公开(公告)号：US09074092B2

公开(公告)日：2015-07-07

申请号：US12973270

申请日：2010-12-20

申请人： Ryan Thomas Neill ,  Michael Eugene Donelson ,  Bryan Steven Bishop ,  James Collins Maine ,  Wesley Raymond Hale

发明人： Ryan Thomas Neill ,  Michael Eugene Donelson ,  Bryan Steven Bishop ,  James Collins Maine ,  Wesley Raymond Hale

IPC分类号： C08G63/00 ,  C08L67/02 ,  B32B27/06 ,  B32B27/36

CPC分类号： C08L67/02 ,  B32B27/06 ,  B32B27/36 ,  B32B2270/00 ,  C08L2205/02 ,  C08L2205/03

摘要： Polyester blends containing recycled, post-consumer polyethylene terephthalate are described. The blends have the advantage of being miscible (visually clear) and remaining clear after post-extrusion heat histories.

摘要翻译： 描述了含有回收的，消费后的聚对苯二甲酸乙二醇酯的聚酯共混物。 混合物具有可混溶（视觉透明）的优点，并且在挤出后的热历史之后保持透明。

公开(公告)号：US08389117B2

公开(公告)日：2013-03-05

申请号：US12577324

申请日：2009-10-12

申请人： Marcus David Shelby ,  Scott Ellery George ,  Gary Robert Robe ,  Freddie Wayne Williams ,  Michael Eugene Donelson ,  Joshua Seth Cannon ,  Emmett Patrick O'Brien ,  Jeremy Richard Lizotte ,  Anthony Joseph Pasquale

发明人： Marcus David Shelby ,  Scott Ellery George ,  Gary Robert Robe ,  Freddie Wayne Williams ,  Michael Eugene Donelson ,  Joshua Seth Cannon ,  Emmett Patrick O'Brien ,  Jeremy Richard Lizotte ,  Anthony Joseph Pasquale

IPC分类号： C08L9/00

CPC分类号： C09J167/02 ,  B32B2037/1215 ,  C08G63/199 ,  Y10T428/1331 ,  Y10T428/1352 ,  Y10T428/28 ,  Y10T428/2813 ,  Y10T428/2826 ,  Y10T428/2852 ,  Y10T428/31786 ,  Y10T428/3179 ,  Y10T428/4935

摘要： Disclosed are hot-melt adhesives prepared from polyesters containing 1,4-cyclohexane-dicarboxylic acid as a diacid component and a diol component containing at least two diols chosen from 1,4-cyclohexanedimethanol, triethylene glycol, and diethylene glycol. These adhesives set up rapidly within a well-defined temperature window. The hot-melt adhesives can be used in a variety of applications, but are especially suited as seaming adhesives for roll-applied labels. These adhesives have melting temperatures and crystallization properties that allow their application at temperatures cool enough to prevent curling and premature shrinkage of the shrink label during seaming, and yet produce strong label seams that can withstand the elevated temperatures of a shrink tunnel without sacrificing line speed. Also disclosed are labeled containers and a process for applying a roll-on, shrink label to a container using the hot-melt adhesives of the invention.

摘要翻译： 公开了由含有1,4-环己烷二羧酸作为二酸组分的聚酯和含有至少两种选自1,4-环己烷二甲醇，三甘醇和二甘醇的二醇的二醇组分制备的热熔粘合剂。 这些粘合剂在一个明确定义的温度窗口内快速建立。 热熔粘合剂可以用于各种应用中，但特别适用于辊涂标签的接缝粘合剂。 这些粘合剂具有熔融温度和结晶性能，使得它们可以在足够温度下使用，以防止收缩标签在接缝过程中发生卷曲和过早收缩，并且还能产生强大的标签接缝，其能够承受收缩隧道的高温而不牺牲线速度。 还公开了标记的容器和使用本发明的热熔粘合剂将卷绕的收缩标签施加到容器的方法。

公开(公告)号：US20120184643A1

公开(公告)日：2012-07-19

申请号：US13097696

申请日：2011-04-29

申请人： Michael Eugene Donelson ,  James Collins Maine ,  Gary Stuart Hawkins ,  Jeff Scott Howell

发明人： Michael Eugene Donelson ,  James Collins Maine ,  Gary Stuart Hawkins ,  Jeff Scott Howell

IPC分类号： C08L67/03

CPC分类号： C08L67/02 ,  C08G63/12 ,  C08K3/015 ,  C08K3/10 ,  C08K3/22 ,  C08K3/24 ,  C08K3/32 ,  C08L75/16 ,  C08L2205/02 ,  C08L2666/18 ,  C08L2666/54

摘要： This invention relates to a polymer blend comprising:(A) about 1% by weight to about 99% by weight of at least one polymer (A) comprising terephthalic acid residues, 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues; (B) about 1% by weight to about 99% by weight of at least one polymer (B) comprising 1,4-cyclohexanedicarboxylic acid residues and 1,4-cyclohexanedimethanol residues, and (C) about 0.01% by weight to about 20% by weight of at least one antimicrobial agent; said weight percentages being based on the total weight of the polymer blend.

摘要翻译： 本发明涉及一种聚合物共混物，其包含：（A）约1重量％至约99重量％的至少一种包含对苯二甲酸残基的聚合物（A），2,2,4,4-四甲基-1,3- 环丁二醇残基; 和1,4-环己烷二甲醇残基; （B）约1重量％至约99重量％的至少一种包含1,4-环己烷二羧酸残基和1,4-环己烷二甲醇残基的聚合物（B），和（C）约0.01重量％至约20重量％ 重量％的至少一种抗微生物剂; 所述重量百分比基于聚合物共混物的总重量。

公开(公告)号：US20100089288A1

公开(公告)日：2010-04-15

申请号：US12634736

申请日：2009-12-10

申请人： Marcus David Shelby ,  Michael Eugene Donelson ,  Bradley Howard Dayvolt ,  Alan Kent Wilson ,  Bryan Kirkman

发明人： Marcus David Shelby ,  Michael Eugene Donelson ,  Bradley Howard Dayvolt ,  Alan Kent Wilson ,  Bryan Kirkman

IPC分类号： C09D101/10

CPC分类号： G02B5/3033 ,  C08B3/06 ,  C08B3/08 ,  C08B3/16 ,  C08J5/18 ,  C08J2301/14 ,  C08K5/0016 ,  C08L1/14

摘要： The present inventions relate to cellulose esters having low hydroxyl content for use in optical applications, such as liquid crystal display (LCD) films. Films with low hydroxyl levels and a given ratio of non-acetyl ester to hydroxyl level have low intrinsic birefringence. These films can be cast, molded, or otherwise oriented without an appreciable birefringence or optical distortion (i.e. retardation). These films are useful in polarizer, protective, and compensator films and in molded optical parts, such as lenses. The resins of the present inventions can also be made to have “+C plate” behavior either by melt or solvent based processing, which is uncharacteristic of cellulose esters. Such +C behavior allows films having unique compensatory behavior. Other embodiments of the invention relate to methods of melt casting films while minimizing birefringence. Another embodiment of the invention is directed to films made from the cellulose esters described herein further comprising a plasticizer.

摘要翻译： 本发明涉及用于光学应用的低羟基含量的纤维素酯，例如液晶显示（LCD）膜。 具有低羟基水平和给定比例的非乙酰酯与羟基水平的膜具有低固有双折射。 这些膜可以铸造，模制或以其他方式定向，而没有明显的双折射或光学变形（即延迟）。 这些膜可用于偏光镜，保护膜和补偿膜以及模制光学部件，例如透镜。 本发明的树脂也可以通过熔体或溶剂基处理制成具有“+ C”板的行为，这是纤维素酯的不合格的。 这种+ C行为允许电影具有独特的补偿行为。 本发明的其它实施方案涉及熔融浇铸薄膜的方法，同时最小化双折射。 本发明的另一个实施方案涉及由本文所述的纤维素酯制成的进一步包含增塑剂的薄膜。

公开(公告)号：US06984354B2

公开(公告)日：2006-01-10

申请号：US10090327

申请日：2002-03-04

申请人： Marcus David Shelby ,  Michael Eugene Donelson

发明人： Marcus David Shelby ,  Michael Eugene Donelson

IPC分类号： B29C49/24 ,  A47J41/02

CPC分类号： B29C49/24 ,  B29B2911/14113 ,  B29B2911/1412 ,  B29B2911/14133 ,  B29B2911/1416 ,  B29B2911/14166 ,  B29B2911/14213 ,  B29B2911/14593 ,  B29B2911/14653 ,  B29C49/04 ,  B29C49/041 ,  B29C49/06 ,  B29C49/22 ,  B29C2045/14918 ,  B29C2049/2412 ,  B29C2049/2422 ,  B29C2795/002 ,  B29K2009/00 ,  B29K2023/06 ,  B29K2023/086 ,  B29K2023/12 ,  B29K2067/00 ,  B29K2069/00 ,  B29K2077/00 ,  B29L2031/7158

摘要： A new process for making a labeled container using a stretch blow molding process wherein a label sleeve is positioned over at least a portion of the exterior surface of a preform to produce a sleeved preform and the sleeved preform is stretch blow molded to produce a labeled container having a snug-fit label.

公开(公告)号：USH2088H1

公开(公告)日：2003-11-04

申请号：US10185915

申请日：2002-06-27

申请人： Steven Lee Stafford ,  Lavonna Suzanne Buehrig ,  Louis Thomas Germinario ,  Terrill M. McGee ,  Gary Wayne Minnick ,  Eric Jon Moskala ,  Michael Eugene Donelson

发明人： Steven Lee Stafford ,  Lavonna Suzanne Buehrig ,  Louis Thomas Germinario ,  Terrill M. McGee ,  Gary Wayne Minnick ,  Eric Jon Moskala ,  Michael Eugene Donelson

IPC分类号： B29C3902

摘要： A method for reducing or eliminating plate-out during the process used to produce stretch blow molded containers from polyester preforms by crystallizing the low molecular weight polyester molecules in or on the preform exterior surface before stretch blow molding the preform into a container. The molecules are crystallized using a crystallization process selected from (1) treating the outer surface of the preform with a solvent that is capable of crystallizing low molecular weight polyester molecules in polyester or (2) heating the outer surface of the preform to a temperature and for a time suitable for crystallizing low molecular weight polyester molecules in polyester. Plate-out is reduced because the crystallized molecules do not migrate out of the preform and form plate-out deposits on the mold.

公开(公告)号：US08633262B2

公开(公告)日：2014-01-21

申请号：US13097696

申请日：2011-04-29

申请人： Michael Eugene Donelson ,  James Collins Maine ,  Gary Stuart Hawkins ,  Jeff Scott Howell

发明人： Michael Eugene Donelson ,  James Collins Maine ,  Gary Stuart Hawkins ,  Jeff Scott Howell

IPC分类号： C08K3/10

CPC分类号： C08L67/02 ,  C08G63/12 ,  C08K3/015 ,  C08K3/10 ,  C08K3/22 ,  C08K3/24 ,  C08K3/32 ,  C08L75/16 ,  C08L2205/02 ,  C08L2666/18 ,  C08L2666/54

摘要： This invention relates to a polymer blend comprising: (A) about 1% by weight to about 99% by weight of at least one polymer (A) comprising terephthalic acid residues, 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues; (B) about 1% by weight to about 99% by weight of at least one polymer (B) comprising 1,4-cyclohexanedicarboxylic acid residues and 1,4-cyclohexanedimethanol residues, and (C) about 0.01% by weight to about 20% by weight of at least one antimicrobial agent; said weight percentages being based on the total weight of the polymer blend.

摘要翻译： 本发明涉及一种聚合物共混物，其包含：（A）约1重量％至约99重量％的至少一种包含对苯二甲酸残基的聚合物（A），2,2,4,4-四甲基-1,3- 环丁二醇残基; 和1,4-环己烷二甲醇残基; （B）约1重量％至约99重量％的至少一种包含1,4-环己烷二羧酸残基和1,4-环己烷二甲醇残基的聚合物（B），和（C）约0.01重量％至约20重量％ 重量％的至少一种抗微生物剂; 所述重量百分比基于聚合物共混物的总重量。

公开(公告)号：US20130217830A1

公开(公告)日：2013-08-22

申请号：US13398262

申请日：2012-02-16

申请人： Emmett Dudley Crawford ,  Michael Eugene Donelson

发明人： Emmett Dudley Crawford ,  Michael Eugene Donelson

IPC分类号： C08G63/199 ,  C08L69/00 ,  B65D23/00 ,  C08L67/02

CPC分类号： C08L67/02 ,  C08G63/199 ,  C08L2201/10 ,  C08L2203/10 ,  C08L2205/02

摘要： The present invention relates to a clear, semicrystalline article comprising a polyester comprising terephthalic acid residues as the dicarboxylic acid component, and 1 to 15 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and 85 to 99 mole % of 1,4-cyclohexanedimethanol residues as the glycol component. The article may be in the form of a film or sheet, a bottle, or a fiber. The article, when produced by a process involving strain-induced crystallization, is characterized with high crystallinity.

摘要翻译： 本发明涉及一种透明的半结晶制品，其包含含有作为二羧酸成分的对苯二甲酸残基的聚酯和1〜15摩尔％的2,2,4,4-四甲基-1,3-环丁二醇残基和85〜99 摩尔％的1,4-环己烷二甲醇残基作为二醇组分。 制品可以是薄膜或片材，瓶子或纤维的形式。 该制品当通过涉及应变诱导结晶的方法制备时，具有高结晶度的特征。

公开(公告)号：US08431232B2

公开(公告)日：2013-04-30

申请号：US12577333

申请日：2009-10-12

申请人： Marcus David Shelby ,  Scott Ellery George ,  Gary Robert Robe ,  Freddie Wayne Williams ,  Michael Eugene Donelson ,  Joshua Seth Cannon ,  Candace Michele Tanner

发明人： Marcus David Shelby ,  Scott Ellery George ,  Gary Robert Robe ,  Freddie Wayne Williams ,  Michael Eugene Donelson ,  Joshua Seth Cannon ,  Candace Michele Tanner

IPC分类号： B27 ,  C08G63/16

CPC分类号： C09J167/02 ,  B32B2037/1215 ,  C08G63/199 ,  Y10T428/1331 ,  Y10T428/1352 ,  Y10T428/28 ,  Y10T428/2813 ,  Y10T428/2826 ,  Y10T428/2852 ,  Y10T428/31786 ,  Y10T428/3179 ,  Y10T428/4935

摘要： Disclosed are hot-melt adhesives prepared from aromatic-aliphatic polyesters containing terephthalic acid in combination with adipic acid, glutaric acid, or a mixture thereof, as diacid components and a diol component containing 1,4-butanediol, 1,6-hexanediol, or a combination thereof. These adhesives set up rapidly within a well-defined temperature window. The hot-melt adhesives can be used in a variety of applications, but are especially suited as seaming adhesives for roll-applied labels. These adhesives have melting temperatures and crystallization properties that allow their application at temperatures cool enough to prevent curling and premature shrinkage of the shrink label during seaming, and yet produce strong label seams that can withstand the elevated temperatures of a shrink tunnel without sacrificing line speed. Also disclosed are labeled containers and a process for applying a roll-on, shrink label to a container using the hot-melt adhesives of the invention.

摘要翻译： 公开了由含有对苯二甲酸与己二酸，戊二酸或其混合物组合的芳族 - 脂族聚酯制备的热熔粘合剂，作为二酸组分和含有1,4-丁二醇，1,6-己二醇或 其组合。 这些粘合剂在一个明确定义的温度窗口内快速建立。 热熔粘合剂可以用于各种应用中，但特别适用于辊涂标签的接缝粘合剂。 这些粘合剂具有熔融温度和结晶性能，使得它们可以在足够温度下使用，以防止收缩标签在接缝过程中发生卷曲和过早收缩，并且还能产生强大的标签接缝，其能够承受收缩隧道的高温而不牺牲线速度。 还公开了标记的容器和使用本发明的热熔粘合剂将卷绕的收缩标签施加到容器的方法。

公开(公告)号：US08329893B2

公开(公告)日：2012-12-11

申请号：US12196333

申请日：2008-08-22

申请人： Marcus David Shelby ,  Michael Eugene Donelson ,  Bradley Howard Dayvolt ,  Alan Kent Wilson ,  Bryan Kirkman

发明人： Marcus David Shelby ,  Michael Eugene Donelson ,  Bradley Howard Dayvolt ,  Alan Kent Wilson ,  Bryan Kirkman

IPC分类号： A61K6/00 ,  A61K9/28 ,  C08B3/16

CPC分类号： G02B5/3033 ,  C08B3/06 ,  C08B3/08 ,  C08B3/16 ,  C08J5/18 ,  C08J2301/14 ,  C08K5/0016 ,  C08L1/14

摘要： The present invention relates to cellulose esters having low hydroxyl content for use in optical applications, such as liquid crystal display (LCD) films. Films made with low hydroxyl levels and a given ratio of non-acetyl ester to hydroxyl level have been found to have low intrinsic birefringence. Therefore, these films can be cast, molded, or otherwise oriented without an appreciable birefringence or optical distortion (i.e. retardation). Such features make these films useful in polarizer, protective, and compensator films as well as molded optical parts, such as lenses. Furthermore, it has also been found that resins of the present invention can also be made to have “+C plate” behavior either by melt or solvent based processing, a characteristic which is not typical of cellulose esters. Such +C behavior allows films to be produced having unique compensatory behavior. Other embodiments of the invention relate to methods melt casting films while minimizing birefringence formation.

摘要翻译： 本发明涉及用于光学应用的低羟基含量的纤维素酯，例如液晶显示（LCD）膜。 已经发现具有低羟基水平和给定比例的非乙酰酯与羟基水平的膜具有低固有双折射。 因此，这些膜可以铸造，模制或以其它方式取向，而没有明显的双折射或光学变形（即延迟）。 这些特征使得这些膜可用于偏振器，保护膜和补偿膜以及模制的光学部件，例如透镜。 此外，还发现本发明的树脂也可以通过基于熔体或溶剂的加工而具有+ C板的性能，这是不是典型的纤维素酯的特征。 这种+ C行为允许制作具有独特补偿行为的胶片。 本发明的其它实施方案涉及熔融流延膜的方法，同时最小化双折射形成。