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    Photochromic contact lenses and methods of manufacturing
    33.
    发明授权
    Photochromic contact lenses and methods of manufacturing 有权
    光致变色隐形眼镜及制造方法

    公开(公告)号：US07560056B2

    公开(公告)日：2009-07-14

    申请号：US12027522

    申请日：2008-02-07

    申请人： Barry Van Gemert ,  Anil Kumar ,  Frank P. Mallak ,  Robert W. Walters

    发明人： Barry Van Gemert ,  Anil Kumar ,  Frank P. Mallak ,  Robert W. Walters

    IPC分类号： G02C7/10 ,  B29D11/00

    CPC分类号： B29D11/00048 ,  B29D11/00317 ,  B29D11/00653

    摘要： Described are contact lenses having photochromic materials within the central or pupillary area of the lens and methods for manufacturing such lenses. In one method, a photochromic amount of at least one photochromic material is added to the pupillary region of a casting mold containing a polymerizable monomer that can be at least partially cured before and/or after the addition. Another method involves providing an amount of polymerizable photochromic monomer for the pupillary region and an amount of polymerizable non-photochromic monomer for the remainder of the contact lens in a casting mold. The photochromic and non-photochromic monomers can differ by their degree of polymerization, viscosity and/or density.

    摘要翻译： 描述了在透镜的中心或瞳孔区域内具有光致变色材料的隐形眼镜及其制造方法。 在一种方法中，将光致变色量的至少一种光致变色材料添加到含有可聚合单体的铸模的瞳孔区域中，该可聚合单体可以在添加之前和/或之后至少部分固化。 另一种方法包括提供一定量的用于瞳孔区域的可聚合光致变色单体和一定量的用于在模具中的隐形眼镜的其余部分的可聚合的非光致变色单体。 光致变色和非光致变色单体可以通过其聚合度，粘度和/或密度而不同。

    Photochromic materials having electron-withdrawing substituents
    34.
    发明授权
    Photochromic materials having electron-withdrawing substituents 有权
    具有吸电子取代基的光致变色材料

    公开(公告)号：US07556751B2

    公开(公告)日：2009-07-07

    申请号：US11314141

    申请日：2005-12-21

    申请人： Anu Chopra ,  Beon-Kyu Kim ,  Barry Van Gemert

    发明人： Anu Chopra ,  Beon-Kyu Kim ,  Barry Van Gemert

    IPC分类号： G02B5/23

    CPC分类号： G03C1/73 ,  C07D311/94 ,  C07D409/04 ,  C09K9/02 ,  C09K2211/1011 ,  C09K2211/1088

    摘要： Photochromic materials comprising indeno-fused naphthopyrans having a first electron-withdrawing substituent and, in certain non-limiting embodiments, a second electron-withdrawing substituent are disclosed. The photochromic materials according to the various embodiments may display faster fade rates, bathochromic shift, and higher performance ratings compared to comparable indeno-fused naphthopyrans without the electron-withdrawing substituents. Photochromic compositions and articles, such as optical elements, incorporating the photochromic materials are also disclosed.

    摘要翻译： 公开了包含具有第一吸电子取代基的茚并稠合萘并吡喃的光致变色材料，在某些非限制性实施方案中为第二吸电子取代基。 根据各种实施方案的光致变色材料可以显示比没有吸电子取代基的可比的茚并稠合萘并吡喃更快的褪色速率，红移偏移和更高的性能等级。 还公开了掺入光致变色材料的光致变色组合物和制品，例如光学元件。

    PHOTOCHROMIC CONTACT LENSES AND METHODS OF MANUFACTURING
    35.
    发明申请
    PHOTOCHROMIC CONTACT LENSES AND METHODS OF MANUFACTURING 有权
    光敏接触镜片及其制造方法

    公开(公告)号：US20080125512A1

    公开(公告)日：2008-05-29

    申请号：US12027522

    申请日：2008-02-07

    申请人： Barry Van Gemert ,  Anil Kumar ,  Frank P. Mallak ,  Robert W. Walters

    发明人： Barry Van Gemert ,  Anil Kumar ,  Frank P. Mallak ,  Robert W. Walters

    IPC分类号： G02C7/04 ,  B29D11/02

    CPC分类号： B29D11/00048 ,  B29D11/00317 ,  B29D11/00653

    摘要： Described are contact lenses having photochromic materials within the central or pupillary area of the lens and methods for manufacturing such lenses. In one method, a photochromic amount of at least one photochromic material is added to the pupillary region of a casting mold containing a polymerizable monomer that can be at least partially cured before and/or after the addition. Another method involves providing an amount of polymerizable photochromic monomer for the pupillary region and an amount of polymerizable non-photochromic monomer for the remainder of the contact lens in a casting mold. The photochromic and non-photochromic monomers can differ by their degree of polymerization, viscosity and/or density.

    摘要翻译： 描述了在透镜的中心或瞳孔区域内具有光致变色材料的隐形眼镜及其制造方法。 在一种方法中，将光致变色量的至少一种光致变色材料添加到含有可聚合单体的铸模的瞳孔区域中，该可聚合单体可以在添加之前和/或之后至少部分固化。 另一种方法包括提供一定量的用于瞳孔区域的可聚合光致变色单体和一定量的用于在模具中的隐形眼镜的其余部分的可聚合的非光致变色单体。 光致变色和非光致变色单体可以通过其聚合度，粘度和/或密度而不同。

    Photochromic materials having extended pi-conjugated systems and compositions and articles including the same
    36.
    发明申请
    Photochromic materials having extended pi-conjugated systems and compositions and articles including the same 审中-公开
    具有延伸的π-共轭体系的光致变色材料和包含其的组合物和制品

    公开(公告)号：US20060228557A1

    公开(公告)日：2006-10-12

    申请号：US11102279

    申请日：2005-04-08

    申请人： Beon-Kyu Kim ,  Jun Deng ,  Wenjing Xiao ,  Barry Van Gemert ,  Anu Chopra

    发明人： Beon-Kyu Kim ,  Jun Deng ,  Wenjing Xiao ,  Barry Van Gemert ,  Anu Chopra

    IPC分类号： B32B9/00 ,  C07D498/02 ,  C07D491/02 ,  C07D493/02 ,  G02F1/361

    CPC分类号： C09K9/02 ,  C07D311/78 ,  C07D405/04 ,  C07D409/04 ,  C07D493/04 ,  C07D495/04 ,  C09K2211/1007 ,  C09K2211/1022 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/1096 ,  G03C1/685 ,  G03C1/73 ,  Y10T428/31504

    摘要： Various non-limiting embodiments disclosed herein relate to photochromic materials having extended pi-conjugated systems. For example, various non-limiting embodiments disclosed herein provide a photochromic material, such as an indeno-fused naphthopyran, which comprises a group that extends the pi-conjugated system of the indeno-fused naphthopyran bonded at the 11-position thereof. Further, the photochromic materials according to certain non-limiting embodiments disclosed herein may display hyperchromic absorption of electromagnetic radiation as compared to conventional photochromic materials and/or may have a closed-form absorption spectrum that is bathochromically shifted as compared to conventional photochromic materials. Other non-limiting embodiments relate to photochromic compositions and photochromic articles, such as optical elements, made using the disclosed photochromic materials, and methods of making the same.

    摘要翻译： 本文公开的各种非限制性实施方案涉及具有延伸的π-共轭体系的光致变色材料。 例如，本文公开的各种非限制性实施方案提供光致变色材料，例如茚并稠合的萘并吡喃，其包含延伸在其11位键合的茚并稠合的萘并吡喃的π-共轭体系的基团。 此外，与常规光致变色材料相比，根据本文公开的某些非限制性实施方案的光致变色材料可以显示电磁辐射的超色吸收和/或可以具有与常规光致变色材料相比被红移的闭合形式的吸收光谱。 其它非限制性实施方案涉及光致变色组合物和光致变色制品，例如使用所公开的光致变色材料制备的光学元件及其制备方法。

    Polymeric matrix compatibilized naphthopyrans
    37.
    发明授权
    Polymeric matrix compatibilized naphthopyrans 有权
    聚合物基体相容萘并吡喃

    公开(公告)号：US06555028B2

    公开(公告)日：2003-04-29

    申请号：US09828260

    申请日：2001-04-06

    申请人： Robert W. Walters ,  Barry Van Gemert

    发明人： Robert W. Walters ,  Barry Van Gemert

    IPC分类号： G02B523

    CPC分类号： C07D407/12 ,  C07D311/92 ,  C07D311/94 ,  C07D311/96 ,  C08G65/3315 ,  C08G65/3318 ,  C08G65/3346 ,  C08K5/1545 ,  C09B57/00 ,  C09B57/02 ,  C09B69/109 ,  C09K9/02 ,  G02B1/041 ,  G02B1/043 ,  G02B5/23

    摘要： Described are polymeric matrix compatibilized naphthopyran compounds, examples of which are certain 2H-naphtho[1,2-b]pyrans, 3H-naphtho[2,1-b]pyrans and indeno[2,1-f]naphtho[1,2-b]pyrans each having at least one substituent containing terminal and/or pendant groups selected from hydroxyl, carboxyl, sulfo, sulfono, (meth)acryloxy, 2-(methacryloxy)ethylcarbamyl, epoxy or a mixture thereof. Specific substituents are also present on the naphtho, indeno and/or pyrano portions of the compounds. These compounds may be represented by the following graphic formulae: Also described are various substrates that contain or that are coated with such compounds. Optically clear articles such as contact lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, are also described.

    摘要翻译： 描述的是聚合物基质相容的萘并吡喃化合物，其实例是一定的2H-萘并[1,2-b]吡喃，3H-萘并[2,1-b]吡喃和茚并[2,1-f]萘并[1,2 （甲基丙烯酰氧基）乙基氨基甲酰基，环氧基或它们的混合物中的至少一个含有末端和/或侧基的取代基的-b]吡喃各自具有选自羟基，羧基，磺基，磺基，（甲基）丙烯酰氧基， 具体的取代基也存在于化合物的萘酚，茚并和/或吡喃葡萄糖部分上。 这些化合物可以由以下图形表示：还描述了含有这些化合物或者被这些化合物包被的各种底物。 还描述了光学清洁的物品，例如隐形眼镜或其它掺入新型萘并吡喃化合物或其组合与互补光致变色化合物的塑料透明胶片。

    Photochromic naphthopyrans
    38.
    发明授权
    Photochromic naphthopyrans 有权
    光致变色萘并吡喃

    公开(公告)号：US06348604B1

    公开(公告)日：2002-02-19

    申请号：US09656509

    申请日：2000-09-06

    申请人： Clara M. Nelson ,  Anu Chopra ,  David B. Knowles ,  Barry Van Gemert ,  Anil Kumar

    发明人： Clara M. Nelson ,  Anu Chopra ,  David B. Knowles ,  Barry Van Gemert ,  Anil Kumar

    IPC分类号： G02B523

    CPC分类号： C07D311/92 ,  C07D493/04 ,  G02B5/23

    摘要： Described are novel photochromic 2H-naphtho[1,2-b]pyran compounds essentially characterized by having two adjacent moderate to strong electron donor substituents at the 8 and 9 positions or a fused heterocyclic group formed by the substituents coming together, weak to moderate electron donors at the 2 position and a rating of at least 80 in the Relative &Dgr;OD at Saturation Test. The compounds also have certain substituents at the 5 position and optionally at the 6 position of the naphtho portion of the compound. These compounds may be represented by the following graphic formula: Also described are polymeric organic host materials that contain or that are coated with such compounds. Optically clear articles such as ophthalmic lenses or adjacent plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., certain other naphthopyrans, benzopyrans, and spiro(indoline)type compounds, are also described.

    摘要翻译： 描述了新颖的光致变色2H-萘并[1,2-b]吡喃化合物，其基本上特征在于在8和9位具有两个相邻的中等至强电子给体取代基或由取代基组成的稠合杂环基团，弱至中等电子 捐助者在2位置，并且在饱和度测试的相对DELTAOD中评级至少为80。 化合物在化合物的萘酚部分的5位和任选地位置上也具有某些取代基。 这些化合物可以由以下图解表示：还描述了含有这些化合物或被这些化合物包被的聚合物有机主体材料。 还描述了光学透明的物品，例如将眼用透镜或相邻的塑料透明胶片结合到新的萘并吡喃化合物或其组合与互补光致变色化合物，例如某些其它萘并吡喃，苯并吡喃和螺（二氢吲哚）型化合物。

    Indeno-fused photochromic naphthopyrans
    39.
    发明授权
    Indeno-fused photochromic naphthopyrans 有权
    印度融合的光致变色萘并吡喃

    公开(公告)号：US06296785B1

    公开(公告)日：2001-10-02

    申请号：US09656510

    申请日：2000-09-06

    申请人： Clara M. Nelson ,  Anu Chopra ,  Olga G. Petrovskaia ,  David B. Knowles ,  Barry Van Gemert ,  Anil Kumar

    发明人： Clara M. Nelson ,  Anu Chopra ,  Olga G. Petrovskaia ,  David B. Knowles ,  Barry Van Gemert ,  Anil Kumar

    IPC分类号： C07D31178

    CPC分类号： C07D311/94 ,  C07D311/96 ,  G02B5/23

    摘要： Described are novel photochromic indeno-fused naphthopyran compounds, examples of which include naphthopyran compounds having a substituted or unsubstituted indeno group, the 2,1 positions of which are fused to the naphtho portion of the naphthopyran as shown below. Also present on the naphthopyran are moderate to strong electron donor substituents at the number 6- and 7-positions and optionally at the 8-position of the pyran ring or a cyclic group fused to the h side of the naphtho portion and weak to moderate electron donor substiuents at the 3-position of the pyran ring. Certain substituents may also be present at the number 5, 8, 9, 10, 11, 12, or 13 carbon atoms of the compounds. These compounds have a rating of at least 80 in the Relative &Dgr;OD at Saturation Test and may be represented by the following graphic formula: Also described are polymeric organic host materials that contain or that are coated with such compounds. Optically clear articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., certain other naphthopyrans, benzopyrans, and spiro(indoline)type compounds, are also described.

    摘要翻译： 描述了新的光致变色茚并稠合萘并吡喃化合物，其实例包括具有取代或未取代的茚并基团的萘并吡喃化合物，其2,1个位置与萘并吡喃的萘酚部分稠合，如下所示。 还存在于萘并吡喃上的是中子至强电子给体取代基，位于吡喃环的6-位和7-位，任选在8-位或稠合于萘酚部分的h侧的环状基团，弱至中等电子 在吡喃环3位的供体位。 某些取代基也可以存在于化合物的5,8,9,10,11,12或13个碳原子上。 这些化合物在饱和度测试中的相对DELTAOD中的等级至少为80，并且可以由以下图形表示：还描述了含有或涂覆有这些化合物的聚合物有机主体材料。 还描述了光学透明的物品，例如将眼用透镜或其它塑料透明胶片掺入新的萘并吡喃化合物或其组合与互补的光致变色化合物，例如某些其它萘并吡喃，苯并吡喃和螺（二氢吲哚）型化合物。

    Polymerizable polyalkoxylated naphthopyrans
    40.
    发明授权
    Polymerizable polyalkoxylated naphthopyrans 有权
    可聚合的聚烷氧基化萘并吡喃

    公开(公告)号：US6113814A

    公开(公告)日：2000-09-05

    申请号：US437982

    申请日：1999-11-10

    申请人： Barry Van Gemert ,  Anu Chopra ,  Anil Kumar

    发明人： Barry Van Gemert ,  Anu Chopra ,  Anil Kumar

    IPC分类号： G03C1/73 ,  C07D311/92 ,  C07D311/94 ,  C07D407/12 ,  C08G65/331 ,  C08G65/334 ,  C08K5/1545 ,  C08L101/00 ,  C09K9/02 ,  G02B1/04 ,  G02B5/23 ,  G05F3/02 ,  G02C7/10

    CPC分类号： C07D407/12 ,  C07D311/92 ,  C07D311/94 ,  C08G65/3315 ,  C08G65/3318 ,  C08G65/3346 ,  C08K5/1545 ,  C09B57/02 ,  C09K9/02 ,  G02B1/041 ,  G02B1/043

    摘要： Described are novel photochromic polymerizable polyalkoxylated naphthopyran compounds, examples of which are certain 2H-naphtho[1,2-b]pyrans, 3H-naphtho[2,1-b]pyrans and indeno[2,1-f]naphtho[1,2-b]pyrans each having at least one polyalkoxylated substituent of from 1 to 50 alkoxy units per substituent which is end-capped with a polymerizable group. Specific substituents are also present on the naphtho, indeno and pyrano portions of the compounds. These compounds may be represented by the following graphic formulae: ##STR1## Also described are various substrates, e.g., paper, glass, polymeric organic materials, etc., that contain or that are coated with such compounds. Optically clear articles such as contact lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., certain other naphthopyrans, indenonaphthopyrans, benzopyrans, oxazine-type compounds, etc., are also described.

    摘要翻译： 描述了新的光致变色可聚合的聚烷氧基化萘并吡喃化合物，其实例是某些2H-萘并[1,2-b]吡喃，3H-萘并[2,1-b]吡喃和茚并[2,1-f]萘并[ 2-b]吡喃，每个具有至少一个具有1至50个烷氧基单元的聚烷氧基化取代基，每个取代基被可聚合基团封端。 具体的取代基也存在于化合物的萘并茚并吡喃部分上。 这些化合物可以由以下图解表示：还描述了含有或涂覆有这些化合物的各种基材，例如纸，玻璃，聚合有机材料等。 还描述了光学透明的物品，例如将新颖的萘并吡喃化合物或其组合与互补的光致变色化合物（例如某些其它萘并吡喃，茚并萘并吡喃，苯并吡喃，恶嗪型化合物等）结合的隐形眼镜或其它塑料透明胶片。