摘要:
A mixture of aromatic hydrocarbons, comprising xylenes, is isomerized in the presence of ZSM-22 zeolite to produce a product stream wherein the proportion of para-xylene is substantially equal to the equilibrium ratio of the para-isomer. The process is conducted at about 500.degree. F. to about 1100.degree. F., at about 0 to about 3000 psig, optionally in the presence of hydrogen, and also optionally with the catalyst comprising about 0.005% to about 5.0% of a metal, e.g., platinum, palladium or cobalt, based on total catalyst weight.
摘要:
Disclosed is a zeolite base catalyst useful particularly for the selective production of para-dialkylsubstituted benzene. The catalyst comprises a porous crystalline zeolite having silica deposited thereon and having incorporated therein phosphorous. Described also in the process for making the catalyst and the parameters for the use of the catalyst in dialkylation processes.
摘要:
A catalytic process is provided for isomerizing an isomerization feed containing an aromatic C.sub.8 mixture of ethylbenzene and xylene in which the para-xylene content is less than equilibrium which comprises contacting said feed, under conversion conditions, with a catalyst comprising a crystalline aluminosilicate zeolite having a crystal size of at least about 1 micron, a silica to alumina ratio of at least about 12 and a constraint index, as hereinafter defined, within the approximate range of 1 to 12 to yield an isomerization product characterized by a reduced ethylbenzene content and an enhanced para-xylene content.
摘要:
A process is provided for alkylation or transalkylation of aromatic hydrocarbons by contacting same with an alkylating or transalkylating agent in a reaction zone maintained under alkylation/transalkylation effective conditions and in the presence of a catalyst comprising a crystalline aluminosilicate zeolite characterized by a unique X-ray diffraction pattern, said catalyst under said conditions being capable of affording a high and selective yield of desired alkylaromatic product while maintaining excellent aging properties.
摘要:
Zeolitic Imidazolate Frameworks (ZIFs) characterized by organic ligands consisting of imidazole ligands that are either essentially all 2-chloroimidazole ligands or essentially all 2-bromoimidazole ligands are disclosed. Methods for separating propane and propene with the ZIFs of the present invention, as well as other ZIFs, are also disclosed.
摘要:
Zeolitic Imidazolate Frameworks (ZIFs) characterized by organic ligands consisting of imidazole ligands that are either essentially all 2-chloroimidazole ligands or essentially all 2-bromoimidazole ligands are disclosed. Methods for separating propane and propene with the ZIFs of the present invention, as well as other ZIFs, are also disclosed.
摘要:
The present invention is related to a method for kinetically separating a light hydrocarbon mixture comprising at least two components by preferentially adsorbing a first component on a zeolite adsorbent comprising 8-member rings of tetrahedra as the pore opening controlling hydrocarbon diffusion and alkali metal cations balancing a framework charge, wherein a second component is not preferentially adsorbed. The novel process comprises contacting the light hydrocarbon mixture with a zeolite adsorbent having a SiO2/Al2O3 ratio greater than about 50 and less than 200 and further having a diffusion rate at least 50 times greater for the first component as compared to the second component, and then recovering at least one of the first component or the second component.
摘要翻译:本发明涉及一种用于动态分离含有至少两种组分的轻质烃混合物的方法,该轻质烃混合物优先吸附在包含八元环四面体的沸石吸附剂上的第一组分,作为开孔控制烃扩散和碱金属阳离子平衡 框架电荷,其中第二组分不被优先吸附。 该新方法包括使轻质烃混合物与沸石吸附剂接触,所述沸石吸附剂具有大于约50或更小的SiO 2 / Al 2 O 3 并且与第二组分相比,第一组分的扩散速率至少为50倍,然后回收第一组分或第二组分中的至少一种。
摘要:
A method of selectively adsorbing propylene in mixtures of propylene/propane and propylene/olefins through the use of zeolites having structures with a maximum of 8-member rings of tetraheda controlling the diffusion rate. Suitable zeolite adsorbents are those having the CHA and ITE structure types. Other 8-member ring zeolites, including aluminosilicates, with a Si:Al molar ratio of at least about 200 and having substantially no free acid are also suitable adsorbents.
摘要:
An electronic accessory assembly to be used with a host electronic instrument provides previously recorded data from a non-volatile memory as to the accessory's operational capabilities. This memory is accessed by a host device either when the host device is powered up, or when an new accessory is connected to the host device. The host device then uses this information along with the operational requirements of the user to set the operational parameters of the accessory/host combination to optimally perform the functions required by the user.
摘要:
A process is provided for converting feedstock aromatic compounds by alkylation, transalkylation, disproportionation and/or isomerization over a catalyst comprising zeolite ZSM-58.