Conjugated polymer preparation via Suzuki-coupling in emulsion
    31.
    发明授权
    Conjugated polymer preparation via Suzuki-coupling in emulsion 有权
    通过Suzuki偶联在乳液中共轭聚合物制备

    公开(公告)号:US07074884B2

    公开(公告)日:2006-07-11

    申请号:US10493650

    申请日:2002-10-22

    IPC分类号: C08G79/08 B32B9/00

    摘要: A process for preparing a conjugated polymer, which comprises polymerizing in a reaction mixture (a) an aromatic monomer having at least two boron derivative functional groups selected from the group consisting of boronic acid groups, boronic ester groups, and borane groups, and an aromatic monomer having at least two reactive halide functional groups, or (b) an aromatic monomer having one reactive halide functional group and one boron derivative functional group selected from the group consisting of boronic acid groups, boronic ester groups, and borane groups, an amount of a catalyst suitable for catalyzing the polymerization of the aromatic monomers, and a base in an amount sufficient to convert the boron derivative functional groups into boron anionic groups, characterized in that the reaction mixture further comprises a first solvent and a second solvent with which said first solvent is substantially immiscible and an emulsifier in an amount sufficient to form an emulsion of the reaction mixture.

    摘要翻译: 一种制备共轭聚合物的方法,其包括在反应混合物(a)中具有至少两个选自硼酸基团,硼酸酯基团和硼烷基团的硼衍生官能团的芳族单体和芳族单体聚合 具有至少两个反应性卤化物官能团的单体,或(b)具有一个反应性卤化物官能团的芳族单体和一个选自硼酸基,硼酸酯基和硼烷基的硼衍生官能团, 适用于催化芳族单体的聚合的催化剂和足以将硼衍生物官能团转化为硼阴离子基团的量的碱,其特征在于所述反应混合物还包含第一溶剂和第二溶剂,其中所述第一溶剂 溶剂是基本上不混溶的,并且乳化剂的量足以形成反应物的乳液 动作混合物

    Conjugated polymer preparation via suzuki-coupling in emulsion
    33.
    发明申请
    Conjugated polymer preparation via suzuki-coupling in emulsion 有权
    通过Suzuki偶联在乳液中的共轭聚合物制备

    公开(公告)号:US20050037230A1

    公开(公告)日:2005-02-17

    申请号:US10493650

    申请日:2002-10-22

    摘要: A process for preparing a conjugated polymer, which comprises polymerizing in a reaction mixture (a) an aromatic monomer having at least two boron derivative functional groups selected from the group consisting of boronic acid groups, boronic ester groups, and borane groups, and an aromatic monomer having at least two reactive halide functional groups, or (b) an aromatic monomer having one reactive halide functional group and one boron derivative functional group selected from the group consisting of boronic acid groups, boronic ester groups, and borane groups, an amount of a catalyst suitable for catalyzing the polymerization of the aromatic monomers, and a base in an amount sufficient to convert the boron derivative functional groups into boron anionic groups, characterized in that the reaction mixture further comprises a first solvent and a second solvent with which said first solvent is substantially immiscible and an emulsifier in an amount sufficient to form an emulsion of the reaction mixture.

    摘要翻译: 一种制备共轭聚合物的方法,其包括在反应混合物(a)中具有至少两个选自硼酸基团,硼酸酯基团和硼烷基团的硼衍生官能团的芳族单体和芳族单体聚合 具有至少两个反应性卤化物官能团的单体,或(b)具有一个反应性卤化物官能团的芳族单体和一个选自硼酸基,硼酸酯基和硼烷基的硼衍生官能团, 适用于催化芳族单体的聚合的催化剂和足以将硼衍生物官能团转化为硼阴离子基团的量的碱,其特征在于所述反应混合物还包含第一溶剂和第二溶剂,其中所述第一溶剂 溶剂是基本上不混溶的,并且乳化剂的量足以形成反应物的乳液 动作混合物

    PHOSPHORESCENT OLED
    35.
    发明申请
    PHOSPHORESCENT OLED 有权
    磷光OLED

    公开(公告)号:US20090236972A1

    公开(公告)日:2009-09-24

    申请号:US11721321

    申请日:2005-12-12

    IPC分类号: H01J1/63 B05D5/12 C09K11/06

    摘要: An organic light emitting device having a phase-separated light-emissive layer comprising: a charge transport phase comprising a charge transport material; and an emitting phase, the emitting phase comprising a plurality of discrete emissive domains dispersed in the charge transport phase, each emitting domain comprising a host material and one or more metal complexes for emitting light by phosphorescence; wherein the charge transport material has a T1 energy level lower than the T1 energy level of the metal complexes and the host material has a T1 energy level higher than the T1 energy level of the metal complexes.

    摘要翻译: 一种具有相分离的发光层的有机发光器件,包括:电荷输送相,其包含电荷输送材料; 和发射相,所述发射相包括分散在所述电荷传输阶段中的多个离散发射畴,每个发射区包括主体材料和一个或多个通过磷光发射光的金属络合物; 其中所述电荷传输材料具有低于所述金属络合物的T1能级的T1能级,并且所述主体材料具有高于所述金属络合物的T1能级的T1能级。

    Polymer containing substituted triphenylamine units
    39.
    发明授权
    Polymer containing substituted triphenylamine units 有权
    含有取代的三苯胺单元的聚合物

    公开(公告)号:US07351788B2

    公开(公告)日:2008-04-01

    申请号:US10481439

    申请日:2002-06-20

    IPC分类号: C08G61/00 C08G61/10

    摘要: A method for making a polymer containing a first repeat unit having formula: —Ar—N(R)—Ar(N(R′)—Ar)x— which may be substituted or unsubstituted where x or 0 or 1; each Ar is the same or different and independently is a substituted or unsubstituted aryl or heteroaryl group and R and R′ each is hydrogen or a substituent group and a second repeat unit that is the same or different from the first repeat unit and comprises a substituted or unsubstituted, aryl or heteroaryl group.

    摘要翻译: 制备含有第一重复单元的聚合物的方法,所述第一重复单元具有下式:-Ar-N(R)-Ar(N(R')-Ar)x - ,其可以是取代或未取代的,其中x或 0或1; 每个Ar相同或不同,独立地为取代或未取代的芳基或杂芳基,R和R'各自为氢或取代基,第二重复单元与第一重复单元相同或不同,并且包含取代的 或未取代的芳基或杂芳基。