公开(公告)号：US11322801B2

公开(公告)日：2022-05-03

申请号：US16785738

申请日：2020-02-10

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Helmi Alkordi ,  Mohamed Eddaoudi

IPC: H01M4/13 ,  H01M50/46 ,  H01M4/50 ,  H01M50/411 ,  H01M50/403

Abstract: Provided herein are nanostructured electrode separators comprising metal organic materials capable of attaching to one or more electrodes and electrically insulating at least one electrode while allowing migration of ionic charge carriers through the nanostructured electrode separator. Methods of using such electrode separators include positioning a nanostructured electrode separator between two electrodes of an electrochemical cell.

公开(公告)号：US11229872B2

公开(公告)日：2022-01-25

申请号：US16903820

申请日：2020-06-17

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Infas Haja Mohideen ,  Karim Adil ,  Youssef Belmabkhout ,  Mohamed Eddaoudi ,  Prashant M. Bhatt

IPC: B01D53/04 ,  B01D53/047 ,  B01J20/28 ,  B01J20/22 ,  B01J20/30 ,  C07C45/78 ,  B01D53/02

Abstract: Embodiments of the present disclosure include a metal-organic framework (MOF) composition comprising one or more metal ions, a plurality of organic ligands, and a solvent, wherein the one or more metal ions associate with the plurality of organic ligands sufficient to form a MOF with kag topology. Embodiments of the present disclosure further include a method of making a MOF composition comprising contacting one or more metal ions with a plurality of organic ligands in the presence of a solvent, sufficient to form a MOF with kag topology, wherein the solvent comprises water only. Embodiments of the present disclosure also describe a method of capturing chemical species from a fluid composition comprising contacting a MOF composition with kag topology and pore size of about 3.4 Å to 4.8 Å with a fluid composition comprising two or more chemical species and capturing one or more captured chemical species from the fluid composition.

公开(公告)号：US10903019B2

公开(公告)日：2021-01-26

申请号：US16471812

申请日：2017-12-29

Applicant: King Abdullah University of Science and Technology

Inventor： Arijit Mallick ,  Bilal Ahmed ,  Osama Shekhah ,  Husam N. Alshareef ,  Mohamed Eddaoudi

IPC: H01G11/30 ,  C07D471/06 ,  C07F7/00 ,  H01G11/86

Abstract: Embodiments of the present disclosure describe an electrode material comprising a metal ion cluster and an organic linker with a redox-active center associated with the metal ion cluster sufficient to form a metal-organic framework. Embodiments of the present disclosure further describe a method of forming an electrode material comprising contacting a metal ion cluster with an organic linker including a redox-active center sufficient to form a metal-organic framework. Embodiments of the present disclosure also describe a metal-organic framework composition comprising a metal ion cluster and an organic linker with a redox-active center associated with the metal ion cluster.

公开(公告)号：US10781387B2

公开(公告)日：2020-09-22

申请号：US15506331

申请日：2015-08-25

Applicant: King Abdullah University of Science and Technology ,  Saudi Arabian Oil Company

Inventor： Mohamed Eddaoudi ,  Youssef Belmabkhout

IPC: B01D53/72 ,  B01D53/02 ,  B01D53/14 ,  B01D53/44 ,  B01D53/52 ,  B01D53/62 ,  B01D53/80 ,  B01D53/81 ,  B01D53/96 ,  C10L3/06 ,  C10L3/10 ,  B01J31/16 ,  B01J20/22 ,  B01J20/28 ,  B01D53/04

Abstract: Embodiments provide a method of compound removal from a fluid. The method includes contacting one or more metal organic framework (MOF) compositions with a fluid and sorbing one or more compounds, such as CO2, H2S and condensable hydrocarbons. One or more of CO2, H2S and condensable hydrocarbons can be sorbed simultaneously or in series. The metal organic framework can be an M-soc-MOF.

公开(公告)号：US10759724B2

公开(公告)日：2020-09-01

申请号：US15952511

申请日：2018-04-13

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Youssef Belmabkhout ,  Mohamed Infas Haja Mohideen ,  Karim Adil ,  Prashant M. Bhatt ,  Osama Shekhah ,  Valeriya Chernikova

IPC: C07C7/13 ,  B01J20/02 ,  B01J20/04 ,  B01J20/22 ,  B01J20/28 ,  B01J31/16

Abstract: Embodiments of the present disclosure describe a zeolite-like metal-organic framework composition comprising a metal-organic framework composition with ana topology characterized by the formula [MIII(4, 5-imidazole dicarboxylic acid)2X(solvent)a]n wherein MIII comprises a trivalent cation of a rare earth element, X comprises an alkali metal element or alkaline earth metal element, and solvent comprises a guest molecule occupying pores. Embodiments of the present disclosure describe a method of separating paraffins comprising contacting a zeolite-like metal-organic framework with ana topology with a flow of paraffins, and separating the paraffins by size.

公开(公告)号：US10559801B2

公开(公告)日：2020-02-11

申请号：US15852231

申请日：2017-12-22

Applicant: KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGY

Inventor： Mohamed Helmi Alkordi ,  Mohamed Eddaoudi

IPC: H01M4/13 ,  H01M2/16 ,  H01M4/50 ,  H01M2/14

Abstract: Provided herein are nano structured electrode separators comprising metal organic materials capable of attaching to one or more electrodes and electrically insulating at least one electrode while allowing migration of ionic charge carriers through the nanostructured electrode separator. Methods of using such electrode separators include positioning a nanostructured electrode separator between two electrodes of an electrochemical cell.

公开(公告)号：US10414781B2

公开(公告)日：2019-09-17

申请号：US15766413

申请日：2016-10-06

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Rasha Abdulhalim ,  Youssef Belmabkhout

IPC: C07F5/00 ,  B01D53/14 ,  B01D53/26 ,  B01D53/28 ,  B01J20/22 ,  C02F1/28 ,  F25B17/08 ,  B01D53/02 ,  C02F103/08

Abstract: A method for preparing a metal-organic framework (MOF) comprising contacting one or more of a rare earth metal ion component with one or more of a tetratopic ligand component, sufficient to form a rare earth-based MOF for controlling moisture in an environment. A method of moisture control in an environment comprising adsorbing and/or desorbing water vapor in an environment using a MOF, the MOF including one or more of a rare earth metal ion component and one or more of a tetratopic ligand component. A method of controlling moisture in an environment comprising sensing the relative humidity in the environment comprising a MOF; and adsorbing water vapor on the MOF if the relative humidity is above a first level, sufficient to control moisture in an environment. The examples relate to a MOF created from 1,2,4,5-Tetrakis(4-carboxyphenyl)benzene (BTEB) as tetratopic ligand, 2-fluorobenzoic acid and Y(NO3)3, Tb(NO3)3 and Yb(NO3)3 as rare earth metals.

公开(公告)号：US10364718B2

公开(公告)日：2019-07-30

申请号：US15509780

申请日：2015-09-11

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Youssef Belmabkhout ,  Osama Shekhah

IPC: B01D53/02 ,  F01N3/08 ,  B01J20/22 ,  F01N3/022

Abstract: In general, this disclosure describes method of capturing and storing CO2 on a vehicle. The method includes contacting an vehicle exhaust gas with one or more of a first metal organic framework (MOF) composition sufficient to separate CO2 from the exhaust gas, contacting the separated CO2 with one or more of a second MOF composition sufficient to store the CO2 and wherein the one or more first MOF composition comprises one or more SIFSIX-n-M MOF and wherein M is a metal and n is 2 or 3. Embodiments also describe an apparatus or system for capturing and storing CO2 onboard a vehicle.

公开(公告)号：US10328380B2

公开(公告)日：2019-06-25

申请号：US15564935

申请日：2016-04-07

Applicant: King Abdullah University of Science and Technology ,  SAUDI ARABIAN OIL COMPANY

Inventor： Mohamed Eddaoudi ,  Amandine Cadiau ,  Prashant M. Bhatt ,  Karim Adil ,  Youssef Belmabkhout

IPC: B01D53/02 ,  B01D53/52 ,  B01D53/62 ,  B01D53/72 ,  B01D53/80 ,  B01D53/81 ,  B01D53/96 ,  B01J31/16 ,  B01J20/22 ,  B01J20/28 ,  B01J20/34 ,  C07F5/06 ,  C07F9/00 ,  C07F15/02 ,  C07F15/04

Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Methods include capturing one or more of H2S, H2O, and CO2 from fluid compositions, such as natural gas.

公开(公告)号：US10273209B2

公开(公告)日：2019-04-30

申请号：US15314445

申请日：2015-05-26

Applicant: KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGY ,  Mohamed Eddaoudi ,  Dongxu Xue ,  Ryan Luebke ,  Vincent Guillerm ,  Abdul Malik Puthan Peedikakkal ,  Karim Adil ,  Lukasz Weselinski

Inventor： Mohamed Eddaoudi ,  Dongxu Xue ,  Ryan Luebke ,  Vincent Guillerm ,  Abdul Malik Puthan Peedikakkal ,  Karim Adil ,  Lukasz Weselinski

IPC: C07D209/88 ,  B01J20/22 ,  B01J31/16 ,  C07C63/66 ,  C07C65/05 ,  C07C65/11 ,  B01J37/04 ,  B01J37/06 ,  C07D317/36

Abstract: A molecular building block composition can include a metal ion component; and a ligand component including a core including at least one functional group associated with the metal ion component and the core.