公开(公告)号：US4941909A

公开(公告)日：1990-07-17

申请号：US334952

申请日：1989-02-14

申请人： Jean Wenger ,  Paul Winternitz ,  Martin Zeller

发明人： Jean Wenger ,  Paul Winternitz ,  Martin Zeller

IPC分类号： A01N43/54 ,  C07D239/52 ,  C07D239/54 ,  C07D239/553 ,  C07D405/12 ,  C07D409/12

CPC分类号： C07D239/54 ,  A01N43/54 ,  C07D239/52 ,  C07D405/12 ,  C07D409/12

摘要： The invention is concerned with novel compounds of the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 have the significances given in the description, as well as enol ethers and salts thereof and their manufacture, weed control compositions which contain such compounds as active substances and the use of the active substances or compositions for the control of weeds. The invention is also concerned with certain starting materials which have herbicidal activity and with weed control compositions containing these.

摘要翻译： PCT No.PCT / CH88 / 00107 Sec。 371日期1989年2月14日 102（e）日期1989年2月14日PCT Filed 1988年6月16日PCT Pub。 出版物WO88 / 10254 日本公开1988年12月29日。本发明涉及式（I）所示的新型化合物，其中R1，R2，R3，R4，R5和R6具有说明书中给出的含义，以及烯醇醚及其盐， 它们的制造，杂草控制组合物含有活性物质等化合物，以及使用活性物质或组合物来控制杂草。 本发明还涉及具有除草活性的某些原料和含有这些的杂草控制组合物。

公开(公告)号：US08436037B2

公开(公告)日：2013-05-07

申请号：US13198739

申请日：2011-08-05

申请人： Hans Tobler ,  Harald Walter ,  Josef Ehrenfreund ,  Camilla Corsi ,  Fanny Giordano ,  Martin Zeller ,  Gottfried Seifert ,  Shailesh Shah ,  Neil George ,  Ian Jones ,  Paul Bonnett

发明人： Hans Tobler ,  Harald Walter ,  Josef Ehrenfreund ,  Camilla Corsi ,  Fanny Giordano ,  Martin Zeller ,  Gottfried Seifert ,  Shailesh Shah ,  Neil George ,  Ian Jones ,  Paul Bonnett

IPC分类号： A01N43/56 ,  C07D231/14

CPC分类号： C07C211/61 ,  A01N43/56 ,  C07C205/06 ,  C07C209/325 ,  C07C209/70 ,  C07C2603/66 ,  C07D231/14

摘要： The present invention relates to a process for the preparation of compounds of formula I wherein R1 and R2 are each independently of the other hydrogen or C1-C5alkyl and R3 is CF3 or CF2H, by a) reaction of a compound of formula II wherein R1 and R2 are as defined for formula I, with at least one reducing agent to form a compound of formula III wherein R1 and R2 are as defined for formula I, and b) reaction of that compound with at least one reducing agent to form a compound of formula IV wherein R1 and R2 are as defined for formula I, and (c) reaction of that compound with a compound of formula V wherein Q is chlorine, fluorine, bromine, iodine, hydroxy or C1-C6alkoxy and R3 is as defined for formula I, to form the compound of formula I; and to novel intermediates for use in that process.

摘要翻译： 本发明涉及一种制备式Ⅰ化合物的方法，其中R1和R2分别独立地为氢或C1-C5烷基，R3为CF3或CF2H，通过a）式II化合物与式 R 2如式I所定义，与至少一种还原剂形成式III化合物，其中R 1和R 2如式I所定义，和b）该化合物与至少一种还原剂的反应形成式 式IV其中R1和R2如式I所定义，和（c）该化合物与式V化合物的反应，其中Q是氯，氟，溴，碘，羟基或C 1 -C 6烷氧基，R 3如式 I，形成式I化合物; 以及用于该过程的新型中间体。

公开(公告)号：US08129560B2

公开(公告)日：2012-03-06

申请号：US12063907

申请日：2006-08-08

申请人： Martin Charles Bowden ,  Thomas Aitcheson Clark ,  Fanny Giordano ,  Beat Jau ,  Hans-Dieter Schneider ,  Gottfried Seifert ,  Martin Zeller ,  Dominik Faber ,  Juerg Wiss

发明人： Martin Charles Bowden ,  Thomas Aitcheson Clark ,  Fanny Giordano ,  Beat Jau ,  Hans-Dieter Schneider ,  Gottfried Seifert ,  Martin Zeller ,  Dominik Faber ,  Juerg Wiss

IPC分类号： C07C255/37 ,  C07C231/02 ,  C07C231/06 ,  C07C43/23 ,  C07C213/02

CPC分类号： C07C231/12 ,  C07C33/46 ,  C07C59/70 ,  C07C69/734 ,  C07C213/02 ,  C07C235/34 ,  C07C251/16 ,  C07C255/37 ,  C07C315/04 ,  C07C319/20 ,  C07C317/46 ,  C07C323/62

摘要： A process for the preparation of a compound of formula (I), the process comprising: (i) the reaction of a compound of formula (III), with a compound of formula (IV) to give a compound of formula (II), and (ii) the reaction of the compound of formula (II) with a leaving group, to give the compound of formula (I).

摘要翻译： 一种制备式（I）化合物的方法，该方法包括：（i）式（III）化合物与式（IV）化合物的反应，得到式（II）化合物， 和（ii）式（II）化合物与离去基团的反应，得到式（I）化合物。

公开(公告)号：US07781615B2

公开(公告)日：2010-08-24

申请号：US12096796

申请日：2006-12-11

申请人： Hans Tobler ,  Harald Walter ,  Camilla Corsi ,  Josef Ehrenfreund ,  Fanny Giordano ,  Martin Zeller

发明人： Hans Tobler ,  Harald Walter ,  Camilla Corsi ,  Josef Ehrenfreund ,  Fanny Giordano ,  Martin Zeller

IPC分类号： C07C211/45 ,  C07C211/48 ,  C07C209/10 ,  C07C209/68 ,  C07C17/266 ,  C07C25/22

CPC分类号： C07C209/62 ,  C07B2200/09 ,  C07C17/23 ,  C07C17/30 ,  C07C17/354 ,  C07C25/22 ,  C07C25/24 ,  C07C209/10 ,  C07C209/70 ,  C07C211/61 ,  C07C2603/66 ,  C07C23/10

摘要： The present invention relates to a novel a process for the preparation of the compound of the general formula (I), wherein R1 and R2 are independently H or C1-6 alkyl, which comprises treating with a reducing agent either a compound of the general formula (II), wherein R1 and R2 have the meanings given for the compound of the formula (I), R3 is H or C1-4alkyl and Ph is phenyl, or a compound of the general formula (III), wherein R1, R2, R3 and Ph have the meanings given for the compound of the formula (II), the reducing agent being effective to cleave the benzyl moiety Ph-CH(R3)— from the benzylamino moiety PhCH(R3)NH— in the compound of the formula (II) or in the compound of the formula (III) to leave an amino group and, in addition, in the case of the compound of the formula (III), to reduce both the 2,3-double bond and the double bond joining the R1R2C— moiety to the 9-position of the benzonorbornene ring to single bonds. It also relates to processes for the preparation of the compounds (II) and (III) and their precursors and to the compounds (II) and (III) themselves and certain of their precursors, which are novel compounds. The compounds (I) are useful for the preparation of various fungicidal heterocyclyl-carboxylic acid benzonorbornen-5-yl-amides.

摘要翻译： 本发明涉及一种制备通式（I）化合物的方法，其中R 1和R 2独立地为H或C 1-6烷基，其包括用还原剂处理通式 （II）化合物，其中R1和R2具有式（I）化合物所给出的含义，R 3是H或C 1-4烷基，Ph是苯基，或通式（III）的化合物，其中R1，R2， R3和Ph具有式（II）化合物所给出的含义，还原剂有效地从式（II）化合物中的苄基氨基部分PhCH（R3）NH-切割苄基部分Ph-CH（R3） （II）化合物或式（III）化合物中，以留下氨基，另外，在式（III）化合物的情况下，为了还原2,3-双键和双键 将R1R2C-部分连接到苯并降冰片烯环的9位到单键。 它还涉及制备化合物（II）和（III）及其前体以及化合物（II）和（III）本身及其某些新型化合物的前体的方法。 化合物（I）可用于制备各种杀真菌性杂环基 - 羧酸苯并降冰片烯-5-基 - 酰胺。

公开(公告)号：US20090118532A1

公开(公告)日：2009-05-07

申请号：US12063907

申请日：2006-08-08

申请人： Martin Charles Bowden ,  Thomas Aitcheson Clark ,  Fanny Giordano ,  Beat Jau ,  Hans-Dieter Schneider ,  Gottfried Seifert ,  Martin Zeller ,  Dominik Faber ,  Juerg Wiss

发明人： Martin Charles Bowden ,  Thomas Aitcheson Clark ,  Fanny Giordano ,  Beat Jau ,  Hans-Dieter Schneider ,  Gottfried Seifert ,  Martin Zeller ,  Dominik Faber ,  Juerg Wiss

IPC分类号： C07C255/37 ,  C07C231/02 ,  C07C231/06 ,  C07C43/23 ,  C07C213/02

CPC分类号： C07C231/12 ,  C07C33/46 ,  C07C59/70 ,  C07C69/734 ,  C07C213/02 ,  C07C235/34 ,  C07C251/16 ,  C07C255/37 ,  C07C315/04 ,  C07C319/20 ,  C07C317/46 ,  C07C323/62

摘要： A process for the preparation of a compound of formula (I) wherein: R is an alkynyl group; R1 is alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkyl-alkyl, phenyl and phenylalkyl, it being possible in turn for all of the receding groups to carry one or more identical or different halogen atoms; alkoxy; alkenyloxy; alkynyloxy; alkoxyalkyl; haloalkoxy; alkylthio; haloalkylthio; alkysulfonyl; formyl; alkanoyl; hydroxy; halogen; cyano; nitro; amino; alkylamino; dialkylamino; carboxyl; alkoxycarbonyl; alkenyloxycarbonyl; or alkynyloxycarbonyl; and n is an integer from 0 to 3, said process comprising: (i) the reaction of a compound of formula (III) wherein R, R1 and n are as hereinbefore defined; m and m′ are independently 0 or 1; when m and m′ are both 0, A is an alkyl, alkenyl or alkynyl group (suitably having up to eight carbon atoms), optionally substituted by one or more groups independently selected from halogen, hydroxy, alkoxy, C1-4 dialkylamino or cyano; when one of m and m′ is 0 and the other is 1, A is an alkanediyl, alkenediyl or alkynediyl group containing at least two carbon atoms (and suitably having up to eight carbon atoms), optionally substituted by one or more groups independently selected from halogen, hydroxy, alkoxy, C1-4 dialkylamino or cyano; when m and m′ are both 1, A is an alkanetriyl, alkenetriyl or alkynetriyl group containing at least three carbon atoms (and suitably having up to eight carbon atoms), optionally substituted by one or more groups independently selected from halogen, hydroxy, alkoxy, C1-4 dialkylamino or cyano; and wherein if the group A contains three or more carbon atoms, one or more of the carbon atoms may each optionally be replaced with an oxygen atom, provided that there is at least one carbon atom between any two oxygen atoms in the molecule, with a compound of formula (IV) to give a compound of formula (II) wherein R, R1 and n are as hereinbefore defined, and (ii) the reaction of a compound of formula (II) with, wherein L is a leaving group, to give the compound of formula (I) as hereinbefore defined, is disclosed.

公开(公告)号：US06482859B1

公开(公告)日：2002-11-19

申请号：US09485280

申请日：2000-02-04

申请人： Martin Zeller ,  André Jeanguenat

发明人： Martin Zeller ,  André Jeanguenat

IPC分类号： A61K3118

CPC分类号： C07C311/06 ,  A01N41/06 ,  A01N43/10 ,  C07C217/60 ,  C07C237/08 ,  C07C307/06 ,  C07C311/11 ,  C07C313/06 ,  C07C2601/14 ,  C07D333/16

摘要： The invention relates to novel pesticidally active compounds of the general formula I as well as possible isomers and mixtures of isomers thereof, wherein n is a number zero or one; and R1 is C1-C12alkyl that is unsubstituted or may be substituted by C1-C4alkoxy, C1-C4alkylthio, C1-C4alkylsulfonyl, C3-C8cycloalkyl, cyano, C1C6alkoxycarbonyl, C3-C6alkenyloxycarbonyl or by C3-C6alkynyloxycarbonyl; C3-C8cycloalkyl; C2-C12alkenyl; C2-C12alkynyl; C1-C12haloalkyl: or a group NR11R12 wherein R11 and R12 are each independently of the other hydrogen or C1-C8alkyl, or together are tetra- or penta-methylene; R2 and R3 are each independently of the other hydrogen; C1-C8alkyl; C1-C8alkyl substituted by hydroxy, C1-C4alkoxy, mercapto or by C1-C4alkylthio; C3-C8alkenyl; C3-C8alkynyl; C3-C8cycloalkyl; C3-C8cycloalkyl-C1-C4alkyl; or the two groups R2 and R3 together with the carbon atom to which they are bonded form a three- to eight-membered ring; R4, R5, R6 and R7 are identical or different and are each independently of the others hydrogen or C1-C4alkyl; R8 is C1-C6alkyl, C3-C6alkenyl or C3-C6alkynyl; A is C1-C6alkylene; and B is optionally mono- or poly-nuclear, unsubstituted or substituted aryl; optionally mono- or poly-nuclear, unsubstituted or substituted heteroaryl; C4-C12alkyl; or C3-C8cycloalkyl. The novel compounds have plant-protecting properties and are suitable for protecting plants against infestation by phytopathogenic microorganisms.

摘要翻译： 本发明涉及具有通式的新的杀虫活性化合物，以及可能的异构体及其异构体的混合物，其中n为数个零或一; 并且R 1是未被取代或可以被C 1 -C 4烷氧基，C 1 -C 4烷硫基，C 1 -C 4烷基磺酰基，C 3 -C 8环烷基，氰基，C 1 -C 6烷氧基羰基，C 3 -C 6炔氧基羰基或C 3 -C 6炔氧基羰基取代的C 1 -C 12烷基; C 3 -C 8环烷基; C 2 -C 12烯基; C 2 -C 12炔基; C 1 -C 12卤代烷基或NR 11 R 12基团，其中R 11和R 12各自独立地为氢或C 1 -C 8烷基，或一起为四或五亚甲基; R 2和R 3各自独立地为氢; C1-C8烷基; 由羟基，C 1 -C 4烷氧基，巯基或被C 1 -C 4烷硫基取代的C 1 -C 8烷基; C3-C8链烯基; C3-C8炔基; C 3 -C 8环烷基; C 3 -C 8环烷基-C 1 -C 4烷基; 或两个R 2和R 3与它们所键合的碳原子一起形成三至八元环; R 4，R 5，R 6和R 7相同或不同，各自独立地为氢或C 1 -C 4烷基 ; R 8为C 1 -C 6烷基，C 3 -C 6烯基或C 3 -C 6炔基; A为C 1 -C 6亚烷基; 和B是任选的单核或多核，未取代或取代的芳基; 任选的单核或多核，未取代或取代的杂芳基; C4-C12烷基; 或C3-C8环烷基。新化合物具有植物保护性质，并且适合于保护植物免受植物病原微生物侵扰。

公开(公告)号：US06316389B1

公开(公告)日：2001-11-13

申请号：US09202887

申请日：1997-06-16

申请人： Henry Szczepanski ,  Martin Zeller ,  Ottmar Franz Hüter

发明人： Henry Szczepanski ,  Martin Zeller ,  Ottmar Franz Hüter

IPC分类号： A01N3708

CPC分类号： C07D213/30 ,  A01N37/38 ,  A01N37/50 ,  A01N43/40 ,  A01N43/80 ,  C07C69/736 ,  C07C251/42 ,  C07C251/54 ,  C07C255/62 ,  C07C323/60 ,  C07C2601/10 ,  C07D213/61 ,  C07D213/69 ,  C07D239/26 ,  C07D241/12 ,  C07D261/08 ,  C07D263/32 ,  C07D277/24 ,  C07D317/22 ,  C07D333/16

摘要： Compounds of the formula I in which: where: X is CH or N; Y is O; S, S═O or NR5; Z is OR2, SR2, N(R3)R4; or Y and Z together form 5- to 7-membered ring which contains, 2 or 3 hetero atoms O and/or N and which is unsubstituted or substituted by C1-C4alkyl, halo-C1-C4alkyl, halogen, ═O or cyclopropyl; V is a direct bond or C1-C6alkylene, which is unsubstituted or substituted by C1-C3alkyl, C2-C3alkylidene or C3-C6cycloalkylidene; U is O, S, NR7, SO or SO2; W is substituted or unsubstituted aryl or substituted or unsubstituted heteroaryl; R1 is cyclopropyl, C1C6alkyl or halo-C1-C6alkyl; R2 and R3 independently of one another are C1-C6alkyl or halo-C1-C6alkyl; R4 and R5 independently of one another are hydrogen, C1-C6alkyl or C1-C6alkoxy; R7 is hydrogen, C1-C6alkyl, benzyl, C1-C6alkylcarbonyl, halo-C1-C6alkylcarbonyl, halo-C2-C6alkenylcarbonyl; R21 and R22 independently of one another are hydrogen, halogen, C1-C8alkyl or C1-C8alkoxy or C1-C8alkylthio; R23, R24, R25, R26 independently of one another are hydrogen, halogen, C1-C8alkyl or C1-C8alkoxy; are pesticidally active. They can be used for pest control, in particular as fungicides, acaricides and insecticides in crop protection.

摘要翻译： 式Iin的化合物，其中：其中：X为CH或N; Y为O; S，S = O或NR5; Z是OR2，SR2，N（R3）R4; 或Y和Z一起形成5-至7-元环，其含有2或3个杂原子O和/或N，并且其未被取代或被C 1 -C 4烷基，卤代-C 1 -C 4烷基，卤素，O或环丙基取代; V C 1 -C 3亚烷基或C 3 -C 6亚烷基; U是O，S，NR 7，SO或SO 2; W是取代或未取代的芳基或取代或未取代的杂芳基 R 1和R 2各自独立地为C 1 -C 6烷基或卤代-C 1 -C 6烷基; R 4和R 5彼此独立地为氢，C 1 -C 6烷基或C 1 -C 6烷氧基; R 7为 R 2和R 22彼此独立地是氢，卤素，C 1 -C 8烷基或C 1 -C 8烷氧基或C 1 -C 8烷硫基; R 23是氢，C 1 -C 6烷基，苄基，C 1 -C 6烷基羰基，卤代C 1 -C 6烷基羰基 R 24，R 25，R 26彼此独立地是氢，卤素，C 1 -C 8烷基或C 1 -C 8烷氧基; 具有杀虫活性，可用于防治害虫，特别是杀虫剂，杀螨剂和作物保护中的杀虫剂。

公开(公告)号：US5585519A

公开(公告)日：1996-12-17

申请号：US431230

申请日：1995-04-28

申请人： Martin Zeller

发明人： Martin Zeller

IPC分类号： C07D275/02 ,  A01N41/06 ,  C07C303/36 ,  C07C307/06 ,  C07C311/06 ,  C07C311/07 ,  C07C311/11 ,  C07C311/14 ,  C07C311/20 ,  C07C313/06 ,  C07C313/20 ,  C07C317/04 ,  C07C323/60 ,  C07C323/65 ,  C07D295/26 ,  C07C233/76

CPC分类号： C07D295/26 ,  C07C307/06 ,  C07C311/06 ,  C07C311/07 ,  C07C311/11 ,  C07C311/14 ,  C07C313/06 ,  C07C313/20 ,  C07C317/04 ,  C07C323/60 ,  C07C2101/08 ,  C07C2101/14

摘要： .alpha.-Amino acid amides of the formula I ##STR1## in which n is the number zero or one;R.sub.1 is C.sub.1 -C.sub.12 alkyl, which is unsubstituted or can be substituted by C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfonyl, C.sub.3 -C.sub.8 cycloalkyl, cyano, C.sub.1 -C.sub.6 alkoxycarbonyl, C.sub.3 -C.sub.6 alkenyloxycarbonyl or C.sub.3 -C.sub.6 alkynyloxycarbonyl; C.sub.3 -C.sub.8 cycloalkyl; C.sub.2 -C.sub.12 alkenyl; C.sub.2 -C.sub.12 alkynyl; C.sub.1 -C.sub.12 halogenoalkyl or a group NR.sub.13 R.sub.14 ; in whichR.sub.13 and R.sub.14 independently of one another are hydrogen or C.sub.1 -C.sub.6 alkyl or together are tetra- or pentamethylene;R.sub.2 and R.sub.3 independently of one another are hydrogen; C.sub.1 -C.sub.8 alkyl; C.sub.1 -C.sub.8 alkyl which is substituted by hydroxyl, C.sub.1 -C.sub.4 alkoxy, mercapto or C.sub.1 -C.sub.4 alkylthio; C.sub.3 -C.sub.8 alkenyl; C.sub.3 -C.sub.8 alkynyl; C.sub.3 -C.sub.8 cycloalkyl or C.sub.3 -C.sub.8 cycloalkyl-C.sub.1 -C.sub.4 alkyl, or in which the two groups R.sub.2 and R.sub.3, together with the carbon atom to which they are bonded, form a three- to eight-membered carbocyclic ring;R.sub.4 is hydrogen or C.sub.1 -C.sub.6 alkyl;R.sub.5 is hydrogen; C.sub.1 -C.sub.6 alkyl or phenyl, which is unsubstituted or can be substituted by halogen, nitro, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 halogenoalkyl, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkylthio; andR.sub.6 is a group G ##STR2## in which R.sub.7 and R.sub.8 independently of one another are hydrogen or C.sub.1 -C.sub.6 alkyl;p is the number zero or one; andR.sub.9, R.sub.10 and R.sub.11 independently of one another are hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 halogenoalkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.1 -C.sub.6 alkoxy, C.sub.3 -C.sub.6 alkenyloxy, C.sub.3 -C.sub.6 alkynyloxy, C.sub.1 -C.sub.6 alkylthio, halogen or nitro are valuable microbicides. They can be employed in crop protection in the form of suitable compositions, for example for controlling fungal diseases.

摘要翻译： α型氨基酰胺，其中n是数字0或1; R 1是未被取代或可以被C 1 -C 4烷氧基，C 1 -C 4烷硫基，C 1 -C 4烷基磺酰基，C 3 -C 8环烷基，氰基，C 1 -C 6烷氧基羰基，C 3 -C 6烯氧基羰基或C 3 -C 6炔氧基羰基取代的C 1 -C 12烷基; C 3 -C 8环烷基; C 2 -C 12烯基; C 2 -C 12炔基; C 1 -C 12卤代烷基或NR 13 R 14基团; 其中R 13和R 14彼此独立地是氢或C 1 -C 6烷基或一起是四或五亚甲基; R2和R3彼此独立地是氢; C1-C8烷基; 被羟基，C 1 -C 4烷氧基，巯基或C 1 -C 4烷硫基取代的C 1 -C 8烷基; C3-C8链烯基; C3-C8炔基; C 3 -C 8环烷基或C 3 -C 8环烷基-C 1 -C 4烷基，或其中两个基团R 2和R 3与它们所键合的碳原子一起形成三至八元碳环; R4是氢或C1-C6烷基; R5是氢; 硝基，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 1 -C 4烷氧基或C 1 -C 4烷硫基取代的C 1 -C 6烷基或苯基; 并且R 6是基团G G，其中R 7和R 8彼此独立地是氢或C 1 -C 6烷基; p是数字0或1; 并且R 9，R 10和R 11彼此独立地是氢，C 1 -C 6烷基，C 1 -C 6卤代烷基，C 3 -C 6烯基，C 3 -C 6炔基，C 1 -C 6烷氧基，C 3 -C 6烯氧基，C 3 -C 6炔氧基，C 1 -C 6烷硫基，卤素或硝基是有价值的 杀菌剂 它们可以以合适的组合物的形式用于作物保护，例如用于防治真菌疾病。

公开(公告)号：US5380701A

公开(公告)日：1995-01-10

申请号：US135768

申请日：1993-10-12

申请人： Paul Winternitz ,  Martin Zeller

发明人： Paul Winternitz ,  Martin Zeller

IPC分类号： A01N43/54 ,  C07D239/54 ,  C07D239/553 ,  C07D239/02 ,  C07D413/00 ,  C07D417/00

CPC分类号： C07D239/54 ,  A01N43/54 ,  C07D239/553

摘要： The invention relates to 3-aryluracils of formula I ##STR1## wherein W is a group of formula ##STR2## in which the linkage to the ring nitrogen atom is through the carbon atom: R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.3 - or C.sub.4 alkenyl or C.sub.3 - or C.sub.4 alkynyl;R.sub.2 is halogen or cyano;R.sub.3 is hydrogen or fluoro;R.sub.4 is hydrogen, halogen or C.sub.1 -C.sub.4 alkyl;R.sub.5 is C.sub.1 -C.sub.4 alkyl or C.sub.1 C.sub.4 haloalkyl;R.sub.6 to R.sub.9 are each independently of one another hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.1 -C.sub.4 haloalkyl or phenyl; orR.sub.6 and R.sub.7 or R.sub.8 and R.sub.9, together with the linking carbon atom, form a 3-, 4-, 5- or 6-membered ring which may be substituted by one or more C.sub.1 -C.sub.4 alkyl groups; or R.sub.7 and R.sub.9, together with the linking carbon atoms, form a 3-, 4-, 5- or 6-membered ring which may be substituted by one or more C.sub.1 -C.sub.4 alkyl groups;m is 0 or 1;R.sub.10 is hydrogen, C.sub.1 C.sub.4 alkyl, C.sub.3 - or C.sub.4 alkenyl, C.sub.3 - or C.sub.4 alkynyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.6 alkoxy-C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.6 alkylthio-C.sub.1 -C.sub.4 alkyl;R.sub.11 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.3 - or C.sub.4 alkenyl, C.sub.3 -C.sub.5 alkynyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 alkenyloxy, C.sub.1 -C.sub.6 alkoxy-C.sub.1-C.sub.4 alkyl, C.sub.1 -C.sub.6 alkylthio-C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.2 -C.sub.4 cyanoalkyl, C.sub.1 -C.sub.4 alkoxycarbonyl-C.sub.1 -or -C.sub.2 alkyl, carboxy-C.sub.1 -or -C.sub.2 alkyl, (C.sub.1 -C.sub.4 alkoxy).sub.2 -P(O)-C.sub.1 -or -C.sub.2 alkyl, aryl, aryl-C.sub.1 -C.sub.4 alkyl, heteroaryl, heteroaryl-C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.6 cycloalkyl-C.sub.1 -C.sub.4 alkyl; orR.sub.10 and R.sub.11, together with the linking nitrogen atom, form a 4-, 5-, 6- or 7-membered ring which may be substituted by one or more C.sub.1 -C.sub.4 alkyl groups and which may contain --O--, --S-- or --NH-- as further hetero atoms; and R.sub.12 is C.sub.1 - C.sub.4 alkyl, C.sub.3 - or C.sub.4 alkenyl or C.sub.3 - or C.sub.4 alkynyl; and,if R.sub.1 is hydrogen, the agrochemically acceptable salts of the compounds of formula I.The compounds are suitable for use as active ingredients of herbicidal compositions for weed control.

摘要翻译： 本发明涉及式I的3-芳基尿嘧啶（Ⅰ），其中W是式为“IMAGE”的基团，其中与环氮原子的连接通过碳原子：R 1是氢，C 1 -C 4烷基，C 1 C 1-4卤代烷基，C 3 - 或C 4链烯基或C 3 - 或C 4炔基; R2是卤素或氰基; R3是氢或氟; R4是氢，卤素或C1-C4烷基; R5是C1-C4烷基或C1C4卤代烷基; R 6至R 9各自独立地为氢，C 1 -C 4烷基，C 3 -C 6烯基，C 3 -C 6炔基，C 1 -C 4卤代烷基或苯基; 或R6和R7或R8和R9与连接碳原子一起形成可被一个或多个C 1 -C 4烷基取代的3-，4-，5-或6-元环; 或者R 7和R 9与连接碳原子一起形成可被一个或多个C 1 -C 4烷基取代的3-，4-，5-或6-元环; m为0或1; R 10是氢，C 1 -C 4烷基，C 3 - 或C 4链烯基，C 3 - 或C 4炔基，C 1 -C 4卤代烷基，C 1 -C 6烷氧基-C 1 -C 4烷基，C 1 -C 6烷硫基-C 1 -C 4烷基; R 11是氢，C 1 -C 4烷基，C 3 - 或C 4链烯基，C 3 -C 5炔基，C 1 -C 4卤代烷基，C 1 -C 6烷氧基，C 1 -C 6烯氧基，C 1 -C 6烷氧基-C 1 -C 4烷基，C 1 -C 6烷硫基-C 1 -C 4烷基，C 3 -C 6环烷基， -C 1-4氰基烷基，C 1 -C 4烷氧基羰基-C 1或-C 2烷基，羧基-C 1 - 或-C 2烷基，（C 1 -C 4烷氧基）2 -P（O）-C 1 - 或-C 2烷基，芳基，芳基-C 1 -C 4烷基，杂芳基，杂芳基 C 1 -C 4烷基，C 3 -C 6环烷基-C 1 -C 4烷基; 或R 10和R 11与连接的氮原子一起形成可被一个或多个C 1 -C 4烷基取代并且可以含有-O - ， - S- 或-NH-作为另外的杂原子; 且R 12为C 1 -C 4烷基，C 3或C 4链烯基或C 3 - 或C 4炔基; 并且如果R 1是氢，则是式I化合物的农业化学上可接受的盐。该化合物适合用作除草组合物作为杂草控制的活性成分。

公开(公告)号：US5232898A

公开(公告)日：1993-08-03

申请号：US807024

申请日：1991-12-09

申请人： Milos Suchy ,  Paul Winternitz ,  Martin Zeller

发明人： Milos Suchy ,  Paul Winternitz ,  Martin Zeller

IPC分类号： A01N43/74 ,  A01N43/84 ,  C07D413/04 ,  C07D417/04

CPC分类号： C07D413/04 ,  A01N43/74 ,  A01N43/84 ,  C07D417/04

摘要： The invention is concerned with compounds of the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, n and X have the significances given in the description, as well as enol ethers and salts thereof and their manufacture. The compounds have herbicidal properties and are accordingly suitable as active ingredients of weed control compositions. The invention is also concerned with weed control compositions containing one or more of such substances as well as the use of the substances or compositions for the control of weeds. Certain starting materials, which also have herbicidal activity, and their production are also described.

摘要翻译： 本发明涉及下式的化合物，其中R1，R2，R3，R4，R5，R6，R7，n和X具有说明书中给出的含义，以及烯醇醚及其盐及其制备方法 。 这些化合物具有除草性质，因此适合作为杂草控制组合物的活性成分。 本发明还涉及含有一种或多种这些物质的杂草控制组合物以及用于控制杂草的物质或组合物的使用。 还描述了具有除草活性的某些原料及其生产。