公开(公告)号：US20080050534A1

公开(公告)日：2008-02-28

申请号：US11836581

申请日：2007-08-09

Applicant: Frank Louwet ,  Louis Bollens

Inventor： Frank Louwet ,  Louis Bollens

IPC: B05D3/06 ,  C08J3/28 ,  C09D11/10

CPC classification number: C09D165/00 ,  C09D5/24 ,  C09D11/101 ,  G03F7/027 ,  G03F7/093 ,  G03F7/16 ,  H01B1/127 ,  H01L51/0022 ,  H01L51/0036 ,  H01L51/0037 ,  H05K3/105

Abstract: A composition comprising a polyanion and a polymer or copolymer of a substituted or unsubstituted thiophene as a solution or as a dispersion in a liquid medium and at least one compound with at least two vinyl groups, wherein said liquid medium comprises at least one non-aqueous solvent and has less than 30% by weight of water; and said composition comprises more than 0.1% by weight of the polymer or copolymer of a substituted or unsubstituted thiophene and is capable of UV-photopolymerization due to said composition comprising at least one vinyl-compound capable of initiating UV-photopolymerization and/or at least one UV-photoinitiator; an ink with the composition of the composition; and a process for producing a layer or pattern on an object with the composition.

Abstract translation: 一种组合物，其包含聚阴离子和取代或未取代的噻吩作为溶液或作为液体介质中的分散体的聚合物或共聚物和至少一种具有至少两个乙烯基的化合物，其中所述液体介质包含至少一种非水性 并且具有小于30重量％的水; 并且所述组合物包含大于0.1重量％的取代或未取代的噻吩的聚合物或共聚物，并且由于所述组合物包含至少一种能够引发UV-光聚合的乙烯基化合物和/或至少 一种UV-光引发剂; 具有组合物组成的油墨; 以及用于在具有该组成的物体上产生层或图案的工艺。

公开(公告)号：US07122130B2

公开(公告)日：2006-10-17

申请号：US10894441

申请日：2004-07-19

Applicant: Jean-Piere Tahon ,  Roger Van den Bogaert ,  Bert Groenendaal ,  Frank Louwet

Inventor： Jean-Piere Tahon ,  Roger Van den Bogaert ,  Bert Groenendaal ,  Frank Louwet

IPC: H01B1/12

CPC classification number: H01B1/128 ,  C08J3/09 ,  C08J2365/00 ,  C08L65/00 ,  C09D5/24 ,  C09D11/033 ,  C09D11/36 ,  C09D11/52 ,  C09D165/00 ,  Y10T428/2809

Abstract: A method for preparing a composition containing between 0.08 and 3.0% by weight of polymer or copolymer of a 3,4-dialkoxythiophene in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, a polyanion and at least one non-aqueous solvent from a dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion in water which is prepared in the substantial absence of oxygen, comprising in the following order the steps of: i) mixing at least one of the non-aqueous solvents with the aqueous dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion; and ii) evaporating water from the mixture prepared in step i) until the content of water therein is reduced by at least 65% by weight; a printing ink, printing paste or coating composition, capable of yielding layers with enhanced conductivity at a given transparency, prepared according to the above-described method; a coating process with the coating composition thereby producing a layer with enhanced conductivity at a given transparency; and a printing process with the printing ink or paste thereby producing a layer with enhanced conductivity at a given transparency.

公开(公告)号：US07048874B2

公开(公告)日：2006-05-23

申请号：US10308567

申请日：2002-12-03

Applicant: Frank Louwet ,  Bert Groenendaal

Inventor： Frank Louwet ,  Bert Groenendaal

IPC: H01B1/00 ,  C08G61/12 ,  C09D165/00

CPC classification number: C08G61/126 ,  C08G2261/122 ,  C08G2261/1424 ,  C08G2261/1426 ,  C08G2261/1452 ,  C08G2261/3223 ,  C08G2261/43 ,  C08G2261/51 ,  C08G2261/794 ,  C09D165/00 ,  H01G9/028 ,  H01G11/48 ,  Y02E60/13 ,  Y10T428/31533 ,  C08L25/18

Abstract: A process for preparing an aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer, containing structural units according to formula (I): in which R1 and R2 independently of one another represent hydrogen or a C1-5-alkyl group or together form an optionally substituted C1-5-alkylene residue, comprising the step of: preparing the polythiophene or thiophene copolymer with an initiator in a reaction medium in the presence of polyanions under oxidizing or reducing conditions under an inert atmosphere such that when said initiator is added less than 3 mg of oxygen per litre of the reaction medium is present in the reaction medium; an aqueous or non-aqueous solution or dispersion prepared therewith; the use of an aqueous or non-aqueous dispersion or solution comprising the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer for coating an object; a printable paste containing the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer; and an electroconductive or an antistatic layer prepared using an aqueous or non-aqueous solution or dispersion comprising the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer.

Abstract translation: 一种制备含有根据式（I）的结构单元的聚噻吩或噻吩共聚物的水溶液或非水溶液或分散体的方法：其中R 1和R 2 = >彼此独立地表示氢或C 1-5 - 烷基或一起形成任选取代的C 1-5 - 亚烷基残基，包括以下步骤：制备 聚噻吩或噻吩共聚物与反应介质中的聚噻吩或噻吩共聚物在聚阴离子存在下，在惰性气氛下在氧化或还原条件下，使得每当该反应介质中加入小于3mg的氧气时， 中; 用其制备的水性或非水溶液或分散体; 使用包含聚噻吩或噻吩共聚物的水溶液或非水溶液或分散体的水性或非水分散体或溶液来涂覆物体; 含有聚噻吩或噻吩共聚物的水溶液或非水溶液或分散体的可印刷浆料; 以及使用包含聚噻吩或噻吩共聚物的水溶液或非水溶液或分散体的水性或非水溶液或分散体制备的导电或抗静电层。

公开(公告)号：US20060100103A1

公开(公告)日：2006-05-11

申请号：US11257480

申请日：2005-10-24

Applicant: Carlo Uyttendaele ,  Johan Loccufier ,  Frank Louwet

Inventor： Carlo Uyttendaele ,  Johan Loccufier ,  Frank Louwet

IPC: B41M5/20

CPC classification number: G03C1/49845 ,  G03C1/4989

Abstract: A thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element comprising at least one substantially light-insensitive organic silver salt, at least one organic reducing agent therefor in thermal working relationship therewith, at least one binder and at least one toning agent represented by formula (I): wherein X represents the optionally substituted atoms necessary to form a 6-membered ring.

Abstract translation: 一种包含支持体和热敏元件的热敏记录材料，所述热敏元件包含至少一种基本上不光敏的有机银盐，至少一种与其热处理关系的有机还原剂，至少一种粘合剂和至少一种调色剂 由式（I）表示：其中X表示形成6元环所需的任选取代的原子。

公开(公告)号：US06887556B2

公开(公告)日：2005-05-03

申请号：US10316274

申请日：2002-12-11

Applicant: Johan Lamotte ,  Frank Louwet ,  Tom Cloots ,  Huub Van Aert

Inventor： Johan Lamotte ,  Frank Louwet ,  Tom Cloots ,  Huub Van Aert

IPC: H01B1/12 ,  H01L51/00 ,  H01L51/30 ,  H01L51/40 ,  H05K3/02 ,  H05K3/10 ,  D06N7/04

CPC classification number: H05K3/105 ,  H01B1/127 ,  H01L51/0021 ,  H01L51/0036 ,  H05K3/02 ,  Y10T428/24355 ,  Y10T428/24802 ,  Y10T428/269 ,  Y10T428/2933 ,  Y10T428/2971 ,  Y10T428/31855

Abstract: A material for making a conductive pattern, the material comprising a support and a heat-differentiable element, the heat-differentiable element comprising an outermost layer containing a polyanion and an intrinsically conductive polymer and optionally a second layer contiguous with the outermost layer, characterized in that the outermost layer and/or the optional second layer contains hydrophobic thermocoagulable latex particles in a weight ratio range with respect to the intrinsically conductive polymer in the range of 20:1 to 1:5, the hydrophobic thermocoagulable latex particles are capable upon heating of increasing the conductivity of the heated parts of the outermost layer relative to the unheated parts of the outermost layer and/or changing the removability of the heated parts of the outermost layer relative to the unheated parts of the outermost layer and the heat-differentiable element does not comprise a di- or polyhydroxy organic compound or an aprotic compound with a dielectric constant, ∈, ≧15; a method of making a conductive pattern on a support therewith; and a use of the material for making a conductive pattern in making an electronic circuit in the production of an electric or semiconductor device such as a printed circuit board, an integrated circuit, a display or touch screen, an electroluminescent device or a photovoltaic cell.

Abstract translation: 一种用于制造导电图案的材料，该材料包括支撑体和可热分解的元件，该热可分离元件包括含有聚阴离子和本征导电聚合物的最外层，以及任选地与最外层邻接的第二层，其特征在于 最外层和/或任选的第二层含有相对于本征导电聚合物的重量比范围为20:1至1:5的疏水性热凝胶乳胶颗粒，疏水性热凝胶乳颗粒能够加热 增加最外层的加热部分相对于最外层的未加热部分的导电性和/或改变最外层的加热部分相对于最外层和可热分散元件的未加热部分的可去除性 不包含二 - 或多羟基有机化合物或具有夹层的非质子化合物 三次常数∈，> = 15; 在其上的支撑件上形成导电图案的方法; 以及在制造诸如印刷电路板，集成电路，显示器或触摸屏，电致发光器件或光伏电池的电气或半导体器件中的电子电路中制造导电图案的材料的用途。

公开(公告)号：US20050042556A1

公开(公告)日：2005-02-24

申请号：US10645160

申请日：2003-08-21

Applicant: Frank Louwet ,  Tom Cloots ,  Hieronymus Andriessen

Inventor： Frank Louwet ,  Tom Cloots ,  Hieronymus Andriessen

IPC: H01B1/12 ,  H01B1/22 ,  H01L51/00 ,  H01L51/30 ,  H01L51/52 ,  H05K3/10 ,  G03C1/46

CPC classification number: H05K3/106 ,  H01B1/127 ,  H01B1/22 ,  H01L51/0021 ,  H01L51/0037 ,  H01L51/445 ,  H01L51/5203 ,  H05K2201/0329 ,  Y02E10/549

Abstract: A process for preparing a substantially transparent conductive layer configuration on a support, the layer configuration comprising in any order at least a first layer containing an intrinsically conductive polymer optionally containing structural units represented by formula (I): wherein n is larger than 1 and each of R1 and R2 independently represents hydrogen or an optionally substituted C1-4 alkyl group or together represent an optionally substituted C1-4 alkylene group or an optionally substituted cycloalkylene group, preferably an ethylene group, an optionally alkyl-substituted methylene group, an optionally C1-12 alkyl- or phenyl-substituted ethylene group, a 1,3-propylene group or a 1,2-cyclohexylene group; and a second layer consisting of a non-continuous layer of conductive silver, the process comprising the step of: preparing the second layer by a photographic process; and light emitting diodes, photovoltaic devices, transistors and electroluminescent devices comprising a layer configuration prepared according to this process.

Abstract translation: 一种用于在载体上制备基本上透明的导电层构型的方法，所述层构型至少包含含有本发明的导电聚合物的第一层，所述固有导电聚合物任选含有由式（I）表示的结构单元：其中n大于1， R 1和R 2独立地表示氢或任选取代的C 1-4烷基或一起表示任选取代的C 1-4亚烷基或任选取代的亚环烷基，优选亚乙基，任选烷基取代的 亚甲基，任选的C 1-12烷基或苯基取代的亚乙基，1,3-亚丙基或1,2-亚环己基; 以及由不连续的导电银层组成的第二层，该方法包括以下步骤：通过摄影法制备第二层; 以及发光二极管，光电器件，晶体管和电致发光器件，其包括根据该工艺制备的层构型。

公开(公告)号：US20050040372A1

公开(公告)日：2005-02-24

申请号：US10894441

申请日：2004-07-19

Applicant: Jean-Piere Tahon ,  Roger Van den Bogaert ,  Bert Groenendaal ,  Frank Louwet

Inventor： Jean-Piere Tahon ,  Roger Van den Bogaert ,  Bert Groenendaal ,  Frank Louwet

IPC: B05D5/00 ,  H01B1/00

CPC classification number: H01B1/128 ,  C08J3/09 ,  C08J2365/00 ,  C08L65/00 ,  C09D5/24 ,  C09D11/033 ,  C09D11/36 ,  C09D11/52 ,  C09D165/00 ,  Y10T428/2809

Abstract: A method for preparing a composition containing between 0.08 and 3.0% by weight of polymer or copolymer of a 3,4-dialkoxythiophene in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, a polyanion and at least one non-aqueous solvent from a dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion in water which is prepared in the substantial absence of oxygen, comprising in the following order the steps of: i) mixing at least one of the non-aqueous solvents with the aqueous dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion; and ii) evaporating water from the mixture prepared in step i) until the content of water therein is reduced by at least 65% by weight; a printing ink, printing paste or coating composition, capable of yielding layers with enhanced conductivity at a given transparency, prepared according to the above-described method; a coating process with the coating composition thereby producing a layer with enhanced conductivity at a given transparency; and a printing process with the printing ink or paste thereby producing a layer with enhanced conductivity at a given transparency.

Abstract translation: 一种制备含有0.08至3.0重量％的3,4-二烷氧基噻吩的聚合物或共聚物的组合物的方法，其中两个烷氧基可以相同或不同，或一起代表任选取代的氧 - 亚烷基 - 氧桥， 聚阴离子和至少一种非水溶剂，其由（3,4-二烷氧基噻吩）的聚合物或共聚物和聚阴离子在水中的分散体组成，其在基本上不存在氧的情况下制备，包括以下步骤： i）将至少一种非水溶剂与（3,4-二烷氧基噻吩）和聚阴离子的聚合物或共聚物的水分散体混合; 和ii）从步骤i）中制备的混合物蒸发水，直到其中的水含量降低至少65重量％; 印刷油墨，印刷浆料或涂料组合物，其能够产生根据上述方法制备的在给定透明度下具有增强的导电性的层; 所述涂料组合物由此在给定的透明度下产生具有增强的导电性的层; 以及具有印刷油墨或糊料的印刷方法，从而在给定的透明度下产生具有增强的导电性的层。

公开(公告)号：US06852830B2

公开(公告)日：2005-02-08

申请号：US10319976

申请日：2002-12-16

Applicant: Bert Groenendaal ,  Frank Louwet

Inventor： Bert Groenendaal ,  Frank Louwet

IPC: C07D333/02 ,  C07D495/04 ,  C08G61/12 ,  C08G65/34 ,  C08G69/10 ,  C08G75/00 ,  C09K3/16 ,  C09K9/02 ,  H01B1/12 ,  H05K1/09 ,  H05K3/32

CPC classification number: C07D495/04 ,  C08G61/126 ,  H01B1/127 ,  H01G11/48 ,  H05K1/095 ,  H05K3/321 ,  Y02E60/13

Abstract: A thiophene compound represented by formula (I): in which A represents a C1-5-alkylene bridge; R represents a —R1—(C═O)—R2 group; —R1— represents a —R3— or —R4—X—R5— group; R2 is hydrogen, a hydroxy group, a thiol group, —NR6R7, —OR8 or a —SR9 group; R3, R4 and R5 are independently an alkylene group or an arylene group; X is a —O—, —S— or ═NR10; R6 and R7 are independently hydrogen, an optionally substituted amino group or an optionally substituted alkyl group; R8 and R9 are independently an optionally substituted alkyl group (optionally with at least one substituent selected from the group consisting of an alcohol, amide, ether, ester or sulfonate group), an optionally substituted aryl group or a —SiR11R12R13 group; R10 is an alkyl, aryl or acyl group; and R11, R12 and R13 are independently an optionally substituted alkoxy or alkyl group; polymers derived therefrom; a process for polymerizing a thiophene according to formula (I), optionally chemically or electrochemically; and solutions, dispersions, pastes and layers containing polymers derived therefrom.

Abstract translation: 由式（I）表示的噻吩化合物：其中A表示C1-5亚烷基桥; R表示-R 1 - （C = O）-R 2基团; -R 1 - 表示-R 3 - 或-R 4 -X-R 5 - 基团; R 2是氢，羟基，硫醇基，-NR 6 R 7，-OR 8或-SR 9基团; R 3，R 4和R 5独立地是亚烷基或亚芳基; X是-O-，-S-或= NR 10; R 6和R 7独立地是氢，任选取代的氨基或任选取代的烷基; R 8和R 9独立地为任选取代的烷基（任选具有至少一个选自醇，酰胺，醚，酯或磺酸酯基的取代基），任选取代的芳基或 - SiR 11 R 12 R 13基团; R 10是烷基，芳基或酰基; 和R 11，R 12和R 13独立地是任选取代的烷氧基或烷基; 衍生自其的聚合物; 根据式（I）聚合噻吩的方法，任选化学或电化学方法; 以及含有由其衍生的聚合物的溶液，分散体，糊剂和层。

公开(公告)号：US06740479B2

公开(公告)日：2004-05-25

申请号：US10617647

申请日：2003-07-11

Applicant: Johan Loccufier ,  Frank Louwet ,  André Roefs

Inventor： Johan Loccufier ,  Frank Louwet ,  André Roefs

IPC: G03E5305

CPC classification number: G03C5/3056

Abstract: A silver halide photographic processing solution comprising at least one polymeric compound inhibiting sludge formation and preventing “pi-line” artefact, more particularly in radiographic non-destructive testing applications, wherein said polymeric compound comprises at least one monomer unit having a silver complexing moiety and at least one monomer unit having a solubilizing group, and wherein both said silver ion complexing moiety and said solubilizing group are comprised in same or different monomer units.

Abstract translation: 一种卤化银照相处理溶液，其包含至少一种抑制污泥形成的聚合物，并防止“pi系”人造物，更特别是在射线照相非破坏性测试应用中，其中所述聚合物包含至少一个具有银络合部分的单体单元和 至少一个具有增溶基团的单体单元，并且其中所述银离子络合部分和所述增溶基团都包含相同或不同的单体单元。

公开(公告)号：US06300052B1

公开(公告)日：2001-10-09

申请号：US09138048

申请日：1998-08-21

Applicant: Frank Louwet ,  Huub Van Aert ,  Frank Ruttens ,  Ivan Hoogmartens

Inventor： Frank Louwet ,  Huub Van Aert ,  Frank Ruttens ,  Ivan Hoogmartens

IPC: G03C1498

CPC classification number: G03C1/49863 ,  G03C1/4989

Abstract: A substantially light-insensitive black and white thermographic material comprising a support and a thermosensitive element containing a substantially light-insensitive organic silver salt, a reducing agent therefor in thermal working relationship therewith and a binder, wherein the binder is a water-dispersible film-forming polymer having covalently bonded ionic groups and the thermographic material is thermally developable under substantially water-free conditions; and a process for producing the substantially light-insensitive black and white thermographic material comprising the steps of: producing an aqueous dispersion of the substantially light-insensitive organic silver salt; producing one or more aqueous coating compositions containing together the aqueous dispersion of the substantially light-insensitive organic silver salt, the reducing agent and the binder; and applying the one or more aqueous coating compositions to the support, thereby forming after drying the thermosensitive element.

Abstract translation: 一种基本上不透光的黑色和白色热成像材料，其包括载体和含有基本上不光敏的有机银盐的热敏元件，与其热加工关系的还原剂和粘合剂，其中所述粘合剂是水分散性膜 - 具有共价键离子基团的成型聚合物，并且热成像材料在基本上无水条件下是可热显影的; 以及用于生产基本上不透光的黑白热成像材料的方法，包括以下步骤：制备基本上不光敏的有机银盐的水分散体; 制备一种或多种含有基本上不光敏的有机银盐，还原剂和粘合剂的水性分散体的水性涂料组合物; 并将一种或多种水性涂料组合物施加到载体上，从而在干燥热敏元件之后形成。