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    3-aryluracil derivatives and their use for weed control
    2.
    发明授权
    3-aryluracil derivatives and their use for weed control 失效
    3-芳基尿嘧啶衍生物及其用于杂草控制的用途

    公开(公告)号：US5336663A

    公开(公告)日：1994-08-09

    申请号：US971445

    申请日：1992-11-04

    申请人： Jean Wenger ,  Paul Winternitz ,  Martin Zeller

    发明人： Jean Wenger ,  Paul Winternitz ,  Martin Zeller

    IPC分类号： A01N43/54 ,  C07C271/22 ,  C07C275/40 ,  C07C275/42 ,  C07C323/29 ,  C07D233/56 ,  C07D239/52 ,  C07D239/54 ,  C07D239/70 ,  C07D405/10 ,  C07D409/04 ,  C07D409/10 ,  A01N43/48

    CPC分类号： C07D239/54 ,  A01N43/54 ,  C07C271/22 ,  C07D239/52 ,  C07D239/70 ,  C07D405/10 ,  C07D409/10 ,  C07C2101/02 ,  C07C2101/08 ,  C07C2101/14

    摘要： 3-Aryluracil derivatives of the formula I ##STR1## in which --W-- is the group ##STR2## where the ring nitrogen atom is bonded via the C atom; R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.3 alkenyl or C.sub.4 alkenyl or C.sub.3 alkynyl or C.sub.4 alkynyl;R.sub.2 is halogen or cyano;R.sub.3 is hydrogen or halogen;R.sub.4 is hydrogen, halogen or C.sub.1 -C.sub.4 alkyl;R.sub.5 is C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 haloalkyl; or R.sub.4 and R.sub.5 together are --(CH.sub.2).sub.n --;n is the number 3 or 4;R.sub.13 is C.sub.1 -C.sub.4 alkyl, C.sub.3 alkenyl or C.sub.4 alkynyl or C.sub.3 alkynyl or C.sub.4 alkynyl; andQ is one of the groups a) to e): ##STR3## where R.sub.6 to R.sub.12 are substituents, m is 3, 4 or 5, X is oxygen or sulfur and t is 2, 3 or 4, and if R.sub.1 is hydrogen, the agrochemically acceptable salts of compounds of the formula I. the compounds of formula I have herbicidal properties and are suitable as the active ingredient in a herbicide.

    摘要翻译： 其中-W-是环氮原子通过C原子键合的基团的式I（I）的3-芳基脲衍生物; R1是氢，C1-C4烷基，C1-C4卤代烷基，C3-烯基或C4-烯基或C3-炔基或C4-炔基; R2是卤素或氰基; R3是氢或卤素; R4是氢，卤素或C1-C4烷基; R5是C1-C4烷基或C1-C4卤代烷基; 或者R 4和R 5一起是 - （CH 2）n - ; n是3或4; R 13是C 1 -C 4烷基，C 3链烯基或C 4炔基或C 3炔基或C 4炔基; （3）其中R6至R12为取代基，（5）其中R6至R12为取代基， m是3,4或5，X是氧或硫，t是2,3或4，如果R1是氢，则式I化合物的农业化学上可接受的盐。式I化合物具有除草性质并且是合适的 作为除草剂中的活性成分。

    Heterocyclic compounds
    3.
    发明授权
    Heterocyclic compounds 失效
    杂环化合物

    公开(公告)号：US4941909A

    公开(公告)日：1990-07-17

    申请号：US334952

    申请日：1989-02-14

    申请人： Jean Wenger ,  Paul Winternitz ,  Martin Zeller

    发明人： Jean Wenger ,  Paul Winternitz ,  Martin Zeller

    IPC分类号： A01N43/54 ,  C07D239/52 ,  C07D239/54 ,  C07D239/553 ,  C07D405/12 ,  C07D409/12

    CPC分类号： C07D239/54 ,  A01N43/54 ,  C07D239/52 ,  C07D405/12 ,  C07D409/12

    摘要： The invention is concerned with novel compounds of the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 have the significances given in the description, as well as enol ethers and salts thereof and their manufacture, weed control compositions which contain such compounds as active substances and the use of the active substances or compositions for the control of weeds. The invention is also concerned with certain starting materials which have herbicidal activity and with weed control compositions containing these.

    摘要翻译： PCT No.PCT / CH88 / 00107 Sec。 371日期1989年2月14日 102（e）日期1989年2月14日PCT Filed 1988年6月16日PCT Pub。 出版物WO88 / 10254 日本公开1988年12月29日。本发明涉及式（I）所示的新型化合物，其中R1，R2，R3，R4，R5和R6具有说明书中给出的含义，以及烯醇醚及其盐， 它们的制造，杂草控制组合物含有活性物质等化合物，以及使用活性物质或组合物来控制杂草。 本发明还涉及具有除草活性的某些原料和含有这些的杂草控制组合物。

    3-aryluracil derivatives and the use thereof for weed control
    4.
    发明授权
    3-aryluracil derivatives and the use thereof for weed control 失效
    3-芳基尿嘧啶衍生物及其用于杂草控制的用途

    公开(公告)号：US5380701A

    公开(公告)日：1995-01-10

    申请号：US135768

    申请日：1993-10-12

    申请人： Paul Winternitz ,  Martin Zeller

    发明人： Paul Winternitz ,  Martin Zeller

    IPC分类号： A01N43/54 ,  C07D239/54 ,  C07D239/553 ,  C07D239/02 ,  C07D413/00 ,  C07D417/00

    CPC分类号： C07D239/54 ,  A01N43/54 ,  C07D239/553

    摘要： The invention relates to 3-aryluracils of formula I ##STR1## wherein W is a group of formula ##STR2## in which the linkage to the ring nitrogen atom is through the carbon atom: R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.3 - or C.sub.4 alkenyl or C.sub.3 - or C.sub.4 alkynyl;R.sub.2 is halogen or cyano;R.sub.3 is hydrogen or fluoro;R.sub.4 is hydrogen, halogen or C.sub.1 -C.sub.4 alkyl;R.sub.5 is C.sub.1 -C.sub.4 alkyl or C.sub.1 C.sub.4 haloalkyl;R.sub.6 to R.sub.9 are each independently of one another hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.1 -C.sub.4 haloalkyl or phenyl; orR.sub.6 and R.sub.7 or R.sub.8 and R.sub.9, together with the linking carbon atom, form a 3-, 4-, 5- or 6-membered ring which may be substituted by one or more C.sub.1 -C.sub.4 alkyl groups; or R.sub.7 and R.sub.9, together with the linking carbon atoms, form a 3-, 4-, 5- or 6-membered ring which may be substituted by one or more C.sub.1 -C.sub.4 alkyl groups;m is 0 or 1;R.sub.10 is hydrogen, C.sub.1 C.sub.4 alkyl, C.sub.3 - or C.sub.4 alkenyl, C.sub.3 - or C.sub.4 alkynyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.6 alkoxy-C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.6 alkylthio-C.sub.1 -C.sub.4 alkyl;R.sub.11 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.3 - or C.sub.4 alkenyl, C.sub.3 -C.sub.5 alkynyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 alkenyloxy, C.sub.1 -C.sub.6 alkoxy-C.sub.1-C.sub.4 alkyl, C.sub.1 -C.sub.6 alkylthio-C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.2 -C.sub.4 cyanoalkyl, C.sub.1 -C.sub.4 alkoxycarbonyl-C.sub.1 -or -C.sub.2 alkyl, carboxy-C.sub.1 -or -C.sub.2 alkyl, (C.sub.1 -C.sub.4 alkoxy).sub.2 -P(O)-C.sub.1 -or -C.sub.2 alkyl, aryl, aryl-C.sub.1 -C.sub.4 alkyl, heteroaryl, heteroaryl-C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.6 cycloalkyl-C.sub.1 -C.sub.4 alkyl; orR.sub.10 and R.sub.11, together with the linking nitrogen atom, form a 4-, 5-, 6- or 7-membered ring which may be substituted by one or more C.sub.1 -C.sub.4 alkyl groups and which may contain --O--, --S-- or --NH-- as further hetero atoms; and R.sub.12 is C.sub.1 - C.sub.4 alkyl, C.sub.3 - or C.sub.4 alkenyl or C.sub.3 - or C.sub.4 alkynyl; and,if R.sub.1 is hydrogen, the agrochemically acceptable salts of the compounds of formula I.The compounds are suitable for use as active ingredients of herbicidal compositions for weed control.

    摘要翻译： 本发明涉及式I的3-芳基尿嘧啶（Ⅰ），其中W是式为“IMAGE”的基团，其中与环氮原子的连接通过碳原子：R 1是氢，C 1 -C 4烷基，C 1 C 1-4卤代烷基，C 3 - 或C 4链烯基或C 3 - 或C 4炔基; R2是卤素或氰基; R3是氢或氟; R4是氢，卤素或C1-C4烷基; R5是C1-C4烷基或C1C4卤代烷基; R 6至R 9各自独立地为氢，C 1 -C 4烷基，C 3 -C 6烯基，C 3 -C 6炔基，C 1 -C 4卤代烷基或苯基; 或R6和R7或R8和R9与连接碳原子一起形成可被一个或多个C 1 -C 4烷基取代的3-，4-，5-或6-元环; 或者R 7和R 9与连接碳原子一起形成可被一个或多个C 1 -C 4烷基取代的3-，4-，5-或6-元环; m为0或1; R 10是氢，C 1 -C 4烷基，C 3 - 或C 4链烯基，C 3 - 或C 4炔基，C 1 -C 4卤代烷基，C 1 -C 6烷氧基-C 1 -C 4烷基，C 1 -C 6烷硫基-C 1 -C 4烷基; R 11是氢，C 1 -C 4烷基，C 3 - 或C 4链烯基，C 3 -C 5炔基，C 1 -C 4卤代烷基，C 1 -C 6烷氧基，C 1 -C 6烯氧基，C 1 -C 6烷氧基-C 1 -C 4烷基，C 1 -C 6烷硫基-C 1 -C 4烷基，C 3 -C 6环烷基， -C 1-4氰基烷基，C 1 -C 4烷氧基羰基-C 1或-C 2烷基，羧基-C 1 - 或-C 2烷基，（C 1 -C 4烷氧基）2 -P（O）-C 1 - 或-C 2烷基，芳基，芳基-C 1 -C 4烷基，杂芳基，杂芳基 C 1 -C 4烷基，C 3 -C 6环烷基-C 1 -C 4烷基; 或R 10和R 11与连接的氮原子一起形成可被一个或多个C 1 -C 4烷基取代并且可以含有-O - ， - S- 或-NH-作为另外的杂原子; 且R 12为C 1 -C 4烷基，C 3或C 4链烯基或C 3 - 或C 4炔基; 并且如果R 1是氢，则是式I化合物的农业化学上可接受的盐。该化合物适合用作除草组合物作为杂草控制的活性成分。

    Heterocyclic substituted uracil derivatives
    5.
    发明授权
    Heterocyclic substituted uracil derivatives 失效
    杂环取代的尿嘧啶衍生物

    公开(公告)号：US5232898A

    公开(公告)日：1993-08-03

    申请号：US807024

    申请日：1991-12-09

    申请人： Milos Suchy ,  Paul Winternitz ,  Martin Zeller

    发明人： Milos Suchy ,  Paul Winternitz ,  Martin Zeller

    IPC分类号： A01N43/74 ,  A01N43/84 ,  C07D413/04 ,  C07D417/04

    CPC分类号： C07D413/04 ,  A01N43/74 ,  A01N43/84 ,  C07D417/04

    摘要： The invention is concerned with compounds of the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, n and X have the significances given in the description, as well as enol ethers and salts thereof and their manufacture. The compounds have herbicidal properties and are accordingly suitable as active ingredients of weed control compositions. The invention is also concerned with weed control compositions containing one or more of such substances as well as the use of the substances or compositions for the control of weeds. Certain starting materials, which also have herbicidal activity, and their production are also described.

    摘要翻译： 本发明涉及下式的化合物，其中R1，R2，R3，R4，R5，R6，R7，n和X具有说明书中给出的含义，以及烯醇醚及其盐及其制备方法 。 这些化合物具有除草性质，因此适合作为杂草控制组合物的活性成分。 本发明还涉及含有一种或多种这些物质的杂草控制组合物以及用于控制杂草的物质或组合物的使用。 还描述了具有除草活性的某些原料及其生产。

    Heterocyclic compounds
    6.
    发明授权
    Heterocyclic compounds 失效
    杂环化合物

    公开(公告)号：US5266554A

    公开(公告)日：1993-11-30

    申请号：US990826

    申请日：1992-12-14

    申请人： Milos Suchy ,  Jean Wenger ,  Paul Winternitz ,  Martin Zeller

    发明人： Milos Suchy ,  Jean Wenger ,  Paul Winternitz ,  Martin Zeller

    IPC分类号： A01N43/54 ,  C07D239/54 ,  C07D239/70 ,  C07D239/96

    CPC分类号： C07D239/54 ,  A01N43/54 ,  C07D239/70 ,  C07D239/96

    摘要： The invention relates to novel compounds of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 have the meanings given in the description, to enol ethers and salts thereof and their preparation, to weed control compositions that comprise such compounds as active ingredients, and to the use of the compounds or compositions to control weeds. The invention relates also to certain novel starting materials and to the preparation thereof.

    摘要翻译： 本发明涉及式I的新化合物，其中R1，R2，R3，R4和R5具有本说明书中给出的含义，其烯醇醚及其盐及其制备方法涉及包含这些化合物的杂草控制组合物 活性成分，以及使用化合物或组合物来控制杂草。 本发明还涉及某些新的起始材料及其制备。

    Herbicidal 3-aryluracils
    7.
    发明授权
    Herbicidal 3-aryluracils 失效
    除草剂3-ARYLURACILS

    公开(公告)号：US5183492A

    公开(公告)日：1993-02-02

    申请号：US656133

    申请日：1991-02-27

    申请人： Milos Suchy ,  Paul Winternitz ,  Martin Zeller

    发明人： Milos Suchy ,  Paul Winternitz ,  Martin Zeller

    IPC分类号： C07D239/553 ,  A01N43/54 ,  C07C271/10 ,  C07D239/54 ,  C07D239/70 ,  C07D239/96 ,  C07F7/08 ,  C07F7/18

    CPC分类号： C07D239/54 ,  A01N43/54 ,  C07F7/0812 ,  C07F7/1896

    摘要： The invention is concerned with compounds of the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 have the significances given in the description, as well as enol ethers and salts thereof and their manufacture. The compounds have herbicidal properties and are accordingly suitable as active ingredients of weed control compositions. The invention is also concerned with weed control compositions containing one or more of such substances and with the use of the substances or compositions for the control of weeds.

    摘要翻译： 本发明涉及下式的化合物，其中R1，R2，R3，R4，R5和R6具有说明书中给出的含义，以及烯醇醚及其盐及其制备。 这些化合物具有除草性质，因此适合作为杂草控制组合物的活性成分。 本发明还涉及含有一种或多种这些物质的杂草控制组合物以及使用用于控制杂草的物质或组合物。

    PROCESS FOR THE PREPARATION OF AMINES
    9.
    发明申请
    PROCESS FOR THE PREPARATION OF AMINES 有权
    制备氨基酸的方法

    公开(公告)号：US20090221856A1

    公开(公告)日：2009-09-03

    申请号：US12096796

    申请日：2006-12-11

    申请人： Hans Tobler ,  Harald Walter ,  Camilla Corsi ,  Josef Ehrenfreund ,  Fanny Giordano ,  Martin Zeller

    发明人： Hans Tobler ,  Harald Walter ,  Camilla Corsi ,  Josef Ehrenfreund ,  Fanny Giordano ,  Martin Zeller

    IPC分类号： C07C211/31

    CPC分类号： C07C209/62 ,  C07B2200/09 ,  C07C17/23 ,  C07C17/30 ,  C07C17/354 ,  C07C25/22 ,  C07C25/24 ,  C07C209/10 ,  C07C209/70 ,  C07C211/61 ,  C07C2603/66 ,  C07C23/10

    摘要： The present invention relates to a novel a process for the preparation of the compound of the general formula (I), wherein R1 and R2 are independently H or C1-6 alkyl, which comprises treating with a reducing agent either a compound of the general formula (II), wherein R1 and R2 have the meanings given for the compound of the formula (I), R3 is H or C1-4alkyl and Ph is phenyl, or a compound of the general formula (III), wherein R1, R2, R3 and Ph have the meanings given for the compound of the formula (II), the reducing agent being effective to cleave the benzyl moiety Ph-CH(R3)— from the benzylamino moiety PhCH(R3)NH— in the compound of the formula (II) or in the compound of the formula (III) to leave an amino group and, in addition, in the case of the compound of the formula (III), to reduce both the 2,3-double bond and the double bond joining the R1R2C— moiety to the 9-position of the benzonorbornene ring to single bonds. It also relates to processes for the preparation of the compounds (II) and (III) and their precursors and to the compounds (II) and (III) themselves and certain of their precursors, which are novel compounds. The compounds (I) are useful for the preparation of various fungicidal heterocyclyl-carboxylic acid benzonorbornen-5-yl-amides.

    摘要翻译： 本发明涉及一种制备通式（I）化合物的方法，其中R 1和R 2独立地为H或C 1-6烷基，其包括用还原剂处理通式 （II）化合物，其中R1和R2具有式（I）化合物所给出的含义，R 3是H或C 1-4烷基，Ph是苯基，或通式（III）的化合物，其中R1，R2， R3和Ph具有式（II）化合物所给出的含义，还原剂有效地从式（II）化合物中的苄基氨基部分PhCH（R3）NH-切割苄基部分Ph-CH（R3） （II）化合物或式（III）化合物中，以留下氨基，另外，在式（III）化合物的情况下，为了还原2,3-双键和双键 将R1R2C-部分连接到苯并降冰片烯环的9位到单键。 它还涉及制备化合物（II）和（III）及其前体以及化合物（II）和（III）本身及其某些新型化合物的前体的方法。 化合物（I）可用于制备各种杀真菌性杂环基 - 羧酸苯并降冰片烯-5-基 - 酰胺。