公开(公告)号：US11760833B2

公开(公告)日：2023-09-19

申请号：US17487686

申请日：2021-09-28

申请人： FUJIFILM Business Innovation Corp. ,  National University Corporation Chiba University

发明人： Wataru Yamada ,  Satoya Sugiura ,  Natsumi Kaneko ,  Katsuyoshi Hoshino

IPC分类号： C08G61/12 ,  C03C17/32 ,  C03C17/44

CPC分类号： C08G61/126 ,  C03C17/32 ,  C03C17/44 ,  B05D2203/35 ,  C03C2217/72 ,  C08G2261/141 ,  C08G2261/1424 ,  C08G2261/3223 ,  C08G2261/36 ,  C08G2261/43 ,  C08G2261/71 ,  C08G2261/90

摘要： A liquid composition includes a thiophene polymer; and at least one polymerization component selected from the group including a monomer and an oligomer.

公开(公告)号：US20190241785A1

公开(公告)日：2019-08-08

申请号：US16250717

申请日：2019-01-17

申请人： Massachusetts Institute of Technology

发明人： Gang Chen ,  Karen K. Gleason ,  Yanfei Xu ,  Xiaoxue Wang

IPC分类号： C09K5/14 ,  C08G61/12 ,  C09D165/00 ,  H01L21/02

CPC分类号： C09K5/14 ,  C08G61/126 ,  C08G2261/11 ,  C08G2261/1414 ,  C08G2261/334 ,  C08G2261/43 ,  C09D165/00 ,  H01L21/02118 ,  H01L21/02271

摘要： Disclosed are thermally conductive quinoid-type conjugated polymer thin films. One such film comprises conjugated poly(3-hexylthiophene) (P3HT). The thin films can be fabricated using oxidative chemical vapor deposition (oCVD), which offers unique advantages for integrating polymer films into various devices. By avoiding the use of solvents in the deposition of monomers and oxidants and undesirable solvent-derived surface-tension driven effects, such as dewetting, the oCVD coatings can conformally coat complex geometries, can be scaled to large areas, and can be fabricated at relatively low substrate temperatures on electrically insulating substrates. Disclosed is the formation of ordered polymer structures with rigid backbones achieved by oCVD with stacking in the transverse direction via π-π interactions. P3HT films with record-high thermal conductivity of 2.2 W/m-K near room temperature have been prepared.

公开(公告)号：US20170346095A1

公开(公告)日：2017-11-30

申请号：US15106562

申请日：2015-01-13

申请人： Masayoshi NOMURA

发明人： Masayoshi NOMURA

IPC分类号： H01M4/60 ,  C08G61/12 ,  H01M10/0565 ,  H01M4/02

CPC分类号： H01M4/608 ,  C08G61/126 ,  C08G2261/122 ,  C08G2261/1424 ,  C08G2261/145 ,  C08G2261/312 ,  C08G2261/3223 ,  C08G2261/43 ,  C08G2261/514 ,  H01L51/0036 ,  H01L51/0043 ,  H01M10/0565 ,  H01M2004/028

摘要： A polythiophene derivative including a repeating unit represented by General Formula (1) below: where R1 and R2 each independently denote a group having from 2 through 9 carbon atoms represented by —(R3—S)p—R4 (where R3 denotes an alkylene group having from 1 through 4 carbon atoms, R4 denotes an alkyl group having from 1 through 6 carbon atoms or an aromatic group having from 5 through 6 carbon atoms, and p denotes an integer of 1 or 2), Ar denotes an optionally substituted divalent or monovalent aromatic ring moiety or aromatic heterocyclic moiety, m denotes a natural number of 2 or more, and n denotes a natural number of 0 or 2 or more.

公开(公告)号：US20170233596A1

公开(公告)日：2017-08-17

申请号：US15420997

申请日：2017-01-31

申请人： SHIN-ETSU CHEMICAL CO., LTD.

发明人： Jun HATAKEYAMA ,  Takayuki NAGASAWA

IPC分类号： C09D125/18 ,  C08L65/00 ,  H01L51/00 ,  C08L25/18 ,  H01B1/12 ,  C09D5/24 ,  C09D165/00

CPC分类号： C09D125/18 ,  C08F12/20 ,  C08F12/22 ,  C08F12/26 ,  C08F12/30 ,  C08F212/14 ,  C08F214/18 ,  C08G73/0266 ,  C08G2261/1424 ,  C08G2261/3223 ,  C08G2261/43 ,  C08G2261/512 ,  C08G2261/794 ,  C08L25/18 ,  C08L27/12 ,  C08L33/08 ,  C08L33/10 ,  C08L65/00 ,  C08L79/02 ,  C08L2201/10 ,  C08L2201/54 ,  C08L2201/56 ,  C08L2203/20 ,  C09D5/24 ,  C09D7/65 ,  C09D127/12 ,  C09D165/00 ,  H01B1/127 ,  H01B1/128 ,  H01L27/323 ,  H01L51/0036 ,  H01L51/004 ,  H01L51/5088 ,  H01L51/5206 ,  H01L2251/5361 ,  C08F220/24 ,  C08F2220/282

摘要： The present invention provides a conductive polymer composite including: (A) a π-conjugated polymer, and (B) a dopant polymer which contains a repeating unit “a” shown by the following general formula (1) and has a weight-average molecular weight in the range of 1,000 to 500,000. There can be provided a conductive polymer composite that has excellent filterability and film-formability by spin coating, and also can form a conductive film having high transparency and flatness when the film is formed therefrom.

公开(公告)号：US20170226269A1

公开(公告)日：2017-08-10

申请号：US15500266

申请日：2015-08-11

申请人： POLITECNICO DI MILANO

发明人： Maurizio Stefano GALIMBERTI ,  Vincenzina BARBERA ,  Ada TRUSCELLO ,  Roberto SEBASTIANO ,  Antonio Marco VALERIO

IPC分类号： C08G18/38 ,  C08G18/73 ,  C08G61/12 ,  C08G63/685 ,  C08G64/02 ,  C08K3/04 ,  C08G65/34

CPC分类号： C08G18/3844 ,  C08G18/44 ,  C08G18/4646 ,  C08G18/5057 ,  C08G18/73 ,  C08G18/8012 ,  C08G18/8058 ,  C08G61/124 ,  C08G63/6856 ,  C08G64/0241 ,  C08G65/34 ,  C08G2261/3221 ,  C08G2261/43 ,  C08G2650/50 ,  C08G2650/56 ,  C08K3/04 ,  C08K3/041 ,  C08K3/042 ,  C08L75/04 ,  C08L69/00 ,  C08L67/02

摘要： The present invention relates to a polymer comprising repeating units consisting of a substituted pyrrole ring. In particular, the repeating units consist of substituted pyrrole containing polar groups capable of interacting with carbon allotropes such as carbon nanotubes, graphene or nanographites, in order to improve the chemical-physical characteristics of the allotropes mainly by increasing their dispersibility and stability in liquid media and in polymer matrices. The invention also relates to products of addition of these polymers with carbon allotropes in order to obtain easily dispersible macromolecules.

公开(公告)号：US09518151B2

公开(公告)日：2016-12-13

申请号：US14785522

申请日：2013-11-20

申请人： SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY, CHINESE ACADEMY OF SCIENCES

发明人： Qiang Fang ,  Chao Yuan ,  Kaikai Jin ,  Yingchun Liu ,  Shen Diao ,  Kai Li

IPC分类号： C08G65/38 ,  C08G65/40 ,  C07C41/30 ,  C08G61/12 ,  H01L51/05 ,  C07C41/16 ,  C07C41/24 ,  C07C41/09 ,  C07C43/247 ,  C09D171/12 ,  C08G2/00

CPC分类号： C08G65/40 ,  C07C41/09 ,  C07C41/16 ,  C07C41/24 ,  C07C41/30 ,  C07C43/247 ,  C07C2601/04 ,  C08G61/12 ,  C08G65/007 ,  C08G65/4025 ,  C08G65/4075 ,  C08G65/4093 ,  C08G2261/146 ,  C08G2261/344 ,  C08G2261/43 ,  C08G2261/65 ,  C09D171/12 ,  H01L51/052 ,  C07C43/225

摘要： The present invention belongs to the field of preparation of high performance polymers, and specifically relates to a low dielectric constant polymer containing dinaphthyl and hexafluorocyclobutyl ether units, and preparation method and use thereof. The polymer is prepared as follows: under the effect of an alkali, 1-naphthol bromotetrafluoroethane ether is prepared from 1-naphthol and tetrafluorodibromoethane in an organic solvent, and then reduced by a zinc powder so as to obtain 1-naphthol trifluorovinyl ether. 1-naphthol trifluorovinyl ether is treated at a high temperature to obtain a bisnaphthol hexafluorocyclobutyl ether monomer. The monomer is subjected to oxidative coupling in the presence of ferric trichloride so as to obtain a thermal polymer containing dinaphthyl and hexafluorocyclobutyl structural units with a good film-forming property, and in a nitrogen atmosphere, the temperature for 5% weight loss (Td5%) of the obtained film is 437° C., and the carbon residue yield at 1000° C. is 54.24%. The dielectric constant (30 MHz) of the film is 2.33. The polymer is suitable for use in the electronic and electrical industries as an insulation coating layer and an encapsulating material for electron components.

摘要翻译： 本发明属于高性能聚合物的制备领域，具体涉及含有二萘基和六氟环丁基醚单元的低介电常数聚合物及其制备方法和用途。 聚合物制备如下：在碱的作用下，1-萘酚溴四氟乙醚由1-萘酚和四氟二溴乙烷在有机溶剂中制备，然后用锌粉还原，得到1-萘酚三氟乙烯醚。 1-萘酚三氟乙烯醚在高温下处理，得到双萘酚六氟环丁基醚单体。 单体在三氯化铁存在下进行氧化偶合，得到含有成膜性能好的二萘基和六氟环丁基结构单元的热聚合物，在氮气气氛中，5％重量损失温度（Td5％ ）为437℃，1000℃下的碳残渣产率为54.24％。 该膜的介电常数（30MHz）为2.33。 聚合物适用于电子和电气工业中作为绝缘涂层和用于电子部件的封装材料。

公开(公告)号：US20160257780A1

公开(公告)日：2016-09-08

申请号：US15032882

申请日：2014-10-29

申请人： ARKEMA FRANCE ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ,  UNIVERSITE DE BORDEAUX ,  INSTITUT POLYTECHNIQUE DE BORDEAUX

发明人： Christophe NAVARRO ,  Usein ISMAILOV ,  Muhammad MUMTAZ ,  Eric CLOUTET ,  Cyril BROCHON ,  Georges HADZIIOANNOU

IPC分类号： C08G61/12 ,  C08L65/00 ,  H01L51/00 ,  H01L51/44

CPC分类号： C08G61/126 ,  C08G2261/12 ,  C08G2261/1424 ,  C08G2261/3223 ,  C08G2261/43 ,  C08G2261/51 ,  C08G2261/794 ,  C08L65/00 ,  H01L51/0037 ,  H01L51/0043 ,  H01L51/0048 ,  H01L51/444 ,  Y02E10/549 ,  C08L25/18

摘要： The invention relates to a process for synthesizing poly(3,4-ethylenedioxythiophene)-electrolytic (co)polymer composite in a single step.

摘要翻译： 本发明涉及在单一步骤中合成聚（3,4-亚乙基二氧噻吩） - 电解（共）聚合物复合材料的方法。

公开(公告)号：US09290610B2

公开(公告)日：2016-03-22

申请号：US14255715

申请日：2014-04-17

申请人： Tongji University

发明人： Mei-rong Huang ,  Xin-gui Li ,  Shao-Jun Huang

IPC分类号： C08G61/10 ,  H01G9/022 ,  H01G11/56 ,  H01M10/0565 ,  C08G61/02 ,  C08G61/00

CPC分类号： C08G61/10 ,  C08G2261/314 ,  C08G2261/43 ,  C08G2261/70 ,  H01G9/038 ,  H01G11/56 ,  H01M10/0565 ,  H01M2300/0082 ,  Y02E60/13

摘要： The present application provides methods of producing polyanthracene including polymerization of anthracene monomers in the presence of oxidants and reaction solvents. The present application further provides polyanthracene produced by methods described herein that has higher solubility in organic solvents and better thermal stability and ablation resistance.

摘要翻译： 本申请提供了生产聚蒽的方法，包括在氧化剂和反应溶剂存在下聚合蒽单体。 本申请还提供了通过本文描述的在有机溶剂中具有较高溶解度和更好的热稳定性和耐烧蚀性的方法制备的聚蒽。

公开(公告)号：US20160075917A1

公开(公告)日：2016-03-17

申请号：US14418799

申请日：2013-07-31

申请人： National University Corporation Chiba University

发明人： Katsuyoshi HOSHINO ,  Reo TAGAWA

IPC分类号： C09D181/02 ,  C03C17/32 ,  C03C17/44 ,  B05D7/04 ,  B05D5/06

CPC分类号： C09D181/02 ,  B05D5/067 ,  B05D7/04 ,  B05D2203/35 ,  C03C17/009 ,  C03C17/32 ,  C03C17/44 ,  C03C2217/72 ,  C08G61/126 ,  C08G2261/1412 ,  C08G2261/1424 ,  C08G2261/3223 ,  C08G2261/43 ,  C08G2261/792 ,  C08K3/16 ,  C08K3/24

摘要： Provided are a film having a metallic luster, said film being easier to manufacture and exhibiting little degradation over time, an article having the film formed thereon, and a manufacturing method for the film having a metallic luster. The film, which has a metallic luster, according to one aspect of the present invention is characterized by containing a thiophene polymer. The manufacturing method for the film, which has a metallic luster, according to another aspect of the present invention is characterized by thiophene being polymerized using an oxidizing agent and made into a solution containing the thiophene polymer, and then coating and drying the solution containing the thiophene polymer on an article. The article having the film, which has a metallic luster, formed thereon according to another aspect of the present invention is characterized by containing a thiophene polymer.

摘要翻译： 提供了具有金属光泽的膜，所述膜更容易制造并且随时间呈现出很小的劣化，其上形成有膜的制品以及具有金属光泽的膜的制造方法。 根据本发明的一个方面，具有金属光泽的膜的特征在于含有噻吩聚合物。 根据本发明另一方面的具有金属光泽的膜的制造方法的特征在于使用氧化剂将噻吩聚合并制成含有噻吩聚合物的溶液，然后涂布并干燥含有 噻吩聚合物。 根据本发明的另一方面，具有形成在其上的具有金属光泽的膜的制品的特征在于含有噻吩聚合物。

公开(公告)号：US20160002391A1

公开(公告)日：2016-01-07

申请号：US14765982

申请日：2014-02-06

申请人： AVERTICA, INC.

发明人： Nicholas Brendan Duck

IPC分类号： C08G61/12 ,  C12P17/10

CPC分类号： C08G12/04 ,  C08G12/06 ,  C08G12/08 ,  C08G12/40 ,  C08G61/124 ,  C08G67/00 ,  C08G2261/12 ,  C08G2261/135 ,  C08G2261/1422 ,  C08G2261/18 ,  C08G2261/3241 ,  C08G2261/364 ,  C08G2261/43 ,  C08G2261/44 ,  C08G2261/74 ,  C08G2261/76 ,  C08J3/24 ,  C08J2361/22 ,  C08J2361/32 ,  C08L61/22 ,  C08L61/32 ,  C09B23/107 ,  C09B26/02 ,  C09B47/00 ,  C09B55/006 ,  C09B57/00 ,  C09B57/008 ,  C12P17/10 ,  H01G9/004 ,  H01G11/04 ,  H01G11/26 ,  H01G11/32 ,  H01G11/48 ,  H01G2009/0007 ,  H01M4/62 ,  H01M4/622 ,  H01M4/624 ,  H01M4/8673 ,  Y02E10/549 ,  Y02E60/122 ,  Y02E60/13 ,  Y02E60/50

摘要： The present invention relates generally to substrates for making polymers and methods for making polymers. The present invention also relates generally to polymers and devices comprising the same.