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公开(公告)号：US5101003A
公开(公告)日：1992-03-31
申请号：US474411
申请日：1990-02-02
IPC分类号： C08G79/02
CPC分类号： C08G79/02
摘要： The synthesis of the first examples of a new class of inorganic macromolecules, the polythiophosphazenes, is reported. When heated at 90.degree. C., the cyclothiophosphazene N.sub.3 P.sub.2 SCl.sub.5 undergoes ring-opening polymerization to yield the high polymeric polythiophosphazene [N.sub.3 P.sub.2 SCl.sub.5 ].sub.n. The latter functions as a reactive macromolecular intermediate and undergoes halogen replacement with sodium phenoxide and sodium o-phenylphenoxide to afford the polymers [N.sub.3 P.sub.2 S(OPh).sub.5 ].sub.n and [N.sub.3 P.sub.2 S(OC.sub.6 H.sub.4 Ph--o).sub.3.25 Cl.sub.1.75 ].sub.n, respectively.
摘要翻译： 报道了一类新的无机大分子，即聚硫代磷腈的合成。 当在90℃下加热时，环硫基磷腈N 3 P 2 SCl 5进行开环聚合，得到高分子聚硫代磷腈[N 3 P 2 SCl 5] n。 后者用作反应性大分子中间体，并用苯酚钠和邻苯基苯酚钠进行卤素置换，分别得到聚合物[N 3 P 2 S（OPh）5] n和[N 3 P 2 S（OC 6 H 4 Ph-o）3.25 Cl1.75] n。
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32.发明授权Ionically cross-linkable polyphosphazene: poly(bis(carboxylatophenoxy) phosphazene) and its hydrogels and membranes 失效可离子交联的聚磷腈：聚（双（羧基苯氧基）磷腈）及其水凝胶和膜
公开(公告)号：US5053451A
公开(公告)日：1991-10-01
申请号：US467821
申请日：1990-01-19
申请人： Harry R. Allcock , Sukky Kwon
发明人： Harry R. Allcock , Sukky Kwon
CPC分类号： C08G79/025 , B01D71/72
摘要： Hexachlorocyclotriphosphazene and poly(dichlorophosphazene) react with the sodium salt of ethyl p-hydroxybenzoate to give small molecule cyclic and high polymeric phosphazenes with aryloxy ester side groups; reaction of these compounds with potassium tert-butoxide brings about complete hydrolysis of the ester groups to yielding aqueous media-soluble, carboxylic acid bearing cyclic and high polymeric phosphazenes; the carboxylic acid bearing high polymer formed ionic cross-links when treated in aqueous media with salts of di- or trivalent cations yield hydrogels and membranes. The cross-linked gels were stable in neutral or strongly acidic aqueous media, but the cross-linking process was reversed in basic aqueous solutions of excess monovalent cations.
摘要翻译： 六氯环三磷腈和聚（二氯磷腈）与对羟基苯甲酸乙酯的钠盐反应，得到具有芳氧基酯侧基的小分子环状和高聚磷腈; 这些化合物与叔丁醇钾的反应导致酯基的完全水解以产生含水介质可溶的含羧酸的环状和高聚磷腈; 当在水性介质中用二价或三价阳离子盐处理时，含羧酸的高聚物形成离子交联产生水凝胶和膜。 交联凝胶在中性或强酸性水性介质中稳定，但在过量一价阳离子的碱性水溶液中交联过程相反。
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公开(公告)号：US4656017A
公开(公告)日：1987-04-07
申请号：US756799
申请日：1985-07-19
IPC分类号： C01B21/098 , C01B25/10
CPC分类号： C01B21/098 , C01B21/0986
摘要： Cyclic phosphonitrilic halides are formed rapidly and in high yield in a controllable multi-step process including the step of reacting a nitrogenous base (e.g. pyridine) with a phosphorus tetrahalide (e.g. phosphorus pentachloride) in a suitable inert liquid reaction medium (e.g. monochlorobenzene) to form a complex and in a subsequent step reacting this complex with an ammonium halide (e.g. ammonium chloride) at a temperature above about 90.degree. C. up to the reflux temperature of the reaction medium to form cyclic phosphonitrilic halides, mainly trimer.
摘要翻译： 在可控制的多步骤方法中快速和高产率地形成环状次膦酰卤，其包括使氮碱（例如吡啶）与四卤化磷（例如五氯化磷）在合适的惰性液体反应介质（例如一氯苯）中反应至 形成复合物，并且在随后的步骤中，使该配合物与卤化铵（例如氯化铵）在高于约90℃的温度下反应直到反应介质的回流温度，以形成主要是三聚体的环状次膦酰卤。
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公开(公告)号：US4495174A
公开(公告)日：1985-01-22
申请号：US390345
申请日：1982-06-21
CPC分类号： A61K47/48223 , A61K31/80 , C08G79/025
摘要： A long-acting, local anesthetic, comprising a polymeric phosphazene backbone, and 2-amino-4-picoline radical having local anesthetic activity and an amino functional group on the ring of said radical through which said radical is covalently attached to the phosphazene backbone by a phosphorous-nitrogen single bond is disclosed along with medicaments containing such anesthetics.
摘要翻译： 包含聚合磷腈骨架的长效局部麻醉剂和具有局部麻醉活性的2-氨基-4-甲基吡啶基和所述基团的环上的氨基官能团，所述基团通过其将所述基团共价连接到磷腈骨架上 公开了含有这种麻醉剂的药物的磷 - 氮单键。
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公开(公告)号：US4444972A
公开(公告)日：1984-04-24
申请号：US491125
申请日：1983-05-03
CPC分类号： C08G79/02 , C09D185/02 , H01B1/12 , H01L39/121 , Y10S505/811
摘要： Carboranylmethylene-substituted cyclophosphazenes which can be thermally polymerized into carboranylmethylene-substituted phosphazene polymers, useful as thermally stable coatings and, due to the characteristics of these polymers in acting as a ligand for transition metals, metallocarboranylmethylene phosphazene polymers which can act as immobilized catalyst systems, and are electrically conductive and superconductive.
摘要翻译： 可以热聚合成碳硼烷基亚甲基取代的磷腈聚合物的碳硼烷基亚甲基取代的环磷腈，可用作热稳定涂层，并且由于这些聚合物作为过渡金属配体的特性，可以充当固定催化剂体系的金属碳化硼烷基亚甲基膦腈聚合物， 并且是导电和超导的。
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公开(公告)号：US4288585A
公开(公告)日：1981-09-08
申请号：US129799
申请日：1980-03-12
申请人： Robert A. Administrator of the National Aeronatuics and Space Administration, with respect to an invention of Frosch , Harry R. Allcock , John P. O'Brien , Angelo G. Scopelianos , Larry L. Fewell
发明人： Robert A. Administrator of the National Aeronatuics and Space Administration, with respect to an invention of Frosch , Harry R. Allcock , John P. O'Brien , Angelo G. Scopelianos , Larry L. Fewell
CPC分类号： C08G79/025
摘要： Carboranyl-substituted polyphosphazenes are prepared by heat polymerizing a carboranyl halocyclophosphazene at 250.degree. C. for about 120 hours in the absence of oxygen and moisture. The cyclophosphazene is obtained by allowing a lithium carborane, e.g. the reaction product of methyl-o-carborane with n-butyllithium in ethyl ether, to react with e.g. hexachlorocyclotriphosphazene at ambient temperatures and in anhydrous conditions. For greater stability in the presence of moisture, the chlorine substituents of the polymer are then replaced by aryloxy or alkoxy groups, such as CF.sub.3 CH.sub.2 O--.The new substantially inorganic polymers are thermally stable materials which produce a high char yield when exposed to extreme temperatures, and can thus serve to insulate less heat and fire resistant substances.
摘要翻译： 碳硼烷基取代的聚磷腈通过在250℃下在不存在氧和水分的情况下将碳硼烷基卤代环磷腈加热聚合约120小时来制备。 环磷腈是通过使碳二亚硼酸锂， 甲基邻碳硼烷与正丁基锂在乙醚中的反应产物， 六氯环三磷腈在环境温度和无水条件下。 为了在存在水分的情况下获得更大的稳定性，聚合物的氯取代基然后被芳氧基或烷氧基取代，例如CF 3 CH 2 O-。 新的基本上无机的聚合物是热稳定的材料，当暴露在极端温度下时产生高的焦炭产率，并且因此可以用来绝热较少的耐热和耐火物质。
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公开(公告)号：US06558546B2
公开(公告)日：2003-05-06
申请号：US10001899
申请日：2001-11-01
IPC分类号： B01D3900
CPC分类号： B01D67/0088 , B01D67/0032 , B01D69/02 , B01D69/141 , B01D71/44 , B01D2323/36 , B01J20/28033 , B01J20/28097 , Y10T428/249954 , Y10T428/249986
摘要： A pore plugging material, for pH dependent membrane diffusion, in which cyclic olefins having phosphazene-functional moieties provide predictable erosion properties when used to plug pores in separation barriers and other porous membranes. Specific properties of the polymers are dependent on several factors, including molecular weight and identity of side groups attached to the phosphazene moiety. However, as a class, phosphazene-functional cyclic olefins provide both predictable erodibility and uniformly benign hydrolysis products and are, therefore, uniquely suitable as pore plugging polymers for separation barriers and membranes of all kinds. The invention, therefore, embraces the provision of a pH-sensitive erodible pore plugging material for pores in separation barriers and membranes of all kinds.
摘要翻译： 用于pH依赖性膜扩散的孔堵塞材料，其中具有磷腈官能团的环状烯烃当用于堵塞分离屏障和其它多孔膜中的孔时提供可预测的侵蚀性质。 聚合物的具体性质取决于几个因素，包括连接于磷腈部分的侧基的分子量和同一性。 然而，作为一类，磷腈官能的环烯烃提供可预测的可蚀性和均匀的良性水解产物，因此，其独特地适用于分离屏障和各种膜的孔堵聚合物。 因此，本发明包括为分离屏障和各种膜中的孔提供用于pH敏感的可侵蚀孔隙堵塞材料。
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38.发明授权Synthesis polyphosphazenes with controlled molecular weight and polydisperity 失效合成聚磷腈，具有受控的分子量和多不连续性
公开(公告)号：US5914388A
公开(公告)日：1999-06-22
申请号：US917069
申请日：1997-08-22
申请人： Harry R. Allcock , Christopher T. Morrissey , Ian Manners , Charles H. Honeyman , James M. Nelson , Chester A. Crane , Scott D. Reeves , A. Paul Primrose , Thomas J. Hartle , R. Prange
发明人： Harry R. Allcock , Christopher T. Morrissey , Ian Manners , Charles H. Honeyman , James M. Nelson , Chester A. Crane , Scott D. Reeves , A. Paul Primrose , Thomas J. Hartle , R. Prange
IPC分类号： C08G79/02
CPC分类号： C08G79/025
摘要： A process for the preparation of polyphosphazenes is provided that includes the cationic solution polymerization reaction of a phosphoranimine, using a main group or transition metal halide, or other appropriate halide salt, including a linear phosphazene salt of any chain length, or a preformed non-phosphazene polymer containing a main or transition metal chloride, as an initiator. In a preferred embodiment, triarmed-star polyphosphazenes having the formula N{RN(H)R'.sub.2 P--(N.dbd.PR'.sub.2).sub.n }.sub.3 are prepared via this method. Also, a methods for synthesis of the monomer Cl.sub.3 P.dbd.NSiMe.sub.3 and cyclic trimer N.sub.3 P.sub.3 X.sub.6 from the reactants N(SiR.sub.3).sub.3 and PX.sub.5 are also described.
摘要翻译： 提供了一种制备聚磷腈的方法，其包括使用主要基团或过渡金属卤化物或其它合适的卤化物盐（包括任何链长的线性磷腈盐）或预成型非离子表面活性剂的正亚胺的阳离子溶液聚合反应， 含有主要或过渡金属氯化物的磷腈聚合物作为引发剂。 在优选的实施方案中，通过该方法制备具有式N {RN（H）R'2P-（N = PR'2）n} 3的三臂星型聚磷腈。 此外，还描述了从反应物N（SiR 3）3和PX 5合成单体Cl 3 P = NSiMe 3和环状三聚体N 3 P 3 X 6的方法。
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39.发明授权Synthesis of polyphosphazenes with controlled molecular weight and polydispersity 失效具有受控分子量和多分散性的聚磷腈的合成
公开(公告)号：US5698664A
公开(公告)日：1997-12-16
申请号：US429521
申请日：1995-04-26
CPC分类号： C08G79/025
摘要： A process for the preparation of polyphosphazenes is provided that includes the cationic solution polymerization reaction of a phosphoranimine, using a main group or transition metal halide, or other appropriate halide salt, including a linear phosphazene salt of any chain length, or a preformed nonphosphazene polymer containing a main or transition metal chloride, as an initiator.
摘要翻译： 提供了一种制备聚磷腈的方法，其包括使用主族或过渡金属卤化物或其它合适的卤化物盐（包括任何链长的线性磷腈盐）或预制的非磷腈聚合物的正亚胺的阳离子溶液聚合反应 含有主要或过渡金属氯化物作为引发剂。
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公开(公告)号：US5494682A
公开(公告)日：1996-02-27
申请号：US210018
申请日：1994-03-18
申请人： Smadar Cohen , Carmen Bano , Karyn B. Visscher , Marie Chow , Harry R. Allcock , Robert S. Langer
发明人： Smadar Cohen , Carmen Bano , Karyn B. Visscher , Marie Chow , Harry R. Allcock , Robert S. Langer
IPC分类号： A61K9/127 , A61K9/16 , A61K9/50 , A61K31/70 , A61K31/708 , A61K31/715 , A61K35/12 , A61K38/00 , A61K47/02 , A61K47/30 , A61K47/32 , A61K47/34 , A61K49/22 , A61K51/12 , B01J13/02 , B01J13/10 , B01J13/14 , C08G79/02 , C12N11/04
CPC分类号： A61K49/223 , A61K49/225 , A61K49/226 , A61K51/1258 , A61K9/1271 , A61K9/1641 , A61K9/5031 , B01J13/14 , C08G79/025 , C12N11/04 , A61K2123/00 , Y10T428/2984 , Y10T428/2985 , Y10T428/2987
摘要： A method for encapsulating biologically-labile materials such as proteins, liposomes, bacteria and eucaryotic cells within a synthetic polymeric capsule, and the product thereof, are disclosed. The method is based on the use of a water-soluble polymer with charged side chains that are crosslinked with multivalent ions of the opposite charge to form a gel encapsulating biological material, that is optionally further stabilized by interactions with multivalent polyions of the same charge as those used to form the gel. In the preferred embodiment, hydrolytically stable polyphosphazenes are formed of monomers having carboxylic acid side groups that are crosslinked by divalent or trivalent cations such as Ca.sup.2+ or Al.sup.3+, then stabilized with a polycation such as poly-L-lysine. A variety of different compositions can be formed from the crosslinked polymer. In a preferred embodiment, microcapsules are made by spraying an aqueous solution of polyphosphazene and material to be encapsulated into a calcium chloride solution.
摘要翻译： 公开了一种将生物不稳定材料如蛋白质，脂质体，细菌和真核细胞包封在合成聚合物胶囊内的方法及其产品。 该方法基于使用具有带电侧链的水溶性聚合物，其与相反电荷的多价离子交联以形成包封生物材料的凝胶，其可任选地通过与相同电荷的多价离子的相互作用进一步稳定 用于形成凝胶的那些。 在优选的实施方案中，水解稳定的聚磷腈由具有羧酸侧基的单体形成，其通过二价或三价阳离子如Ca 2+或Al 3+交联，然后用聚阳离子如聚-L-赖氨酸稳定。 可以从交联聚合物形成各种不同的组合物。 在优选的实施方案中，通过将聚磷腈的水溶液和待包封的材料喷雾到氯化钙溶液中来制备微胶囊。
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