公开(公告)号：US4421895A

公开(公告)日：1983-12-20

申请号：US329596

申请日：1981-12-10

申请人： Adolf Echte ,  Hermann Gausepohl ,  Karl Gerberding

发明人： Adolf Echte ,  Hermann Gausepohl ,  Karl Gerberding

IPC分类号： C08F2/06 ,  C08F279/02 ,  C08F279/04 ,  C08F287/00 ,  C08F291/02

CPC分类号： C08F291/02 ,  C08F279/02 ,  C08F279/04 ,  C08F287/00

摘要： A process for making ABS polymer particles comprising continuous polymerization of a mixture of at least one of each of (a) an aromatic vinyl monomer, and (b) an ethylenically unsaturated monomer in a weight ratio of (a):(b) of 90:10 to 10:90 in the presence of at least one of each of (c) a rubber-like polymer in an amount of 3 to 35 percent by weight relative to the total weight of the monomers (a) and (b), (d) a solvent, (e) a radical initiator and (f) an optional chain transfer agent. The process is carried out at temperatures between 80.degree. C. to 180.degree. C. in two or more reaction zones while the reaction mixture is stirred and while the monomers and solvents are removed in a degassing zone. The rubber-like polymer (c) has a solution viscosity of less than 80 mPa.s and a ratio of the solution viscosity of (c) to a percent of solvent expressed by 100[(d)/(a+b+c+d)] equal to or less than 2.5 mPa.s/percent of solvent.

摘要翻译： 制备ABS聚合物颗粒的方法，包括（a）芳族乙烯基单体和（b）烯属不饱和单体中的至少一种（a）：（b）为90的混合物的混合物的连续聚合 在（c）相对于单体（a）和（b）的总重量为3〜35重量％的量的橡胶状聚合物中的至少一种存在下，10〜10:90， （d）溶剂，（e）自由基引发剂和（f）任选的链转移剂。 该方法在两个或更多个反应区中在80℃至180℃的温度下进行，同时搅拌反应混合物，同时在脱气区中除去单体和溶剂。 橡胶状聚合物（c）的溶液粘度小于80mPa.s，溶液粘度（c）与溶剂百分比的比例由100 [（d）/（a + b + c + d）]等于或小于2.5mPa.s /％的溶剂。

公开(公告)号：US3954722A

公开(公告)日：1976-05-04

申请号：US500517

申请日：1974-08-26

申请人： Adolf Echte ,  Johann Zizlsperger ,  Ernst Tetzlaff ,  Rudi Wilhelm Reffert

发明人： Adolf Echte ,  Johann Zizlsperger ,  Ernst Tetzlaff ,  Rudi Wilhelm Reffert

IPC分类号： C08F2/00 ,  C08F2/02 ,  C08F2/04 ,  C08F2/06

CPC分类号： C08F2/04 ,  C08F2/02

摘要： A continuous process for the polymerisation of olefinically unsaturated monomers in bulk or in solution in which at least a portion of the low-viscosity materials to be fed to the polymerization zone is thoroughly mixed with a portion of the high-viscosity contents of the polymerization zone in a mixing zone disposed upstream of the polymerization zone, which mixture is then continuously fed to the polymerization zone. The resulting polymers have a uniform composition and a narrow molecular weight distribution. They may be converted to shaped articles by thermoplastic methods.

摘要翻译： 用于在本体或溶液中聚合烯属不饱和单体的连续方法，其中将要进料到聚合区的至少一部分低粘度物质与聚合区的高粘度含量的一部分充分混合 在设置在聚合区上游的混合区中，然后将该混合物连续地进料至聚合区。 所得聚合物具有均匀的组成和窄的分子量分布。 它们可以通过热塑性方法转化成成型制品。

公开(公告)号：US5116907A

公开(公告)日：1992-05-26

申请号：US589276

申请日：1990-09-28

申请人： Ehrenfried Baumgartner ,  Adolf Echte ,  Juergen Mertes

发明人： Ehrenfried Baumgartner ,  Adolf Echte ,  Juergen Mertes

IPC分类号： C08F212/10 ,  C08F20/52 ,  C08F212/00 ,  C08F212/08 ,  C08F220/42 ,  C08F220/44 ,  C08F220/54 ,  C08F220/56

CPC分类号： C08F212/08 ,  C08F220/54

摘要： A molding material is described which contains, in each based on the sum of A, B and C,A. from 5 to 95, in particular from 20 to 80, % by weight of a copolymer comprisinga) from 1 to 95% by weight of styrene,b) not more than 40% by weight of acrylonitrile andc) from 5 to 98% by weight of an amide of methacrylic acid of the formula I ##STR1## where R is primary, secondary or tertiary alkyl, cycloalkyl, aryl or aralkyl of 1 or 6 or 7, respectively, to 12 carbon atoms, with the proviso that, when alkyl is methyl or isopropyl, the copolymer has a styrene content of less than 75% by weight,B. from 5 to 60, in particular from 10 to 40, % by weight of a graft polymer B, prepared by emulsion polymerization of a mixture of styrene and acrylonitrile in the weight ratio from 60:40 to 90:10 in the presence of, based on the amount of expected copolymer, from 40 to 80, in particular from 50 to 70, % by weight of a conventional particulate, partially crosslinked diene rubber or acrylate rubber, andC. Not more than 90, in particular from 10 to 40, % by weight of a further thermoplastic resin C.

摘要翻译： 描述了一种成型材料，其各自基于A，B和C的总和，A为5至95，特别是20至80，共聚物的重量％包含a）1至95％ 苯乙烯的重量，b）不大于40重量％的丙烯腈和c）5至98重量％的式I的甲基丙烯酸酰胺其中R是伯，仲或叔烷基 1或6或7的环烷基，芳基或芳烷基分别为12个碳原子，条件是当烷基为甲基或异丙基时，该共聚物的苯乙烯含量小于75重量％，B为5 至60重量％，特别是10至40重量％的接枝聚合物B，其通过以60:40至90:10的重量比以苯乙烯和丙烯腈的混合物的乳液聚合制备，基于 预期的共聚物的量，40至80，特别是50至70重量％的常规颗粒部分交联的二烯橡胶或丙烯酸酯橡胶 r和C.不大于90，特别是10至40，另外的热塑性树脂C的重量％

公开(公告)号：US4493922A

公开(公告)日：1985-01-15

申请号：US573853

申请日：1984-01-25

申请人： Adolf Echte ,  Hermann Gausepohl

发明人： Adolf Echte ,  Hermann Gausepohl

IPC分类号： C08L51/04 ,  C08L55/02 ,  C08L53/02

CPC分类号： C08L51/04 ,  Y10S525/901

摘要： An impact-resistant thermoplastic molding material, containing polystyrene as the matrix, and, dispersed therein, two elastomeric polymers or copolymers I and II composed entirely or predominantly of 1,3-dienes and containing particles of different mean size, namely, in I, particles from 0.2 to 0.6 .mu.m in size and having capsule particle morphology, and, in II, particles from 2 to 8 .mu.m in size, having cell particle or coil particle morphology.

摘要翻译： 一种抗冲击热塑性成型材料，其包含聚苯乙烯作为基体，并分散在其中，两个完全或主要由1,3-二烯构成并含有不同平均尺寸的颗粒的弹性聚合物或共聚物I和II，即I， 颗粒尺寸为0.2至0.6微米，具有胶囊颗粒形态，II型颗粒尺寸为2至8微米，具有细胞颗粒或线粒体形态。

公开(公告)号：US4427826A

公开(公告)日：1984-01-24

申请号：US273689

申请日：1981-06-15

申请人： Adolf Echte ,  Hermann Gausepohl ,  Hermann P. Hofmann ,  Hans Mittnacht

发明人： Adolf Echte ,  Hermann Gausepohl ,  Hermann P. Hofmann ,  Hans Mittnacht

IPC分类号： C08F2/38 ,  C08F4/00 ,  C08F279/02

CPC分类号： C08F279/02

摘要： A process, carried out without a diluent or in solution, in more than 2 reaction zones, for the continuous preparation of rubber-modified polymers of vinylaromatics, wherein a monomeric aromatic vinyl compound and an elastomeric polymer, in an amount of from 3 to 16% by weight based on the monomer, are polymerized, in the absence of a free radical initiator, but in the presence of a mercaptan as a chain transfer agent, at from 80.degree. to 180.degree. C. in a first reaction zone, with stirring, up to a maximum monomer conversion, U.sub.max, given by the equationU.sub.max =K-1where K is the amount of rubber in % by weight based on monomer, and, in a second reaction zone, polymerization is continued, with stirring, to a conversion of up to about 50% by weight, after which a chain transfer agent is introduced in an amount of from 0.01 to 0.2% by weight, based on vinyl-aromatic monomer, and polymerization is continued, if appropriate in more than one reaction zone, up to a monomer conversion of less than 85% by weight. The polymer is treated in a devolatilization zone to remove vinyl-aromatic monomer and solvent, if any, and these constituents are recycled to the process. The process produces products which exhibit good gloss coupled with good mechanical properties, and which can be employed for conventional applications.

摘要翻译： 用于连续制备乙烯基芳族化合物的橡胶改性聚合物的方法，其中没有稀释剂或在溶液中，在多于2个反应区中进行，其中单体芳族乙烯基化合物和弹性体聚合物的量为3-16 基于单体的重量％在不存在自由基引发剂的情况下，在作为链转移剂的硫醇存在下，在第一反应区中在80-180℃下进行聚合，同时搅拌 ，达到最大单体转化率，Umax，由方程式Umax = K-1给出，其中K是基于单体的以重量％计的橡胶量，并且在第二反应区中，在搅拌下继续聚合至 高达约50重量％的转化率，之后以基于乙烯基芳族单体的0.01至0.2重量％的量引入链转移剂，并且如果适当的话在多于一个反应中继续聚合 区域，单体转化率小于 85重量％。 将聚合物在脱挥发区进行处理以除去乙烯基芳族单体和溶剂（如果有的话），并将这些组分再循环到该方法中。 该方法产生具有良好光泽性和良好机械性能的产品，并且其可用于常规应用。

公开(公告)号：US4065532A

公开(公告)日：1977-12-27

申请号：US564618

申请日：1975-04-03

申请人： Hans Wild ,  Guenter Jeckel ,  Adolf Echte ,  Johann Zizlsperger ,  Rudi Wilhelm Reffert ,  Gunter Thielen

发明人： Hans Wild ,  Guenter Jeckel ,  Adolf Echte ,  Johann Zizlsperger ,  Rudi Wilhelm Reffert ,  Gunter Thielen

IPC分类号： B29C31/00 ,  B29B7/00 ,  B29B9/00 ,  B29C31/02 ,  B29C47/00 ,  B29C47/10 ,  B29C47/76 ,  B29B1/04 ,  B29B1/10

CPC分类号： B29C47/76 ,  B29C47/1063 ,  B29C47/0009 ,  B29C47/762 ,  B29K2105/0005 ,  Y10S425/812

摘要： A process for admixing additives to plastics and simultaneously removing volatile constituents in a horizontal devolatilizing extruder. Taken in sequence in the direction of flow, the additives are first introduced into the devolatilizing extruder from above, and the plastic melt, solution or dispersion is then introduced from below, while the bulk of the volatile constituents are withdrawn from the devolatilizing extruder at an orifice located vertically above the point at which the plastic is fed in. The process permits the removal of volatile constituents with simultaneous admixture of additives during aftertreatment of plastics, in a single step and at very high throughputs.

摘要翻译： 将添加剂与塑料混合并同时除去挥发性成分的方法。 在流动方向上依次进行，首先从上方将添加剂引入脱挥发分挤出机中，然后从下方引入塑料熔体，溶液或分散体，同时将大部分挥发性成分从脱挥发分挤出机中取出， 孔位于垂直于塑料进料点的位置。该方法允许在一个步骤中以非常高的通量在塑料后处理中同时添加添加剂的同时除去挥发性成分。

公开(公告)号：US4061858A

公开(公告)日：1977-12-06

申请号：US703955

申请日：1976-07-09

申请人： Hans Wild ,  Rudolf Jung ,  Adolf Echte ,  Johann Zizlsperger ,  Hermann Gausepohl

发明人： Hans Wild ,  Rudolf Jung ,  Adolf Echte ,  Johann Zizlsperger ,  Hermann Gausepohl

IPC分类号： C08F6/00 ,  C08F6/02 ,  C08F20/44 ,  C07C121/30

CPC分类号： C07C253/34

摘要： Acrylonitrile or monomer mixtures containing acrylonitrile are purified by treating them with alkaline reacting compounds followed by distillation. The products are particularly suitable for the manufacture of acrylonitrile polymers showing improved color stability.

摘要翻译： 通过用碱性反应化合物处理丙烯腈或丙烯腈的单体混合物，然后蒸馏纯化。 该产品特别适用于制备显示改进的颜色稳定性的丙烯腈聚合物。

公开(公告)号：US5011871A

公开(公告)日：1991-04-30

申请号：US323753

申请日：1989-03-15

申请人： Rainer Bueschl ,  Adolf Echte ,  Konrad Schulte ,  Hans Mittnacht

发明人： Rainer Bueschl ,  Adolf Echte ,  Konrad Schulte ,  Hans Mittnacht

IPC分类号： C08F279/02

CPC分类号： C08F279/02

摘要： An impact resistance thermoplastic molding composition contains, each percentage being based on A+B, from 80 to 55% by weight of a hard matrix A of a copolymer containing at least 95% by weight of an aromatic vinyl monomer a.sub.11 of from 8 to 10 carbon atoms and at least one comonomer a.sub.12 in a proportion of 0.1 to 5% by weight, based on A, and from 45 to 20% by weight of a soft phase B which, uniformly dispersed in the hard matrix, has an average particle diameter d.sub.50 (volume average) of from 3.5 to 9 .mu.m and is obtainable by polymerization of the mixture of monomers a.sub.11 and a.sub.12 in the presence of an elastomer (rubber) and subsequent isolation of the useful product, wherein the comonomer a.sub.12 has the general formula I ##STR1## where X is --OR.sup.2, --COOR.sup.2 or --CONHR.sup.3,R.sup.1 is hydrogen or methyl andR.sup.2 and R.sup.3 are each alkyl of from 1 or 2 to 10 carbon atoms with at least one OH or epoxy group or at least one other polar group.

摘要翻译： 抗冲击性热塑性成型组合物含有以百分比为基准的A + B，80〜55重量％的含有至少95重量％的芳族乙烯基单体a11为8〜10的共聚物的硬质基质A 碳原子和至少一种共聚单体a 12，其比例为0.1至5重量％，基于A，和45至20重量％的均匀分散在硬质基质中的软相B具有平均粒径 d50（体积平均）为3.5至9μm，可通过在弹性体（橡胶）存在下聚合单体a11和a12的混合物，随后分离有用的产物而获得，其中共聚单体a12具有通式 （I）其中X是-OR2，-COOR2或-CONHR3，R1是氢或甲基，R2和R3各自为具有1或2至10个碳原子的烷基，具有至少一个OH或环氧基团或在 至少另一个极地组。

公开(公告)号：US4985503A

公开(公告)日：1991-01-15

申请号：US338556

申请日：1989-04-14

申请人： Klaus Bronstert ,  Hans Hoenl ,  Adolf Echte ,  Peter Klaerner

发明人： Klaus Bronstert ,  Hans Hoenl ,  Adolf Echte ,  Peter Klaerner

IPC分类号： C08F2/16 ,  C08F2/38 ,  C08F279/02 ,  C08F285/00

CPC分类号： C08F285/00 ,  C08F279/02

摘要： Process for preparing impact-resistant translucent rubber-modified polystyrene by polymerizing compounds of the styrene class in the presence of a rubber containing thiol groups.

摘要翻译： 通过在含硫醇基的橡胶存在下聚合苯乙烯类的化合物制备耐冲击半透明橡胶改性聚苯乙烯的方法。

公开(公告)号：US4952654A

公开(公告)日：1990-08-28

申请号：US324015

申请日：1989-03-16

申请人： Rainer Bueschl ,  Adolf Echte ,  Juergen Mertes

发明人： Rainer Bueschl ,  Adolf Echte ,  Juergen Mertes

IPC分类号： C08F20/52 ,  C08F220/10 ,  C08F220/14 ,  C08F220/54 ,  C08F220/56

CPC分类号： C08F220/14 ,  C08F220/54

摘要： A heat distortion resistant, transparent thermoplastic molding material contains a copolymer of the monomers(a) methyl methacrylate and(b) an N-substituted amide of methacrylic acid.The molding material contains from 5 to 95% by weight of monomer (a) and from 95 to 5% by weight of monomer or monomers (b), the percentages being based on (a)+(b), and furthermore, as monomer (b), and N-substituted amide of the formula ##STR1## where R is a primary, secondary or tertiary alkyl radical, cycloalkyl, aryl or aralkyl of 2 to 12 carbon atoms.The molding material is used for the production of heat distortion resistant moldings or laminates.

摘要翻译： 耐热变形，透明的热塑性成型材料包含单体（a）甲基丙烯酸甲酯和（b）甲基丙烯酸的N-取代酰胺的共聚物。 成型材料含有5至95重量％的单体（a）和95至5重量％的单体或单体（b），其百分比基于（a）+（b），此外，作为单体 （b）和式“IMAGE”的N-取代酰胺，其中R是2至12个碳原子的伯，仲或叔烷基，环烷基，芳基或芳烷基。 成型材料用于生产耐热变形模制品或层压材料。