摘要:
N,O-bis(trimethylsilyl)acetamide is improved in thermal stability by adding about 0.01 to 5 mol % of a 2-mercaptobenzothiazole or a salt thereof thereto.
摘要:
Highly pure diethylaminotrimethylsilane can be manufactured in a high yield through the reaction between diethylamine and an N,O-bis(trimethylsilyl)acetamide represented by the following general formula: ##STR1## wherein X represents H or F.
摘要:
A process for preparing hexamethylcyclo-trisilazane by heating octamethylcyclotetra-silazane in the presence of a catalyst such as a Lewis acid or a sulfur compound of the following formula ##STR1## wherein M represents Ca, Mg, Al, Fe or NH.sub.4, R represents OH, a phenyl group or a substituted phenyl group, x is 0, 1 or 2 and y is 0, 1, 2 or 3 provided that x and y are not zero at the same time, and z is 0, 1, 2 or 3.
摘要:
A silylating agent comprising an N-(trialkylsilyl)benzanilide having the following general formula: ##STR1## wherein R.sup.1 is a lower alkyl group. This agent is reacted with a secondary amine to produce an N,N-dialkylaminotrialkylsilane. This process is free of formation of amine hydrochlorides as by-products. Therefore, the problem associated with disposal of such amine hydrochlorides and the problem of limitations on the use of the silane compound product due to mixing of such amine hydrochlorides can be obviated effectively.
摘要:
Several thexyl trialkoxy silanes as a novel class of organosilicon compounds were synthesized by the reaction of dehydrochlorination condensation between thexyl trichlorosilane and an alcohol, e.g., methyl, ethyl, isopropyl and isobutyl alcohols, and characterized by the analytical data. These compounds are useful as an intermediate in the synthetic preparation of other organosilicon compounds, starting material of various silicones, surface-treatment agent of inorganic materials and additive in complex catalysts.
摘要:
Hexamethylcyclotrisilazane is prepared by reacting dimethyldichlorosilane with ammonia at a temperature between -20.degree. C. and 20.degree. C. Preferably, ammonia is blown into dimethyldichlorosilane at the temperature, and the reaction mixture is washed with 20% or higher alkaline water within one hour from the end of reaction for removing ammonium chloride by dissolving it in the water. Then hexamethylcyclotrisilazane of high purity is prepared in high yields. The method can be scaled up for commercial manufacture.
摘要:
A coating composition primarily comprising a disilane compound of the formula (A): XmR13-mSi—Y—SiR13-mXm (A) wherein R1 is a monovalent hydrocarbon group, Y is a divalent fluorinated organo group, X is a hydrolyzable group, and m is 1, 2 or 3, or a (partial) hydrolyzate thereof is applied and cured to form a protective coat having excellent chemical resistance and antireflection.
摘要:
A coating composition comprising the reaction product of a benzotriazole compound having a polymerizable vinyl group and a hydroxyl group with a silane compound and/or a (partial) hydrolyzate thereof is applied to plastic substrates, typically polycarbonate resin substrates to form transparent coatings having improved mar, weather and chemical resistance.
摘要:
An aqueous coating composition including (A) an amino group-containing organopolysiloxane, (B) water and (C) at least one of a surface-active agent represented by the general formula (I): wherein R1 to R4are a C1-C8 alkyl group, R5 and R6 are a C1-C6 alkylene group, R7 and R8 are selected from a hydrogen atom, a C1-C6 alkyl group and a C2-C6 acyl group, and m and n are an integer of 0 to 40, provided that m and n are not 0 at the same time and that of m+n ranges from 1 to 40 on the average; and a nonionic surface-active agent containing a perfluoroalkyl group and an alkylene oxide group. In the composition, (C) is present in a content of 0.01% to 5% by weight based on the total of (A), (B) and (C), and an alcohol is present in an amount not more than 10% by weight of the composition. The aqueous coating composition has superior uniform-coating properties and storage stability.
摘要:
A composition comprising (1) 0.1-50 parts by weight of the reaction product of a hydroxyl group-containing benzophenone compound with a silane and/or a hydrolyzate thereof and (2) 100 parts by weight of a silane compound and/or a hydrolyzate thereof is applied to a polycarbonate sheet to form a protective coating having mar and weather resistance. A composition comprising the reaction product of a hydroxyl group-containing benzophenone compound with a silane and/or a hydrolyzate thereof is useful for undercoating.