公开(公告)号：US20220363996A1

公开(公告)日：2022-11-17

申请号：US17755327

申请日：2020-10-29

Applicant: Eastman Chemical Company

Inventor： Xianchun Wu ,  Daryl Bitting ,  Kenny Randolph Parker ,  Michael Gary Polasek ,  David Eugene Slivensky ,  Carey Dan Ashcroft ,  Damon Ray Billodeaux

IPC: C10G1/08 ,  C10G1/10

Abstract: A pyrolysis method and system are provided that enhances the production of C3 and C4 alkanes in the resulting pyrolysis effluent. More particularly, the disclosed pyrolysis method and system may be configured to enhance the production of C3 and C4 alkanes due to the use of certain pyrolysis catalysts and more intense pyrolysis conditions.

公开(公告)号：US20190218169A1

公开(公告)日：2019-07-18

申请号：US16243232

申请日：2019-01-09

Applicant: Eastman Chemical Company

Inventor： Stephanie Kay Clendennen ,  Vasudev R. Bhonde ,  Damon Ray Billodeaux ,  Matthew Allen Boone ,  Kim Dumoleijn ,  Stijn Simonne Paul Van de Vyver ,  Kristof Moonen ,  Neil Warren Boaz

IPC: C07C207/02 ,  C07C201/00 ,  C11D1/75 ,  C11D1/83 ,  C11D1/835 ,  C11D1/94 ,  C11D3/395 ,  C11D3/39 ,  C11D11/00 ,  C11D3/43 ,  C09D7/63 ,  C09K8/584 ,  C10L1/18

CPC classification number: C07C211/04 ,  A61K8/416 ,  A61K8/44 ,  A61K8/466 ,  A61Q5/02 ,  A61Q19/10 ,  C07C201/00 ,  C07C207/02 ,  C07C229/12 ,  C07C309/14 ,  C07H5/06 ,  C09D7/63 ,  C09K8/584 ,  C10L1/18 ,  C11D1/75 ,  C11D1/83 ,  C11D1/835 ,  C11D1/90 ,  C11D1/94 ,  C11D3/3942 ,  C11D3/395 ,  C11D3/43 ,  C11D11/0017 ,  C11D11/0023

Abstract: The invention provides branched trialkylamine oxides with improved properties. The trialkylamine oxides of the invention produced from branched trialkylamines, in one embodiment, can be made using certain branched C10-12 enals and aldehydes. The invention also provides an trialkylamine oxide having the formula: wherein R5, R6 and R7 are independently at least one of C3H7, C2H5, CH3, or H, or mixtures thereof; and wherein R5 and R6 are not H at the same time. In one embodiment, the trialkylamine oxides of the invention can be useful in making various products, for example, as surfactants.

公开(公告)号：US09440944B2

公开(公告)日：2016-09-13

申请号：US14337544

申请日：2014-07-22

Applicant: Eastman Chemical Company

Inventor： Daniel Latham Terrill ,  Brian David McMurray ,  Damon Ray Billodeaux ,  James Lon Little ,  Adam Scott Howard

IPC: C07D323/00 ,  C07D321/06 ,  C07D319/12 ,  C07D317/12 ,  C07D321/08

CPC classification number: C07D323/00 ,  C07D317/12 ,  C07D319/12 ,  C07D321/06 ,  C07D321/08

Abstract: A process for making a cyclic compounds such as cyclic acetal or cyclic ketones by feeding aldehyde or ketone compounds and polyhydroxyl compounds to a reaction zone at a molar ratio of polyhydroxyl compounds to aldehyde or ketone compounds of at least 3:1, reacting these compounds in the presence of a solid acid such as an acidic ion exchange resin, to generate a liquid reaction mixture without separating water from the reaction mixture as it is being formed in the reaction mixture, withdrawing the liquid reaction mixture from the reaction zone as a liquid product stream, and feeding the liquid reaction product stream to a distillation column to separate cyclic acetal compounds from unreacted polyhydroxyl compounds, and optionally recycling back the unreacted polyhydroxyl compounds to the reaction zone. The process produces cyclic acetal compounds in yields of at least 90% with long catalyst life. The process is also suitable to make cyclic ketals from ketone compounds.

Abstract translation: 通过将醛或酮化合物和多羟基化合物以多羟基化合物与醛或酮化合物的摩尔比至少为3:1的比例将醛或酮化合物和多羟基化合物进料到反应区中来制备环状化合物如环缩醛或环酮的方法，使这些化合物在 固体酸如酸性离子交换树脂的存在，以便在反应混合物中形成液体反应混合物而不从反应混合物中分离出水，以液体产物的形式从反应区抽出液体反应混合物 流，并将液体反应产物流进料到蒸馏塔中以从未反应的多羟基化合物中分离出环状缩醛化合物，并任选地将未反应的多羟基化合物回收到反应区。 该方法产生环状缩醛化合物，产率至少为90％，催化剂寿命长。 该方法也适用于由酮化合物制备环状缩酮。

公开(公告)号：US20140303404A1

公开(公告)日：2014-10-09

申请号：US14307956

申请日：2014-06-18

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： Damon Ray Billodeaux ,  Thomas James Devon ,  Brent Alan Tennant ,  Charles Edwan Sumner, JR.

IPC: C07C41/28

CPC classification number: C07C41/28 ,  C07C43/13

Abstract: Catalyst compositions of alumina supports containing palladium and nickel are selective in a vapor phase hydrogenolysis reaction to convert cyclic acetal compounds and/or cyclic ketal compounds in the presence of hydrogen to their corresponding hydroxy ether hydrocarbon reaction products.

Abstract translation: 含有钯和镍的氧化铝载体的催化剂组合物在气相氢解反应中是选择性的，以在氢气存在下将环状缩醛化合物和/或环状缩酮化合物转化成其相应的羟基醚烃反应产物。