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公开(公告)号：US4358432A
公开(公告)日：1982-11-09
申请号：US819510
申请日：1977-07-26
申请人： Takaharu Gamo , Yoshio Moriwaki , Toshio Yamashita
发明人： Takaharu Gamo , Yoshio Moriwaki , Toshio Yamashita
CPC分类号： C01B3/0031 , Y02E60/327 , Y02P20/129 , Y02P20/134 , Y10S420/90
摘要： An economical metallic material for absorption and desorption of hydrogen comprising an alloy having the general formula represented by AB.sub.x, wherein A is Ca or a metallic material which is an alloy including Ca, B is Ni or a metallic material which is an alloy including Ni, and x is in the range of 3.8-6.3, and exhibiting a hydrogen dissociation equilibrium pressure (or plateau pressure, pressure of the plateau region of hydrogen dissociation pressure-hydride composition isotherm) below 1 atm at normal temperatures.The material of the invention very easily absorbs large amounts of hydrogen and efficiently releases it at other predetermined temperatures, pressure and electrochemical conditions, whereby it is able to store hydrogen safely, usefully and economically. It is also suitable for use especially as media for thermal energy storage such as solar energy, waste heat from the electric power generators, and iron foundries, as the alloy of this invention has a plateau pressure below 1 atm at room temperature and of several atmospheres at 35.degree.-100.degree. C.
摘要翻译： 一种用于吸收和解吸氢的经济金属材料，包括具有由ABx表示的通式的合金，其中A为Ca或作为包含Ca，B的合金的金属材料为Ni或金属材料，其为包含Ni， x在3.8-6.3的范围内，并且在正常温度下表现出低于1atm的氢解离平衡压力（或平台压力，氢解离压 - 氢化物组成等温线的平台区的压力）。 本发明的材料非常容易地吸收大量的氢并且在其它预定的温度，压力和电化学条件下有效地将其释放，由此能够安全，有用和经济地储存氢。 特别是作为太阳能，来自发电机的废热和铁铸造的热能储存介质，特别是作为本发明的合金，在室温和几个大气压下的平台压力低于1atm 在35°-100℃
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公开(公告)号：US4350673A
公开(公告)日：1982-09-21
申请号：US008932
申请日：1979-02-02
CPC分类号： C01B3/0031 , Y02E60/327 , Y10S420/90
摘要： There is described an alloy metal hydride for storing and releasing hydrogen at predetermined temperatures and pressures intended for storing and transporting said hydrogen and also for use as a hydrogen supply source of a fuel cell and fuel electrode. The alloy of this invention consists of 30 to 80 percent by weight Ti and 20 to 70 percent by weight Mn having a high dissociation pressure, easy hydrogen activation, low heat of formation of hydrides and a very fast rate of absorption and desorption, also the alloy is of light weight and of low cost, therefore being of great industrial use.
摘要翻译： 描述了用于在用于储存和运输所述氢的预定温度和压力下储存和释放氢的合金金属氢化物，并且还用作燃料电池和燃料电极的氢气供应源。 本发明的合金由30重量％至80重量％的Ti和20至70重量％的Mn具有高的解离压力，易于氢活化，较低的氢化物形成热和非常快的吸收和解吸速率， 合金重量轻，成本低，工业用途十分广泛。
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公开(公告)号：US4144103A
公开(公告)日：1979-03-13
申请号：US836905
申请日：1977-09-26
IPC分类号： C22F1/18 , C01B3/00 , C01B6/24 , C22C1/00 , C22C14/00 , C22C22/00 , C22F1/00 , C22F1/02 , C22F1/16
CPC分类号： C22F1/02 , C01B6/24 , C22C22/00 , Y02E60/327 , Y10S420/90
摘要： The present invention relates a method of making a hydrogen storage alloy comprising the steps of: preparing an alloy having, as main elements, 37 to 42 atomic percent of titanium and 58 to 63 atomic percent of manganese, which alloy is produced directly in an argon arc furnace or an induction furnace; heating the prepared alloy in an electric furnace at a high temperature below the melting temperature of the alloy under vacuum or an inert atmosphere; and cooling the heated alloy down to room temperature. The method of the present invention allows the alloy to have a homogeneous single phase, thereby providing an alloy with excellent hydrogen storage characteristics.
摘要翻译： 本发明涉及一种制备储氢合金的方法，包括以下步骤：制备一种合金，其中主要成分为37至42原子％的钛和58至63原子％的锰，该合金直接在氩气中生产 电弧炉或感应炉; 在真空或惰性气氛下，在合金的熔融温度以下的高温下在电炉中加热制备的合金; 并将加热的合金冷却至室温。 本发明的方法允许合金具有均匀的单相，从而提供具有优异储氢特性的合金。
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公开(公告)号：US07481853B2
公开(公告)日：2009-01-27
申请号：US11383228
申请日：2006-05-15
申请人： Sumihito Ishida , Keisuke Tanaka , Yoshio Moriwaki , Hideo Kaiya
发明人： Sumihito Ishida , Keisuke Tanaka , Yoshio Moriwaki , Hideo Kaiya
CPC分类号： H01M10/052 , H01M2/0212 , H01M2/20 , H01M4/04 , H01M6/42 , H01M10/0565 , Y10T29/4911 , Y10T29/49114
摘要： A non-aqueous electrolyte secondary battery comprising: a positive electrode plate including an outer jacket comprising a sheet-shaped positive electrode current collector and a positive electrode active material layer formed on an inner surface of the outer jacket except for a peripheral portion thereof; a negative electrode plate including an outer jacket comprising a sheet-shaped negative electrode current collector and a negative electrode active material layer formed on an inner surface of the outer jacket except for a peripheral portion thereof; a separator layer comprising a polymer electrolyte interposed between the positive electrode active material layer and the negative electrode active material layer, wherein the peripheral portion of the positive electrode current collector and the peripheral portion of the negative electrode current collector are bonded together, with an insulating material interposed therebetween.
摘要翻译： 一种非水电解质二次电池，包括：正极板，包括外护套，所述外护套包括片状正电极集电体和形成在所述外护套的除了其周边部分的内表面之外的正极活性物质层; 包括外护套的负极板，所述外护套包括形成在所述外护套的除了其周边部分的内表面之外的片状负极集电体和负极活性物质层; 隔离层，其包含插入正极活性物质层和负极活性物质层之间的聚合物电解质，其中正极集电体的周边部分和负极集电体的周边部分用绝缘体 介于其间的材料。
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35.发明授权
公开(公告)号：US5962156A
公开(公告)日：1999-10-05
申请号：US801340
申请日：1997-02-19
CPC分类号： C22C1/0441 , H01M4/383 , Y02E60/327 , Y10S420/90
摘要： A nickel-metal hydride storage battery having a high capacity and excellent cycle life is disclosed. The battery employs, as its material for the negative electrode, a hydrogen storage alloy powder having a composition represented by the general formula Zr.sub.1-x M3.sub.x Mn.sub.a Mo.sub.b Cr.sub.c M1.sub.d M2.sub.e Ni.sub.f, where M1 represents at least one element selected from the group consisting of V, Nb and rare earth elements, M2 represents at least one element selected from the group consisting of Fe, Co and Cu, and M3 represents at least one element selected from the group consisting of Ti and Hf, and where 0.ltoreq.x.ltoreq.0.3, 0.3.ltoreq.a.ltoreq.0.7, 0.01.ltoreq.b.ltoreq.0.2, 0.05.ltoreq.c.ltoreq.0.3, 0.ltoreq.d.ltoreq.0.1, 0.ltoreq.e.ltoreq.0.2, 0.8.ltoreq.f.ltoreq.1.3, and 1.6.ltoreq.a+b+c+d+e+f.ltoreq.2.2, and wherein said hydrogen storage alloy has at least one of a Laves phase having a crystal structure of the MgCu.sub.2 -type (C15) and a Laves phase having a crystal structure of the MgZn.sub.2 -type (C14), and wherein a sum of integrated intensities of diffraction peaks other than those attributed to the presence of said Laves phase is not more than 5% of a sum of integrated intensities of all diffraction peaks in a diffraction angle 2.theta. of 10.degree. to 80.degree. in a powder X-ray diffraction pattern by Cu K.alpha. radiation.
摘要翻译： 公开了一种具有高容量和优异的循环寿命的镍氢蓄电池。 作为负极材料，电池使用具有通式Zr1-xM3xMnaMobCrcM1dM2eNif表示的组成的储氢合金粉末，其中M1表示选自V，Nb和稀土元素中的至少一种元素， M2表示选自Fe，Co和Cu中的至少一种元素，M3表示选自Ti和Hf中的至少一种元素，并且其中0≤x≤0.3,0.3， = a = 0.2,0.8， = f
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公开(公告)号：US5879429A
公开(公告)日：1999-03-09
申请号：US827080
申请日：1997-03-26
CPC分类号： B22F1/025 , C01B3/0084 , H01M4/242 , H01M4/383 , Y02E60/327 , Y02P70/54 , Y10S420/90
摘要： A method for producing a hydrogen storage alloy electrode comprising the step of treating a hydrogen storage alloy by immersing it in an alkaline solution containing cobalt ion or copper ion at a high temperature at a stage wherein the alloy is in powder state before formed into an electrode and/or at a stage wherein the alloy has been formed into an electrode. By this treatment, a hydrogen storage alloy electrode having an excellent high-rate discharge performance at a low temperature is obtained.
摘要翻译： 一种储氢合金电极的制造方法，其特征在于，具有以下步骤：将所述储氢合金浸入含有钴离子或铜离子的碱性溶液中的高温下，在合金处于粉末状态之前，形成电极 和/或其中合金已经形成电极的阶段。 通过该处理，获得了在低温下具有优异的高倍率放电性能的储氢合金电极。
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公开(公告)号：US5837317A
公开(公告)日：1998-11-17
申请号：US813889
申请日：1997-03-07
申请人： Yoshio Moriwaki , Yoichi Izumi , Yasuharu Yamamura , Hideo Kaiya
发明人： Yoshio Moriwaki , Yoichi Izumi , Yasuharu Yamamura , Hideo Kaiya
IPC分类号： C22C1/00 , B22F1/02 , C22C1/04 , H01M4/26 , H01M4/38 , H01M10/30 , B05D7/00 , B05D3/02 , B05D3/12 , B05D5/12
CPC分类号： C22C1/0441 , B22F1/025 , H01M4/383 , Y02P70/54
摘要： The present invention provides a method of producing a hydrogen storage alloy low in cobalt content which can restrains a decrease in cycle life characteristic and preservation characteristic of an alkaline storage battery when the alloy is used as a negative electrode. The method includes the following steps. An Mm-Ni system hydrogen storage alloy which has a crystal structure of CaCu.sub.5 and contains 15 atom % or less of cobalt is powdered to have an average particle diameter of 10-100 .mu.m. Then, the powdered alloy is immersed in a treatment solution at 80.degree.-130.degree. C., the treatment solution comprising an alkaline aqueous solution containing 10 g/l or more of lithium hydroxide and having a specific gravity of 1.1 or higher, and cobalt ions which is contained in the alkaline aqueous solution, thereby forming a layer containing nickel and cobalt in higher concentration than in the bulk of the powdered alloy onto the alloy surface.
摘要翻译： 本发明提供一种低合金含量的储氢合金的制造方法，其能够抑制在将该合金用作负极时碱性蓄电池的循环寿命特性和保存特性的降低。 该方法包括以下步骤。 将具有CaCu 5的晶体结构并含有15原子％以下的钴的Mm-Ni体系的储氢合金粉碎成平均粒径为10〜100μm。 然后，将粉末状合金浸入80〜130℃的处理液中，处理液含有10g / l以上的氢氧化锂，比重为1.1以上的碱性水溶液，钴 离子，其包含在碱性水溶液中，从而在合金表面上形成含有比在粉末状合金中高的浓度的含有镍和钴的层。
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公开(公告)号：US5149383A
公开(公告)日：1992-09-22
申请号：US677572
申请日：1991-03-29
申请人： Hajime Seri , Yoshio Moriwaki , Akemi Shintani , Tsutomu Iwaki
发明人： Hajime Seri , Yoshio Moriwaki , Akemi Shintani , Tsutomu Iwaki
IPC分类号： H01M4/38
CPC分类号： H01M4/383 , Y10S420/90
摘要： The present invention provides a hydrogen storage alloy electrode made of a pentanary or higher multi-component hydrogen storage alloy or a hydride thereof where the alloy comprises at least Zr, Mn, Cr, Ni, and M where M is one or more elements selected from V an Mo, and a major component of the alloy phase is C.sub.15 (MgCu.sub.2) type Laves phase. This hydrogen storage alloy electrode may be enhanced in its performance by subjecting the alloy after the production thereof to a homogenizing heat-treatment at a temperature of 900.degree. to 1300.degree. C. in vacuum or in an inert gaseous atmosphere.
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公开(公告)号：US4370163A
公开(公告)日：1983-01-25
申请号：US184173
申请日：1980-09-04
CPC分类号： C22C14/00 , C01B3/0031 , Y02E60/327 , Y10S420/90
摘要： A hydrogen storage Ti-Fe alloy of the general formula, Ti.sub.1-x A.sub.x Fe.sub.y-z B.sub.z, in which A is Zr, Hf or a mixture thereof, B is a member selected from Cr, Cu, Co, Mo, V, Ni, Nb, Mn and a mixture thereof, and x, y and z are values of certain ranges, respectively. The alloy is predominantly comprised of an effective alloy phase of CsCl type body-centered cubic crystals. The alloy of the formula where z=O is within the scope of the invention. A process for making an alloy of this type is also disclosed.
摘要翻译： A为通式为Ti1-xAxFey-zBz的储氢Ti-Fe合金，其中A为Zr，Hf或其混合物，B为选自Cr，Cu，Co，Mo，V，Ni，Nb， Mn及其混合物，x，y和z分别为一定范围的值。 该合金主要由CsCl型体心立方晶体的有效合金相组成。 其中z = 0的式的合金在本发明的范围内。 还公开了制造这种合金的方法。
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公开(公告)号：US4195989A
公开(公告)日：1980-04-01
申请号：US954619
申请日：1978-10-25
CPC分类号： C22C22/00 , C01B3/0031 , Y02E60/327 , Y10S420/90
摘要： The disclosure relates to a hydrogen storage material composed of a Ti-Mn-M alloy in which M represents at least one metal selected from the group consisting of vanadium, chromium, iron, cobalt, nickel, copper and molybdenum, and which defines an alloy phase of a Laves phase having a hexagonal crystal structure of MgZn.sub.2 (C.sub.14) type and crystal lattice parameters a=4.86.about.4.90A and C=7.95.about.8.02A. The hydrogen storage material is economical and suited to practical purposes, since it readily absorbs a large amount of hydrogen at room temperature and reversibly discharges a large amount of hydrogen with safety through variations of ambient hydrogen pressure, temperature conditions or electro-chemical conditions.
摘要翻译： 本公开涉及由Ti-Mn-M合金构成的储氢材料，其中M表示选自钒，铬，铁，钴，镍，铜和钼中的至少一种金属，并且其定义为合金 具有MgZn2（C14）型六方晶体结构的Laves相和晶格参数a = 4.86的差相4.90A和C = 7.95的差8.02A。 储氢材料是经济的并且适用于实际目的，因为它容易在室温下吸收大量的氢气，并通过环境氢气压力，温度条件或电化学条件的变化可靠地排放大量的氢气。
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