公开(公告)号：US20080188612A1

公开(公告)日：2008-08-07

申请号：US11815481

申请日：2006-01-26

申请人： Frank Louwet ,  Geert Deroover ,  Bert Groenendaal ,  Markus Hartenstein ,  Joachim Storsberg

发明人： Frank Louwet ,  Geert Deroover ,  Bert Groenendaal ,  Markus Hartenstein ,  Joachim Storsberg

IPC分类号： C08L31/00

CPC分类号： C08F293/00 ,  C09D11/326 ,  C09D17/003 ,  Y10T428/31855

摘要： A pigment dispersion includes a pigment and a block copolymer having ionic aromatic monomers. The pigment dispersions can be used for manufacturing inkjet inks and for the coating of colored layers. A process for preparing the pigment dispersion is also disclosed.

摘要翻译： 颜料分散体包括颜料和具有离子性芳族单体的嵌段共聚物。 颜料分散体可用于制造喷墨油墨和着色层的涂布。 还公开了制备颜料分散体的方法。

公开(公告)号：US07378039B2

公开(公告)日：2008-05-27

申请号：US11150774

申请日：2005-06-10

申请人： Frank Louwet ,  Bert Groenendaal

发明人： Frank Louwet ,  Bert Groenendaal

IPC分类号： H01B1/12 ,  B05D5/12

CPC分类号： C08G61/126 ,  C08G2261/122 ,  C08G2261/1424 ,  C08G2261/1426 ,  C08G2261/1452 ,  C08G2261/3223 ,  C08G2261/43 ,  C08G2261/51 ,  C08G2261/794 ,  C09D165/00 ,  H01G9/028 ,  H01G11/48 ,  Y02E60/13 ,  Y10T428/31533 ,  C08L25/18

摘要： A process for preparing an aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer, containing structural units according to formula (I): in which R1 and R2 independently of one another represent hydrogen or a C1-5-alkyl group or together form an optionally substituted C1-5-alkylene residue, comprising the step of: preparing the polythiophene or thiophene copolymer with an initiator in a reaction is medium in the presence of polyanions under oxidizing or reducing conditions under an inert atmosphere such that when said initiator is added less than 3 mg of oxygen per litre of the reaction medium is present in the reaction medium; an aqueous or non-aqueous solution or dispersion prepared therewith; the use of an aqueous or non-aqueous dispersion or solution comprising the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer for coating an object; a printable paste containing the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer; and an electroconductive or an antistatic layer prepared using an aqueous or non-aqueous solution or dispersion comprising the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer.

摘要翻译： 一种制备含有根据式（I）的结构单元的聚噻吩或噻吩共聚物的水溶液或非水溶液或分散体的方法：其中R 1和R 2 = >彼此独立地表示氢或C 1-5 - 烷基或一起形成任选取代的C 1-5 - 亚烷基残基，包括以下步骤：制备 在氧化或还原条件下，在惰性气氛下，在聚阴离子存在下，将聚噻吩或噻吩共聚物与反应中的引发剂进行介质反应，使得当每升反应介质中加入少于3mg氧气时， 反应介质; 用其制备的水性或非水溶液或分散体; 使用包含聚噻吩或噻吩共聚物的水溶液或非水溶液或分散体的水性或非水分散体或溶液来涂覆物体; 含有聚噻吩或噻吩共聚物的水溶液或非水溶液或分散体的可印刷浆料; 以及使用包含聚噻吩或噻吩共聚物的水溶液或非水溶液或分散体的水性或非水溶液或分散体制备的导电或抗静电层。

公开(公告)号：US20060027791A1

公开(公告)日：2006-02-09

申请号：US11180051

申请日：2005-07-12

申请人： Jean-Pierre Tahon ,  Roger Van den Bogaert ,  Bert Groenendaal ,  Frank Louwet

发明人： Jean-Pierre Tahon ,  Roger Van den Bogaert ,  Bert Groenendaal ,  Frank Louwet

IPC分类号： C08G65/38 ,  H01B1/12

CPC分类号： H01B1/128 ,  C08J3/09 ,  C08J2365/00 ,  C08L65/00 ,  C09D5/24 ,  C09D11/033 ,  C09D11/36 ,  C09D11/52 ,  C09D165/00 ,  Y10T428/2809

摘要： A method for preparing a composition containing between 0.08 and 3.0% by weight of polymer or copolymer of a 3,4-dialkoxythiophene in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, a polyanion and at least one non-aqueous solvent from a dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion in water which is prepared in the substantial absence of oxygen, comprising in the following order the steps of: i) mixing at least one of the non-aqueous solvents with the aqueous dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion; and ii) evaporating water from the mixture prepared in step i) until the content of water therein is reduced by at least 65% by weight; a printing ink, printing paste or coating composition, capable of yielding layers with enhanced conductivity at a given transparency, prepared according to the above-described method; a coating process with the coating composition thereby producing a layer with enhanced conductivity at a given transparency; and a printing process with the printing ink or paste thereby producing a layer with enhanced conductivity at a given transparency.

摘要翻译： 一种制备含有0.08至3.0重量％的3,4-二烷氧基噻吩的聚合物或共聚物的组合物的方法，其中两个烷氧基可以相同或不同，或一起代表任选取代的氧 - 亚烷基 - 氧桥， 聚阴离子和至少一种非水溶剂，其由（3,4-二烷氧基噻吩）的聚合物或共聚物和聚阴离子在水中的分散体组成，其在基本上不存在氧的情况下制备，包括以下步骤： i）将至少一种非水溶剂与（3,4-二烷氧基噻吩）和聚阴离子的聚合物或共聚物的水分散体混合; 和ii）从步骤i）中制备的混合物蒸发水，直到其中的水含量降低至少65重量％; 印刷油墨，印刷浆料或涂料组合物，其能够产生根据上述方法制备的在给定透明度下具有增强的导电性的层; 所述涂料组合物由此在给定的透明度下产生具有增强的导电性的层; 以及具有印刷油墨或糊料的印刷方法，从而在给定的透明度下产生具有增强的导电性的层。

公开(公告)号：US20080017833A1

公开(公告)日：2008-01-24

申请号：US11749617

申请日：2007-05-16

申请人： Frank Louwet ,  Bert Groenendaal

发明人： Frank Louwet ,  Bert Groenendaal

IPC分类号： C08K3/00

CPC分类号： H01B1/127 ,  C08G61/126 ,  C09D5/24 ,  H01G9/028 ,  H01G11/48 ,  H01G11/56 ,  H01L51/0037 ,  Y02E60/13

摘要： An aqueous dispersion of latex particles, said latex particles containing a polymer containing monomer units according to formula (I): in which R1 and R2 independently of one another represent hydrogen or a C1-5-alkyl group or together form an optionally substituted C1-5-alkylene residue and at least one polyanion compound, said latex having a primary particle size of less than 40 nm and said dispersion contains an organic compound containing a di- or polyhydroxy- and/or carboxy groups or amide or lactam group or an aprotic compound with a dielectric constant, ε, ≧15, wherein said latex particles contain said at least one polyanion compound and said polymer in a weight ratio of at least 4; a process for preparing an electroconductive coating comprising the steps of: preparing an aqueous solution or dispersion of the above-mentioned polymer by polymerization with an initiator in a reaction medium in the presence of at least one polyanion compound under oxidizing or reducing conditions, wherein the weight ratio of the at least one polyanion compound to said structural units during the reaction is in the range of 4:1 to 20:1; preparing a first coating composition containing said polymer associated with said at least one polyanion compound and an organic compound containing a di- or polyhydroxy- and/or carboxy groups or amide or lactam group in a aqueous or non-aqueous medium; coating said first coating composition on an object thereby producing a first layer; and heating said first layer at a temperature of at least 100° C.; and a process for preparing an electroconductive coating comprising the steps of: preparing an aqueous solution or dispersion of the above-mentioned polymer by polymerization with an initiator in a reaction medium in the presence of at least one polyanion compound under oxidizing or reducing conditions, wherein the weight ratio of said at least one polyanion compound to said structural units during the reaction is in the range of 4:1 to 20:1; preparing a second coating composition containing said polymer associated with said at least one polyanion compound and an aprotic compound with a dielectric constant, ε, ≧15 in an aqueous or non-aqueous medium; coating said second coating composition on an object thereby producing a second layer; and heating said second layer at a temperature of at least 50° C.

公开(公告)号：US07105620B2

公开(公告)日：2006-09-12

申请号：US10844551

申请日：2004-05-12

申请人： Bert Groenendaal ,  Frank Louwet

发明人： Bert Groenendaal ,  Frank Louwet

IPC分类号： C08F234/04 ,  C08F28/06 ,  C08L45/00 ,  C08G61/12

CPC分类号： C08G61/126 ,  C09D165/00 ,  H01G11/48 ,  H01G11/56 ,  Y02E60/13

摘要： An aqueous dispersion of a copolymer of at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of at least 2.2 g/L and a polyanion; a preparation process therefor; its use for coating; a printing ink containing the aqueous dispersion; an electro-conductive layer containing a copolymer of at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of at least 2.2 g/L and a polyanion derived from an aqueous dispersion thereof; and an antistatic layer containing a copolymer of at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of at least 2.2 g/L and a polyanion derived from an aqueous dispersion thereof.

摘要翻译： 至少一种3,4-二亚烷基二氧噻吩化合物在25℃下在水中的溶解度小于2.2g / L的共聚物的水分散体与至少一种在水中溶解度为25的3,4-亚烷基二氧噻吩化合物 至少2.2g / L的聚阴离子; 其准备过程; 其用于涂料; 含有水分散体的印刷油墨; 含有至少一种在25℃下在水中的溶解度低于2.2g / L的3,4-亚烷基二氧噻吩化合物与至少一种在水中溶解度的3,4-亚烷基二氧噻吩化合物的共聚物的导电层 在25℃下为至少2.2g / L，衍生自其水分散体的聚阴离子; 以及含有至少一种在25℃下在水中的溶解度低于2.2g / L的3,4-亚烷基二氧噻吩化合物与至少一种在水中溶解度的3,4-亚烷基二氧噻吩化合物的共聚物的抗静电层 25℃至少为2.2g / L和衍生自其水分散体的聚阴离子。

公开(公告)号：US07932320B2

公开(公告)日：2011-04-26

申请号：US11749617

申请日：2007-05-16

申请人： Frank Louwet ,  Bert Groenendaal

发明人： Frank Louwet ,  Bert Groenendaal

IPC分类号： C08K3/00

CPC分类号： H01B1/127 ,  C08G61/126 ,  C09D5/24 ,  H01G9/028 ,  H01G11/48 ,  H01G11/56 ,  H01L51/0037 ,  Y02E60/13

摘要： An aqueous dispersion of latex particles, said latex particles containing a polymer containing monomer units according to formula (I): in which R1 and R2 independently of one another represent hydrogen or a C1-5-alkyl group or together form an optionally substituted C1-5-alkylene residue and at least one polyanion compound.

摘要翻译： 胶乳颗粒的水分散体，所述胶乳颗粒含有含有根据式（I）的单体单元的聚合物：其中R 1和R 2彼此独立地表示氢或C 1-5 - 烷基或一起形成任选取代的C1- 5-亚烷基残基和至少一种聚阴离子化合物。

公开(公告)号：US20080167411A1

公开(公告)日：2008-07-10

申请号：US11815473

申请日：2006-01-26

申请人： Frank Louwet ,  Geert Deroover ,  Bert Groenendaal ,  Markus Hartenstein ,  Joachim Storsberg

发明人： Frank Louwet ,  Geert Deroover ,  Bert Groenendaal ,  Markus Hartenstein ,  Joachim Storsberg

IPC分类号： C09D11/10

CPC分类号： C09D11/326 ,  C08F293/005 ,  C09D17/003 ,  Y10T428/31855

摘要： A pigment dispersion includes a pigment with at least one carboxylic acid group and a block copolymer including aromatic monomers having at least one carboxylic acid group or a salt thereof and aromatic monomers having at least one sulfonic acid group or a salt thereof.The pigment dispersions can be used for manufacturing inkjet inks and for the coating of colored layers.

摘要翻译： 颜料分散体包括具有至少一个羧酸基团的颜料和包含具有至少一个羧酸基团的芳族单体或其盐以及具有至少一个磺酸基的芳族单体或其盐的嵌段共聚物。 颜料分散体可用于制造喷墨油墨和着色层的涂布。

公开(公告)号：US07223357B2

公开(公告)日：2007-05-29

申请号：US11180051

申请日：2005-07-12

申请人： Jean-Pierre Tahon ,  Roger Van den Bogaert ,  Bert Groenendaal ,  Frank Louwet

发明人： Jean-Pierre Tahon ,  Roger Van den Bogaert ,  Bert Groenendaal ,  Frank Louwet

IPC分类号： H01B1/12

CPC分类号： H01B1/128 ,  C08J3/09 ,  C08J2365/00 ,  C08L65/00 ,  C09D5/24 ,  C09D11/033 ,  C09D11/36 ,  C09D11/52 ,  C09D165/00 ,  Y10T428/2809

摘要： A method for preparing a composition containing between 0.08 and 3.0% by weight of polymer or copolymer of a 3,4-dialkoxythiophene in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, a polyanion and at least one non-aqueous solvent from a dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion in water which is prepared in the substantial absence of oxygen, comprising in the following order the steps of: i) mixing at least one of the non-aqueous solvents with the aqueous dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion; and ii) evaporating water from the mixture prepared in step i) until the content of water therein is reduced by at least 65% by weight; a printing ink, printing paste or coating composition, capable of yielding layers with enhanced conductivity at a given transparency, prepared according to the above-described method; a coating process with the coating composition thereby producing a layer with enhanced conductivity at a given transparency; and a printing process with the printing ink or paste thereby producing a layer with enhanced conductivity at a given transparency.

摘要翻译： 一种制备含有0.08至3.0重量％的3,4-二烷氧基噻吩的聚合物或共聚物的组合物的方法，其中两个烷氧基可以相同或不同，或一起代表任选取代的氧 - 亚烷基 - 氧桥， 聚阴离子和至少一种非水溶剂，其由（3,4-二烷氧基噻吩）的聚合物或共聚物和聚阴离子在水中的分散体组成，其在基本上不存在氧的情况下制备，包括以下步骤： i）将至少一种非水溶剂与（3,4-二烷氧基噻吩）和聚阴离子的聚合物或共聚物的水分散体混合; 和ii）从步骤i）中制备的混合物蒸发水，直到其中的水含量降低至少65重量％; 印刷油墨，印刷浆料或涂料组合物，其能够产生根据上述方法制备的在给定透明度下具有增强的导电性的层; 所述涂料组合物由此在给定的透明度下产生具有增强的导电性的层; 以及具有印刷油墨或糊料的印刷方法，从而在给定的透明度下产生具有增强的导电性的层。

公开(公告)号：US07147936B2

公开(公告)日：2006-12-12

申请号：US10642933

申请日：2003-08-18

申请人： Frank Louwet ,  Geert Van Dyck ,  Johan Loccufier ,  Bert Groenendaal ,  Hieronymus Andriessen

发明人： Frank Louwet ,  Geert Van Dyck ,  Johan Loccufier ,  Bert Groenendaal ,  Hieronymus Andriessen

IPC分类号： C07D211/021 ,  H01L51/50

CPC分类号： C08G61/126 ,  C08L25/08 ,  C08L2666/06 ,  C09J165/00 ,  H01G11/48 ,  H01G11/56 ,  Y02E60/13 ,  Y10S428/917

摘要： A layer configuration on a support, the layer configuration comprising a layer containing a polymer containing optionally substituted 3,4-alkylenedioxythiophene structural units, in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, and a compound selected from the group consisting of polyphosphoric acids, polyphosphoric acid salts, thia-alkanedicarboxylic acids, cyclohexadiene compounds and polyhydroxy-compounds selected from the group consisting of tetronic acid derivatives; ortho-dihydroxybenzene compounds with at least one sulpho group, compounds according to formula (I): HO—CH2—CH(OH)—(CH2)m—S—CH2—C(R1)(R2)—CH2—S—(CH2)n—CH(OH)—CH2—OH  (I) wherein R1 and R2 are independently H, —OH or alkyl, and n and m are independently 1, 2 or 3; compounds according to formula (II): HO—(CH2)p—S—CH2—S—(CH2)q—OH  (II) wherein p and q are independently 2, 3 or 4; compounds hydrolyzable to tetronic acid derivatives; compounds hydrolyzable to compounds according to formula (I); and sulpho-substituted 2-thia-alkyl-benzimidazole compounds.

摘要翻译： 在支撑体上的层构型，该层构型包括含有含有任选取代的3,4-亚烷基二氧噻吩结构单元的聚合物的层，其中两个烷氧基可以相同或不同，或一起代表任选取代的氧基 - 桥，以及选自多磷酸，多磷酸盐，硫杂烷二羧酸，环己二烯化合物和选自由以下组成的组的多羟基化合物的化合物：四氢酸衍生物; 具有至少一个磺酸基的邻二羟基苯化合物，根据式（I）的化合物：<？in-line-formula description =“In-line formula”end =“lead”？> HO-CH 2 -CH（OH） - （CH 2 CH 2）m -S- CH 2 -C（R 1） （R 2） - CH 2 -S-（CH 2）n - （CH 2）n - （CH 2） -CH 2 -O-OH（I）<β在线公式描述=“在线式”末端=“尾”→其中R 1和R 2， SUP> 2独立地是H，-OH或烷基，n和m独立地是1,2或3; 根据式（II）的化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> HO-（CH 2） > -S-CH 2 -S-（CH 2）2 -O-OH（II）<β在线配方说明书=“ 其中p和q独立地为2,3或4; 可水解成四氢酸衍生物的化合物; 可水解成根据式（I）的化合物的化合物的化合物; 和磺基取代的2-硫代 - 烷基 - 苯并咪唑化合物。

公开(公告)号：US20050009986A1

公开(公告)日：2005-01-13

申请号：US10844551

申请日：2004-05-12

申请人： Bert Groenendaal ,  Frank Louwet

发明人： Bert Groenendaal ,  Frank Louwet

IPC分类号： C08G61/12 ,  C09D165/00 ,  C08F20/58

CPC分类号： C08G61/126 ,  C09D165/00 ,  H01G11/48 ,  H01G11/56 ,  Y02E60/13

摘要： An aqueous dispersion of a copolymer of at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of at least 2.2 g/L and a polyanion; a preparation process therefor; its use for coating; a printing ink containing the aqueous dispersion; an electro-conductive layer containing a copolymer of at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of at least 2.2 g/L and a polyanion derived from an aqueous dispersion thereof; and an antistatic layer containing a copolymer of at least one 3,4-alkylenedioxy-thiophene compound with a solubility in water at 25° C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of at least 2.2 g/L and a polyanion derived from an aqueous dispersion thereof.

摘要翻译： 至少一种3,4-二亚烷基二氧噻吩化合物在25℃下在水中的溶解度小于2.2g / L的共聚物的水分散体与至少一种在水中溶解度为25的3,4-亚烷基二氧噻吩化合物 至少2.2g / L的聚阴离子; 其准备过程; 其用于涂料; 含有水分散体的印刷油墨; 含有至少一种在25℃下在水中的溶解度低于2.2g / L的3,4-亚烷基二氧噻吩化合物与至少一种在水中溶解度的3,4-亚烷基二氧噻吩化合物的共聚物的导电层 在25℃下为至少2.2g / L，衍生自其水分散体的聚阴离子; 以及含有至少一种在25℃下在水中溶解度小于2.2g / L的3,4-亚烷基二氧基 - 噻吩化合物与至少一种具有溶解度的3,4-亚烷基二氧噻吩化合物的共聚物的抗静电层 25℃下的水至少为2.2g / L，衍生自其水分散体的聚阴离子。