公开(公告)号：US5011871A

公开(公告)日：1991-04-30

申请号：US323753

申请日：1989-03-15

申请人： Rainer Bueschl ,  Adolf Echte ,  Konrad Schulte ,  Hans Mittnacht

发明人： Rainer Bueschl ,  Adolf Echte ,  Konrad Schulte ,  Hans Mittnacht

IPC分类号： C08F279/02

CPC分类号： C08F279/02

摘要： An impact resistance thermoplastic molding composition contains, each percentage being based on A+B, from 80 to 55% by weight of a hard matrix A of a copolymer containing at least 95% by weight of an aromatic vinyl monomer a.sub.11 of from 8 to 10 carbon atoms and at least one comonomer a.sub.12 in a proportion of 0.1 to 5% by weight, based on A, and from 45 to 20% by weight of a soft phase B which, uniformly dispersed in the hard matrix, has an average particle diameter d.sub.50 (volume average) of from 3.5 to 9 .mu.m and is obtainable by polymerization of the mixture of monomers a.sub.11 and a.sub.12 in the presence of an elastomer (rubber) and subsequent isolation of the useful product, wherein the comonomer a.sub.12 has the general formula I ##STR1## where X is --OR.sup.2, --COOR.sup.2 or --CONHR.sup.3,R.sup.1 is hydrogen or methyl andR.sup.2 and R.sup.3 are each alkyl of from 1 or 2 to 10 carbon atoms with at least one OH or epoxy group or at least one other polar group.

摘要翻译： 抗冲击性热塑性成型组合物含有以百分比为基准的A + B，80〜55重量％的含有至少95重量％的芳族乙烯基单体a11为8〜10的共聚物的硬质基质A 碳原子和至少一种共聚单体a 12，其比例为0.1至5重量％，基于A，和45至20重量％的均匀分散在硬质基质中的软相B具有平均粒径 d50（体积平均）为3.5至9μm，可通过在弹性体（橡胶）存在下聚合单体a11和a12的混合物，随后分离有用的产物而获得，其中共聚单体a12具有通式 （I）其中X是-OR2，-COOR2或-CONHR3，R1是氢或甲基，R2和R3各自为具有1或2至10个碳原子的烷基，具有至少一个OH或环氧基团或在 至少另一个极地组。

公开(公告)号：US4839418A

公开(公告)日：1989-06-13

申请号：US141098

申请日：1988-01-05

申请人： Hans-Dieter Schwaben ,  Adolf Echte ,  Rainer Bueschl ,  Rainer Schlichtmann ,  Peter Klaerner ,  Hubert Kindler

发明人： Hans-Dieter Schwaben ,  Adolf Echte ,  Rainer Bueschl ,  Rainer Schlichtmann ,  Peter Klaerner ,  Hubert Kindler

IPC分类号： C08F287/00 ,  C08L25/06 ,  C08L51/00

CPC分类号： C08F287/00 ,  C08L25/06 ,  C08L51/00

摘要： A thermoplastic molding material contains, in each case based on the molding material comprising A+B,A from 80 to 60% by weight of a hard matrix composed of polystyrene andB from 20 to 40% by weight of a soft phase which is obtainable by polymerization of styrene in the presence of a linear styrene/butadienne block copolymer which has an ill defined transition, contains from 35 to 45% by weight of styrene and from 65 to 55% by weight of butadiene and has a block polystyrene content of from 25 to 35% by weight, the soft phase being uniformly distributed in the hard matrix and having a particle diameter of less than 0.8 .mu.m.The typical features of the said molding material are that the median particle diameter d.sub.50 (volume average of the soft phase B is from 0.25 to 0.38 .mu.m, the width of the particle size distribution, (d.sub.95 14 d.sub.5), is from 0.2 to 0.6 .mu.m, the d.sub.60 value is from 0.26 to 0.40 .mu.m and the d.sub.90 value is from 0.40 to 0.75.

摘要翻译： 在各种情况下，热塑性成型材料基于包含A + B的成型材料，80-60重量％的由聚苯乙烯和B组成的硬质基质的A含有20-40重量％的软相， 在具有不规则转变的线性苯乙烯/丁二烯嵌段共聚物的存在下苯乙烯的聚合包含35-45％（重量）的苯乙烯和65-55％（重量）的丁二烯，并且具有 25〜35重量％，软相均匀分布在硬质基质中，粒径小于0.8μm。 所述成型材料的典型特征是中值粒径d50（软相B的体积平均值为0.25至0.38μm，粒度分布的宽度（d9514d5））为0.2至0.6μm m，d60值为0.26〜0.40μm，d90为0.40〜0.75。

公开(公告)号：US4952654A

公开(公告)日：1990-08-28

申请号：US324015

申请日：1989-03-16

申请人： Rainer Bueschl ,  Adolf Echte ,  Juergen Mertes

发明人： Rainer Bueschl ,  Adolf Echte ,  Juergen Mertes

IPC分类号： C08F20/52 ,  C08F220/10 ,  C08F220/14 ,  C08F220/54 ,  C08F220/56

CPC分类号： C08F220/14 ,  C08F220/54

摘要： A heat distortion resistant, transparent thermoplastic molding material contains a copolymer of the monomers(a) methyl methacrylate and(b) an N-substituted amide of methacrylic acid.The molding material contains from 5 to 95% by weight of monomer (a) and from 95 to 5% by weight of monomer or monomers (b), the percentages being based on (a)+(b), and furthermore, as monomer (b), and N-substituted amide of the formula ##STR1## where R is a primary, secondary or tertiary alkyl radical, cycloalkyl, aryl or aralkyl of 2 to 12 carbon atoms.The molding material is used for the production of heat distortion resistant moldings or laminates.

摘要翻译： 耐热变形，透明的热塑性成型材料包含单体（a）甲基丙烯酸甲酯和（b）甲基丙烯酸的N-取代酰胺的共聚物。 成型材料含有5至95重量％的单体（a）和95至5重量％的单体或单体（b），其百分比基于（a）+（b），此外，作为单体 （b）和式“IMAGE”的N-取代酰胺，其中R是2至12个碳原子的伯，仲或叔烷基，环烷基，芳基或芳烷基。 成型材料用于生产耐热变形模制品或层压材料。

公开(公告)号：US4427826A

公开(公告)日：1984-01-24

申请号：US273689

申请日：1981-06-15

申请人： Adolf Echte ,  Hermann Gausepohl ,  Hermann P. Hofmann ,  Hans Mittnacht

发明人： Adolf Echte ,  Hermann Gausepohl ,  Hermann P. Hofmann ,  Hans Mittnacht

IPC分类号： C08F2/38 ,  C08F4/00 ,  C08F279/02

CPC分类号： C08F279/02

摘要： A process, carried out without a diluent or in solution, in more than 2 reaction zones, for the continuous preparation of rubber-modified polymers of vinylaromatics, wherein a monomeric aromatic vinyl compound and an elastomeric polymer, in an amount of from 3 to 16% by weight based on the monomer, are polymerized, in the absence of a free radical initiator, but in the presence of a mercaptan as a chain transfer agent, at from 80.degree. to 180.degree. C. in a first reaction zone, with stirring, up to a maximum monomer conversion, U.sub.max, given by the equationU.sub.max =K-1where K is the amount of rubber in % by weight based on monomer, and, in a second reaction zone, polymerization is continued, with stirring, to a conversion of up to about 50% by weight, after which a chain transfer agent is introduced in an amount of from 0.01 to 0.2% by weight, based on vinyl-aromatic monomer, and polymerization is continued, if appropriate in more than one reaction zone, up to a monomer conversion of less than 85% by weight. The polymer is treated in a devolatilization zone to remove vinyl-aromatic monomer and solvent, if any, and these constituents are recycled to the process. The process produces products which exhibit good gloss coupled with good mechanical properties, and which can be employed for conventional applications.

摘要翻译： 用于连续制备乙烯基芳族化合物的橡胶改性聚合物的方法，其中没有稀释剂或在溶液中，在多于2个反应区中进行，其中单体芳族乙烯基化合物和弹性体聚合物的量为3-16 基于单体的重量％在不存在自由基引发剂的情况下，在作为链转移剂的硫醇存在下，在第一反应区中在80-180℃下进行聚合，同时搅拌 ，达到最大单体转化率，Umax，由方程式Umax = K-1给出，其中K是基于单体的以重量％计的橡胶量，并且在第二反应区中，在搅拌下继续聚合至 高达约50重量％的转化率，之后以基于乙烯基芳族单体的0.01至0.2重量％的量引入链转移剂，并且如果适当的话在多于一个反应中继续聚合 区域，单体转化率小于 85重量％。 将聚合物在脱挥发区进行处理以除去乙烯基芳族单体和溶剂（如果有的话），并将这些组分再循环到该方法中。 该方法产生具有良好光泽性和良好机械性能的产品，并且其可用于常规应用。

公开(公告)号：US4144204A

公开(公告)日：1979-03-13

申请号：US686367

申请日：1976-05-14

申请人： Hans Mittnacht ,  Adolf Echte ,  Helmut Jenne ,  Manfred Lieb ,  Klaus Bronstert ,  Hansjoerg Adler

发明人： Hans Mittnacht ,  Adolf Echte ,  Helmut Jenne ,  Manfred Lieb ,  Klaus Bronstert ,  Hansjoerg Adler

IPC分类号： C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L25/00 ,  C08L25/10 ,  C08L51/00 ,  C08L51/02 ,  C08L51/04 ,  C08L77/00 ,  C08L101/00 ,  C08L9/00 ,  C08L25/04

CPC分类号： C08L51/04 ,  C08L25/10

摘要： Thermoplastic molding compositions, based on polymers of a monovinyl-aromatic compound which have been modified with rubber to increase their impact strength, which also exhibit increased stress crack resistance.The increased stress crack resistance is achieved if the proportion of the soft component in the polymer which has been modified to increase its impact strength, and the particle size and swelling index of the soft component phase, conform to particular values, and the tensile strength and yield stress of the thermoplastic molding compositions bear a particular ratio to one another.The molding compositions may in particular be used for the manufacture of internal liners of refrigerators and foodstuff packaging containers.

摘要翻译： 基于已经用橡胶改性以提高其冲击强度的单乙烯基 - 芳族化合物的聚合物的热塑性模塑组合物，其也表现出增加的抗应力开裂性。

公开(公告)号：US4330641A

公开(公告)日：1982-05-18

申请号：US204527

申请日：1980-11-06

申请人： Adolf Echte ,  Hermann Gausepohl ,  Helmut Jenne ,  Hans Mittnacht

发明人： Adolf Echte ,  Hermann Gausepohl ,  Helmut Jenne ,  Hans Mittnacht

IPC分类号： C08F255/06 ,  C08F279/02 ,  C08F279/04 ,  C08F279/06

CPC分类号： C08F255/06 ,  C08F279/02

摘要： Thermoplastic molding materials which contain a copolymer which has been made impact-resistant with a rubber. The copolymer is produced by polymerizing a mixture of a monovinyl-aromatic compound and an acrylic acid derivative or methacrylic acid derivative in the presence of a rubber. The folding materials contain a specific proportion of soft component. The diameter of the particles of the soft component, and the swelling index of the soft component, lie within a specific range, and the tensile strength of the molding material is higher than the yield strength.

摘要翻译： 含有已经用橡胶抗冲击的共聚物的热塑性成型材料。 共聚物通过在橡胶存在下聚合单乙烯基 - 芳族化合物和丙烯酸衍生物或甲基丙烯酸衍生物的混合物来制备。 折叠材料含有特定比例的软组分。 软组分的颗粒直径和软组分的溶胀指数在特定范围内，成型材料的拉伸强度高于屈服强度。

公开(公告)号：US4654418A

公开(公告)日：1987-03-31

申请号：US627984

申请日：1984-07-05

申请人： Rosemarie Berger ,  Hermann Dreher ,  Juergen Hambrecht ,  Eduard Heil ,  Rudi W. Reffert ,  Johann Swoboda ,  Adolf Echte ,  Peter Siebel

发明人： Rosemarie Berger ,  Hermann Dreher ,  Juergen Hambrecht ,  Eduard Heil ,  Rudi W. Reffert ,  Johann Swoboda ,  Adolf Echte ,  Peter Siebel

IPC分类号： C08G65/46 ,  C08G65/42

CPC分类号： C08G65/46

摘要： The catalyst is removed in the preparation of high molecular weight polyphenylene ethers from monohydric phenols, which are alkyl-substituted at the two ortho-positions but not at the para-position and may or may not be alkyl-substituted at the meta-position, by an oxidative coupling reaction with oxygen at from 15.degree. to 50.degree. C. in the presence of a catalyst complex obtained from a copper salt and an organic amine, in the presence of from 1 to 20 parts by weight of a solvent per part by weight of the monomeric phenol, and in the presence or absence of an activator, and removal of the metal component of the catalyst from the polyphenylene ether solution with a complex-forming or chelate-forming compound in aqueous solution, in the presence or absence of reducing and stabilizing substances and assistants for accelerating the interphase reactions and for phase separation, by a method in which the continuous removal of the copper catalyst is carried out in one or more mixer-settler stages at a phase volume ratio of the organic phase to the aqueous phase of from 1:0.1 to 1:1.0, preferably from 1:0.4 to 1:0.6.

摘要翻译： 在从一元酚制备高分子量聚苯醚时除去催化剂，该二元酚在两个邻位进行烷基取代，而不是在对位，在间位可以是或不是烷基取代的， 在由铜盐和有机胺获得的催化剂配合物的存在下，在15〜50℃下，与氧气进行氧化偶合反应，每份由1〜20份重量的溶剂 单体苯酚的重量，并且在存在或不存在活化剂的情况下，在存在或不存在复合物形成或螯合形成化合物的情况下，在聚苯醚溶液中除去催化剂的金属组分 减少和稳定物质和辅助剂，用于加速相间反应和相分离，方法是连续除去铜催化剂的方法是在一个或多个混合沉淀器 以有机相与水相的相体积比为1:0.1至1:1.0，优选1:0.4至1:0.6。

公开(公告)号：US4605699A

公开(公告)日：1986-08-12

申请号：US722155

申请日：1985-04-11

申请人： Konrad Mitulla ,  Juergen Hambrecht ,  Adolf Echte ,  Johann Swoboda ,  Peter Siebel ,  Josef Schwaab ,  Herbert Frank

发明人： Konrad Mitulla ,  Juergen Hambrecht ,  Adolf Echte ,  Johann Swoboda ,  Peter Siebel ,  Josef Schwaab ,  Herbert Frank

IPC分类号： C08L51/00 ,  C08L69/00

CPC分类号： C08L51/003 ,  C08L69/00 ,  Y10S525/902

摘要： A thermoplastic molding material consists of from 10 to 90 parts by weight of a polycarbonate A and from 90 to 10 parts by weight of a graft copolymer B having a mean particle size of from 200 to 700 nm (d.sub.50 value of the integral mass distribution). The graft polymer B is formed from an elastomer (rubber) (b.sub.1), which accounts for from 10 to 80% by weight, and a grafted shell (b.sub.2), which accounts for from 90 to 20% by weight, the percentages in each case being based on (B).The elastomer (b.sub.1) is composed of from 50 to 99.9% by weight of an alkyl acrylate, where alkyl is of 1 to 8 carbon atoms, and from 0.1 to 5% by weight of a copolymerizable polyfunctional crosslinking monomer.The grafted shell (b.sub.2) is produced in three stages and contains, as graft monomers,(b.sub.2 a.sub.1) from 5 to 40% by weight of a monoethylenically unsaturated aromatic hydrocarbon of not more than 12 carbon atoms, in the first stage,(b.sub.2 a.sub.2) from 15 to 50% by weight of a mixture of a monoethylenically unsaturated aromatic hydrocarbon of not more than 12 carbon atoms and a copolymerizable ethylenically unsaturated monomer, in a weight ratio of from 90:10 to 60:40, in the second stage, and(b.sub.2 a.sub.3) from 10 to 85% by weight of an alkyl (meth)acrylate in the third stage, the percentages in each case being based on (b.sub.2).

摘要翻译： 热塑性成型材料由10〜90重量份的聚碳酸酯A和90〜10重量份的平均粒径为200〜700nm的接枝共聚物B（整体质量分布的d50）组成， 。 接枝聚合物B由占总重量的10〜80重量％的弹性体（橡胶）（b1）和接枝壳（b2）的90〜20重量％构成。 情况基于（B）。 弹性体（b1）由50〜99.9重量％的丙烯酸烷基酯（其中烷基为1〜8个碳原子）和0.1〜5重量％的可共聚的多官能交联单体组成。 接枝壳（b2）分三个阶段制成，在第一阶段，（b2a2）含有5-40重量％的不大于12个碳原子的单烯属不饱和芳族烃作为接枝单体，（b2a1） 15重量％至50重量％的不超过12个碳原子的单烯属不饱和芳族烃和可共聚烯属不饱和单体的混合物，其重量比为90:10至60:40，第二阶段为 （b2a3）在第三阶段为10〜85重量％的（甲基）丙烯酸烷基酯，其各自的百分比基于（b2）。

公开(公告)号：US4440906A

公开(公告)日：1984-04-03

申请号：US337404

申请日：1982-01-06

申请人： Franz Brandstetter ,  Juergen Hambrecht ,  Adolf Echte

发明人： Franz Brandstetter ,  Juergen Hambrecht ,  Adolf Echte

IPC分类号： C08L25/00 ,  C08L25/04 ,  C08L33/00 ,  C08L33/02 ,  C08L51/00 ,  C08L51/02 ,  C08L51/04 ,  C08L51/06 ,  C08L71/00 ,  C08L71/12 ,  C08L61/04

CPC分类号： C08L25/00 ,  C08L51/003 ,  C08L71/123 ,  C08L51/04 ,  C08L71/12 ,  Y10S525/905

摘要： The use of tricyclodecenyl alcohol in place of other crosslinking agents for crosslinking the soft component of impact-resistant polystyrene based on a polystyrene-grafted poly(alkyl acrylate) improves the flow of mixtures of the said polystyrene with polyphenylene ethers.

摘要翻译： 基于聚苯乙烯接枝的聚（丙烯酸烷基酯），使用三环癸烯醇代替用于交联耐冲击聚苯乙烯的软组分的其它交联剂改善了所述聚苯乙烯与聚苯醚的混合物的流动。

公开(公告)号：US5104936A

公开(公告)日：1992-04-14

申请号：US507738

申请日：1990-04-12

申请人： Uwe Blumenstein ,  Adolf Echte ,  Peter Klaerner

发明人： Uwe Blumenstein ,  Adolf Echte ,  Peter Klaerner

IPC分类号： C08L25/10 ,  C08L7/00 ,  C08L25/04 ,  C08L51/00 ,  C08L51/04 ,  C08L55/00 ,  C08L55/02

CPC分类号： C08L25/04 ,  C08L51/04 ,  C08L51/00

摘要： Molding materials comprising a matrix of high impact polystyrene and rubber incorporated in the form of discrete particles contain not less than 50% by weight of polystyrene A and an effective amount of up to 50% by weight of a graft rubber B. The graft rubber B consists of from 40 to 95% by weight of an elastomeric core b.sub.1 and from 5 to 60% by weight of a shell b.sub.2, i.e. from 5 to 50% by weight of a first shell B.sub.21 of styrene and from 50 to 95% by weight of a second shell b.sub.22 of from 60 to 90% by weight of styrene and from 10 to 40% by weight of acrylonitrile, A and B, b.sub.1 and b.sub.2, b.sub.21 and b.sub.22 and styrene and acrylonitrile each summing to 100% by weight.

摘要翻译： 包含高分子颗粒形式的高抗冲聚苯乙烯和橡胶的基质的成型材料含有不少于50重量％的聚苯乙烯A和有效量的至多50重量％的接枝橡胶B。接枝橡胶B 由40至95重量％的弹性体芯b1和5至60重量％的壳b2，即5至50重量％的苯乙烯的第一壳B21和50至95重量％ 的第二壳体b22为60至90重量％的苯乙烯和10至40重量％的丙烯腈，A和B，b1和b2，b21和b22以及苯乙烯和丙烯腈各自归为100重量％。