  C01B25/37 ,  C01B25/45 ,  C01G21/00 ,  C01G31/00 ,  C01G39/00 ,  C01P2006/40 ,  H01M4/13 ,  H01M4/131 ,  H01M4/136 ,  H01M4/1391 ,  H01M4/1397 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/582 ,  H01M6/40 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0566 ,  Y10T29/10 ,  Y10T156/1002

    Abstract: Active materials of the invention contain at least one alkali metal and at least one other metal capable of being oxidized to a higher oxidation state. Preferred other metals are accordingly selected from the group consisting of transition metals (defined as Groups 4-11 of the periodic table), as well as certain other non-transition metals such as tin, bismuth, and lead. The active materials may be synthesized in single step reactions or in multi-step reactions. In at least one of the steps of the synthesis reaction, reducing carbon is used as a starting material. In one aspect, the reducing carbon is provided by elemental carbon, preferably in particulate form such as graphites, amorphous carbon, carbon blacks and the like. In another aspect, reducing carbon may also be provided by an organic precursor material, or by a mixture of elemental carbon and organic precursor material.

    Abstract translation: 本发明的活性材料含有至少一种碱金属和至少一种能被氧化成较高氧化态的其它金属。 因此，优选的其它金属选自过渡金属（定义为周期表第4-11部分）以及某些其它非过渡金属如锡，铋和铅。 活性物质可以在单步反应或多步反应中合成。 在合成反应的至少一个步骤中，使用还原性碳作为原料。 一方面，还原碳由元素碳提供，优选为颗粒形式，例如石墨，无定形碳，炭黑等。 另一方面，还原碳还可以由有机前体材料或元素碳和有机前体材料的混合物提供。

    Sodium Ion Batteries
    36.
    发明申请
    Sodium Ion Batteries 审中-公开
    钠离子电池

    公开(公告)号：US20110052986A1

    公开(公告)日：2011-03-03

    申请号：US12899216

    申请日：2010-10-06

    Applicant: Jeremy Barker ,  Yazid Saidi ,  Jeff Swoyer

    Inventor： Jeremy Barker ,  Yazid Saidi ,  Jeff Swoyer

    IPC: H01M4/40 ,  H01M4/58 ,  H01M4/46 ,  H01M4/52

    CPC classification number: H01M10/054 ,  H01M4/5825 ,  H01M4/587 ,  H01M10/052 ,  H01M10/056 ,  H01M2300/002 ,  H01M2300/0048

    Abstract: Sodium ion batteries are based on sodium based active materials selected among compounds of the general formula AaMb(XY4)c wherein A comprises sodium, M comprises one or more metals, comprising at least one metal which is capable of undergoing oxidation to a higher valence state, and XY4 represents phosphate or a similar group. The anode of the battery includes a carbon material that is capable of inserting sodium ions. The carbon anode cycles reversibly at a specific capacity greater than 100 mAh/g.

    Abstract translation: 钠离子电池基于选自通式AaMb（XY4）c的化合物中的钠基活性材料，其中A包含钠，M包含一种或多种金属，其包含至少一种能够经历氧化至更高价态的金属 ，XY4表示磷酸酯或类似基团。 电池的阳极包括能够插入钠离子的碳材料。 碳阳极在大于100mAh / g的比容量下可逆地循环。

    Methods Of Making Transition Metal Compounds Useful As Cathode Active Materials
    39.
    发明申请
    Methods Of Making Transition Metal Compounds Useful As Cathode Active Materials 审中-公开
    过渡金属化合物用作阴极活性材料的方法

    公开(公告)号：US20080020277A1

    公开(公告)日：2008-01-24

    申请号：US11842191

    申请日：2007-08-21

    Applicant: Jeremy Barker ,  M. Saidi ,  Jeffrey Swoyer ,  Ming Dong

    Inventor： Jeremy Barker ,  M. Saidi ,  Jeffrey Swoyer ,  Ming Dong

    IPC: H01M4/58 ,  H01M4/48 ,  H01M4/62

    CPC classification number: H01M4/5825 ,  C01B25/37 ,  C01B25/45 ,  C01G21/00 ,  C01G31/00 ,  C01G39/00 ,  C01P2006/40 ,  H01M4/13 ,  H01M4/131 ,  H01M4/136 ,  H01M4/1391 ,  H01M4/1397 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/582 ,  H01M6/40 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0566 ,  Y10T29/10 ,  Y10T156/1002

    Abstract: A method for carrying out solid state reactions under reducing conditions is provided. Solid state reactants include at least one inorganic metal compound and a source of reducing carbon. The reaction may be carried out in a reducing atmosphere in the presence of reducing carbon. Reducing carbon may be supplied by elemental carbon, by an organic material, or by mixtures. The organic material is one that can form decomposition products containing carbon in a form capable of acting as a reductant. The reaction proceeds without significant covalent incorporation of organic material into the reaction product. In a preferred embodiment, the solid state reactants also include an alkali metal compound. The products of the method find use in lithium ion batteries as cathode active materials. Preferred active materials include lithium-transition metal phosphates and lithium-transition metal oxides. In a preferred embodiment, the reaction product contains carbon particles intimately mixed among crystals of the active materials.

    Abstract translation: 提供了一种在还原条件下进行固态反应的方法。 固态反应物包括至少一种无机金属化合物和还原性碳源。 反应可以在还原性碳存在下在还原气氛中进行。 还原碳可以由元素碳，有机材料或混合物来提供。 有机材料可以形成能够作为还原剂形式的含有碳的分解产物。 反应进行而没有将有机材料显着共价掺入反应产物中。 在优选的实施方案中，固态反应物还包括碱金属化合物。 该方法的产品可用于锂离子电池作为阴极活性材料。 优选的活性材料包括锂 - 过渡金属磷酸盐和锂 - 过渡金属氧化物。 在优选的实施方案中，反应产物含有在活性物质晶体之间密切混合的碳颗粒。

    Lithium metal fluorophosphate and preparation thereof
    40.
    发明授权
    Lithium metal fluorophosphate and preparation thereof 有权
    金属氟磷酸锂及其制备方法

    公开(公告)号：US07261977B2

    公开(公告)日：2007-08-28

    申请号：US10905649

    申请日：2005-01-14

    Applicant: Jeremy Barker ,  M. Yazid Saidi ,  Jeffrey Swoyer

    Inventor： Jeremy Barker ,  M. Yazid Saidi ,  Jeffrey Swoyer

    IPC: H01M4/58

    CPC classification number: H01M4/136 ,  C01B25/455 ,  H01M4/58 ,  H01M4/5825 ,  H01M10/0525 ,  H01M2004/028

    Abstract: The invention provides new and novel lithium-metal-fluorophosphates which, upon electrochemical interaction, release lithium ions, and are capable of reversibly cycling lithium ions. The invention provides a rechargeable lithium battery which comprises an electrode formed from the novel lithium-metal-fluorophosphates. The lithium-metal-fluorophosphates comprise lithium and at least one other metal besides lithium.

    Abstract translation: 本发明提供了新的和新型的锂 - 金属 - 氟磷酸盐，其在电化学相互作用时释放锂离子，并且能够可逆地循环锂离子。 本发明提供一种可充电锂电池，其包括由新型锂金属 - 氟磷酸盐形成的电极。 除了锂之外，锂金属 - 氟磷酸盐还包含锂和至少一种其它金属。

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