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公开(公告)号:US12173402B2
公开(公告)日:2024-12-24
申请号:US16927509
申请日:2020-07-13
Applicant: ASM IP Holding B.V.
Inventor: Timo Hatanpää , Katja Väyrynen , Mikko Ritala , Markku Leskelä
IPC: C23C16/00 , C23C16/40 , C23C16/455 , H01L21/285 , H01L21/768 , H01L23/532
Abstract: A method of forming a transition metal containing films on a substrate by a cyclical deposition process is disclosed. The method may include: contacting the substrate with a first vapor phase reactant comprising a transition metal halide compound comprising a bidentate nitrogen containing adduct ligand; and contacting the substrate with a second vapor phase reactant. A method for supplying a transition metal halide compound comprising a bidentate nitrogen containing ligand to a reaction chamber is disclosed, along with related vapor deposition apparatus.
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32.
公开(公告)号:US11959171B2
公开(公告)日:2024-04-16
申请号:US17866706
申请日:2022-07-18
Applicant: ASM IP Holding B.V.
Inventor: Timo Hatanpää , Katja Väyrynen , Mikko Ritala , Markku Leskelä
IPC: C23C16/14 , C23C16/455
CPC classification number: C23C16/45553 , C23C16/14
Abstract: Methods of forming a transition metal containing film on a substrate by a cyclical deposition process are disclosed. The methods may include: contacting the substrate with a first vapor phase reactant comprising a transition metal halide compound comprising a bidentate nitrogen containing adduct ligand; and contacting the substrate with a second vapor phase reactant comprising a reducing agent precursor. The deposition methods may also include forming a transition metal containing film with an electrical resistivity of less than 50 μΩ-cm at a film thickness of less than 50 nanometers.
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公开(公告)号:US11667595B2
公开(公告)日:2023-06-06
申请号:US17302276
申请日:2021-04-29
Applicant: ASM IP Holding B.V.
Inventor: Timo Hatanpää , Miika Mattinen , Mikko Ritala , Markku Leskelä
IPC: C07C49/92 , C07C45/77 , C23C16/30 , C23C16/455
CPC classification number: C07C49/92 , C07C45/77 , C23C16/305 , C23C16/45553 , C07C45/77 , C07C49/92
Abstract: Methods are provided for synthesizing W(IV) beta-diketonate precursors. Additionally, methods are provided for forming W containing thin films, such as WS2, WNx, WO3, and W via vapor deposition processes, such as atomic layer deposition (ALD) type processes and chemical vapor deposition (CVD) type processes. Methods are also provided for forming 2D materials containing W.
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公开(公告)号:US11499222B2
公开(公告)日:2022-11-15
申请号:US17254366
申请日:2019-06-21
Applicant: ASM IP Holding B.V.
Inventor: Katja Väyrynen , Timo Hatanpää , Mikko Ritala , Markku Leskelä
IPC: C23C16/18 , C23C16/08 , C23C16/455
Abstract: A method of depositing a metal-containing material is disclosed. The method can include use of cyclic deposition techniques, such as cyclic chemical vapor deposition and atomic layer deposition. The metal-containing material can include intermetallic compounds. A structure including the metal-containing material and a system for forming the material are also disclosed.
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公开(公告)号:US20220251701A1
公开(公告)日:2022-08-11
申请号:US17666903
申请日:2022-02-08
Applicant: ASM IP Holding B.V.
Inventor: Miika Mattinen , Timo Hatanpää , Mikko Ritala , Markku Leskelä
Abstract: The current disclosure relates to the manufacture of semiconductor devices. Specifically, the disclosure relates to a method of forming a transition metal-comprising material on a substrate by a cyclic deposition process. The method comprises providing a substrate in a reaction chamber, providing a transition metal precursor comprising a transition metal compound in the reaction chamber, and providing a second precursor in the reaction chamber, wherein the transition metal compound comprises a transition metal halide bound to an adduct ligand, and the second precursor comprises a chalcogen or a pnictogen. The disclosure further relates to a method of forming a transition metal layer, and to semiconductor devices. Further, a vapor deposition assembly is disclosed.
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公开(公告)号:US20210388503A1
公开(公告)日:2021-12-16
申请号:US17303806
申请日:2021-06-08
Applicant: ASM IP HOLDING B.V.
Inventor: Jani Hämäläinen , Mikko Ritala , Markku Leskelä
IPC: C23C16/56 , H01L21/02 , H01L21/465 , C23C16/455 , C23F1/12 , C23C16/30
Abstract: Vapor deposition methods for depositing transition metal dichalcogenide (TMDC) films, such as rhenium sulfide thin films, are provided. In some embodiments TMDC thin films are deposited using a deposition cycle in which a substrate in a reaction space is alternately and sequentially contacted with a vapor phase transition metal precursor, such as a transition metal halide, a reactant comprising a reducing agent, such as NH3 and a chalcogenide precursor. In some embodiments rhenium sulfide thin films are deposited using a vapor phase rhenium halide precursor, a reducing agent and a sulfur precursor. The deposited TMDC films can be etched by chemical vapor etching using an oxidant such as O2 as the etching reactant and an inert gas such as N2 to remove excess etching reactant. The TMDC thin films may find use, for example, as 2D materials.
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公开(公告)号:US20210317576A1
公开(公告)日:2021-10-14
申请号:US17254111
申请日:2019-06-21
Applicant: ASM IP Holding B.V.
Inventor: Katja Väyrynen , Timo Hatanpää , Anton Vihervaara , Mikko Ritala , Markku Leskelä
IPC: C23C16/455 , C23C16/08 , C23C16/18
Abstract: A method of depositing a metal-containing material is disclosed. The method can include use of cyclic deposition techniques, such as cyclic chemical vapor deposition and atomic layer deposition. The metal-containing material can include intermetallic compounds. A structure including the metal-containing material and a system tor forming the material are also disclosed.
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公开(公告)号:US20210277519A1
公开(公告)日:2021-09-09
申请号:US17330994
申请日:2021-05-26
Applicant: ASM IP Holding B.V.
Inventor: Maarit Mäkelä , Timo Hatanpää , Mikko Ritala , Markku Leskelä
IPC: C23C16/455 , C23C16/18 , C23C16/06
Abstract: Vapor deposition processes for forming thin films comprising gold on a substrate in a reaction space are provided. The processes can be cyclical vapor deposition processes, such as atomic layer deposition (ALD) processes. The processes can include contacting the substrate with a gold precursor comprising at least one sulfur donor ligand and at least one alkyl ligand, and contacting the substrate with a second reactant comprising ozone. The deposited thin films comprising gold can be uniform, continuous, and conductive at very low thicknesses.
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公开(公告)号:US20210269914A1
公开(公告)日:2021-09-02
申请号:US17254366
申请日:2019-06-21
Applicant: ASM IP Holding B.V.
Inventor: Katja Väyrynen , Timo Hatanpää , Mikko Ritala , Markku Leskelä
IPC: C23C16/18 , C23C16/08 , C23C16/455
Abstract: A method of depositing a metal-containing material is disclosed. The method can include use of cyclic deposition techniques, such as cyclic chemical vapor deposition and atomic layer deposition. The metal-containing material can include intermetallic compounds. A structure including the metal-containing material and a system for forming the material are also disclosed.
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公开(公告)号:US20210164101A1
公开(公告)日:2021-06-03
申请号:US17173467
申请日:2021-02-11
Applicant: ASM IP HOLDING B.V.
Inventor: Viljami Pore , Timo Hatanpää , Mikko Ritala , Markku Leskelä
Abstract: Atomic layer deposition (ALD) processes for forming Group VA element containing thin films, such as Sb, Sb—Te, Ge—Sb and Ge—Sb—Te thin films are provided, along with related compositions and structures. Sb precursors of the formula Sb(SiR1R2R3)3 are preferably used, wherein R1, R2, and R3 are alkyl groups. As, Bi and P precursors are also described. Methods are also provided for synthesizing these Sb precursors. Methods are also provided for using the Sb thin films in phase change memory devices.
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