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公开(公告)号：US20080194773A1
公开(公告)日：2008-08-14
申请号：US11579587
申请日：2005-04-25
IPC分类号： C08F20/06 , C08F283/00
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： [Problems] There is provided a curable composition having good adhesion by using a non-organotin catalyst.[Means to Solve Problems] The curable composition comprises (A) an organic polymer having a silicon-containing group being capable of crosslinking by forming siloxane bonds and (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst, and is characterized in that a stress at 50% tension is within a range from 0.01 MPa to 0.20 MPa, when determined by adding and mixing 1.5 parts of tin octylate, 0.25 part by weight of laurylamine and 0.6 part by weight of pure water to 100 parts by weight of the component (A), subjecting the mixture to centrifugal defoaming, pouring the mixture carefully into a polyethylene frame not to mix air bubbles thereto, aging the mixture at 23° C. for one hour, and further at 70° C. for 20 hours, punching the obtained 3 mm thick cured sheet according to JIS K6251 to obtain No. 3 dumbbell, and carrying out a tension test (tensile speed: 200 mm/min) at 23° C. at 50% RH.
摘要翻译： [问题]提供了通过使用非有机锡催化剂具有良好粘附性的可固化组合物。 [解决问题的方法]固化性组合物包含（A）具有能够通过形成硅氧烷键交联的含硅基团的有机聚合物和（B）选自钛催化剂，铝催化剂和锆的一种或多种 催化剂，其特征在于，当通过加入和混合1.5份辛酸锡，0.25重量份月桂胺和0.6重量份纯水测定时，50％张力下的应力在0.01MPa至0.20MPa的范围内 至100重量份的组分（A），将混合物进行离心脱泡，将混合物小心地注入聚乙烯框架中以不混合气泡，将混合物在23℃下老化1小时，进一步在70℃ ℃下冲洗20小时，根据JIS K6251冲压得到的3mm厚的固化片，得到3号哑铃，在23℃，50％RH下进行拉伸试验（拉伸速度：200mm / min） 。
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公开(公告)号：US20080021140A1
公开(公告)日：2008-01-24
申请号：US11547027
申请日：2005-03-18
IPC分类号： C08L101/10 , C08K5/09 , C08L71/02 , C08K5/47
CPC分类号： C08G65/336 , C08K5/09 , C08K5/44 , C08L71/02 , C08L101/10 , C08L2205/02 , C08L2666/02 , C08L2666/14
摘要： The present invention has its object to provide a curable composition having good curability and capable of keeping a curability and mechanical strength even after storage by using a substantially metal-free curing catalyst. The present invention provides a curable composition which comprises (A) an organic polymer having a silicon-containing group capable of crosslinking by forming a siloxane bond, (B) a carboxylic acid of which the carbon atom adjacent to a carbonyl group is a quaternary carbon, and (C) a polymer plasticizer.
摘要翻译： 本发明的目的是提供一种具有良好固化性的固化性组合物，即使在使用基本上无金属的固化催化剂进行保存后也能够保持固化性和机械强度。 本发明提供一种可固化组合物，其包含（A）具有通过形成硅氧烷键而能够交联的含硅基团的有机聚合物，（B）与羰基相邻的碳原子为季碳的羧酸 ，（C）聚合物增塑剂。
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公开(公告)号：US20070287780A1
公开(公告)日：2007-12-13
申请号：US11579635
申请日：2005-04-25
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： [Problem] There is provided a curable composition having satisfactory curability and adhesion by use of a non-tin curing catalyst, and minimizing lowering of mechanical properties of a cured article obtained after storing. [Means to Solve] A one-component type curable composition comprising (A) a polyoxyalkylene polymer (a1) having a silicon-containing group being capable of crosslinking by forming siloxane bonds and/or a (meth)acrylate polymer (a2) having a silicon-containing group being capable of crosslinking by forming siloxane bonds, (B) a chelate type methyl titanate (b1) and/or a chelate type ethyl titanate (b2), and (C) a compound having, in its molecule, a hydrolyzable silicon group and a nitrogen-substituted group.
摘要翻译： [问题]提供了通过使用非锡固化催化剂具有令人满意的固化性和粘合性的可固化组合物，并且使储存后获得的固化物的机械性能降至最低。 [解决方法]一种单组分型可固化组合物，其包含（A）具有能够通过形成硅氧烷键而交联的含硅基团的聚氧化烯聚合物（a1）和/或具有（甲基）丙烯酸酯聚合物 含硅基团能够通过形成硅氧烷键交联，（B）螯合型甲基钛酸酯（b1）和/或螯合型钛酸乙酯（b2），和（C）在其分子中具有可水解的 硅基和氮取代基。
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公开(公告)号：US20060199933A1
公开(公告)日：2006-09-07
申请号：US10568616
申请日：2004-08-12
IPC分类号： C08G77/60
CPC分类号： C08K5/09 , C08G18/244 , C08L101/10 , C08L75/04
摘要： The present invention provides a curable composition including: an organic polymer (A) which has on average 1.1 to 50 groups per one molecule thereof each represented by the general formula (1) and has one or more silicon-containing functional groups capable of cross-linking by forming siloxane bonds: —NR1—C(═O)— (1) wherein R1 is a hydrogen atom, or a substituted or unsubstituted monovalent organic group; and a metal carboxylate and/or a carboxylic acid (B), the curable composition giving a cured article excellent in curability and also excellent in heat resistance although a non-organotin catalyst is used.
摘要翻译： 本发明提供一种可固化组合物，其包含：有机聚合物（A），其每一分子平均具有1.1至50个基团，各自由通式（1）表示，并且具有一个或多个能够交联的含硅官能团， 通过形成硅氧烷键进行连接：<？in-line-formula description =“In-line formula”end =“lead”→NR 1 -C（-O） - （1） 其中R 1是氢原子，或取代或未取代的一价有机基团;在式中， 和金属羧酸盐和/或羧酸（B），虽然使用非有机锡催化剂，但固化性组合物赋予固化性优异且耐热性优异的固化物。
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公开(公告)号：US07073451B1
公开(公告)日：2006-07-11
申请号：US10523033
申请日：2003-09-08
CPC分类号： F22B29/065 , F22B37/645
摘要： A furnace wall comprises: a furnace wall bottom part composed of furnace wall tubes having upward-spiraled fluid passages; a nose part which has nose wall tubes disposed in a middle part of a furnace rear wall adjoining the furnace wall bottom part; and a screen part having screen tubes, wherein the terminal parts of the furnace wall tubes are located lower than the nose part. Consequently, the drain generated in the nose wall tubes while the operation of the boiler is suspended can naturally fall inside the furnace wall tubes located lower than the nose part, and in a case where the header is connected with the terminal parts of the furnace wall tubes, the drain generated in the nose wall tubes can naturally fall inside the header. In addition, the furnace wall tubes which extend upright from the terminal parts of the furnace wall tubes can be provided to connect parts of the furnace wall tubes directly with the header, to connect the header with the nose wall tubes via vertical tubes and; and to connect other parts of the furnace wall tubes directly with the screen tubes, thereby integrating the vertical furnace wall tubes, the vertical tubes, and the screen tubes by being welded via membrane bars. This results in the furnace wall structure not requiring reinforcing supports for supporting the weight of the furnace wall bottom part.
摘要翻译： 炉壁包括：炉壁底部，由具有向上螺旋形流体通道的炉壁管组成; 鼻子部分，其具有设置在邻近炉壁底部的炉后壁的中间部分中的鼻壁管; 以及具有筛管的筛部，其中，所述炉壁管的端部位于比所述鼻部低的位置。 因此，当锅炉的操作被暂停时在鼻壁管中产生的排水管可以自然地落在位于比鼻部低的炉壁管内，并且在集管与炉壁的端部连接的情况下 管子中，在鼻壁管中产生的排水管自然会落在集管内。 另外，可以提供从炉壁管的端部部分直立延伸的炉壁管，以将炉壁管的部分直接与集管连接，通过垂直管将管头与鼻壁管连接; 并将炉壁管的其他部分与筛管直接连接，从而通过膜条进行焊接来整合垂直炉壁管，垂直管和筛管。 这导致炉壁结构不需要用于支撑炉壁底部的重量的加强支撑件。
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36.发明申请Curable composition and methods for improving recovery properties and creep properties 有权用于改善回收性能和蠕变性能的可固化组合物和方法公开(公告)号：US20060128919A1
公开(公告)日：2006-06-15
申请号：US10533309
申请日：2003-10-22
CPC分类号： C08G65/336 , C08L101/10 , C09K3/1018
摘要： Disclosed are a curable composition characterized by using a curable composition including an organic polymer (A1) having one or more silicon-containing functional groups capable of cross-linking by forming siloxane bonds in which the one or more silicon-containing functional groups capable of cross-linking by forming siloxane bonds are silicon-containing functional groups each having three or more hydrolyzable groups on one or more silicon atoms thereof; and a method for controlling the recovery properties, durability and creep resistance of the cured article. Herewith, the present invention provides a curable composition capable of giving a cured article excellent in recovery properties, durability and creep resistance, and a method for controlling the recovery properties, durability and creep resistance of the cured article.
摘要翻译： 公开了一种可固化组合物，其特征在于使用包含具有一个或多个能够通过形成硅氧烷键交联的含硅官能团的有机聚合物（A1）的固化性组合物，其中所述一个或多个能够交叉的含硅官能团 通过形成硅氧烷键的连接是在其一个或多个硅原子上具有三个或更多个可水解基团的含硅官能团; 以及用于控制固化制品的回收性能，耐久性和抗蠕变性的方法。 因此，本发明提供了能够提供回收性，耐久性和抗蠕变性优异的固化物的固化性组合物，以及控制固化物的回收性，耐久性和抗蠕变性的方法。
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公开(公告)号：US20050171315A1
公开(公告)日：2005-08-04
申请号：US11091509
申请日：2005-03-29
CPC分类号： C08L83/04 , C08K5/09 , C09K3/1018
摘要： The present invention provides a curable composition which has a high recovery ratio, a high creep resistance, a practical curability and a storage stability. The present invention relates to a curable composition comprising a reactive silicon group-containing organic polymer (A) and a carboxylic acid (B), (I) wherein the composition comprises, as the carboxylic acid (B), a carboxylic acid (C) in which the carbon atom adjacent to the carbonyl group is a quaternary carbon atom; and/or (II) wherein the composition comprises a metal carboxylate (D) formed between a carboxylic acid in which the carbon atom adjacent to the carbonyl group is a quaternary carbon atom and a metal atom of 208 or less in atomic weight.
摘要翻译： 本发明提供了一种具有高回收率，高抗蠕变性，实用的固化性和储存稳定性的可固化组合物。 本发明涉及包含含活性硅基团的有机聚合物（A）和羧酸（B），（I）的可固化组合物，其中组合物包含羧酸（B），羧酸（C） 其中与羰基相邻的碳原子是季碳原子; 和/或（II）其中所述组合物包含在其中与羰基相邻的碳原子为季碳原子的碳酸酯和原子量为208以下的金属原子之间形成的金属羧酸盐（D）。
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公开(公告)号：US06802223B2
公开(公告)日：2004-10-12
申请号：US10669565
申请日：2003-09-25
申请人： Hiroshi Nakatani , Tatsuya Kimura , Yoshito Sameda , Takuya Iijima , Takashi Higuchi , Makoto Futoo , Hiroaki Nojiri , Kiyonori Nishikawa , Toshihiko Okamoto
发明人： Hiroshi Nakatani , Tatsuya Kimura , Yoshito Sameda , Takuya Iijima , Takashi Higuchi , Makoto Futoo , Hiroaki Nojiri , Kiyonori Nishikawa , Toshihiko Okamoto
IPC分类号： G01F158
摘要： The invention consists in a capacitative electromagnetic flow meter in which excitation is performed at a frequency above the commercially available frequency and having a characteristic correction filter that corrects the gain frequency characteristic of the exciting current such that the exciting flux waveform has a flat section. In the detection unit, the value of the electrostatic capacitance between the face electrodes 4A, 4B and guard electrodes 5A, 5B is made smaller than the value of the electrostatic capacitance between the detecting face electrodes 4A, 4B and the fluid to be measured. The exciting coils are fixed to a cylindrical yoke, being electrostatically screened by coil fixing plates. Fixing by an earth ring is performed with this cylindrical yoke and the two ends of the measurement tube being symmetrical with respect to the tube axis and electrode axes. In addition, fixing is effected by filling the entire interior of the detection unit with epoxy resin.
摘要翻译： 本发明是一种电容式电磁流量计，其中以高于市售频率的频率进行激励，并且具有校正激励电流的增益频率特性的特征校正滤波器，使得激励磁通波形具有平坦部分。 在检测单元中，使面电极4A，4B与保护电极5A，5B之间的静电电容值小于检测面电极4A，4B与待测流体之间的静电电容值。 励磁线圈固定到圆柱形轭，由线圈固定板静电屏蔽。 用该圆柱形磁轭进行固定，测量管的两端相对于管轴和电极轴对称。 此外，通过用环氧树脂填充检测单元的整个内部来实现固定。
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公开(公告)号：US09534158B2
公开(公告)日：2017-01-03
申请号：US14002573
申请日：2012-02-22
IPC分类号： C09J201/10 , C08L101/10 , C08G65/336 , C09J171/02 , C08G65/26
CPC分类号： C09J171/02 , C08G65/2663 , C08G65/336 , C08L101/10 , C08L2205/02 , C09J201/10
摘要： The present invention provides a curable composition useful as a contact adhesive which has a high rate of initial tack development, high tack strength, and long retention time of the developed tack. The curable composition includes an organic polymer (Q) containing a reactive silyl group, and a linear organic polymer (P) having a number average molecular weight larger than that of the polymer (Q) and having a reactive silyl group containing three hydrolyzable groups at only one terminal. The organic polymer (P) and the organic polymer (Q) are mixed at a mixing ratio (P):(Q), in terms of parts by weight, of 60:40 to 5:95.
摘要翻译： 本发明提供一种可用作接触粘合剂的可固化组合物，其具有高的初始粘着力发展速度，高粘着强度和显影粘性的长的保留时间。 可固化组合物包括含有反应性甲硅烷基的有机聚合物（Q）和数均分子量大于聚合物（Q）的直链有机聚合物（P），并且具有含有三个可水解基团的反应性甲硅烷基 只有一个终端。 有机聚合物（P）和有机聚合物（Q）以重量比为60:40至5:95的混合比（P）:( Q）混合。
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40.发明授权Curable composition and method for improving recovery properties and creep properties 有权改善回收性能和蠕变性能的组合物和方法公开(公告)号：US08586688B2
公开(公告)日：2013-11-19
申请号：US13053181
申请日：2011-03-21
CPC分类号： C08G65/336 , C08L101/10 , C09K3/1018
摘要： Disclosed are a curable composition characterized by using a curable composition including an organic polymer (A1) having one or more silicon-containing functional groups capable of cross-linking by forming siloxane bonds in which the one or more silicon-containing functional groups capable of cross-linking by forming siloxane bonds are silicon-containing functional groups each having three or more hydrolyzable groups on one or more silicon atoms thereof; and a method for controlling the recovery properties, durability and creep resistance of the cured article. Herewith, the present invention provides a curable composition capable of giving a cured article excellent in recovery properties, durability and creep resistance, and a method for controlling the recovery properties, durability and creep resistance of the cured article.
摘要翻译： 公开了一种可固化组合物，其特征在于使用包含具有一个或多个能够通过形成硅氧烷键交联的含硅官能团的有机聚合物（A1）的固化性组合物，其中所述一个或多个能够交叉的含硅官能团 通过形成硅氧烷键的连接是在其一个或多个硅原子上具有三个或更多个可水解基团的含硅官能团; 以及用于控制固化制品的回收性能，耐久性和抗蠕变性的方法。 因此，本发明提供了能够提供回收性，耐久性和抗蠕变性优异的固化物的固化性组合物，以及控制固化物的回收性，耐久性和抗蠕变性的方法。
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