公开(公告)号：US06506923B2

公开(公告)日：2003-01-14

申请号：US10074025

申请日：2002-02-14

申请人： Tetsuya Inukai ,  Susumu Ueno ,  Toshio Shinohara ,  Mikio Aramata ,  Yoichi Tanifuji ,  Hajime Ishizaka

发明人： Tetsuya Inukai ,  Susumu Ueno ,  Toshio Shinohara ,  Mikio Aramata ,  Yoichi Tanifuji ,  Hajime Ishizaka

IPC分类号： C07F716

CPC分类号： C07F7/16

摘要： In a process for preparing oganohalosilanes by reacting metallic silicon particles with an organohalide in the presence of a copper catalyst, a contact mass composed of the metallic silicon and the catalyst further contains a minute, but effective amount of a catalytic metal powder which has been produced by an atomizing technique. The process is successful in drastically increasing a formation rate without lowering the selectivity of useful silane.

公开(公告)号：US06250952B1

公开(公告)日：2001-06-26

申请号：US09485306

申请日：2000-02-04

申请人： Katsumi Shiga ,  Hiroshi Kitamura ,  Toshio Shinohara ,  Hidehisa Yamagami

发明人： Katsumi Shiga ,  Hiroshi Kitamura ,  Toshio Shinohara ,  Hidehisa Yamagami

IPC分类号： H01R1358

CPC分类号： H01R13/719 ,  F42B3/188 ,  F42C19/06

摘要： The igniter connector comprises an insulating housing having a bead-receiving cavity open at one end, a partition in a center of a bottom wall of the cavity, a ferrite bead disposed in the bead-receiving cavity, and holes in the bottom wall of the bead-receiving cavity for insertion of pin terminals, the ferrite bead that is inserted in the bead-receiving cavity and secured in the insulating housing with the ferrite bead having a central opening through which the partition is passed when the ferrite bead is inserted in the bead-receiving cavity, a pair of electrical contacts having receptacle sections for electrical connection with the pin terminals are arranged in contact-receiving cavities disposed between the partition and the ferrite bead inserted in the bead-receiving cavity and wire-connecting sections for connection to electrical wires, and a cover member enclosing the bead-receiving cavity of the insulating housing is latched to the housing and has posts coaxially aligning the receptacle sections of the electrical contacts with the holes for the pin terminals. The cover member is equipped with a pressure device that exerts pressure on the ferrite bead holding it down against the bottom of the bead-receiving cavity.

摘要翻译： 点火器连接器包括绝缘壳体，其具有在一端开口的胎圈接收腔，在空腔的底壁的中心的隔板，设置在胎圈接收腔中的铁氧体磁珠，以及位于胎圈接收腔的底壁中的孔 用于插入销端子的胎圈容纳腔，插入胎圈接收腔中的铁氧体磁珠，并且当铁氧体磁珠插入到胎圈接收腔中时固定在具有中心开口的铁氧体磁珠的绝缘壳体中， 胎圈容纳腔，具有用于与销端子电连接的插座部分的一对电触点布置在接触容纳空腔中，接触腔设置在插入胎圈接收腔中的隔板和铁氧体磁珠之间，线连接部分用于连接到 电线和封闭绝缘壳体的胎圈容纳腔的盖构件被锁定到壳体并且具有同轴对准 电触点的插座部分与针脚端子的孔。 盖构件配备有压力装置，其对铁氧体磁珠施加压力，铁氧体磁珠将其保持抵靠胎圈接收腔的底部。

公开(公告)号：US06215012B1

公开(公告)日：2001-04-10

申请号：US09657458

申请日：2000-09-07

申请人： Susumu Ueno ,  Toshio Shinohara ,  Mikio Aramata ,  Yoichi Tanifuji ,  Tetsuya Inukai ,  Kazutoshi Fujioka

发明人： Susumu Ueno ,  Toshio Shinohara ,  Mikio Aramata ,  Yoichi Tanifuji ,  Tetsuya Inukai ,  Kazutoshi Fujioka

IPC分类号： C07F716

CPC分类号： C07F7/16

摘要： When oganohalosilanes are prepared by charging a reactor with a contact mass containing a metallic silicon powder and a copper catalyst, and introducing an organohalide-containing gas into the reactor to effect the direct reaction, a metal complex of an organophosphino compound is added to the contact mass. The invention is successful in producing organohalosilanes at a significantly improved production rate without reducing the selectivity of useful silane.

摘要翻译： 当通过向包含金属硅粉末和铜催化剂的接触物质填充反应器并且将含有机卤化物的气体引入反应器以进行直接反应来制备原料卤代硅烷时，将有机膦基化合物的金属络合物加入到接触 质量 本发明成功地以显着提高的生产速率生产有机卤代硅烷，而不降低有用硅烷的选择性。

公开(公告)号：US5466847A

公开(公告)日：1995-11-14

申请号：US330948

申请日：1994-10-28

申请人： Toshio Shinohara ,  Akio Yokoo ,  Muneo Kudo ,  Motoaki Iwabuchi ,  Kazuyuki Matsumura

发明人： Toshio Shinohara ,  Akio Yokoo ,  Muneo Kudo ,  Motoaki Iwabuchi ,  Kazuyuki Matsumura

IPC分类号： C07B61/00 ,  C07F7/21 ,  C07F7/10

CPC分类号： C07F7/21

摘要： A process for preparing hexamethylcyclo-trisilazane by heating octamethylcyclotetra-silazane in the presence of a catalyst such as a Lewis acid or a sulfur compound of the following formula ##STR1## wherein M represents Ca, Mg, Al, Fe or NH.sub.4, R represents OH, a phenyl group or a substituted phenyl group, x is 0, 1 or 2 and y is 0, 1, 2 or 3 provided that x and y are not zero at the same time, and z is 0, 1, 2 or 3.

摘要翻译： 在催化剂如路易斯酸或下式的硫化合物的存在下加热八甲基环四硅氮烷来制备六甲基环三硅氮烷的方法R表示OH，苯基或取代的苯基，x为0 ，1或2，y为0,1,2或3，条件是x和y不同时为零，z为0,1,2或3。

公开(公告)号：US5403947A

公开(公告)日：1995-04-04

申请号：US265885

申请日：1994-06-27

申请人： Toshio Shinohara

发明人： Toshio Shinohara

IPC分类号： B01J23/46 ,  C07B61/00 ,  C07F7/12 ,  C07F7/14 ,  C07F7/08

CPC分类号： C07F7/14

摘要： A method of producing dicyclopentyldichlorosilane which comprises reacting cyclopentene and dichlorosilane with each other by using a platinum catalyst and/or a rhodium catalyst in the presence of 1,3-diethinyl-1,1,3,3-tetramethyldisiloxane.

摘要翻译： 一种二环戊基二氯硅烷的制造方法，其特征在于，在1,3-二乙烯基-1,1,3,3-四甲基二硅氧烷的存在下，使用铂催化剂和/或铑催化剂使环戊烯与二氯硅烷相互反应。

公开(公告)号：US5264601A

公开(公告)日：1993-11-23

申请号：US921250

申请日：1992-07-29

申请人： Toshio Shinohara ,  Muneo Kudo ,  Susumu Ueno ,  Masao Maruyama

发明人： Toshio Shinohara ,  Muneo Kudo ,  Susumu Ueno ,  Masao Maruyama

IPC分类号： C07D277/72 ,  C07D277/74 ,  C07D277/76 ,  C07F7/18 ,  C07F7/10

CPC分类号： C07F7/1852

摘要： N,O-bis(trimethylsilyl)acetamide is improved in thermal stability by adding about 0.01 to 5 mol % of a 2-mercaptobenzothiazole or a salt thereof thereto.

公开(公告)号：US5227504A

公开(公告)日：1993-07-13

申请号：US882898

申请日：1992-05-14

申请人： Toshio Shinohara ,  Muneo Kudo ,  Kazuyuki Matsumura

发明人： Toshio Shinohara ,  Muneo Kudo ,  Kazuyuki Matsumura

IPC分类号： C07F7/02 ,  C07F7/10

CPC分类号： C07F7/10

摘要： A silylating agent comprising an N-(trialkylsilyl)benzanilide having the following general formula: ##STR1## wherein R.sup.1 is a lower alkyl group. This agent is reacted with a secondary amine to produce an N,N-dialkylaminotrialkylsilane. This process is free of formation of amine hydrochlorides as by-products. Therefore, the problem associated with disposal of such amine hydrochlorides and the problem of limitations on the use of the silane compound product due to mixing of such amine hydrochlorides can be obviated effectively.

摘要翻译： 甲硅烷基化剂，其包含具有以下通式的N-（三烷基甲硅烷基）-N-苯甲酰苯胺：其中R 1是低级烷基。 该试剂与仲胺反应以产生N，N-二烷基氨基三烷基硅烷。 该方法没有形成作为副产物的胺盐酸盐。 因此，与这种胺盐酸盐的处理相关的问题以及由于这种胺盐酸盐的混合而使用硅烷化合物产品的问题的问题可以有效地被消除。

公开(公告)号：US5136073A

公开(公告)日：1992-08-04

申请号：US796360

申请日：1991-11-22

申请人： Toshio Shinohara ,  Muneo Kudo ,  Motoaki Iwabuchi

发明人： Toshio Shinohara ,  Muneo Kudo ,  Motoaki Iwabuchi

IPC分类号： C07F7/18

CPC分类号： C07F7/1836

摘要： Several thexyl trialkoxy silanes as a novel class of organosilicon compounds were synthesized by the reaction of dehydrochlorination condensation between thexyl trichlorosilane and an alcohol, e.g., methyl, ethyl, isopropyl and isobutyl alcohols, and characterized by the analytical data. These compounds are useful as an intermediate in the synthetic preparation of other organosilicon compounds, starting material of various silicones, surface-treatment agent of inorganic materials and additive in complex catalysts.

公开(公告)号：US4811226A

公开(公告)日：1989-03-07

申请号：US139121

申请日：1987-12-23

申请人： Toshio Shinohara

发明人： Toshio Shinohara

IPC分类号： B60N2/02 ,  B60R1/07 ,  G05B19/35 ,  G06F15/20

CPC分类号： G05B19/351 ,  B60N2/0232 ,  B60N2/0252 ,  B60R1/07 ,  B60N2002/0268 ,  G05B2219/36463 ,  G05B2219/37175 ,  G05B2219/37462 ,  G05B2219/42187 ,  G05B2219/45022 ,  G05B2219/45185

摘要： An automatic angle adjusting apparatus for adjusting vehicle equipments to be adjusted to optimum angular positions to a driver such as a fender mirror, an inner mirror, blowing ports of an air conditioner, a speaker and a meter is disclosed. Amounts of adjustment of vehicle seat parts are detected by amounts of adjustment detectors and the optimum angles of the vehicle equipments, a height of the driver or an eye position of the driver are calculated based on the detection signals to automatically adjust the vehicle equipments to the optimum angular position. When the height or the eye position of the driver is calculated, the optimum angles are further calculated based on the calculated height or eye position.

摘要翻译： 公开了一种自动角度调节装置，用于将车辆设备调整为适合于诸如翼子板反射镜，内反射镜，空调吹风口，扬声器和仪表之类的驾驶员的最佳角度位置。 通过调节检测器的量来检测车辆座椅部件的调整量，并且基于检测信号计算车辆设备的最佳角度，驾驶员的高度或驾驶员的眼睛位置，以将车辆设备自动调整为 最佳角度位置。 当计算驾驶员的高度或眼睛位置时，根据计算的高度或眼睛位置进一步计算最佳角度。

公开(公告)号：US4659852A

公开(公告)日：1987-04-21

申请号：US909101

申请日：1986-09-18

申请人： Toshio Shinohara ,  Masahiko Ogawa ,  Akio Yokoo

发明人： Toshio Shinohara ,  Masahiko Ogawa ,  Akio Yokoo

IPC分类号： C07F7/12 ,  C08G77/04 ,  C07F7/08

CPC分类号： C07F7/12 ,  C08G77/04

摘要： The inventive compound 4-chloromethylphenyl methyl dichlorosilane is a novel compound not known in the prior art. The silane compound can readily be prepared by the chlorination of 4-tolyl methyl dichlorosilane with sulfuryl chloride as the chlorinating agent. The novel silane compound is useful as a component of an organochlorosilane mixture as the starting material of various kinds of silicone products or, in particular, silicone resins capable of exhibiting high performance, e.g. sensitivity for radiation-induced curing, not obtained by any combinations of known organochlorosilanes.

摘要翻译： 本发明化合物4-氯甲基苯基甲基二氯硅烷是现有技术中未知的新型化合物。 硅烷化合物可以容易地通过用磺酰氯作为氯化剂氯化4-甲苯基甲基二氯硅烷来制备。 新型硅烷化合物可用作有机氯硅烷混合物的组分，作为各种有机硅产品的起始原料，特别是可显示高性能的有机硅树脂，例如硅氧烷。 辐射诱导的固化的敏感性，不是通过已知有机氯硅烷的任何组合获得的。